Solution

WORK SHEET-11

JEE main - Chemistry

1.
(c) 21
Explanation:
Total number of atoms in CuSO4⋅ 5H2O = 1 + 1 + 4 + 5 × 3 = 21

2.
(d) 2.05 M
Explanation:
Mass of solute = 120 g
Mass of water = 1000 g
Mass of solution = 1120 g
∴ Volume of solution ( m

d
) =
1120

1.15
mL

milli mole = M × Vin mL

120 1120
× 1000 = M ×
60 1.15

∴ M = 2.05

3. (a) 65.40
Explanation:
Atomic mass of an element
= 10.86 × 10-24 g × 6.022 × 1023 mol-1
= 65.4 g mol-1
4.
(d) 5.6 L
Explanation:
NH3​+H2​O⟶NH4​OH
Given,
x 1000
[NH4​OH] = 2.5 M = 35
×
100

∴x=8.75
Now moles of NH4​OH = 8.75

35
= 0.25

1 mole of NH3​produces one mole of NH4​OH

∴0.25 mole of NH4​OH will be produced from 0.25 moles of NH3​
∴ Volume = 0.25 × 22.4 = 5.6L of NH3​

5.
(b) 0.0177
Explanation:
n
Mole fraction of solute = n+N

=
1

1000
= 0.0177
1+
18

6.
(d) pentagonal planar and trigonal bipyramidal
Explanation:

1 / 13
Meridian Senior Secondary School
 i. XeF −

St. No. = Bond pair + Lone Pair

= (5 + 2) = 7
So, hybridisation is = sp3d3
and structure is pentagonal planar.
ii. XeO3F2
St. No. = 5
So, hybridisation is = sp3d
and structure is trigonal bipyramidal.

7.
(c) dsp2
Explanation:
dsp
2
→ 4 × 90
∘
bond angles

8.
(c) N2H2
Explanation:
Here, N — H bond has sp2 hyb. N.
Presence of double bond and less number of hydrogen will increase the % s-character in N—H bond.

9. (a) 2 only
Explanation:
2 only
10.
(c) N (SiH ) 3 3
––
Explanation:
Due to the effect of back bonding L.P. of nitrogen is present in pure p-orbital in N(SiH3)3.

11.
(d) Axial bond length is shorter than equatorial bond length.
Explanation:
Equatorial B.L. > Axial because of repulsions.

12.
(b) Cl-
Explanation:
Electronic configuration of
Cl- = 1s2 2s2 2p6 3s2 3px2 3py2 3pz2
Here, all electrons are paired, so it is diamagnetic.
Electronic configuration of Be+ = 1s2 2s1
Here, one electron is unpaired, so it is paramagnetic Electronic configuration of
Ne2+ = 1s2 2s2 2px2 2py1 2pz1
Here, there are two unpaired electrons thus, it is paramagnetic.
Electronic configuration of
As+ = 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4px1 4py1
Here, there are two unpaired electrons thus, it is paramagnetic.

2 / 13
Meridian Senior Secondary School
13.
(c) CH3OH > CH4 > H2
Explanation:
C H3 OH > C H4 > H2
(H−Bond) (V .W .F.)

14. (a) PF5

Explanation:
In PF5 there is no bond angle which is less than 90o.

15. 4
Explanation:
The molecular orbital configuration of B2 is:
2 2 1 1
2 ∗ 2 ∗
(σ1s) (σ 1s) (σ2s) (σ 2s) (π2px ) (π2py )

The molecular orbital configuration of C2+ is:

2 ∗ 2 2 ∗ 2 2 2 1
(σ1s) (σ 1s) (σ2s) (σ 2s) (π2px ) (π2py ) (σ2pz )

The molecular orbital configuration O2+ is:

2 ∗ 2 2 ∗ 2 2 2 2 ∗ 1
(σ1s) (σ 1s) (σ2s) (σ 2s) (σ2pz ) (π2px ) (π2py ) (π 2px )

The molecular orbital configuration of He2+ is:

2 ∗ 1
(σ1s) (σ 1s)

Hence, B2, C2-, O2+ and He2+ are paramagnetic species.

16. (a) Option (iv)

Explanation:
all of these
17. (a) T1 = T2
Explanation:
Heat produced by 200 Meq of K OH + HCl = 13.7×200

1000
k cal
This is used to raise the temperature of 400 mL solution say by T1
Thus, = 13.7×200

1000
= 400 × S × T1
Now, heat produced by 100 Meq of KOH + HCl = 13.7×100

1000

Thus, 13.7×100

1000
= 200 × S × T2
It is evident that T1 = T2.

18.
(d) 9.92 × 108 Pa
Explanation:
C(graphite) → C(diamond) ΔGo = - PΔV
Mass of 1 mole
Volume of graphite =
Density
−1

= 5.33 cm3 mol-1

12 g mol
= −3
2.25 g cm

Mass of 1 mole
Volume of diamond =
Density
−1

= 3.63 cm3 mol-1

12 g mol
= −3
3.31 g cm

3 / 13
Meridian Senior Secondary School
 Δ V = Vgraphite - Vdiamond

= 1.70 cm3 mol-1

= 1.70 × 10-3 L mo-1
So, ΔGo = PΔV
1895 J mol-1 = P(1.70 × 10-3 L mol-1)
1114.70 × 103 J = P
1114.70 × 103 J/L = P
1114.70 × 103 × 101.33 atm = P
P = 112952 atm × 1.013 × 105 Pa
= 114420.9 × 105 P
= 114420.9 × 105 P
= 11.44 × 109 Pa
Approximately ≈ 9.92 × 108 Pa

19. (a) 15.67

Explanation:
15.67
20.
(b) P3 > P1, w = -ve
Explanation:
P3 > P1, w = -ve

21.
(b) (iv)
Explanation:
(iv)

22.
(c) 41/3 W
Explanation:
Work done ∝ Surface Area and Surface Area ∝ r2
2
1/3 4 3
∝ (V ) (∵ V = πr )
3

∝ V2/3
2/3

= (2)2/3
W2 V2
= ( )
W1 V1

= 41/3
∴ W2 = 41/3 × W1

23.
(c) 0
Explanation:
0

24.
∘ ∘
ΔH − T ΔS
(d) In K = RT

Explanation:

4 / 13
Meridian Senior Secondary School
 ∵ = -RT In K
ΔG
∘

Also ΔG = ΔH − T ΔS
∘ ∘ ∘

∴ -RT In K = ΔH
∘ ∘
− T ΔS
∘ ∘
T ΔS −ΔH
or In K = RT

25. 2
Explanation:
Cm,p − Cm,v = R ⇒ 20.785 − Cm,v = 8.314

−1 −1
⇒ Cm,v = 12.471JK mol

ΔU = nCm,v ΔT
5000
⇒ n = ⇒ n = 2
12.471×(500−300)

26. (a) 107.0 g

Explanation:
pH + pOH = 14
pOH = 14 - 8.26
+
[NH ]

pOH = pKb + log [ NH 3 ]

4

+
[NH ]

⇒ 5.74 = 4.74 + log 0.2

4
⇒ [ NH
+

4
] = 2M
Molar mass of NH4Cl = 53.5 g mol-1
Amount of NH4Cl = 2 × 53.5 = 107 g

27.
(c) [Sn4+] [S2-]2
Explanation:
SnS2 = Sn4+ + 2S2-

28.
(b) Ka3 = Ka1 - Ka2
Explanation:
+ −

H2S ⇌ H+ + HS-; Ka1 =

[H ][HS ]

[ H2 S]

+ 2−
[H ][ S ]

HS- ⇌ H+ + S2-; Ka2 = −

[HS]

+ 2 2−
[H ] [S ]

H2S ⇌ 2H+ + S2-; Ka3 =

[ H2 S]

∴ Ka3 = Ka1 × Ka2

29.
(d) 1.1× 10-9 M
Explanation:
Its given that the final volume is 500 mL and this final volume was arrived when 50 mL of 1 M a2SO4 was added to unknown
Ba2+ solution.
So, we can interpret the volume of unknown Ba2+ solution as 450 mL i.e
450mL + 50mL → 500mL
2+ N a2 S O4 BaSO4
Ba

Solution Solution Solution

From this we can calculate the concentration of S04“ ion in the

solution via
M1V1 = M2V2
1 × 50 = M2 × 500

(as 1M Na2SO4 is taken into consideration)

1
M2 = = 0.1M
10

5 / 13
Meridian Senior Secondary School
 Now for just precipitation,
Ionic product = Solubility product (Ksp)
i.e. [Ba 2+
] [ SO
2−

4
] = Ksp of BaSO 4

Given Ksp of BaSO4 = 1 × 10 −10

So, [Ba 2+
] [0.1] = 1 × 10
−10

or [Ba 2+
] = 1 × 10
−9
M

Remember This is the concentration of Ba2+ ions in final solution. Hence, for calculating the Ba2+] in original solution.
we have to use
M1V1 = M2V2
as M × 450 = 10
1
−9
× 500

So, M = 1.1 × 10
1
−9
M

30. (a) N + 3H ⇌ 2NH

2 2 3

Explanation:
Mole decrease in forward reaction.
31.
(b) i
Explanation:

32. (a) Codeine, 9.95

Explanation:
Based on the given structure, the drug used is codeine.
Codeine is a weak base.
pKa = 8.2
∴ pKb = 5.8

∴ Kb = 1.58 × 10-6
[Codeine] = 0.005 M = C
2

Kb = Cα

1−α

1.58 x 10-6 =
2
0.005α
∴
1

∴ α = 0.0178
∴ [OH-] = Cα = 8.9 × 10-5
pOH = -log10[OH-] = 4.05
∴ pH = 9.95
33.
(c) H2SO4
Explanation:
H2SO4

6 / 13
Meridian Senior Secondary School
34. (a) Both A and R are true and R is the correct explanation of A.
Explanation:
If a Bronsted acid is strong, then its conjugate base is weak and vice-versa.
35. 5
Explanation:
Considering complete dissociation of Ca(OH)2
2+ −
Ca(OH)2 → Ca + 2OH
2 mol
1 mol

pH = 12, ∴ pOH = 14 - 2 = 12 (Considering T = 298K)

∴ [OH-] = 10-12 (M)
100 ml aqueous solution of pH 12 should have
[OH-] = 10-2 (M)
= 10-2 mol in 1000 mL
−2

∴ In 100 mL aqueous solution has 10 ×100

1000

= 10-3 mol of OH-

2 mol of OH- is produced by 1 mol Ca(OH)2

10-3 mol OH- is produced by 1

2
−3
× 10

= 0.5 × 10-3 mol = 0.5 m mol

= 5 × 10-1 m mol
36.
(b) only i
Explanation:
KIO4 + H2O2 → KIO3 + H2O + O2

I2+ + 2e → I5+
−1
(O )2 → (O )2 + 2e
Reductant

NH2OH + 3H2O2 → HNO3 + 4H2O

N- → N5+ + 6e
−1 −2
(O )2 + 2e → 2O
oxidant

37.
(c) only ii
Explanation:
The s-and p- electrons of the outermost shell in iodine gets unpaired during their excitation to 5d-subshell.

38.
(c) It is intermolecular redox reaction
Explanation:
It is intermolecular redox reaction

39.
(d) 1 M
Explanation:
+2 −2
CuSO4 → Cu + SO
4
1 m 1 m
1 m

−2
after reaction SO 4
becomes spectator ion so, their concentration will not change.

40. 23
Explanation:

7 / 13
Meridian Senior Secondary School
 Cr2 O
2−

2
+ 14H+ + 6Fe2+ → 6Fe3+ + 2Cr3+ + 7H2O
x = 14, y = 2, z = 7
Hence(x + y+ z) = 14 + 2 + 7 = 23
41.
(b) K+, Cl-, Ca2+, Sc3+
Explanation:
K+ (18), Cl- (18), Ca2+ (18), Sc3+ (18)

42. (a) Fe, Co, Ni

Explanation:
Fe, Co, Ni
43. (a) 5s → 4d → 5p
Explanation:
According to n + l rule electrons will be filled in the following order of orbitals,
5s → 4d → 5p
44. (a) p-block
Explanation:
Both metallic and non-metallic elements are present in p-block.
45.
(b) Both A and R are true but R is not the correct explanation of A.
Explanation:
Noble gases have completely filled electron shells and a very stable electronic configurations.

46. (a) NH2NH2·HCI

Explanation:
Lasseigne's test is given by only those compounds which contain both carbon and nitrogen. When compounds containing
carbon and nitrogen are heated with sodium then it forms NaCN which is easily detected by FeCI3·

47.
(c) C6H12O
Explanation:
% of carbon = 72%
% of hydrogen = 12%
% of oxygen = 100 - (72 + 12) = 16
Element Atomic ratio Simplest ratio

C = 72%
72

12
=6 6

1
=6

H = 12%
12

1
= 12 12

1
=6

O = 16%
16

16
=1 1

1
=1

∴ Empirical formula of the compound is C6H12O.

48.
(d) All of these
Explanation:
Lassaigne's test is used in detection of nitrogen, sulphur and chlorine.

49. (a) 1.568 × 104

Explanation:

8 / 13
Meridian Senior Secondary School
 0.5gSe ⟶ 100g peroxidase anhydrous enzyme
78.4gSe →
100×78.4
= 1.568 × 10
0.5
Minimum molecular weight ⟶ molecule at least contain one selenium.
4

50.
(c) Hot water
Explanation:
Hot water

51.
(c) C3H6
Explanation:
Cyclic alkanes have general formula as CnH2n.

52. (a)

Explanation:

53.
(c) chiral resolution
Explanation:
chiral resolution

54.
(d) 1-isopropyl-2,4-dimethylbenzene
Explanation:

1-isopropyl-2,4-diethylbenzene

55. 6.0
Explanation:
Dimethylcyclopentane has following isomers:

9 / 13
Meridian Senior Secondary School
56.
(d)

Explanation:

57.
(c) Option (iv)
Explanation:
-CH3 is activating group.

58. (a) C4H8

Explanation:
C4H8

59.
(b) styrene dibromide, benzoic acid
Explanation:

60.
(d) 3, 4, 4-trimethyloctane
Explanation:
3, 4, 4-trimethyloctane

61.
(b) CHO-CHO
Explanation:

10 / 13
Meridian Senior Secondary School
 Ethylene reacts with ozone to produce Acetylene ozonide which is further hydrolyzed in the presence of zinc to form glyoxal.

62. (a)

Explanation:

⇒ sp-hybridisation cannot exist in six membered cyclic ring.

63. (a) (1-methylpropyl)cyclohexane
Explanation:
(1-methylpropyl)cyclohexane
64.
(b) Both A and R are true but R is not the correct explanation of A.
Explanation:
Neopentane is more symmetric than n-pentane and it is expected to show more stable crystal lattice than that of n-pentane and
thus have high melting point.

65. 4.0
Explanation:

Total Possible Isomeric product = 1 + 3 = 4

66.
(c) 10
Explanation:
10

67.
(b) B2O3
Explanation:
B2O3

68.
(b) BBr3 > BCl3 > BF3
Explanation:

11 / 13
Meridian Senior Secondary School
 The relative Lewis acid character of boron trihalides is found to follow the following order,
BBr3 > BCl3 > BF3
but the expected order on the basis of electronegativity of the halogens (electronegativity of halogens decreases from F to I)
should be,
BF3 > BCl3 > BBr3
This anomaly is explained on the basis of the relative tendency of the halogen atom to back donate its unutilized electrons to
the vacant p-orbital of the boron atom. In BF3, boron has a vacant 2p-orbital and each fluorine has fully filled unutilized 2p-
orbitals. Fluorine transfers two electrons to vacant 2 p-orbital of boron, thus forming pπ -pπ bond.

This type of bond has some double-bond character and is known as dative or back bonding. All three bond lengths are the
same. It is possible when a double bond is delocalized. The delocalization may be represented as:

The tendency to back donate decreases from F to I as the energy level difference between B and halogen atom increases from F
to I. So, the order is
BF3 < BCl3 < BBr3

69. (a) 1s2 2s2 2p1

Explanation:
Boron - 1s2 2s2 2p1, B(OH)3 is acidic in nature. Acidity decreases down the group.

70. (a) Ga(OH)3

Explanation:
Al(OH)3 and Ga(OH)3 are amphoteric.

71.
(d) 5
Explanation:
The electronic configuration of tin (Z = 50) is:
[Kr] 4d10 5s2 5p6
The outermost electron is present in 5p orbital.
∴ Value of n = 5

72. (a) B > Al < Ga > In < Tl

Explanation:
On moving down the group from B to Tl, a regular decreasing trend in the I.E. is not observed.
Element B Al Ga In Tl

I.E. (kJ/mol) 801 577 579 558 589

In Ga, there are ten d-electrons in the penultimate shell which screen the nuclear charge less effectively and thus, outer electron
is held firmly. As a result, the ionisation energy of both Al and Ga is nearly the same. The increase in ionisation energy from In
to Tl is due to poor screening effect of 14f electrons present in the inner shell.
Thus, the correct order is, B > Al < Ga > In < Tl
73.
(b) one of the empty orbitals of boron takes part in hybridisation.
Explanation:
one of the empty orbitals of boron takes part in hybridisation.

12 / 13
Meridian Senior Secondary School
74.
(c) Aluminium reacts with excess NaOH to give Al(OH)3.
Explanation:
Al reacts with NaOH to give sodium meta-aluminate.

75.
(c) A is true but R is false.
Explanation:
A is true but R is false.

13 / 13
Meridian Senior Secondary School