SAMPLE PAPER

5 (Difficult Concept]
For Revision
Notes

Tine Allowed: 3 Hours]

|Maximum Marks: 70
General Instructions:
Read the following instructions carefully.
paper with internal choice.
(a) There are 33 qucstions in this question
carrying 1mark each.
(b) SECTION A consists of l6 multiple-choice questions
carrying 2 marks each.
(c) SECTION Bconsists of 5 short answer questions
each.
(d) SECTION C consists of 7 short answer questions carrying 3 marks
each.
(e) SECTION D consists of 2 case-based questions carrying 4 marks
) SECTION E consists of 3 long answer questions carrying 5 marks each.
(g) All questions are compulsory.
(h) Use of log tables and calculators is not allowed.

SECTION A

The following questions are multiple-choice questions with one correct answer. Each question carries
1mark. There is no internal choice in this section.
1. Arrange the following in the increasing order of their boiling points:
A: Butanamine, B: N, N-Dimethylethanamine, C:N-Ethylethanamine
(a) C< B<A (b) A <B<C
(c) A<C<B (d) B< C<A
2. Which one of the following compounds is more reactive towards S,1 reaction?
(a) CH,CHCH,Br (b) C,H,CH,Br
(c) C,H,CH (C,H)Br (d) CH,CH(CH,) Br
3. KMnO, is coloured due to:
(a) d-d transitions (b) charge transfer from ligand to metal
(c) unpaired electrons in d orbital of Mn (d) charge transfer from metal to ligand
4. Which of the following has highest dipole moment?
(a) o-dichlorobenzene (b) p-dichlorobenzene
(c) m-dichlorobenzene (d) All have equal dipole moment
5. For the reaction, A + 2B AB,, the order w.r.t. reactant A is 2 and zero w.r.t. reactant B.
What will be change in rate of reaction if the concentration of A is doubled and B is halved?
(a) increases four times (b) decreases four times
(c) increases two times (d) no change
6. Which of the following tests/reactions is given by aldehydes as well as ketones?
(a) Fehling's test (b) Tollen's test
(c) 2, 4 DNP test (d) Cannizzaro reaction

92 Together witk® EAD Chemistry-12

 7. The CFSE of (CoCI} is 18000 cm, the CFSE for [CoCI, will be:
(a) 18000 cm-! (b) 8000 cm-! (c) 2000 cm (d) 16000 cm-!
8. Which Of the following compound, on treatment with benzene sulphonyl chloride forms an alkali
soluble precipitate?
(a) CH,CONH, (b) (CH),N (c) (CH),NH (d) CH,CH,NH,
9. Match the following:
I(rate constant) Il(unit of rate constant)
(p) First order reaction () mol Ls!
(g) Zero order reaction
(r) 2hd order reaction (ii) L'mols-1
(s) 3 order reaction (iv) L mo's!
(a) (p)-iü), ()-i), (¢)-iv), (s)-(üi) (b) (P)-), (9)-(ü), (-(üiü), (s-iv)
(c) (p)-{iv), (g)-(i), (-i), ($)-() (a) (p-(). (g)-(), (0-iv), (s)-{üü)
10. Arrhenius equation can be represented
graphically as follows:

In k (s)

The () intercept and (i) slope of the graph are:

(a) (i) In A (iü) Ea/R (b) (i) A (ii) Ea
(c) (i) In A (ü) -Ea/R (d) (i) A (i) -Ea
11. Which of the following is least basic in aqueous solution?
(a) CH,NH, (b) (CH,),NH

(c) (CH,),N (d) CH,-C-NH,

12. Which of the following is strongest acid?
(a) p-CIcH,COOH (6) p-OHCGH,COOH
(d) p-NO, C,H,COOH
(c) CH,C00H by statement of a reason
following questions (Q. No. 13 - 16), a statement of assertion followed
Inthe
answer out of the following choices.
is given, Choose the correct
is the correct explanation of A.
(a) Both A and R are true and R A.
R is not the correct explanation of
(b) Both Aand R are true but
(c) A is true but R is false.
(d) A is false but R is true. collides in proper
collision occurs when molecule possess both Ea and
effective
13. Assertion (A): An
collisions.
upon number of effective
orientation.
of reaction depends secondary structures viz alpha-helix
Reason (R): Rate two different types of
Proteins are found to have
14. Assertion (A): structure. hydrogen bonding.
and beta-pleated sheet structure of proteins isstabilized by conductivity.
(R): The secondary conductivity as well as well as molar
Reason in
Dilution leads to increase of time.
15. Assertion :
constant voltage over long period behaviour.
gives paramagnetic
Reason : Mercury cell tetrahedral geometry and electrons.
Assertion (A): [NiCL has has two unpaired
10. hybridised and
is sp' Sample Papers 93
Reason (R): [NiCI,I
 SECTION -B
lollowlngk queston.
questions with internal choice in one questlon. Tlhe
This section contains 5
Short answer type and carry 2 marks eucli.
17. Answver the following questions: scuba divers filled witlh
State Henry's law and explain why are the tunks used by
(a) oxygen)?
(|1.7% helium, 56. 2% nitrogen and 32.I%
Whichhelium
(b) with type of deviation from Raoult's law is shown by ethanol and waler? Give TCUSON,
OR
Assume that argon cxerts a partial pressure of 6 bar. Calculate the solubility of argon
waler, K, = 40 kbar)
water. (Given: Henry's law constant for argon dissolved in
is colourless, Give
18. (a) Solution of |Ni(H,0)J* is green in colour where as (Ni(CN),
(Atomic number of
Ni
(6) What is shape and hybridisation of [NiCI,]? =28\
19. Corrosion is an electrochemical phenomenon. The oxygen in moist air reacts as followe
0,(g) + 2H,0() + 4e’ 40H (ag).
Write down the posible reactions for corrosion of zinc occurring at anode, cathode and overal
reaction to form awhite layer of zinc hydroxide.
20. Attempt any two out of the following:
(a) During the electrophilic substitution reaction of haloarenes, para substituted derivative i .
major product.
(b) The product formed during S,l reaction is a racemic mixture.
(c) Out of the Chloromethane and Fluoromethane, which one has higher dipole moment and suha
21. Account for the following:
(a) There are 5 OH groups in glucose
(b) Glucose is a reducing sugar

SECTION C
This section contains 7 questions with internal choice in one
question. The following questions are short
answer type and carry 3 marks each.
22. (a) Why does the cell voltage of a dry cell not
remain constant during its lifetime?
(b) What the pH of HCl solution when the hydrogen gas
-0.59 V at standard temperature and pressure? electrode shows a potential of
23. (a) Give one example of pseudo first order reaction.
(b) The thermal decomposition of an acid is a first order
reaction with rate constant of 2.3 x 10
at a certain temperature. Calculate how long it
willtake for three fourth of initial quantity to
decompose? (log 4= 0.6021, log 2 = 0.3010)
24. Answer the following questions:
(a) Aniline is acetylated before nitration
reaction. Give reason. Why is CHNHCOCH, less basic
than CH,NH,?
(b) pK, of aniline is lower than the
m-nitroaniline. Why? Which will undergo electrophilic substitution
faster- Aniline or m-nitro aniline?
(c) Primary amine on treatment with benzene
in NaOH however secondary amine gives sulphonyl chloride forms a product which is solubie
Write down the chemical reactions involvedproduct which is insoluble in NaOH. Give reason.
in primary as well as secondary
25. A hydrocarbon (A)with molecular amine.
Both (B) and (C) give a yellow formula CH,n on ozonolysis gives two products (B) and
only (B) give a silver mirror On precipitate when heated with iodine in presence of Naoi wi
reaction with Tollen's reagent.
94 Together with EAD
Chemistry--12
 (a) ldentily (A). (B) nd (O),
b) Write the
reaction ol } witlh lollen's eapent
(e) Write the
cquation for iodot0mtest o
OR
An orgniecompound (A) with noleculn fomula CuOis
Red P and ,. The organie obtained when (B) reacts with
compond
chloride with dry ice followed by acid 03)u e oblaiuedoo lhe rection of
methyl magnessum
(a) ldentity A and B. Ihydolvsis.
(b) Wrie down the
reaction for the lomation of A rom B What is
(c) Give any one this reaction cale
method by which organic
comound B c) be
acid chloride. preparcd from its otrCSpoin%
Write the cquations for the
following reaction:
(a) Salicylie acid is treated with
acetie anlhydride in thc presence of conc.
I) Tert. butyl chloride is H,S0,
i Phenol is
treated witlh sodiunn ethoxide.
treated with chloroform in the
7. (a) ldentify the major product formed when presence of KOH.
reaction. Name the reagent which is uscd 2-cyclohexylchlorocthanc undergoesa dehydrohalogenation
to carry out the reaction.
(b) Why are haloalkanes more reactive towards
and vinylic halides?
nucleophilic substitution reactions than haloarenes
0 (a) Conductivity of substance A" is 5,9 10 S/m and B" is 1 x 106 S/m. Which of the two is
most likely to be copper metal and why?
(b) What is the quantity of clectricity in Coulombs required to producc 4.8 g of Mg from
molten
MgCi? Howmuch Ca will be produced if the same amount of clectricity was passed through
molten CaCl,? (Atomic mass of Mg = 24 u, atomic mass of Ca = 40 u).

SECTION D

The following questions are case-based questions. Each question has an internal choice and carries
A(2+1+1) marks each. Read the passage carefully and answer the questions that follow.
follow:
29. Read the given passage and answer the questions that
intermediate temperatures form thin,
The transition metals when exposed to oxygen at low and
Angstroms in thickness. Transition metal oxides
protective oxide films of up to some thousands of the
between the extremes of ionic and covalent binary compounds formed by elements from
lie deviate by
right side of the periodic table. They range from metallic to semiconducting and
left or are involved, the
small degrees from stoichiometry. Since delectron bonding levels
both large and oxides. The crystal
valence states and hence give risc to a large number of
cations exist in various hexagonal closc-packed lattice of oneoxide set
by considering a cubic or
structures are often classified the octahedral or tetrahedral
interstices. The actual
of ions filling distortions
of ions with the other
set
departures from such regular arrays due in part to
structures, however, generally
show
ligand field effects. These distortions depend not
to
of different size and valence and the position of the transition metal
caused by packing of ions also on the
of d-electrons but
Only on the number
in a period or group. properties of transition metals. Progress in
Oxidation
W. W, & Young, D. J. (1975).
(SOurce: Smeltzer,
17-54.)
Solid State Chemistry, 10,
Sample Papers 95
 defects?
Whv do cytals of oxide of transitionmetals show
(0) ()
higher than Cu?
point of
( ) Why is melting
mctals less CHcive)
(h) Why ae trnsition
OR

Exaplain.
What is cystalstructue of G0?
Mn,0, covalent?
) Why is MnO ionic whees
Chargall 'ormulates His Rules"
30. Strengthening the Foundation:
Francis Crick discovered DNA in the 195(%. Inn
Many people believe that Janes Watson and
this is not the case. Rather, DNA was
first identified in the late 1860s by Swiss chermist realty
Micscher. Then, in the decades following Micscher's
discovery, other scientists n0tably,
of rescarch efforts that revealed
FíPhoeiedrbush
Levene and Erwin Chargaff--carricd out a series additional
about the DNA molccule, including its primary chemical components and the ways in which
joined with one another. Without the scientific foundation provided by these pioneers, Watson and,
desals
Crick may never have reached their groundbreaking conclusion of 1953: that the DNA moeoule

exists the form of a three-dimensional double helix.

research, set out to see whether there
Chargaff, an Austrian biochemist, as his first step in this DNA
were any differences in DNA among different species. After developing a new paper chromatogra
method for separating and identifying smallamounts of organic material, Chargaff reached
major conclusions:
(i) the nucleotide composition of DNA aries among species.
maintains cemat
(ü) Almost all DNA, no matter what organism or tissue type it comes from
simil.
properties, even as its composition varies. In particular, the amount of adenine (A) is
to the amount of thymine (T), and the amount of guanine (G) approximates the amount of
cytosine (C). In other words, the total amount of purines (A + G) and the total amount of
pyrimidines (C + T) are usually nearly equal. This conclusion is now known as "Chareaf.
rule." Chargaff's rule not obeyed in some viruses. These either have single-stranded DNA
or RNA as their genetic material.
Answer the following questions:
(a) Plot a graph between melting point of DNA with increase in GC content and explain.
(6) A segment of DNA has 100 adenine and 150 cytosine bases. What the total number of
nucleotides present in this segment of DNA?
(i) 300 (üi) 200 (i~üi) 500 (iv) 400
(c) The sample of a virus was tested and it was found to contain 20% adenine, 20% thymine, 20%
guanine and the rest cytosine. Is the genetic material of this virus:
() DNA-double helix (ii) DNA-single helix
(üi) RNA (iv) None of these
OR

(c) Which of the following is/are correct about DNA?

() Alldouble helix DNA will have same amount of A and T as wellas G and C
(ii) All DNA are single helix
(üi) Single helix DNA also have same amount of A=T. G=C
(iv) Allof these

96 Tagether witk" EAD Chemistry12

 SECTION E
The following questions are long answer tynes and carry 5 marks each. All
choice. questions have an internal
31, (a) () Why are all
copper
(i) Why is the E halides known except that copper iodide?
(b) (() The formula v+y²y
value for vanadium
comparatively low?
and names ofCo(NH,),C0,Cl could represcnt a carbonate or achloride. Write
possible isomers. the structures
(i) How many ions are
double salt or complexformed when
compound? F¢SO.(NH,),SO,6H,0
is dissolved in water? Is it
OR
(a) (i) Why HCl should not be
used for potassium
(iü) Explain the observation, at the end permanganate
of each period, there is atitrations?
radius of d block elements. slight increase in the atomic
(b) Using Valence bond
theory, explain the following in relation to the
[Mn(CN),: paramagnetic complex
) type of hybridization
(üü) type of complex - inner, (ü) magnetic moment value
outer orbital
complex
32. (a) What will be major
product(s):
(1) Acid catalysed dehydration of
1-methyl
(ü) Benzyl phenyl ether reacts with HBr cyclohexanol.
(iüi) Ethyl methyl ether reacts with one mole of HI
(b) i) Write the reaction and IUPAC name of the
product formed when
(isobutyraldehyde) is treated with ethyl magnesium bromide followed 2-Methylpropanal
by hydrolysis.
(i) What happens when toluene reacts with CrO,CI/CS, followed by hydrolysis? Write
reaction.
chemical
OR
(a) What happens when:
MgBr
( is treated with CH,CHO followed by hydrolysis

(ü) Phenol is treated with conc.(HNO, + H,SO,)

(üü) Propan-2-ol is heated at Cu/573 K
(b) Distinguish between the following by suitable chemical test.
(i) Propanal and propanone
(iü) Benzaldehyde and Benzoic acid
of water. How many grams of ethylene glycol
33. (a) Ishan's automobile radiator is filled with 1.0kg freezing point of the solution lowered to
get the
(Molar mass = 62 g mol') must Ishan add to
-2.8 °C. K, for water is 1.86 K kg mol. Give reason.
Raoult's law is shown by ethanol and acetone mixture?
(b) What type of deviation from
OR
the freezing
sucrose in water has a freezing point of 269.15 K. Calculate
(a) A 10% solution (by mass) of freezing point of pure water is 273.15 K.
in water if the
pont of 10% glucose (Molar mass of glucose = 180 mol")
342 mol)
Given: (Molar mass of sucrose =
(b) Define the following terms: (ü) Abnormal molar
mass
(i) Reverse osmosis 97
Sample Papers