Solutions Slot – 3 (Chemistry) Page # 37

EXERCISE – III SUBJECTIVE QUESTIONS

1. A = 1 (Body center) 47.88

% Ti =  100 = 59.94 %
79.88
1
B=8× = 1 (for corner) Ox. State = +4
8
formula = AB 5. Zn2+ = 8/8 = 1
Al3+ = 4/2 = 2
1 O2– = CCP (4)
2. Au = 8 1 ZnAl2O4
8
1
1 Zu2+ = × 8 octahedral voids
Cu = 6  3 8
2
Formula = AuCu3 1
Al2+ = 4 octahedral voids
2
1 1 O2– = CCP arrangment (1+3) = 4
3. A= 6  8 = 4
2 8
6. In bcc z=2
8
B= no. of void (tetrahedral) 2  56
4 
NA (a3 )
=2
C = Total no. of octahedral voids / 2 4  124
a 3
no. of octahedral voids ( effective) r=  a= in pm
= 1 + 12 × 1/4 = 4 4 3
Bodycenter edgecentre
2  56
C = 4/2 = 2 3
formula = A4B2C2  =  4  124   10–36  6.022  1023
 3 

1 1 = 7.92 × 106 g/cm3
4. O2– = 8 + × 6 =4
8 2 In FCC , Z = 4
1  12  1 / 4 
4
2 4  56
Ti =  3
2 2
 4  124  –36 23
TiO2 formula    10  6.022  10
Ti (At mass) = 47.88  2 
= 8.6 g/cm3

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 Page # 38 Solutions Slot – 3 (Chemistry)
7.
(A) Simple cubic lattice
 143.5 
2r = a  4  6.022  1023 
11.     5.575 g / cm3
a 534 (555  1012 )3
 r = = = 267 pm
2 2
If 100% sites occupied  =5.575 but
(B) 4r = a 3 density is 5.561

534 3 5.561
 r= = 231.23 pm % sites occupied =  100
4 5.575
% sites unoccupied = 100 – (99.75) %
(C) 4r = a 2 = 0.25%
534 2
r= 12. nearest neighbour distance = 2r (in FCC)
4
 a 2 = 4r
= 188.79 pm
a 620
8. In simple FCC Z = 4  2r = =
2 1.414
but here from questins two atoms per
lattice point 2r  438 .47
 z=8 r = 219.23
8  M / NA
  r
a3  0.44
13. r–
 8  12  It could be square plamer
 6.022  1023 
=   g / m3 or
(3.569  1010 )3 octahedral void
but for closed packed crystal
= 3.5 × 106 g/m3  it is octahedral void
= 3.5 g/cm3 = coordination no. = 6
9. z=3 14. interionic distane
M a 3
3 r+ + r– = = 200 3 = 346.4
7.2 = NA 2
24  10–24
 M = 34.68 15. FCC : Z = 4
= no. of atoms in 200 gram
 197 
200 4  
× 6.022 × 1023  6.022  1023 
=
34.68  g / m3
(407  10 12 )3
= 3.47 × 1024 atoms
= 19.41 × 106 g/m3
= 19.41 g/cm3
z  108 / NA
10. 10.6 × 106 g/m3 = a 2
a3 & 2r =
2
a3
  1.692  10–29 a 2
z  r   143.9 pm
4
4 3
z r
PF = 3  100
3 M
a z
16. NA

12 3 a3
=

4 / 3  144  10   100
1.69  10–29
 74 %  F.C.C.
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 Solutions Slot – 3 (Chemistry) Page # 39
a3 119 / 6.023  1023 4
 B3+ Occupy = =2
z 2.75 2
= 7.18 × 10–23 A2+ = 1, B3+ = 2, O2– = 4
z = (654 × 10–10)3 / (7.18 × 10–23)  4 formula = AB2O4
 FCC
r
17. 24 × 1023 atom contain by 200g 22.  2  1 for ideal NaCl crystal
6 × 1023 atom contains by r
200 r r
g = 50 g  0.414  r =
4 r –
0.414
M  50 g/mole r+ = 103.55 pm
tetrahdral sites
50 for tetrahedral voids
4 4  50
 6  1023 =
r
10 3
(200  10 ) 6  10  8  10–24
23
0.225  r < 0.414

4  50 2000
= = r 180
48  10 1 48    0.72
r 2.50
 = 41.67 g/cm3
no can’t slipped

56
4 r 0.65
18. = NA 23. for MgS r  1.84  0.353

a3
coordination no = 4
4r tetrahedral void
2a  4r  a= r
2 0.65
MgO  r = = 0.464
= 4.016 Å  1 .40
4  56 Octahedral voids
 coordination no. = 6
6.022  10  (4.016)3  10  30
23

= 0.574 × 107 g/m3 r 1.69

CsCl = r  1.81  0.934
= 5.74 × 106 g/m3 
 = 5.74 g/cm3 BCC coordination no. = 8

19. NaCl type FCC  4  58.5 

 
6.022  1023 
a 24.  
r+ + r– = = 297 (0.564  10–9 )3
2
 a = 297 × 2 = 594 pm = 2.16 × 106 g/m3
= 594 × 10–10 cm = 2.16 g/cm3
= 5.94 × 10–8 cm
a3 = volume % = 2.096 × 10–22 cm3
 M 
1  
25. 3.94 =  NA   168.5
20. a 3 7
a3 6.022  1023  a3
a 3 7
r+ + r– = = 3 168.5
2 2  a 
1.69 + r– = 3.5 6.022  1023  3.97
r– = 3.5 – 1.69 = 1.81 Å a = 7.05 × 10–23 cm3
3

a = 4.13 × 10–8 cm
21. Total tetrahedral voids = 8
a 3
1 r+ + r– = = 3.577 × 10–8
A occupied = 8 
2+
=1 tetrahedral void 2
8 = 3.577 × 10–10 cm
Total octahatral void = 4 = 3.577 Å

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