Air Pollution
Air Pollution
Air pollution - Air pollution may be defined as the presence of one or more contaminants like
dust, mist, smoke and colour in the atmosphere that are injurious human beings, plants and
animals.
Natural sources of pollution are those that are caused due to natural phenomena. Ex: Volcanic
eruptions, Forest fires, Biological decay, Pollen grains, Marshes, Radioactive materials.
Man made /Artificial sources are those which are created by man. Ex: Thermal power plants,
Vehicular emissions, Fossil fuel burning, agricultural activities etc.
Secondary pollutants are those that are formed by reacting with other components or some basic
component of the atmosphere to form new pollutants.
Ex: Oxides of Nitrogen (NO2 or NO3) react with moisture in the atmosphere to give Nitric acid
Indoor air pollutants are primary air pollutants. The most important indoor air pollutant
is Radon gas.
Sources of indoor air pollutants are:
1. Radon gas is emitted from building materials like bricks, concrete, tiles, etc that
are derived from soil containing radium
2. Radon is also found in natural gas and ground water and is emitted while being
used.
3. Burning fuel in the kitchen and cigarette smoke release pollutants like CO, SO2,
HCHO (Formaldehyde) and BAP (Benzo-(A) pyrene).
(i) Combustion of natural gas, petroleum, coal and wood in industries, automobiles, aircrafts,
railways, thermal plants, agricultural burning, kitchens, etc. (soot, flyash, CO2, CO, nitrogen
oxides, sulphur oxides).
(ii) Metallurgical processing (mineral dust, fumes containing fluorides, sulphides and metallic
pollutants like lead, chromium, nickel, beryllium, arsenic, vanadium, cadmium, zinc, mercury).
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(iv) Cosmetics.
(v) Processing industries like cotton textiles, wheat flour mills, asbestos.
(vii)Rapid industrialization
(viii)Fast urbanization
ix)Rapid growth in population
x)Growth of vehicles on the roads and
xi)Activities of human beings have disturbed the natural balance of the atmosphere.
Natural air pollutants include (a) pollen, spores, (b) marsh gas, (c) volcanic gases and (a)
synthesis of harmful chemicals by electric storms and solar flares. The major cause of pollution
in the urban areas is automobiles which inefficiently burn petroleum, releases 75% of noise and
80% of air pollutants. Concentration of industries in one area is another major cause of air
pollution.
1. Particulate Matter:
It is of two types—settleable and suspended. The settleable dusts have a particle longer than 10
(am. The smaller particles are able to remain suspended for long periods in the air. The important
effects of particulate matter are.
(i) Dust and smoke particles cause irritation of the respiratory tract and produces bronchitis,
asthma and lung diseases.
(ii) Smog is a dark or opaque fog which is formed by the dust and smoke particles causing
condensation of water vapours around them as well as attracting chemicals like SO 2, H2S, NO2,
etc. Smog harms plant life through glazing and necrosis besides reduced availability of light. In
human beings and animals it produces respiratory troubles.
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(iii) Particulate matter suspended in air, scatters and partly absorbs light. In industrial and urban
areas, sunlight is reduced to 1/3 in summer and 2/3 in winter.
(iv) At a concentration above 150 g/100m 3, cotton dust in ginning process produces
pneumoconiosis or lung fibrosis called byssinosis. Lung fibrosis produced in other industries
includes asbestosis (in asbestos industry), silicosis (stone grinders), siderosis (iron mill), coal
miners’ pneumoconiosis, flour mill pneumoconiosis, etc.
2. Carbon monoxide:
It accounts for 50% of the total atmospheric pollutants. It is formed by incomplete combustion of
carbon fuels in various industries, motor vehicles, hearths, kitchens, etc. Carbon monoxide
combines with haemoglobin of blood and impairs its oxygen carrying capacity. At higher
concentration, carbon monoxide proves lethal.
3. Sulphur Oxides:
They occur mainly in the form of sulphur dioxide. It is produced in large quantity during
smelting of metallic ores and burning of petroleum and coal in industries, thermal plants, home
and motor vehicles. In the air, SO2 combines with water to form sulphurous acid (H 2SO3) which
is the cause of acid rain. It causes chlorosis and necrosis of vegetation. Sulphur dioxide, above 1
ppm, affects human beings. It causes irritation to eyes and injury to respiratory tract. It results in
discolouration and deterioration of buildings, sculptures, painted surfaces, fabrics, paper, leather,
etc.
4. Nitrogen Oxides:
They are produced naturally through biological and non-biological activities from nitrates,
nitrites, electric storms, high energy radiations and solar flares. Human activity forms nitrogen
oxides in combustion process of industries, automobiles, incinerators and nitrogen fertilizers.
Nitrogen oxides act on unsaturated hydrocarbons to form peroxy-acyl nitrates or PAN. It gives
rise to photochemical smog. They cause eye irritation, respiratory troubles, blood congestion and
dilation of arteries.
5. Carbon dioxide:
Due to excessive combustion activity, the content of C0 2 has been steadily rising. As carbon
dioxide accumulates in the atmosphere it absorbs more and more of the reflected infrared
radiation. This could cause an increase in temperature referred to as the green house effect.
Melting polar ice caps and glaciers could cause sea levels to rise, flooding most of the major
population centres and fertile lands.
6. Phosgene and Methyl Isocyanate:
Phosgene (COCl2) is a poisonous and suffocating volatile liquid which is employed in dye
industry and synthesis of organic compounds. Release of phosgene and MIC in industrial
accident of Bhopal (Dec. 2, 1984) killed over 2500 and maimed several thousand persons.
7. Aerosols:
They are widely used as disinfectants. Other sources are jet plane emissions which contain
chlorofluorocarbons. Chlorofluorocarbons are also used in refrigeration and formation of certain
types of solid plastic foams. Burning of plastics produces polychlorinated biphenyls (PCBs). The
latter are persistent and pass into the food chain. Chlorofluorocarbons and carbon tetrachloride
react with ozone layers of stratosphere and hence deplete the same.
8. Photochemical oxidants:
Hydrocarbons have carcinogen properties. Some of these are also harmful to plants because they
cause senescence and abscission. In the presence of sunlight, hydrocarbons react with nitrogen
oxides to produce ozone, peroxy-acyl nitrates, aldehydes and other compounds. Peroxy-acyl
nitrates are a major constituent of air pollution. They cause eye irritation and respiratory
diseases.
9. Automobile Exhausts:
They are one of the major sources of air pollution. The important pollutants are Carbon
monoxide, Benzpyrene, Lead, Nitrogen oxides, Sulphur compounds and Ammonia.
10. Pollen and Microbes:
Excess of microbes in the atmosphere directly damage the vegetation, food articles and causes
diseases in plants, animals and human beings. Excess of pollen causes allergic reactions in
several human beings. The common reactions are also collectively called hay-fever. The
important allergic pollen belong to Amaranthus spinosus, Chenopodium album, Cynodon
dactylon, Ricinus communis, Sorghum vulgare, Prosopis chilensis etc.
Nitrogen Dioxide: It is a reddish-brown irritating gas that causes photochemical smog. In the
atmosphere, it gets converted into nitric acid (HNO3). It is caused by burning fossil fuels in
industries and power plants.
Health effects include lung irritation and damage. Environmental effects involve acid deposition
leading to damage of trees, lakes, soil and ancient monuments. NO2 can damage fabrics.
Sulphur Dioxide: It is a colourless and irritating gas that is formed by combustion of sulphur
containing fossil fuels such as coal and oil. In the atmosphere it is converted into Sulphuric acid
which is a major component of acid deposition.
Health effects involve breathing problems for healthy people.
Environmental effects involve reduced visibility and acid deposition on trees, lakes, soils and
monuments leading to their deterioration and adverse effect on aquatic life.
Suspended Particulate Matter (SPM): Includes a variety of particles and droplets (aerosols)
that can be suspended in atmosphere for short to long periods.
Human sources for SPM include burning coal in power and industrial units, burning diesel and
other fuels in vehicles, agriculture, unpaved roads, construction, etc.
Health effects include nose and throat irritation, ling damage, bronchitis, asthama, reproductive
problems and cancer.
Environmental Effects include reduced visibility and acid deposition. Acid deposition may lead
to damaged trees, soils and aquatic life in lakes.
Ozone is a highly reactive gas with an unpleasant odour occurring in the stratosphere where it
protects mankind fro the harmful ultra-violet rays from the Sun. However on earth, it is a
pollutant.
It occurs on earth due to reaction between Volatile Organic Compounds (VOCs) and Nitrogen
Oxides. It moderates the climate
Photochemical smog is a browinsh smoke that frequently forms on clear, sunny days over large
cities with significant amounts of automobile traffic.It is mainly due to chemical reactions among
nitrogen oxides and hydrocarbons in the presence of sunlight.
Health effects include breathing problems, cough, eye, nose and throat irritation, heart diseases,
reduced resistance to colds and pneumonia.
Environmental effects involve damage to plants and trees. Additionally, Smog reduces visibility.
Lead is a solid and highly toxic metal. Its compounds are emitted into the atmosphere as
particulate matter.
Human Sources: Paint, Smelters (metal refineries), lead manufacture, storage batteries, leaded
petrol, etc
Health effects: Lead accumulates in the body and brain leading to nervous system damage and
mental retardation (especially in children), digestive and other health problems. Lead containing
chemicals are known to cause cancer in test animals.
Environmental Effects: It can harm wildlife.
Chromium: It is a solid toxic metal emitted into the atmosphere as particulate matter.
Human sources: Paint, Smelters, Chromium manufacture, Chromium plating.
Health Effects: Perforation of nasal septum, chrome holes, etc.
CONTROL MEASURES
The atmosphere has several built-in self cleaning processes such as dispersion, gravitational
settling, flocculation, absorption, rain-washout, etc to cleanse the atmosphere. However, control
of contaminants at their source level is a desirable and effective method through preventive or
control technologies.
Source control: Some measures that can be adopted in this direction are:
1. Using unleaded petrol
2. Using fuels with low sulphur and ash content
3. Encouraging people to use public transport, walk or use a cycle as opposed to
private vehicles
4. Ensure that houses, schools, restaurants and playgrounds are not located on busy
streets
5. Plant trees along busy streets as they remove particulates, carbon dioxide and
absorb noise
6. Industries and waste disposal sites should be situated outsdide the city preferably
on the downwind of the city.
7. Catalytic converters should be used to help control emissions of carbon monoxide
and hydrocarbons
Control measures in industrial centers
1. Emission rates should be restricted to permissible levels by each and every
industry
2. Incorporation of air pollution control equipment in design of plant layout must be
made mandatory
3. Continuous monitoring of the atmosphere for pollutants should be carried out to
know the emission levels.
EQUIPMENT USED TO CONTROL AIR POLLUTION
The following equipment is used to control air pollution:
1. Control of SPM by gravitation
Control of SPM by gravitation
Equipment used: Gravitational Settling Chamber A typical gravitational chamber is shown
below.
The dust laden gas enters at the inlet and due to the sudden increase in cross-section the
particulate matter settles at the bottom and can be removed from the dust hoppers as shown
The clean gas free from particulate matter exits from the outlet
IMPORTANT FACTS:
Simple to construct and maintain
Efficient to remove particles of diameter greater than 50 mm from gas streams
They are used as pre-cleaners before passing gases through high efficiency collection devices
They rely on gravitational settling and are the simplest and oldest mechanical collectors for
removal of particulates from gas streams
Flow within the chamber must be uniform without macroscopic mixing
Dust removal system must be sealed to prevent production of turbulence due to air from leaking
into chamber
Efficiency of the equipment increases with increased residence time of the waste gas. Hence, the
equipment is operated at lowest possible gas velocity
The size of the unit depends on:
gas velocity which should preferably be less than 0.3 m/s
ADVANTAGES
Low capital and energy cost
Low maintenance and operating costs
Low pressure drop
Reliable
Equipment is not subjected to abrasion due to low gas velocity
Equipment provides incidental cooling of gas stream
Temperature and pressure limitations depend on material of construction
Pollutants are collected in dry state
DISADVANTAGES
Low particulate matter collection efficiency
Unable to handle sticky materials
Large size
Trays in multiple tray settling chamber may warp under high temperatures.
Cyclones use the principle of inertia to remove particulate matter from a gas stream. Several
cyclones operating in parallel is known as multicyclone. In a cyclone separator, dirty gas is fed
into a chamber where a spiral vortex exists. The large particles hit the inside walls of the
container and drop down into the collection hooper. The clean flue gas escapes from the top of
the chamber. Cyclones can be used efficiently to remove particles of size 10 microns or more.
High efficiency cyclones can remove particles of dimeter as small as 2.5 microns. They are the
least expensive of all particulate collection devices. They are used as rough separators before the
gas is passed through fine filtration systems. Their efficiency is between 50-99%. Cyclone
separators work best on flue gases that contain large amount of big particulate matter.
ADVANTAGES:
Cyclones are less expensive to install or maintain as they do not contain any moving parts
It is easy to dispose particulate matter as it is collected in the dry state
Space requirement is very less
DISADVANTAGES:
They are not efficient in collecting particulate matter smaller than 10 microns
They cannnot handle sticky material
A typical filter is a tubular bag which is closed at the upper end and has a hopper attached at the
lower end to collect the particles when they are dislodged from the fabric. Many such bags are
hung in a baghouse. For efficient filtration and a longer life the filter bags must be cleaned
occasionally by a mechanical shaker to prevent too many particulate layers from building up on
the inside surfaces of the bag. A typical bag house filter is shown in the figure below.
ADVANTAGES:
Bag filter is a high quality performance instrument to effectively control particulate emissions
and its efficiency is as high as 99%
Collection efficiency is not affected by sulphur content in fuel
It is not sensitive to particle size distribution
It does not require high voltage
It can be used to collect flammable dust
Special fiber or filter aids can be used to sub-micron level smoke and fumes
DISADVANTAGES:
Fabric life is reduced due to presence of highly acidic or alkaline atmospheres, especially at high
temperatures
Maximum operating temperature is 500 F
Collection of hygroscopic materials or condensation of moisture can lead to fabric plugging, loss
of cleaning efficiency and large pressure losses.
Certain dusts may require special fabric treatments to aid in reducing leakage or to help in cake
removal
Fabric bags are prone to burning or melting at extreme temperatures.
Wet scrubbing involves removal of harmful components from exhaust by spraying a liquid
substance through the gas.
Both methods work similarly and perform the same process of removing pollutants. The
difference lies in the materials they use to remove the pollutant from the gas stream. By
removing acidic gases from the exhaust before it is released into the atmosphere, scrubbers help
in the prevent the formation of acid rain.
Scrubbing is sometimes referred to as flue gas desulfurization.
Scrubbing is the most effective technique for the removal of oxides of sulphur and is widely
used. Scrubbers remove sulphur oxides from flue gases by passing the gases through a spray of
water in a wet scrubber that contains many chemicals, mainly calcium carbonate.
If a dry scrubber is used, the flue gas comes in contact with pulverised limestone. The chemical
reaction between suphur dioxide and calcium carbonate yields calcium sulphite. The calcium
sulphite either falls out of the gas stream or is removed with other particulates.
Scrubbers are highly efficient and remove almost 98% of sulphur from flue gases. However, they
are expensive to maintain and install. They are also energy intensive as the flue gas must be
reheated after coming into contact with water vapour in the wet scrubber to make the gas
buoyant to exit the smoke stacks.
Larger collection surface areas and lower gas flow rates increase efficiency of
electrostatic precipitators due to increased time for the electrical activity to collect the dust
particles
The dust particle migration velocity to the collecting electrodes can be increased by:
Decreasing gas velocity
Increasing gas temperature and
Increasing the voltage field
2. Use of tall chimneys shall reduce the air pollution in the surroundings and compulsory use of
filters and electrostatic precipitators in the chimneys.
3. Removal of poisonous gases by passing the fumes through water tower scrubber or spray
collector.
7. Attempt should be made to develop pollution free fuels for automobiles, e.g., alcohol,
hydrogen, battery power. Automobiles should be fitted with exhaust emission controls.
8. Industrial plants and refineries should be fitted with equipment for removal and recycling of
wastes.
9. Growing plants capable of fixing carbon monoxide, e.g. Phaseolus vulgaris, Coleus blumei,
Daucus carota, Ficus variegata (Bidwell and Bebee, 1974).
10. Growing plants capable of metabolising nitrogen oxides and other gaseous pollutants, e.g.,
Vitis, Pimis, Jttniperus, Quercus, Pyrus, Robinia pseudo-acacia, Viburnum, Crataegus, Ribes,
Rhamnus.
12.Different techniques are used for controlling air pollution caused by 'gaseous pollutants' and
that caused by 'particulate pollutants'.
Methods of controlling gaseous pollutants-The air pollution caused by gaseous
pollutants like hydrocarbons, sulphur dioxide, ammonia, carbon monoxide, etc can be
controlled by using three different methods-Combustion, Absorption and Adsorption.
1. Combustion-This technique is applied when the pollutants are organic gases or vapours.
The organic air pollutants are subjected to 'flame combustion or catalytic combustion' when
they are converted to less harmful product carbon dioxide and a harmless product water.
2. Absorption-In this method, the polluted air containing gaseous pollutants is passed
through a scrubber containing a suitable liquid absorbent. The liquid absorbs the harmful
gaseous pollutants present in air.
3. Adsorption-In this method, the polluted air is passed through porous solid adsorbents
kept in suitable containers. The gaseous pollutants are adsorbed at the surface of the porous
solid and clean air passes through.
Methods of controlling particulate emissions-The air pollution caused by particulate
matter like dust, soot, ash, etc can be controlled by using fabric filters, wet scrubbers,
electrostatic precipitators and certain mechanical devices.
1. Mechanical Devices-It works on the basis of following:
Gravity-In this process, the particulate settle down by the action of gravitational force
and get removed.
Sudden change in the direction of air flow-It brings about separation of particles due to
greater momentum.
2. Fabric Filters-The particulate matter is passed through a porous medium made of woven or
filled fabrics.
The particulate present in the polluted air are filtered and gets collected in the fabric
filters, while the gases are discharged.
The process of controlling air pollution by using fabric filters is called 'bag filtration'.
3. Wet Scrubbers-They are used to trap SO2, NH3 and metal fumes by passing the fumes
through water.
4. Electrostatic Precipitators-When the polluted air containing particulate pollutants is passed
through an electrostatic precipitator, it induces electric charge on the particles and then the
aerosol particles get precipitated on the electrodes.
Some other methods of controlling Air Pollution:
1. Tall chimneys should be installed in factories.
2. Better designed equipment and smokeless fuels should be used in homes and industries.
3. Renewable and non-polluting sources of energy like solar energy, wind energy, etc
should be used.
4. Automobiles should be properly maintained and adhere to emission control standards.
5. More trees should be planted along roadsides and houses.