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The document contains a series of multiple-choice questions related to chemistry, covering topics such as ionization enthalpy, complex nomenclature, reaction rates, enzyme characteristics, and the properties of gases according to Henry's Law. It also includes assertion-reason type questions, case-based questions, and long answer type questions that require detailed explanations and chemical equations. Overall, the document serves as a comprehensive assessment tool for evaluating knowledge in various chemistry concepts.
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0% found this document useful (0 votes)
14 views6 pagesSample Paper 2
The document contains a series of multiple-choice questions related to chemistry, covering topics such as ionization enthalpy, complex nomenclature, reaction rates, enzyme characteristics, and the properties of gases according to Henry's Law. It also includes assertion-reason type questions, case-based questions, and long answer type questions that require detailed explanations and chemical equations. Overall, the document serves as a comprehensive assessment tool for evaluating knowledge in various chemistry concepts.
Uploaded by
divyansh.panda8362Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
/ 6
] section-a —
The following questions are multiple-choice questions with one correct answer. Each question carrie
mark. There is no internal choice in this section.
1. Gadolinium (64) has low value of third ionisation enthalpy because of
(@) small size
(6) high exchange enthalpy
(©) high electronegativity
(d) high basic character
2. The IUPAC name of complex [Ag(H,0),][Ag(CN),] is
(@) dicyanido silver (11) diaquaargentate (II)
(6) diaqua silver (I1) dicyanido argentate (11)
(c) dicyanido silver (I) diaquaargentate (1)
(d) diaqua silver (1) dicyanido argentate (1)
a
DY Kx? Xj
3. + 2Na 5 ox, X is
Br
cl
(a) (6) © @ |
Br
Sample Papers £0, Be iE
a ca,
: 5
a (0 Both (a) and (6) (@)
o o 4
be yf A is 0.1M, which
1 eancentation of A i 01M, Which becom |
mn A -» Product se
a ats he goes nme a8 3)
isc * @) o01sés (©) 04606 5* (@) 0.2303 =
6 cored "x° on reaction with Os followed by 2 and H,0 gives formaldehyde and 2m,
propanal as products. The ‘compound ‘X’ is
(a) methyl but-l-ene (&) 2methyl but-L-ene
{o) 2metyl but2-ene
CaN (AIH, HO
1 BNO 0
: @Ho
ao cHOH
CONH, CHN;Cr
@ O © O © O : @ O
'& The incorrect statement regarding enzymes is
(@) Enzymes are biocatalyst
(6) Enaymes reduce activation energy
(6) Enaymes are polysachharides
(d) Enzymes are very specific for particular reaction and substrate
9. Which of the following will lead to a change in rate constant ‘k? of a reaction?
(@) Pressure (6) Temperature
(©) Concentration (@) Change in volume of reaction vessel
10. Choose the amide which on reduction with LiAIH, pives secondary amine.
(@) Ethanamide (6) N-Methy! ethanamide
(©) N, Neiethy ethanamide (@) Benzamide
11, Acetophenone when x
tophenone when reacted with base C,H, —ONa followed by heating, yields a stable proo
a
eOETO ORO
OH OH
oe
OLED ow 12 Initial rate of formation of NO, is given
2NOG) + Og) —+ 2NO,C)
Initial (NO}_ | Tnitat (0,} | Tita rate of [NO] formation in mol Ls
1 030M 030 M 0.056
i. 0.60 M 030M 0384
it 030M (0.60 0192
| __060M 0.60 Mt (0.768
‘The rate law is
@) r= HNO} (0, ©) r= KNOPF IO! r (r= HNOF (0,
Jn the allowing questions (Q. No. 13-16) a statement of assertion fllomed by statement ofa reason
is given. Chose the correct answer out ofthe falling choles
(@) Both A and R are true and R is the coret explanation of A.
(0) Both A and Rare rue but Ris not the eoret explanation of A.
(©) Aistave but Ris false
@ Ais fase but Ris tue
13, Assertion (A: Primary aliphatic amines react with HNO, to ge unstable dazoium salts
Reason (R): Primary aromatic amines reat with HINO, to form diazonium salts which are stable
even at 300 K.
14. Assertion (A: In Lacs tet 2% 3" alos re dsinguedon th at of hei react with
Gene: HL + Za own sacs een
Reason (Primary alcohols ate mot rast and immediately produce tui at room
temper on rool hes rapt
15, Assertion (A) RNA and DNA are chal de to Ds component
Reason 2): RNA contains Urci, DNA cons Thyme,
16, Aserton A): Zo, CH arent wranstion clement,
Reason (8): They do not have incomplete led obits inground ak wll a xed sate
I sectiov-s &
Tis cto antans 5 questions with internal icin one gus
shot ane ype and carey? mar ach
17 (2) Why does p-dcloo benzene have eo doe moment?
(0) CHG, hs higher pte moment than CHC?
18, Anat the gen graph drawn betwen on. of reictants Vs tine
(0) Pret the order of reaction
(6) Torta can the eoncentraton of retton reduc to 20 arin ine? Exp,
n. The following questions are very
10
Time
19. A compound withthe formula C,H,0 gives a negative Tllens’ reagent test and a postive iodoform
{est It produces semicarbazone and can be reduced to n-hexane with Clemmensen reduction
‘dentify the compound, OR
when aniline reacts with ben
‘What happens wale?
| Hage OOH
nl i 9 ee
1
{
Identify X’ and "Y"
20, (a) What are globular proteins?
primary structure of protein?
ipletion. Calculate the time require
minutes for 50% com
My 0.3010, log 3 = 0.4771 log 4 = 0.6021)
(b) What is meant bY
21, A first order reaction takes 23.1
‘completion of this reaction. (108
4 secriow-¢ E
choice in one question. The following questions ay.
sh,
or,
“This section contains 7 questions with internal
answer type and carry 3 marks each:
BD (a)_A* for NaCl, HCL, CH{COONA are 1260) (2 100, § em? mot. If the conductance of,
M CH,COOH is 5 x 10° Sen Caeulate the dearer ‘of dissociation of CH,COOH.
(©) Given below are hal cell reactions:
Mu; + 8H? + Se" ——> Mav + 410s Phaoznt
40, 42H! 2° 9 HOLE = BY
p= +1510V
Wil the MnO; liberate oxygen from water in presence of sci?
23. @) INC i paramagnetic whereas [Ni(CO), iamagneti though Pot ated wy
(b) Explain (Co(NH,),)* i inner orbital comples, whereas [Ni(NH,),P* is an outer ori
complex. [Atomic number of Co = 27, Ni = 28]
(What is hybridisation, shape and magnetic behaviour of [Cu(NH,),)°*. [Atomic number
c= 29)
24 Some ethylene gycol, HOCH,—CH,OH is added (0
water Iffeeting point of water glycol solution is -15.0
(&, = 052 K kg mot, Ky = 1.86 K kg mot for water)
25, Answer the following questions: (Any 2)
(@) Write the structural formulae of ammine chlorido(ethane 12-diamine)platinam() ois
How many ions it wil produce in aqueous solution?
(6) Whats coordination numberof platinum in above comp
(©), What is hybridisation in [Pt(NH,);C
26, How do you convert the following:
(@) Prop-1-ene to 1-luoropropane
(©) Ethanol to propane nitrile
21. Compound ‘8 having molecu!
(C,H,N) which on diazotization gives ‘C.‘C”
"D"‘C’ on reaction with KI gives “E'. Identify 10
your car's cooling system along with 5 isc}
*C, what i the boiling point ofthe soltioe
ex? Give reason, Will it show opt
by] and its shape? What is use ofthis complex?
(6) Chlorobenzene to 2-Chlorotoluene
‘and KOH gives
id forss
iol
lar formula (C,H,ON), on treatment with Br
reacts with aqueous solution of H;PO, #
“B? and write the chemical reactions
28, (a) What are anomers?
(b) Give difference in properties of anomers.
(6) What is structural difference between glucose and fructose? aa" § os
‘The following questions are case-based questions. Each question has an internal choice and carries
(1+1+2) marks each. Read the passage carefully and answer the questions that follow.
». Henry's Law and its Applications
‘Many gases dissolve in water, Oxygen dissolves only to small extent which sustains all aquatic life
NH, and HCI are highly soluble in water. Solubility of gases increases with increase in pressure
and decreases with inerease in temperature
Henry’ law tates “The partial pressure ofthe gas in vapour
phase (p) 18 proportional to the mole faction ofthe gas in
the solution. p = Ky.” Where K,, is Henrys law constant.
If-we draw a graph between partial pressure of the gas
vversus mole fraction of gas in solution, then we will get
straight line as shown in graph.
Different gases have different K,, values of the same
temperature. This suggests, Ky, isa function of nature of
g
— Paral pressure of HOMO >
g
2s.
‘Answer the following questions: ° ooI 60m
(2), What is slope of the line given in graph? Mole rat of HCI
‘olen fn eyschexane
(©) What is significance of Ky?
(©) @ Why does solubility of gus in liquid decreases with increase in temperature?
(i) Why are cold drinks filled with CO, at high pressure?
oR
(©) @ What is cause of anoxia at high altitude?
(i) Why do scuba divers take air diluted with helium?
30, Phenols are acidic in nature, In substituted phenols, electron withdrawing groups such as —NO;,
enhances acidic strength of phenol, if NO, group is present at o- and p-position. It is duc to
effective delocalisation of negative charge on phenoxide ion. Electron releasing groups, such as.
alkyl groups, do not favour formation of phenoxide ions resulting in decrease in acid strength e.g.
cxesols are less acidic than phenols.
‘The following table gives values of some Phenols and Ethanol
‘Compound ia
foNitrophenol | -0;N—C,H,—OH 12
‘m-Nitrophenol | m-0;N—C,H,-OH, 83
[p-Nitrophenol | p-O,N—CH,—OH 1
Phenol C,H.OH 100
o-Cresol o-CH,—C,H,—OH 102
‘m-Cresol ‘m-CH,—C,H,—OH 101
|p-Cresol p-CH,—CH_—OH 102
Ethanol GH.OH 159
Answer the following questions:
(@) From the above data, how many times phenol is more acidic than ethanol?”
(6) Out of phenols given in the table, which phenol is most acidic and why?
(©) @ Arrange the following in increasing order of acidic strength:
phenol, o-nitro phenol, m-nitro phenol, p-nitro phenol, p-cresol
i) Why are phenols les acidic than carboxylic acids? on -nol
pol, nitro Phenol Phenol, propan
(© @ Arrange 2, 4, 6-trinitro phenol, 3,5-
