GT- 12 CODE-A XII – IIT MAINS MODEL_08.01.

2025
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1 dt  2  3 t 2 sin 2t 
12. If x satisfies the equation   2  x   2 dt  x  2  0,  0      , then
 0 t  2t cos   1   3 t  1 
the value of x is
 2 sin   sin 
A)  B)  C)  D) 2
2 sin   sin  

13. If A is a square matrix of order 3 such that det (A) = 3 and

    
det  adj 4 adj 3adj 3adj  2 A 
1
  
  2m 3n then, m  2n is equal to


A) 2 B) 3 C) 6 D) 4
14. The number of distinct real values of ‘K’ such that the system of equations
x  2 y  z  1, x  3 y  4z  K , x  5 y  10z  K 2 has infinitely many solutions is
A) 0 B) 4 C) 2 D) 3
15. If P  6,1 be the orthocentre of the triangle whose vertices are A  5, 2  , B  8,3 and
C  h, k  , then the point C lies on the circle.
2 2 2 2 2 2 2 2
A) x  y  61  0 B) x  y  52  0 C) x  y  65  0 D) x  y  74  0
16. The coordinates of the focus of the parabola described parametrically by
x  5t 2  2, y  10t  4 is
A)  3,4  B)  7,4 C)  4,2 D)  2,9

17. If coefficient of x y z in  x  y  z  is A, (where A  0, n  N ) then coefficient of x y z is

2 3 4 n 4 4

nA A
A) 2A B) C) D) nA
2 2
x2 y2
18. An ellipse E:   1,  a  b  passes through the vertices of the hyperbola
a 2 b2
x2 y 2
H:   1 . Let the major and mirror axes of the ellipse E coincide with the
49 64
transverse and conjugate axes of the hyperbola H. Let the product of the
1
eccentricities of E and H be . If l is the length of the latusrectum of the ellipse E,
2
then the value of 113l is equal to
A) 1556 B) 1552 C) 1662 D) 776
 z2  
19. If arg   then which of the following is correct?
 z  2i  4
A) | z |min  0 B) | z |min  2  
2  1 C) | z |max  2  
2 1 D) | z |max  4
20. If from each of the three boxes containing 3 white and 1 black, 2 white and 2 black,
1 white and 3 black balls, one ball is drawn at random, then the probability that 2
white and 1 black ball will be drawn is
13 1 1 3
A) B) C) D)
32 4 32 16

II. Numerical Answer Type Questions :

x 1 y  3 z  2
21. Let  ,  ,   be the mirror image of (1,-2, 3) in the line   then
2 4 3
2  4   3  2  _____
2
22. The area (in sq. units) of the region bounded by the curve x  4 y and the straight
line x  4 y  2 is k. Then 8k is

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VELAMMAL BODHI CAMPUS, PONNERI IIT/NEET ACADEMY
GT- 12 CODE-A XII – IIT MAINS MODEL_08.01.2025
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31. A thin smooth rod of length L and mass M is rotating freely with an angular speed
0 about an axis perpendicular to the rod and passing through its center. Two
beads each of mass m and negligible size are at the center of the rod initially. The
beads are free to slide along the rod. The angular speed of the system, when the
beads reach the opposite ends of the rod, will be
M 0 M 0 M 0 M 0
A) B) C) D)
M m M  3m M  6m M  2m
32. Two identical photocathodes receive light of frequencies f1 and f 2 . If the velocities of
the photo electrons (of mass m) coming out are respectively v1 and v2 , then
1/ 2
2h  2h 
A) v12  v22   f1  f 2  B) v1  v2    f1  f 2  
m m 
1/ 2
2h  2h 
C) v12  v22   f1  f 2  D) v1  v2    f1  f 2 
m m 
33. Given below are two statements: one is labelled as Assertion A and the other is
labelled as Reason R.
Assertion (A): Body ‘P’ having mass M moving with speed ‘u’ has head-on collision
elastically with another body ‘Q’ mass m initially at rest, if m << M, body ‘Q’ will
have a maximum speed equal to 2u after collision.
Reason (R): During elastic collision, the momentum and kinetic energy are both
conserved.
A) Both A & R are correct and R is correct explanation of A.
B) Both A & R are correct but R is not correct explanation of A.
C) A is correct but R is incorrect. D) A is incorrect but R is correct
34. A wire elongates by l mm when a load W is hanged from it. If the wire goes over a
pulley and two weights W each are hung at the two ends, the elongation of the wire
will be (in mm).
A) l B) 2l C) Zero D) l/2
35. The binding energy of the electron in a hydrogen atom is 13.6eV, the energy required
to remove the electron from the first excited state of doubly ionized lithium Li++ is:
A) 122.4 eV B) 30.6 eV C) 13.6 eV D) 3.4 eV
36. A goods train accelerating uniformly on a straight railway track, approaches an
electric pole standing on the side of track. Its engine passes the pole with velocity u
and the guard’s room passes with velocity v. The middle wagon of the train passes
the pole with a velocity.
uv 1  u 2  v2 
A) B) u2  v2 C) uv   D)
2 2  2 
37. The equivalent capacitance between A and B in the circuit given below is:

A) 4.9  F B) 3.6  F C) 5.4  F D) 2.4  F

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VELAMMAL BODHI CAMPUS, PONNERI IIT/NEET ACADEMY
GT- 12 CODE-A XII – IIT MAINS MODEL_08.01.2025
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47. The value of aluminium susceptibility is 2.2  10 5 . The percentage increase in the
magnetic field if space within a current carrying toroid is filled with aluminium is
x
. Then the value of x is ______.
10 4
48. The amplitude of wave disturbance propagating in the positive x-direction is given by
1 1
y at time t = 0 and y  at t=1s, where x and y are in metres. The
1  x  1  x  2
2 2

shape of wave does not change during the propagation. The velocity of the wave will
be _____m/s.
49. Nitrogen gas is at 3000C temperature. The temperature at which the rms speed of a
H2 molecule would be equal to the rms speed of a nitrogen molecule, is _____(in K).
(Molar mass of N2 gas 28g) (Nearest integer).
50. Two simple harmonic motion, are represented by the equations


 
y1  10 sin  3 t   , y2  5 sin 3 t  3 cos 3 t . Ratio of amplitude of y1 to y2  x :1 . The
 3
value of x is _____.

I. Single Answer Type Questions:

51. P is the probability of finding the 1s electron of hydrogen atom in a spherical shell of
infinitesimal thickness, dr, at distance r from the nucleus. The volume of this shell
is 4 r 2 dr . The qualitative sketch of the dependence of P on r is:

52.

The final product ‘C’ in the above reaction is

53. A person is considered to be suffering from lead poisoning if its concentration in him
is more than 10 micrograms of lead per deciliter of blood. Concentration in parts
per billion parts is
A) 1 B) 10 C) 100 D) 1000
54. Alanine at its isoelectric point, exist in solution as:
H 3 N   CH  COO  H 2 N  CH  COOH
A) B)
CH 3 CH3
H 3 N   CH  COOH H 2 N  CH  COO 
C) D)
CH 3 CH 3
55. A lead storage battery has been used for one month (30 days) at the rate of one hour
per day by drawing a constant current of 2 amperes. H2SO4 consumed by the
battery is
A) 1.12 mole B) 2.24 mole C) 3.36 mole D) 4.48 mole

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VELAMMAL BODHI CAMPUS, PONNERI IIT/NEET ACADEMY
GT- 12 CODE-A XII – IIT MAINS MODEL_08.01.2025
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62. What is the correct order of stability of the following benzyl carbocations:

A) I > II > III B) I < II < III C) II > I > III D) III > I > II
63.  X   H2 SO4 
Y  a colourless gas with irritating smell
Y   K2Cr2O7  H 2SO4 
 green solution.  X  and Y  are
2
A) SO , SO2
3 B) Cl , HCl
 2
C) S , H 2 S D) CO32 , CO2
64. Which of the following is incorrect
A) CaC2  2 H 2 O  Ca  OH  2  C2 H2 B) Mg2 C3  4 H 2O  2 Mg  OH 2  C3 H4
C) Be2 C  4 H2 O  2 Be  OH 2  CH 4 D) Al4 C3  12 H2 O  4 Al  OH 3  C3 H 4
65. Which of the following carbonyls will have the strongest C – O bond?
A) Mn  CO 6 B) Cr  CO6 C) V  CO 6 D) Fe  CO 5
 

66. Identify the incorrect statement for PCl5 from the following:
A) In this molecule, orbitals of phosphorous undergo sp 3 d hybridization
B) The geometry of PCl5 is Trigonal bipyramidal
C) PCl5 has two axial bonds which are stronger than three equatorial bonds
D) The three equatorial bonds of PCl5 lie in a plane
67. The correct order of EMo 2 / M values with negatives sign for the four successive
elements Cr, Mn, Fe and Co is
A) Fe > Mn > Cr > Co B) Cr > Mn > Fe > Co
C) Mn > Cr > Fe > Co D) Cr > Fe > Mn > Co
68. Consider the following statements:
a) NF3 molecule has a Trigonal planar structure
b) Bond length of N 2 is less than O2
c) Isoelectronic molecules or ions have identical bond order
d) Dipole moment of H 2 S is higher than that of water molecule
Choose the correct answer from the option below
A) a and d are correct B) c and d are correct
C) a and b are correct D) b and c are correct
69. Which of the following order is correct with respect to depression in freezing point?
A) CH3COOH > HCOOH > Cl3C-COOH > F3C-COOH
B) HCOOH > CH3COOH > CF3 – COOH > Cl3C-COOH
C) F3C-COOH > Cl3C-COOH > HCOOH > CH3COOH
D) Cl3COOH > F3COOH > CH3COOH > HCOOH
70. Which one of the following reactions will produce tert-butyl methyl ether in high
yield?
A) tert-butyl chloride + sodium methoxide
B) tert-butyl alcohol + methanol in presence of H 2 SO4
C) tert-butyl bromide + bromomethane in presence of NaOH
D) Sodium tert-butoxide + bromomethane
II. Numerical Answer Type Questions:
71. The vapour pressure of a solution of a non-volatile electrolyte (A) in solvent (B) is
95% of the vapour pressure of the solvent at the same temperature. If molar mass
of B is 30% of molar mass of A, the mass ratio of the solvent and solute are
______(nearest integer)

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