7.Solid State Physics_2
7.Solid State Physics_2
Physics by fiziks
07 Solid State Physics, Devices and Electronics
4 Band Theory 1
5 Magnetism 2
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Q1. Which of the following statements is correct for NaCl crystal structure?
(a) It is simple cubic lattice with one atom basis
(b) It is a face-centered cubic lattice with one atom basis
(c) It is a simple cubic lattice with two atom basis
(d) It is a face-centered cubic lattice with two atom basis
IIT-JAM 2005
Q2. Consider the crystal structure shown in the figure,
a
where black and grey spheres represent atoms of two
different elements and a denotes the lattice constant.
The Bravais lattice for this structure is
(a) Simple cubic
(b) Face-centered cubic a
(c) Body-centered cubic
(d) Triclinic
a
z
Q3. The location of Cs and Cl ions inside the unit
cell of CsCl crystal is shown in the figure. The
Bravais lattice of CsCl is Cl
(a) Simple cubic
a y Cs
(b) Body centred orthorhomble a
(c) Face centred cubic a
(d) Base centred orthorhombic x
IIT-JAM 2019
a 2a
Q4. A plane in a cubic lattice makes intercepts of a, and with the three
2 3
crystallographic axes, respectively. The Miller indices for this plane are:
(a) 2 43 (b) 34 2 (c) 634 (d) 123
IIT-JAM 2017
Q5. Miller indicates of a plane in cubic structure that contains all the directions 100, 011
and 111 are
(a) 011 (b) 101 (c) 100 (d) 110
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07 Solid State Physics, Devices and Electronics
Q6. The figure below shows a cubic unit cell with lattice z
constant a . The shaded crystallographic plane intersects the x -
axis at 0.5 a . The Miller indices of the shaded plane are a
(a) 210 (b) 210
x
Q7. Which one of the following crystallographic planes represent 101 Miller indices of a
y y y
m
x x x x
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Q8. Which of the combinations of crystal structure and their coordination number is (are)
correct?
(a) body centered cubic 8 (b) face centred cubic 6
(c) diamond 4 (d) hexagonal closed packed 12
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Q9. The fraction of volume unoccupied in the unit cell of the body centered cubic lattice is
8 3 3 6 2
(a) (b) (c) (d)
8 8 6 3 2
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Q10. Diamond lattice can be considered as a combination of two fcc lattice displaced along the
body diagonal by one quarter of its length. There are eight atoms per unit cell. The
packing fraction of the diamond structure is
(a) 0.48 (b) 0.74 (c) 0.34 (d) 0.68
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Q11. Sodium Na exhibits body-centred cubic (BCC) crystal structure with atomic radius
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Ans. 5: (a)
Solution: The name of the plane containing all the directions
y 111
100 , 011 & 111 is 0 11 or 01 1
The best suitable answer is option (a) 011
x
100
Ans. 6: (a) z
Solution: (i) Intercepts along x, y, z - axis
a
x , y a, z
2
(ii) Divide by lattice parameters
a/2 a 1
, , , 1,
a a a 2
(iii) Take reciprocal, 2,1, 0
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Ans. 7: (b)
Solution: Plane intercepts
a b c a b c
x: y:z : : : : a::c
h k l 1 0 1
x a , y , z c
Plane is parallel to y - axis and intersecting x and z - axis at a and c . Thus, option (b) is
correct.
Ans. 8: (a), (c), (d)
Solution: Co-ordination number in different crystal structure are
(i) Body central cubic 8
(ii) Face central cubic 12
(iii) Diamond 4
(iv) Hexagonal closed packed 12
Ans. 9: (a)
Solution: The effective number of atoms in bcc structure is E F
1 1 1 1
neff nc n f ni 8 0 1 2
8 2 8 2
The radius of atom and lattice constant are related as
a
a 3
r G
4 a
D C
The volume occupide by the atoms in unit cell is a
3
4 a 3 3 3
2 a
3 4 8
3 8 3 3
volume of unit cell filled volume a 3 a 3 a
8 8
Thus, the fraction of volume unoccupied in the unit cell of the body centered cubic lattice is
8 3
8
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Ans. 10: (c)
4 3
neff r
Solution: P F 3
V
3a 8r
Where, neff 8,V a 3 and 2r a
4 3
4 3
8r
3 3
PF 3
0.34 .
8r 16
3
Ans. 11: 0.43
Solution: For BCC, 3a 4r
4r 4 0.186
a a 0.43 nm
3 3
Ans. 12: 4
Solution: Diamond structure has tetrahedral bond. To fracture the diamond structure along
0 0 1 plane, four bonds need to be broken.
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V
The fractional change in the volume is
V
V 139.91 136.54
0.024
V 139.91
Ans. 16: (c)
1
Solution: The effective number of atoms in BCC is neff 8 1 2
8
The volume of the bcc unit cell of side a is a 3 .
2
Thus, the number of atoms per unit volume is .
a3
Therefore, the correct option is (c).
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Q1. KCl has the NaCl type structure which is fcc with two-atom basis, one at 0, 0, 0 and
the other at 1/ 2,1/ 2,1/ 2 . Assume that the atomic form factors of K and Cl are
identical. In an X - ray diffraction experiment on KCl , which of the following h k l
peaks will be observed?
(a) 10 0 (b) 110 (c) 111 (d) 2 0 0
IIT-JAM 2017
Q2. In the X -ray diffraction pattern recorded for a simple cubic solid (lattice parameter
o o
a 1 A ) using X -rays of wavelength 1 A , the first order diffraction peak(s) would
appear for the
(a) 100 planes (b) 112 planes (c) 210 planes (d) 220 planes
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Q3. X -ray diffraction of a cubic crystal gives an intensity maximum for Bragg angle 200
corresponding to the 110 plane. The lattice parameter of the crystal
is___________ nm .
(Consider wavelength of X ray 0.15 nm )
IIT-JAM 2016
0
Q4. Monochromatic X -rays of wavelength 1A are incident on a simple cubic crystal. The
first order Bragg reflection from 311 plane occurs at angle of 30 0 from the plane. The
0
lattice parameter of the crystal in A is
11
(a) 1 (b) 3 (c) (d) 11
2
IIT-JAM 2009
0
Q5. The value of at which the first-order peak in X -ray ( 1.53A ) diffraction
corresponding to 111 plane of a simple cubic structure with the lattice constant,
0
2.65 A , is approximately
(a) 150 (b) 300 (c) 450 (d) 600
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07 Solid State Physics, Devices and Electronics
Q6. A solid with FCC crystal structure is probed using X -rays of wavelength 0.2 nm . For
the crystallographic plane given by 2, 0, 0 , a first order diffraction peak is observed for a
Bragg angle of 210 . The unit cell size is __________ nm (Round off to 2 decimal places)
IIT-JAM 2020
Q7. An X - ray diffraction XRD experiment is carried out on a crystalline solid having
FCC structure at room temperature. The solid undergoes a phase transformation on
cooling to 200 C and shows orthorhombic structure with small decrease in its unit cell
lengths as compared to the FCC unit cell lengths. As a result the 311 line of the XRD
pattern corresponding to the FCC system
(a) will split into a doublet
(b) will split into a triplet
(c) will remain unchanged
(d) will split into two separate doublets
IIT-JAM 2011
0
Q8. An X -ray beam of wavelength 1.54 A is diffracted from the 110 planes of a solid with
0
a cubic lattice of lattice constant 3.08 A . The first-order Bragg diffraction occurs at
1 1 1 1
(a) sin 1 (b) sin 1 (c) sin 1 (d) sin 1
4 2 2 2 2
IIT-JAM 2012
Q9. Thermal neutrons (energy 300 , k B 0.025 eV ) are sometimes used for structural
determination of materials. The typical lattice spacing of a material for which these can
be used is
(a) 0.01nm (b) 0.05 nm (c) 0.1 nm (d) 0.15 nm
IIT-JAM 2014
Q10. The lattice constant of unit cell of NaCl crystal is 0.563 nm . X -rays of wavelength
0.141 nm are diffracted by this crystal. The angle at which the first order maximum
occurs is _______degrees.
IIT-JAM 2018
0
Q11. In an X - ray diffraction experiment with Cu crystals having lattice parameter 3.61A ,
X - rays of wavelength of 0.090 nm are incident on the family of planes 1 1 0 . The
highest order present in the diffraction pattern is ___________.
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Solution: In KCl the reflection from 111 layer containing K ions is exactly out of phase
with the reflection from the Cl close packed layers. The net effect is that the two reflections
cancel and 111 is absent. This mean the first reflection is from 200
Ans. 2: (a)
Solution: In simple cubic cell, planes are present. The first order diffraction peak would appear
2d sin n sin h2 k 2 l 2 h2 k 2 l 2
2a 2
1 6 5
sin for 100 , sin for 112 , sin for 210 and
2 2 2
8
sin for 220 .
2
Ans. 3: 0.31
Solution: According to Bragg’s law 2d sin n
a 2 d 0.31 nm a 0.31 nm
Ans. 4: (d)
Solution: Expression of Bragg´s law is 2d sin n ,
where, d is the inter-planar spacing defined for cubic lattice of lattice constant a in term of
a
Miller indices h k l as d
h2 k 2 l 2
1 1
a h2 k 2 l 2 3 2 12 12 11 11
2 sin 2 sin 30 0
2 1/ 2
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Ans. 5: (b)
Solution: Expression of Bragg´s law is, 2d sin n
where, d is the inter-planar spacing defined for cubic lattice of lattice constant a in term of Miller
a
indices (h k l) as d
h2 k 2 l 2
1.53 1 1
sin h2 k 2 l 2 3 sin 1 300
2d 2a 2 2.65 2 2
Ans. 6: 0.56
2a sin
Solution: 2d sin
h2 k 2 l 2
Ans. 7: (b)
a
Solution: In FCC the inter-planar spacing is defined as d
h k2 l2
2
1
whereas in Orthorhombic the inter-planar spacing is d
2
h k2 l2
a2 b2 c2
For 311 , numbers XRD peaks in FCC is derived from Bragg’s law as
sin h2 k 2 l 2 3 2 12 12 11
2d 2a 2a 2a
Thus only one peak appears in FCC.
In Orthorhombic, sin
2d h2 k 2 l 2
2
a2 b2 c2
1 1 1
1 sin , 2 sin and 3 sin
2
3 1 12 2 12 2
3 1 2 2
1 1 32 2
2 2 2 2 2 2 2 2 2 2 2 2
a b c a b c a b c
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Ans. 8: (b)
Solution: Expression of Bragg´s law is 2d sin n
where, d is the inter-planar spacing defined for cubic lattice of lattice constant a in term of Miller
a
indices ( h k l ) as d
h2 k 2 l 2
1.54 1 1
sin h2 k 2 l 2 2 sin 1
2d 2a 2 3.08 2 2 2 2
Ans. 9: (c)
Ans. 10: 12.5
Solution: 2d sin
3
sin 1 1
sin
2d 2a
3 0.141
sin 1 sin 0.217 12.53
1 0
2 0.563
Ans. 11: 5
2a
Solution: Bragg’s law is; 2d sin n sin n
h2 k 2 l 2
2a 2 3.611010
For the highest order sin 1 ; n 5.67
h2 k 2 l 2 0.9 1010 2
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Q1. Fermi energy of a certain metal M 1 is 5eV . A second metal M 2 has an electron which
is 6 % higher than that of M 1 . Assuming that the free electron theory is valid for both the
T T
R R
(c) (d)
T T
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Q3. Which one of the following schematic curves best represents the variation of conductivity
of a metal with temperature T ?
(a) (b)
0 T 0 T
(c) (d)
0 T 0 T
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Q4. For a metal, the electron density is 6.4 1028 m 3 . The Fermi energy is __________ eV .
( h 6.626 1034 J s, me 9.11 1031 kg , 1 eV 1.6 1019 J )
(Specify your answer in electron volts eV upto one digit after the decimal point)
IIT-JAM 2018
Q5. A conducting slab of copper PQRS is kept on
Z
the x - y plane in a uniform magnetic field
S R
along x - axis as indicted in the figure. A steady
Q
P I
current I flows through the cross section of the Y
slab along the y - axis. The direction of the B
X
electric field inside the slab, arising due to the
applied magnetic field is along the
(a) negative Y direction (b) positive Y direction
(c) negative Z direction (d) positive Z direction
IIT-JAM 2014
Q6. At some temperature T , two metals A and B , have Fermi energies A and B ,
A
respectively. The free electron density of A is 64 times that of B . The ratio is ____.
B
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Let us consider that n1 , E F1 is the concentration of electron and Fermi energy in metal M1 and
n2 , E F2 is in metal M2.
2
2/3
3 2 n2
EF2 2m
n2 1.06n1 1.06 2/3 1.0396
2/3 2/3
EF1 2 2/3 n1 n1
2/3 2/3
3 2 n1
2m
EF2 1.0396 EF1 1.0396 5eV 5.2 eV
Ans. 2: (a)
Solution: Electrical resistivity of metal varies as
T5 (For T D )
T (For T D )
Ans. 3: (b)
Solution: Resistivity of metal is 0 ph , where 0 is temperature independent
1
The conductivity is defined as
S
0 T
T
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Ans. 4: 5.84
1.05 10
2
34
2
3 6.4 1028
2/3 2/3
Solution: EF 3 2 n 31
2
2m 2 9.1110
6.1 1039 1.53 1020 9.34 1019 J
9.34 1019
eV 5.84eV
1.6 1019
Ans. 5: (c)
Solution: The electrons are moving opposite to the current direction with drift velocity
v d v d yˆ Z
The Lorentz force on electron is
F q vd B
I
E
e v d yˆ B xˆ ev d B zˆ
Y
B
Thus, electron will accumulate on the lower plate and X
positive charge developed on the upper plates. The electric field due to this charge reparation is
acting along - z direction.
Thus, correct option is (c).
Ans. 6: 16
Solution: The Fermi energy for metal A and B is written as
2
2
2/3 2/3
A 3 2 n A and B 3 2 nB
2m 2m
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4. Band Theory
Q1. In a crystalline solid, the energy band structure ( E - k relation) for an electron of mass m
2 k 2k 3
is given by E . The effective mass of the electron in the crystal is
2m
2 m
(a) m (b) m (c) (d) 2m
3 2
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Ans. 1: (c)
2
Solution: The expression of effective mass of electron in solid is m *
d 2E 2
dk
dE 2 d 2 E 2 2 2 m
4k 3 2 4 m*
dk 2m dk 2m m 2
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5. Magnetism
Q2. The following are the plots of the temperature dependence of the magnetic susceptibility
for three different samples.
a b c
(T ) (T ) (T )
0 T 0 T 0 T
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5. Magnetism (Solution)
Ans. 1: (b)
Ans. 2: (b)
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