ANyUAL EXAMINATION 2020-21
SUBJECT - CHEMISTRY
CLASS- XI
TIME 3 HOURS M.M 70
General instructions:
a )There are 33 questions in this
paper
b) Section A : Q. no. 1 to 2 are case based questions having m.c.q
based and assertion reason based on passage of one mark each.
c )Section A: Q no. 3 to 16 are M.C.Q and assertion reason type
carrying I mark each
d) Section B: Qno. 17 to 25 carry 2 marks each
e) Section C: Q no. 26 to 30 carry 3 marks cach
f) Section D: Q no. 31 to 33 carry 5 marks each
Read the
SECTION-A
1) passage given below and answer the following questions:
Ix4=4
The properties of the elements such as atomic and ionie radii, ionization
enthalpy, electron gain enthalpy and electronegativity are directly or
indirectly related to electronic configuration and are called periodic
properties.
) Which of the foilowing has highest ionization enthaipy?
a) N b) P c) O d) C
ii) The highest negative electron gain enthalpy is of
a) F b)N c) S d) Br
ii) The largest atomic size is of
a) N b) O c) S d) P
iv)Bromine belongs to the period
a) third b) fourth c)fifth d)second
2) Read the passage given below and answer the following questions:
Most of the physical and chemical changes are accompanied by energy
changes. These energy changes take place because of the rearrangement
of atoms in reactant to form products. The heat change is calculated as
internal energy, enthalpy ,entropy and gibbs energy.
Note: in the following questions a statement of assertion followed by
a statement of reason is given. Choose the correct answer out of the
following choices.
a) Assertion and reason both are correct statements and reason
explains assertion
b) Assertion and reason both are correct statements but reason
does not explain assertion
statements
reason are wrong
c) Both Assertion and
statement, reasonis Wrong statement.
Assertion is correct
d) is correct statement
Assertion is wrong statement, reason
e)
reaction is always negative.
i)Assertion: Enthalpy of
Reason:Combustion reactions proceeds
with evolution of heat.
ii)Assertion: Work is a state function.
Reason: Work does not depend on path.
during a process is a measure of
iii)Assertion : Decrease in free energy
spontaneity.
Reason:For a spontaneous reaction entropy change is positive
iv)Assertion:Internal energy is a state function.
Reason:lnternal energy change is heat evolved or absorbed at constant
pressure.
Following questions (no. 3 to 11) are multiple choice questions
carryingI mark each:
3. What is the mass percent of carbon in CO
a) 0.034% b) 27.27% c)3.4% d) 28.7%
4. Which ofthe followingsets of quantum numbers represents the highest
energy of an atom?
a) n=3 , F2, m=l , s=+1/2
E) n=4 , l=0 , m=0, s=+1/2
c) n=3 , =0 , m=0, s=+l/2
d)n-3, F , m=1 ,s=+1/2
5.The correct order of the decreasing ionic radii in the following
ISoelectronic species is
a) S> Ci> K> Ca*" b) K>Ca CI>s
c) Ca> K'> S*> Cr d) CI> S*> Ca>K*
6. Predict the correct order among in the
following:
a. bond pair- bond pair> lone pair bond
pair > lone pair-lone pair
-
b. lone pair - bond pair> bond pair -bond
pair> lone pair -lone pair
c. lone
pair -lone pair> lone pair bond pair >bond pair bond pair
-
d. lone pair - lone pair> bond
pair bond > -
pair lone pair-bond par
7.The species which has bond angle 120 is
a.
CH b. NH3 c. BF3 d.NF3
8. The
density of gas A is twice that of B. Molecular mass of A Is
hairo
the molecular mass of B. The
ratio of partial pressure of A and b is
a. 1/4 b. 1/2 c.4/1 d. 2/1
9.In which of the
following substances will hydrogen bond be stroT
a) HCI b) HO d) HS
c) HI
10. Acidity of BF3 can be explained on which of the following coneepts?
a) Arrhenius concept
b) Bronsted Lowery concept
c) Lewis concept
d) Lowery as well as Lewis concept
Bronsted
when mixed, will give a solution with pi
11. Which ofthe following,
greater than 7?
a)0.01 M HCI+0.2 M NaCl
NaOH
b) 100 mL of 0.2 M H2SO,+ 100 mL of 0.3 M
KOH
c) 100 mlL of 0.1 M CH3COOH +100 mL of 0.1
M
d) 25 mL of 0.1 M HNO+ 25 mL of 0.1 M NH3
Note: in the following questions a statement of assertion followed by
a statement of reason is given. Choose the correct answer out of the
following choices.
a) Assertion and reason both are correct statements and reason
explains assertion
b) Assertion and reason both are correct statements but reason
does not explain assertion
c) Both Assertion and reason are wrong statements
d) Assertion is correct statement, reasonis wrong statement.
e) Assertion is wrong statement, reason is correct statement
12)Assertion :Among halogens fluorine is the best oxidant
Reason: fiuorine is the most eiectronegative eiement
13) Assertion: LiCl is predominantly covalent compound.
Reason: the electro negativity difference between Li and Cl is too
small.
14) Assertion:TICI is more stable than TICl3.
Reason: +1 oxidation state of heaviest element is more stable than +3
15)Assertion :All the C-C bond lengths in benzene are equivalent
Reason : Benzene has high resonance energy .
16) Assertion :Acetylene is more acidic than ethene.
Reason: acetylene has sp hybridisation for carbon and therefore more s
character
SECTION B
The following questions Ques no.17-25 are short answer type and
carry 2 marks each.
a)Why is benzene extraordinarily stable though it has three double
bonds?
b) Draw CIs and trans isomers of but-2-ene.
OR
a) Draw the structure of 2-methyl buta-1,3-diene
Show by resonancethat -NO: group on benzene is meta dirccting
group
18) a)Arrange the following carbocations on the basis of increasing
stability:
CH, CH,CH (CH)CH , (CH3):C
b) Draw functional isomers of C2H,O
19) a) AlCl; is a Lewis acid .Explain
) PbO2 is a stronger oxidizing agent than SnO2 Explain.
20) What happens when: (write reactions)
a Sodium metal is dropped in wateer.
b Sodium peroxide dissolves in water.
21) a) Write chemical reactions to show the amphoteric nature of water.
b) Write the formula of a compound in which
oxidation state. Hydrogen shows +1 and -1
22) Balance the following reaction by oxidation number method
Cr:0+ Fes" +H- Cr"+ Fe*" +
H0
23) Calculate the molarity of a solution of ethanol in water in which
mole fraction of ethanol is 0.04.
24) Calculate the ratio between the
proton if the is
wavelength of an electron and a
proton moving with half the velocity of electron.
(Use mass of electron=9.9 x 10°' kg and mass of
Kg) proton 1.6 x
10
=
25) What will be the pressure exerted by a
and 4.4 g of carbon di oxide in a 9 mixture of 3.2 g of methane
dm flask at 27"C. use R= 0.083L bar
kmol
SECTION C
Ques 26-30 are short answer type and carry 3 marks
no.
26. i) To which class of hydrides H20 and NaH each.
ii) Hydrogen generally forms covalent
belongs.
ii) What is the importance of heavy compounds.
water?
27, i) At 450 K Kp is 2x10 / barfor the
,
given reaction at equilibrium.
2S0(g) +O:(g) - 2SO,(g)
What is the value of Kc. (use R= 0.0831L bar
/k/mol
ii) Write the conjugate acids of NH2" and NH3.
28. i) Why do real gases deviate from ideal
behaviour ? Give reason
ii) What are the corrections introduced by Vanderwalls in ideal
gas
equation. Explain and hence write Vanderwalls gas equation.
OR
Pressure of lg of an ideal gas A at 27C is found to be 2 bar. When 2g
of an ideal gas B is introduced in the same flask at same
temperature
the pressure becomes 3 bar. Find the relation between their
molecular massees.
291 List the values of Quantum numbers I and m for n=2.
ii) Write two differences between orbit and orbital.
iii) Write contiguration of Fe *". ( at. no. =26)
30 Give reasons for the following:
YGraphite is used as lubricant.
iN Aluminium alloys are used for makingaircraft body
ii)lf B-CI has dipole moment then why is BCl; is non polar?
SECTION D
Ques no. 31-33 are short answer type and carry 3 marks each.
a) Explain why:
i) a solution of NazC03 is alkaline.
ii) Alkali metals are prepared by electrolysis of their fused
chlorides
ii) Potassium is more reactive than sodium
bCompare the alkali metals and alkaline earth metals with respect
te
i) ionization enthalpy ii) basicity of oxides
32) a) What is aromaticity? Explain it using Huckels rule.
b) Convert benzene into
i) chlorobenzene
ii) p-nitrotoluene
ii) acetophenone
OR
) Complete the following reaction:
CHCH CH2+HBr-
Which rule does this addition foilow, hence write the
mechanism of this reaction.
YArrange the following in increasing order of boiling point:
butane, pentane , propane and hexane
iii) An alkene A on ozonolysis gives a mixture of ethanal and
propanone .write structure and IUPAC of the alkene A.
3) 1) State second law of thermodynamics. Write its mathematical
form als0.
The enthalpy ofcombustion of methane, graphite and
dihydrogen are -890.3 KJ/mol, -393.5 KJ/mol and -285.8 KJ/mol
respectively. Calculate the enthalpy of formation of methane.
ii What is the sign of entropy
change for:
20(g)---Ve 30;(g)
