lowed by acidification give
"Dt when distilled with Zine
The salt of Eon heating _
7A" on teeatinent with CHCIVROH fol
Both B and C give the same product
32, | Anaroinatic compound
‘vo compounds "8! and 'C ne po
dust. Oxidation of D gives E having molecular formula C103."
orgie ves F which may be obtained by datilling A with zine dust, Tdemtity AD.
Fy Fand write the chemical equations for the reactions involved. ern at
OR (S
An organic compound A" with molecular formula (CH#i00) is optically active. OF mild
oxidation, it gives a compound "3! but upon vigorous oxidation, it gives another
compound The compound ‘C along with ‘Dare also formed from 'B! by reacting it with
Todine in the presence of alkali, Deduce the structures of 'A''B,'C and "D'and write the
‘chemical equations for the reactions involved.
33 | Answer the following questions: 5
(a) The wave number of light absorbed by different complexes of Cr jon are given below:
Comptex | _Wavenumber of tight absorbed (em-}) | Energy af light absorbed (k}/mol)
[rast 13640 163
[CrBe}** 17830 213
(crea 21680 259
[cred 26280 314
Out of the ligand’s “A”, “B”, °C” and “D”, which ligand causes maximum orystal field
splitting? Why?
(b) If'the Ligands attached to Cr°* ion in the complexes given in the table above are water,
cyanide ion, chloride ion, and ammonia (not in this order in the table)
© | Identify the ligands A,B,C and D
(© Write the formula and TUPAC name of the following [CrAc)*complex.
(@) A metal ion M" of the first transition series having d’configuration combines with three
didentate ligands.
Assuming Ay
KC] > CH3COOH> sucrose.
(@) According to Raoult’s law, the vapour pressure exerted by a volatile component ofa
, Solutions directly proportional to its mole fraction in the solution. _
. | The table given below shows the results of three experiments on the rat i
beeen compounds P and Q ata constant temperature eer
Experiment] The initial concentration | The initial concentration | Initial rate
of P (mol dm) of Q (mol dm) (mol dm3s:1)
1 01 02 110x10+
2 03 02 991x104
ay 03 o1 496x104
Based on the data, what will be the rate equation for the reacti
@PHQ — &) KPI? (©) WPI(Q] ay ow ne
Samprit took 4 acids, lelp her to i :
oii ce Ip arrange the acids from left to right, in the i
2,4, 6 Trinitrophenol, acetic acid, phe senzoie ‘
C24. 6
Which of the above is most likely to give a ‘racemic mixture? Justify your answer.
OR
(© Compound A reacts with PC to give B which on treatment with KCN followed by
hydrolysis gave propanoic acid, Identify A and B cespeetively.
(b) Convert toluene to benzyl alcohol. ay hp tCOny
(©) Complete the following equation: Fic alien
aye
oN CHACH a,» PAS > CHyal
Ooh me ping ey
KS ae see
St Ae
36, |G) Write the products produced on hydrolysis of Lactose? 3
(6) Give the balanced chemical equation which confirms the presence of aldehydic group in
D-glucose,
(c) Write one structural point of difference between globular ond fibrous protein.
27. | (@) 3
Write the products of the following reactions:
*
(0 + HN —OH See ee
(ii) 26; 1gCHO + conc, NxOH —>
(b) Account for the following: 5
CHsCHO is more reactive than CH;COCHs towards reaction
“bie
. | (@) What type of bonding helps in st
(b) What structural change will’
(c) Name the base that is fou Gi) 1.0
(a) CoHsCONH:
O)CoHsN Cr
(©) CSCHCL
11, | identify the products
@) (1) GCN @) Cit. NO
(b) (1) GHSNC 2) GH; NOs
(©)(1) GH:CN (2) CH; ONO
(d) (1) CoHSNC (2) CoH5 ONO.
(I) and (@) in the Following reactions:
GHCl+ KCN — 5 (1) and CoHsCl + KNO;—— (2)
(d) CoH;CH20H
Aa
(@) Ink
>
(©) Ink]
>
to Archcnnus equation ‘ate constant kis equal to Ae **"*!. Which of the following
‘options represonts the graph of ln kvs 1/T?
vane
Ange =
(i
(b) Ink] a
1
@ ink] if
a
inks
B.
concentration.
attractions.
(a) Both A and R are true, and
(0) A is true but R is false.
(¢) A is false but R is true.
Assertion (A) : Molar conductivity of a strong electrolyte increases with decrease in
Reason(R) : The mobility of ions increases on dilution due to decrease in interionic:
the correct explanation of A.
(b) Both A and R are true, but R is not the correct explanation of A.
14.
(c) Ais true but R is false.
(d) A is false but R is true.
Assertion (A) : [Mn(CN).] * has a magnetic momeat of two unpaired electrons while
[MnCle] has a paramagnetic moment of four unpaired electrons.
Reason (R) : [Ma(CN)s]* is inner orbital complexes involving d?sp* hybridisation ¢ on thes
other hand, [MnCl] * is outer orbital complexes involving sp'd hybridisation,
(a) Both A and R are true, and R is the correct explanation of A.
(b) Both A and R are true, but R is not the correct explanation of A,
woOAY
the presence of Lewis acid,
(©) Ais truc but R is false,
(d)A is false but R is true.
‘Assertion (A) : Aniline forms si
con.HNOs and con. HsSOq
Reason (R) : The ortho and
Assertion (A) : Like bromination of benzene, bromination of phenol is also carried out in
Reason (R): Lewis acid polarises the bromine molecule,
(a) Both A and R are true, and R is the correct explanation of A
(b) Both A and R are true, but R is not the correct explanation of, a) SSS = eae
aa
SECTION D
\s. Bach ques!
ice and
tion has an internal choi
|
morte [UTE
{The d orbitals of the transition elements protrude to the periphery ofan atom
the surroundings as well a5
‘other orbitals (i... s dnd p), hence, they are more influenced by
tfeet the atoms or molecules surrounding them, In some respects, ions of @ BYE a
configuration (n= 1 —9) have similar magnetic and electronic properties. With partly
filled d orbitals these elements exhibit certain characteristic properties such as display of a
variety of oxidation states, formation of coloured ios and entering into complex formation
vith variety of ligands, The transition metals and their compounds also exhibit catalytic
property and magnetic behaviour.
‘Answer the following questions:
(a) The magnetie moments of few transition metal ions are given below:
The following questions are case-based question:
carries 4 marks cach
[ Metal ion’ Magnetic moment
Zn 0.00 %
Ces 38 nd 3d”
Nv Ue naz %
1 wg ae 3a"
Which of the given metal ions :
(B forms colourless aqueous solution?
(ii) exhibits the most stable +3 oxidation state. pas
Give two similarities in the properties of Sc and Zn.
(A purple colour compound A, which is a strong oxidising agent and used for bleaching of
‘voo!, cotton, silk and other textile fibers was added to each ofthe three test tubes along, with
H:S0s It was followed by strong heating.
A BANGALORE SAHODAYA SCHOOLS COMPLEX ASSOCIATION
PRE-BOARD EXAMINATION -2 (2024 ~ 2025)
GRADE XII
Date: 18.01.2025 Max Marks: 70
Subject: CHEMISTRY (043) Time: 3 hours
General Instructions:
“All the answers should be written on the answer shect provided separately.
The intended marks are indicated against each question.
Answers should be written legibly.
‘Anneat presentation would be appreciated.
‘There are 33 questions in this question paper with in
SECTION A consists of 16 multiple-choice questions carryi
SECTION B consists of 5 very short answer questions carrying 2 marks each.
SECTION C consists of 7 short answer questions camying 3 marks each.
SECTION D consists of 2 ense- based questions carrying 4 marks each.
SECTION E consists of 3 long answer questions euitying 5 marks each,
All questions are compulsory.
‘Use of log tables and calculators is not allowed.
ternal choice.
ing ] mark each.
SECTION A
‘The following questions are multiple-choice questions with one correct answer. Each
question carries 1 mark. There fs no internal choice in this seetion,
a
‘Which of the following solutions will live the highest conductivity at 298 K?
(@) 0.01 M HC solution (b) 0.01 M CHCOOH solution
(c)0.1 M HCI solution (@) 0.1 M CHsCOOH solution
ii
2. Given is the following relation for strong, electrolytes :
N=h— AVE
‘Which of the following equality holds?
@)
A=NasO3VA
®
A= Aoas@ > 00
@
A=AoasG +0
@
A=NgasC 41
Which of the following alkyl
appropriate ether: SS
A
a
Tas Aico ee Ren
(a) Both A and R are true, and R is the correct eplenes ereniof
(b) Both A and R are true, but R is not t correct explan®
(c) Ais truc but Ris .
(a) A is false but Ris true
se
SECTION jon. The following
ver type and earry 2 marks excl, — ,
17. }Give reasons for the following : eotrope. The mole
( iterarare (on: 612°C) and atone (b-p. 56°C) ace sixed fo form an if the azeoKrope
fraction of acetone inthis mixture is 0.339, Predict whether the BONNE RTS con,
formed will be (2) 60°C (i) 64.5°C or (ii) $4 °C. Defend your ans
‘OR atement
* i i, Is this sti
(@) A soda bottle will go fat (loose its fizz) faster in Srinagar than” Delhi: Is
correct? Why or why not?
(b) The cells of the transparent tissues Of exterior eye, the cornea, have 4 M08,
optical fluid than does the zqueous humor, a solution just behind the comes: °°
above statement answer the following question: eee
| What would be the direction of osinosis between comeal tissues and aqueous humor —_—_y~
(@) Which of the following two compounds has a chiral center”
more concentrated
ed on the
18.
CH, - CH, -CH- CH, | OHC - CHOH- CH,OH
S ¢
Br
|__CompoundP | _Gompound @
(b) Two compounds X and ¥ are enantiomers of each other, Name one physical property
that (i) is same for X and Y__(ii) is different for X and Y.
19: | What is the quantity of electricity in coulombs required to produce 4.8 gof Mg from molten | 2
MgC? How much Ca will be produced if the same amount of electricity was passed through
the molten CaCl? (Atomic mass of Mg = 24 u, atomic mass of Ca-40u) < agua d ©
OR
‘The standard electrode potential (E°) for Daniel cell is +1.1 V. Calculate the AG* for the
reaction: Zn(s) + Cu°*(ag) > Zn” (ag) + Cu(s) (1 F = 96500 C mol *). &G*< -nF £°
20. | (a) Out of Cu* and Cur’, which ion is unstable in aqueous solution and why? 2
(b) Complete the following chemical equation
Cr; (aq) + 3H2S(g) + 8H"(ag). ————+
21. | (@) On the basis of the standard electrode potential values stated for acid solutions, predict | 2
whether Ti** species may be used to oxidize Fe(I1) to Fe(III) Justify your answer.
[Given : Ti**+ e& —> Ti"; B’ci=0,01V Fe't+e° —_» Fe* ; Bu =0.77V]
(b) The cell constant of a conductivity cell is 0.146 cm". What is the conductivity of 0.01 M.
SECTION C
This section contains 7 questions with an internal choice
questions are short answer types and carry 3 n
19.5 g of CH2ECOOH is dissolved in 500 g
water observed is 1.0°C. Calculate :
(a) Convert Benzene tom
(b) Identify A,B,C,
