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SUMMARY OF QUESTIONS ASKED INPREVOUS BoARD EAMD

1 SOLID STATE
. Distinguish
between crystalline 2017) (2)
solid
and amorphous solid. (March2013,2014,
i21 Goldoccursas tacecenteredcube and has a density of 19.30ke dm-3,Calculateatomic radius
(Molarmass of Au = 197) (March 2013) (2)
o

[Ans. 144 pm] r-

(3) Caleulatethenumber ofatoms presentin2 gram of erystal lattce
which hasface-centeredcubic(fce) crystal (3]
havingedge lengthof 100pm and density10 (Oct.2013)
gem3, [Ans.8 x 1023 atoms] (2
I41 What areSchottkydefectand Frenkeldefect? (Oct.2013)
(5) Face centeredcubiccrystal lattice
ofcopper has density of8,966g-cm3,Calculatethevolume o

theunitcell.Givernmolarmass of copperis63.5g- mol- and Avogadronumber N,is6.022*

(Ans.4.702 x 10-23cm) (March 2014) (3)
ofiron
(6) A unit cell has edge length288 pm and density7.86 .cm-3Findthenumber of atoms per unt
crystal
celland typeofthecrystal lattice.
[Given:Molarmass iron= 56 g- mot';
- (Oct.2014) (3)

of
Avogadro's Number, N, 6.022x 1024,] [Ans.2,Type -bcc]
(7) Explain impuritydefectinstainlesssteelwithdiagram. (March 2015) (2)
(8) Niobiumcrystallises
Calculate
(9) Silver
unitcell
as body centeredcube (BCc)and hasdensity
theatomicradius
inF.C.C.
crystallises
of niobium.(Given:
(face-centered
isfound to be 408.7pm. Calculate
Atomic mass of niobium
cubiccrystal)
density
structure.
of the unitcell.
of 8.55kg/dm,
93). (Ans.O.143nm](March 2015)
The edge lengthof the
)
[Ans.10.51g- cm-] (Oct.2015) (3)
[Given:Molarmass of silver is108g.mot.
(March 2016) (2)
(10)What isferromagnetism? Iron(Z = 26)isstrongly ferromagnetic. Explain.
(11) Silver
crystallisesinFCC structure. Ifdensity of silveris10.51g.cm3,calculatethe volume of unit cell.
(March 2016) (3)
|Atomic
mass of silver(Ag)-108 g. mot) [Ans.68.24 x 10-24 cm)
(July2016) (2)
(12) A facecentered cube (FCC)consists ofhow many atoms? Explain.
of Cesium chloride which crystallizes in BCC type structurewith the edge length
(13) Determinethe density number of
Predictthe co-ordination
412.1pm. The atomic masses ofCs and Cl are 133 and 35.5respectively.
ionifro+ = 1.69A and = re- l.81 A. [Ans. 4 gcm; C.N, -8] (July 2016) (3)
(March 2017) (2)
Cs
of packing incase of simple cubiccell.
the percentage efficiency
[Ans.52.4%]
(14) Calculate
in facecenteredcubic structure.
thenumber ofatoms ina unitell
(15) Calculate ofa metal crystallising inta (March 2017) (2)
[Ans.
thefollowingmolecularsolids intodifferenttypes:
(16) Classify
S, molecule (d) Diamond. (July2017) (2)
(a)Ammonium phosphate (b) Brass (c)
body centered (BCC),
intotwo cubicfacesnamely facecentered(FCC) and
(17) A metal crystallises of the densities
of
edge lengthsare 3.5A and 3.0A respectively. Findthe ratio
whose unitcell (July
2017) (3)
FCC and BCC. (Ans.d,:d, 1.26]
(March 2018) (2)
(18) lonicsolids arehard and brittle. Explain.
is8.54 gram cm, If the edge lengthof unitcellis2.8A and
(19) The density of ironcrystal
mol', f indthenumber of atoms inthe unit cell.
atomic mass is56 gram [Ans. -2.017- 2] (March 2018) (3)
number= 6.022x 102,1 A=1 x 10- cm] Z
(Given:Avogadro's types:
molecular solids i nto diferent
(20) Classify the following
so July2018) (2)
(a) HCI(b) CO, (c)Solid ice (d)
gram cm. Iftheedge lengthof cubicunit
having atomic mass 107.8 gram mo" is10.8
(21) The density of silver
silver atoms in the unitcell.
thenumber of
cellis4.05 x 10-8 cm, find [Ans.Z = 4.009=4] (July2018) (3)
x 1023, 1À =108 cm)
(N,6.022 of anionsin hexagonal
closedpacked stm.ots
number
(22) What isthe ratio of octahedralholes to the
[Ans.1:1] (March 2019) (1)
crystalline solids and amorphoussolids. (March 2019) (3)
Distinguish between crvstal.
(23) DefineAnisotropy. and edge length in body centeredcubic (July2019) (1)
between radiusof atom
(24) Give therelation
the following solids: (i)Diamond (i) (i)
NaCl P, molecule(iv)Brass.
(25) Classify (July2019) (3)
isSchottky defect? P, (c) Diamond (d) NaCl (March
What types: (a) Silver (b) 2020) (2)
the following intodifferent cm.
(26) Classify 288 pm and density of 7.86 g Determinethetype
(27) Unit cell a metal has edge
length of
[Ans.bccl
mass of metal-56
g mol-!) (March 2020) (3)
of
lattice. (Atomic lattice?
of crystal in simple cubic crystal (Sept.2021) (1)
number ofatoms
(28) What isthe coordination structure. What isthe number
of
(hep)
hexagonal close packed
(29) A compound forms Totalvoidsformed in 0,4 mol
of8
(u) Tetrahedral voids(lii)
(i)Octahedral voids
x 102; (i4)4.818x 102;
(ii) 7.227 x 1023.
(Sept.2021) (3)
[Ans.(1)2.4098
(277)
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UTTAM'sXIl
ChemistryPapersSolution
278
(March 2022) (2)
reasons.
(30) Write the consequences ofSchottky defectwith 10-
cubiccells. i
The edge length of unitcell s4.08 x cm.
(31) Goldcrystallises intoface-centred 21
the density of [Molar
gold. mass of gold 197 gmol-|[Ans. 19.27x 10kg-dm) (March 2022)
Caleulate
(March 2022) (2)
(32) Explnin metal deficiencydefectwith example.
(July 2022) (2)
(33) Distinguishbetween Schottky and Frenkeldefect.

(34) Calculate the number of atoms and unitcellpresent in 0.5g of Niobium ifitforms h of unit cellis330.6pm.
body centredcubic structure. The densityof Niobium is8.55 g cm-3 and edge length of
3.25 x10, No. of unitcells
= 1.62 July 2022) (2)
[Ans.No. ofatoms

x
(35) Explainthe followingterms:
(March 2023) (2)
(a)Substitutionalimpuritydefect(b) Interstitial
impuritydefect.
infcc structure.Ifedge lengthof unit densityof silver.
cellis 400 pm, calculate
(36) Silvercrystallizes
(March 2023) (2)
(Atomienass of Ag108). (p) 11.20 cm-.]
[Ans.Density of silver g

2 SOLUTIONS Rk FreeBooles
(1)Derive the relationship
between loweringof vapourpressure and molar mass of
relative
(2)
non-volatilesolute. (March 2013,2017)
(2) Defineosmosis. (March 2013) (1)
(3) What isboilingpoint? (March 2013) (1)

(4) State Henry's law. How does solubility of a gas inwatervaries with the temperature? (0ct.2013; July2017)(2)
(5) Define 'Isotonic solution'. (March 2009, Oct. 2013) (1)
(6) Calculate the amount of Cacl,(van't Hofffactor, i-2.47)dissolvedin 2.5L solution so that
itsosmotic pressure at 300K is 0.75atmosphere.
|Given: Molar mass of CaCl,is11l g. mot',R- 0.082L. atm
K W -
mot) (Ans. 3.425 gl(March 2014) (3)
(7) Explain, why do aquatic animalsprefer tostayat lower level ofwaterduring summer? (March 2014) (2)
(8) A solutioncontaining 0.73g of camphor (molar mass 152g.mol-') in36.8 g of
acetone (boiling point56.3°c) boilsat56.55°C.A solution of0.564g of
unknown compound inthe same weight ofacetone boils at56.46°C.Calculate the molar mass
ofthe unknown compound. [Ans.183.5g-mol-' (Oct.2014) (3)
(9) Define van'tHofffactor. How isit related tothe degree of dissociation? (Oct.2014) (2)
(10) Define: Cryoscopic constant. (Oet.2014,July2018) (1)
(11)Derive van'tHoffgeneralsolutionequation. (March 2015,2019; July2017) (2)
(12) 1.0x 10- kg ofureawhen dissolvedin0.0985 kg of a solvent,decreases point
freezing
of the solventby 0.211 K. 1.6x 10-3kg of anothernon-electrolyte solutewhen dissolved
e
in0.086 gof thesame solventdepresses the freezingpoint by 0.34K.Calculatethe
molarmass of the anothersolute. (Given: Molarmass of urea- 60] [Ans. 68.28g-mol-!](March 2015) (3)
(13) Define cbullioscopic constant.Write its unit. (Oct 2015) (2)
•
(14) What isthe effectof temperature on solubility ofgas in a liquid? (Oct 2015) (2)
(15) Define boilingpoint. Write the formula to determine molarmass of a soluteusingfreezing point
depression method. (March 2016) (2)
(16) The vapourpressureof pure benzene is 640 mm ofHg. 2.175 x 10 kg ofnon-volatile
solute is added to 39 gram ofbenzene,the vapourpressure of solution is 600 mm ofHg.
Calculate molarmass of solute.(C=12, H= 1]. [Ans.69.6x 10-3kg] (March2016) (3)
•(17) Why ismolality of a solutionindependent oftemperature?
(18) Define:(a)Osmosis (b)Freezingpoint.
(March2016) (1
(19) 3.795g ofsulphuris dissolvedin100 g of CS,.
(July2016) (2)
Thissolutionboils at319.81 K.What isthe molecular
formulaof sulphur insolution?The boilingpoint of CS, is319.45K.
-
[Given that K,forCcs, 2.42Kkg mol and atomic
S]
mass of S = 32.)[Ans. (July 2016) (3)
(20)StateHenry'slaw.
(21)A solutionofa substance havingmass 1.8x 10- kg has the (July2016) (1)
osmoticpressure
|Volume -l
of 0.52atm at 28OK.Calculate
dm',R- 8.314 JK-!
the molar mass ofthe
moti
(22) The boilingpoint of benzene is353.23K.
substanceused.
[Ans.79.49 g-mol-] (March 2017) (2)
When 1.80gram of non-volatile solute was
90 gram of benzene. The boiling dissolved
in
pointisraisedto 354.11 K. Calculate
|K,forbenzene 2.53K mot| themolar mass of solute.
(23) State Henry'sLaw. How does [Ans.57.5g-mol-I (March 2017) (2)
of a gas in watervaries
solubility with temperature
(24) Define:(a) Molality ? (July2017) (2)
(b)Osmotic pressure.
(July2017) (2)

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Summary of Board Questions 279
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(25) An organicsubstance(M = 169
at 12°Cwas foundtobe 0.54 is
gram mol-') dissolved
in2000 cm of water.Its osmotic pressur
the solute.
R-
atm. If 0.0821L atm.K-lmol-,calculate
the mass of
July2017) (2)
26) Derivetherelation
between elevation
[Ans.7.796 g]
ofboiling
pointand molar mass of solute. (March2018) (2)
(27)Define:
Semipcrmeablemembrane. (March2018) (1)
(28) (a)StateHenry's
law
(b)22.22gram ofurea was dissolved in300 gramsof water.Calculatethenumber of
molesofureaand molality of the ureasolution.
(Given:Molarmass of urea-60gramn mot')[Ans. (March2018) (2)
(29)Derivevan'tHoffgeneralsolution
0.3703mol;0.1234 mol kg]
equationfor n'moles of solute. (July2018;March 2019) (2)
(30) What isfreezingpointof a liquid?The freezingpointofpurebenzene is278.4K.Calculate the
freezingpointof the solution
when 2.0gramn of a solutehavingmolecularweight100 gram
added to 100 gram ofbenzene. (K, forbenzene-5.12kg mot [Ans.T 277.376K] (July2018) (3)
(31)Definethefollowing terms:
()Isotonic solution (ii)
Hypertonicsolution (lii)
Hypotonicsolution. (March2019) (3)
(32) Deine osmoticpressure.Writemathematicalexpressionbetweencryoscopicconstantand
molarmass of solute. (July2019) (2)
(33) Derive CRT. (July2019) (2)
(34) Definethefollowing:
(i)Molality
(u)Mole fraction. (July2019) (2)

(35)What istheconcentration of dissolved oxygen at50°Cunderpressure of one atrmosphere

ifpartialpressureof oxygen at50°C is0.14atm.
(Hienry'siauw constantfor oxygen 1.3 x 10- mol dm- atm-)[Ans.1.82x 10- mol-dm-"](March 2020) (3)
(36) Define: (a)Molality (b) Osmotic pressure.
(March2020) (2)
(37) Derive themathematicalexpression
elevaton ofboiling point. Stateand evnlatss
between molar o a non -volatile
-Avogadro's law.
solute and
(March 2020) (4)
(38) Define'Cryoscopic constant'. Derive the relation between clevation o f boilingpoint and
molarmass ofsolute. (Sept.2021) (3)
(39) What isthemolarmass of a solute ifa solution prepared by dissolving 0.822 g of it
in
0.3 dm ofwater has an osmotic pressure of 0. 196 atm.at 298 K? [Ans.34 1.9gmol-] (Sept. 2021) (3)
to calculatemolarmass of non volatile solute by osmotic pressure
(40) Derivean expression
mcasurement. (March 2022) (2)
constant for CH,Br,, is0.159 mol dm-3 bar-l at25°C.
(41) Henry'slaw pressureof 0. 164 bar?
What issolubility of CH,Br,inwateratsame temperatureand partial
[Ans.0.026 mol dm-31 (March 2022) (2)
terms:()Isotonic solution (ii)
Osmosis. (March 2022) (2)
(42) Define thefollowing
(ii)Ebullioscopic constant. (July2022) (2)
(43) Define: (i)Osmoticpressure pointof
ofcane sugarhas freezing pointof 271 K.Calculatefreezing
(44) 5%% aqueoussolution [Ans. 269.2 K] (July 2022) (2)
(Molarmass of cane sugar 342gmolJ
5% glucosesolution. 50 g of non-volatile solute
(45) The normal boiling pointof ethylacetate is 77.06 C. A solution of
Evaluatethe molarmass of solute ifK,for ethylacetate
is
in150 g of ethylacetateboils at 84.27°C.
[Ans.128 g mol-'] (July 2022) (2)
2.77K kg mol-!. (March 2023) (1)
(46) Writethe SIunit of cryoscopicconstant. temnperature is
fraction of solute,ifthe vapour pressure of pure benzene at certain
(471 Calculate themole 600 mm Hg. [Ans. Mole fraction0069
ofa solute inbenzene is
640 mmn Hg and vapourpressureof solution (March 2023)
solute by elevation of
determine molar mass of non-volatile
((48) Dcfne osmosis.How will
you
(March 2023) (3)
boilingpoint.
3 IONICEQUILIBRIA
2021,March 2022)
(Sept. (2)
between pH and pOH.
2) Derivetherelationship between solubilityand
Derivethe relationship
(2) Define'Solubility
solubility
(3) Calculate
product
product'.
for Pbl,
the pH of buffer
I
c
of0.01
solutioncomposea basel
M weak base BOH and
-
[Ans.pH 13.95]
(Sept. 2021) (3)

(March 2022) (3)

itss BA.
alt JK, 1.8x 10Sfor 7.568x 10-4 MI
ion.[Ans.
m

0.02M of of H,O* (July2022) (2)

is3.12.Calculate the concentratton
(4) The pH of solution dilutionlaw forweak acid. (July 2022) (2
ofOstwald's
(5) Derivean expression betveen and
solubility nroduct
solubility
Writethe relatonsnp
(6) Defne:Acidicbuffer solution. (March 2023) (2)
forPbCl, in 0.05 solution.What is percent dissociation
in 0.15 solution?
M
acidis10% dissociated
M

(7) A weak monobasic [Ans.%dissociation = 5.74%]I (March 2023) (2)

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 UTTAM's XII
Chemistry PapersSolution
280
oin ANOTSPROVIDER12TH BOARD
4 CHEMICAL THERMODYNAMICS
underwhich AU= AH? 2013) (March (2)
(1) Prove thatAH= AU + AnRT. What isthe condition
K.Calculatethe work done in when
joulcs the gas expands
gas occupies13L at 320
(2) 300 mol ofperfect
againsta constantexternalpressure
(a)isothermally of 0.20atm.
and reversible
(b) isothermal process.
(c) into
vacuum the volume of gas isincreasedby
until 3L. (R 8.314Jmot' K)
J (c) 0]
J (March 2013) (2)
[Ans.(a)-60.78 (b) -165.8
with reasonsignconventionsof AS inthe followingreactions:
(3) Explain
(u)Na+3H2| 2NH
(i)
COzg)
(March 2013) (2)
(4) CalculateAH° forthe followingreaction:
2H,BOs)
Given that:(a)H,BO3aq) HBO2lg) + -0.02kJ
H,O A H°,

(b)H,B,0, 2B,O)tH,O,y A H°,- 17.3kJ

2013) (3)
+ H,O0
(e) H,B,074) +4HBOalajy AH° --11.58kJ [Ans.AHO = +14.40kJ](Oct.

(5) What are theconditions for spontaneousand non-spontaneous

reactions
intermsof
freeenergychange ? Define entropy. (Oct.2013) (2)
(6) DerivetherelationAH - AU- AnRT. (Oct.2013) (2)
(7) Derivea relation
between AH and AU fora chemicalreaction. (March 2014) (2)
(8) One mole of a gas expands by 3L against a constantpressure
of 3 atmosphere.Calculate
the work done in
(a)L.atmosphere (b)Joules(c)Calories.[Ans.(a)-90L-atm (b)-911.7 J (c)-217.98cal.](March 2014) (3)

aA + bBcC
(9) Derivethe relation
between AG° and equilibrium
+ dD
constant(K) forthe reaction
(March 2014) (2)
(10) What isthe valueof AS,pu at 298K?
forthe followingreaction
Rk FreeBools
6COz + 6H,O0
Giventhat, aG0 -2879 kJ mol 4S --210J mol.[Ans.-9.451 kJ]
K (Oct.2014) (3)
(11)Stateand explainHess'slawofconstantheatsummation. (Oct.2014;July2018;March 2020) (2)
(12)Derivetheequation: W- P-AV. (March 2015) (3)
(13)Definethe followingterms:(a)Enthalpy
of fusion
(b)Enthalpy
ofatomization. (March 2015) (2)
(14) Determinewhether thereactionswith the following H and AS valuesare spontaneous
A
or non-spontaneous.
Statewhether the reactionsareexothermicorendothermic.
(a)AH- 110kJ, AS=+40 JK at400 K (b)AH= +40 kJ,AS = -120JK at250 K.
[Ans.(a)spontancousand exothermic(b)non-spontaneous and endothermic] (March 2015) (3)
(15)Writeone statementof first
law of thermodynamics and itsmathematicalexpression. (March 2015) (2)
(16)Derivean expressionfor maximum work inisothermalreversible expansionof two moles of an idealgas.
(Oct.2015) (2)
constantK,forthe reaction
(17) The equilibrium
Ha tL 2HIis130at510 K.CalculateAG° forthefollowingreactionatthe same temperature.
2HI Hap + Lgtu (Given:R 8.314JK-!mot'J [Ans.AG 20490 J] (Oct.2015) (3)
(18)State:
(a)Second law of thermodynamics interms ofentropy
(b)Thirdlawof thermodynamics.
(19)Writemathematicalequations (Oct.2015) (2)
of first
law of thermodynamics for thefollowing
(a) processes:
Adiabatic
process(b)Isochoric
process.
(20) Define Enthalpy
of sublimation. (March 2016) (3
How isit related
toenthalpy
of fusion
and enthalpy of vaporization?
(21)CalculateC-Cl
bond
(March 2016) (2)
enthaplyfrom following
reaction:
CH,C,+ Cl, CH,Clle+ HCI AH° -104kJ if H, C- Cl-
are414, 243 and 431kJ-mol-!
Cland H Clbond enthalpies -
respectively. [Ans.330 kJ mol-!]
(22)Explaintherelationshipbetween Gibb's (March 2016) (3)
standardenergy change of the reactionand
equilibrium
constant.
(23) Calculatethe standard
enthalpyof thereaction, July2016) (2)
2Cieraphae)
+3Hae +C,Hg ;AH° = ? from thefollowingAH° values:
7
(a)C,Haig t Oa10 2CO210 3H,O ;AHO = -1560 kJ
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Summary of Board Questions 2H1
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(b) H2 29 AHO -285.8
kJ
(e)Caphue) +Ozu9 +CO2 Muly 2016) (3)
;AHO-393.5k.J. AO
[Ans. kJ]
-84.,4
(24) Definetheterm'enthalpy'.
What will
happen to the (2)
internal
energyifwork isdone by the system? (March 2017)
sH forthereactionbetween etheneand water toform
(25) Calculate
AH°C,H,OH, -1368 kJ ;AH°C,H
ethylalcoholfromthe followine
Does the
-1410
kJ.
calculated AH° representthe enthalpyof formationof
liquid
ethanol?
AHO =42 kJ,
|Ans. isnot enthalpyof formationof liquid 2017) (3)
ethanol.] (March
(26) Derivean expressionformaximum work. (March2017) (2)
(27) Writethe mathematical expressionof thefirstlawof thermodynamics forthe followingprocesnes
(a)Isothermal (b) Adiabatic
(c) Isochoric(d) Isobaric. (July2017) (2)
(28) Calculatethe standardenthalpyof combustion of CH,COOH,from the following
dnta:
A,H° (CO,)= 393.3kJ mol';A,H°(H,o) --285.8kJmol:; (CH,COOH) -483.2 kJ mol".
(July20O17) (3)
[Ans.AHO-875 kJ mol-.]
(29) Distinguish between isothermal processand adiabatic July 201 7) (2)
process.
(30) Statethird law of thermodynamics. Give its
two uses. (March 2018) (2)
(31)Calculate
theinternal
energyat298K fortheformationof one mole ofammonia, ifthe cnthalpy
change at
pressureis-42.0kJ mol'.(Given:R -8.314JK
constant mol ) [Ans,-39.523
kJ] (March 2018) (3)

(32) Define:(a)Enthalpyofatomization(b) Enthalpyofvaporization. (March 2018) (2)

(33) 5 moles of heliumexpand isothermally

and reversibly
from a pressure40 x 10SNm? to 4 x 10* Nm 300 K. t
Calculatethework done,change ininternal energyand heatabsorbedduringthe expansion.
(R 8.314 motJK' [Ans.W,max --28.720
!) kJ,AU-0,q 287.720kJ] July2018) (3)
(34) Stateand explainHess'slaw of constanthcatsummation. (July2018;March 2020;2022) (2
(July2018) (2
(35) Writethe features of reversible
process.
(March 2019) (2)
(36) Writetheconditions formaximum work done by the system.
(37))Calculatethe work done inthefollowingreactionat 50°C.State whether work isdone
on thesystem or by the system.

+
SOe- [Ans.W=+1.343 kJ;Work is done on the system.
(March 2019) (3)
]
ofcombustion offormaldehyde 4, HO -571 kJ.
(38) The standardenthalpy (March 2019) (3)
How much heat willbe evolvedinthe formationof 22 g of Co,? [Ans.285.5kJ]
the work. Give reason. (July 2019) (1)
(39) Conversion ofcarbonintocarbon dioxidecan notperform
Classifythe followingproperties i nto intensivea nd properties:
extensive
(40) Definethe term enthalpy. (July2019) (3)
()
Pressure(ii) Density (ii)Work (iv)Heat.
chemicalreaction:
(41)Calculatethe work done by thefollowing
RR FreeBools
2NH,NO39)
373 K 2N.0,t
4H,O
on the system orby the system.
Statewhether thework isdone ] (July2019) (2)
[Ans.W =-18.62 kJ,work is done by the system.
kJ, 175.8JK-!.
(42) Forthe reaction:N,OAlg) +
2NOd i AH° = +57.24 ASO =
?
the reactionwillbe spontaneous
At what temperature (March 2020) (2)
will
be spontaneous.]
[Ans.T > 325.6K,thereaction
(b)Standard enthalpy combustion.
of
(a)Reversibleprocess
(43) Define: N2) + 3H2g2NHJ -
Calculatethe enthalpy change for the reaction:
are:
The bond enthalpies
N=N H-H N-H
Bond 389 (Ans.AHO = -83 kJ] (March 2020) (2)
946 435
AHO inkJ mol is
the system and 6 kJ of work
2 kJ ofheat is releasedby
(44) Ina particular reaction, [Ans. A U-+4 kJ] (Sept.2021) (2)
Calculate AU.
done on the system. + 2NH)
enthalpy of N,Ht Hae
thestandard
Calculate (N-N) 159 kJ mo
AH°(H-H) 435 kJ mol, AH°
(45)
if AHO (N-H)= 3 89 kJmol-,
[Ans.-184kJ] 2021) (3)
(Sept.
(i)
Enthalpy of sublimation.
property
(6)Define:(i)Intensive from 20L to30L
and reversibly
expanded isothermally
at 300 K.
2 molesan idealgas are
of [Ans.2023 J] 2021) (4)
(Sept.
8.314JK- mot
thework done.(R
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282
form 10 L to 15Lat300 K.
and reversibly
(47) One mole of an idealgas
iscxpandedisothermally (March 2022) (2)
|Ans,-1.0115 kJ]
Caleulatethe work done in the process.
the standardenthalpyof formationof CH,OH,,
fronthe followingdata:
(48) Caleulate

21,0,,: AHO 726 kJmol-!

COx
(i) CO cO AH393 kJ mol-!

:AHO m- 286 kJ mol-!

-+H,O, (March2022;July2022) (3)
[Ans. A,HO -239kJ mol-!.]
(49) Write the mathematicalcquation forthe first
law of thermodynamicsfor
(March2022) (2)
() Isothermal process(i) Adiabatic process. (July2022) (2)
(50) Detine therelationshipbetween AlH and'AU for gas phase reaction. (March 2023) (1)
(51)Write the correctcondition of spontaneity intermsof Gibb's energy. 10dm
C alculatethe work done during the expansionof2 moles of an idealgas from
(52) Deline cxtensivep roperty. (March2023) (2)
to20 dmat 298 K invacuum. [Ans.Work done 0, Freeexpansion.]
from 20 L to 30 L at 300 K, the work
calculate
gas espanded isothermally and reversibly
(53) 20O0 mmol of an ideal (March2023) (3)
done in the process(R 8.314 JK-1mol-'). [Ans.W.m,=- 2023.08 J.]
(March2023) (2)
(54) Deriverelationship
between AH and AU forgaseous reaction.

5 ELECTROCHEMISTRY ORR Pree Books

of the givensolution
of molarconductivity at
(2)State KohlrauschLaw and writemathematicalexpression
infinitedilution. (March2013) (2)
(March 2013) (2)
(2) Write the cell inleadstorage batteryduringdischarge.
reactions
(3) Inthe electrolysis
of AgNO, solution0.7g ofAg isdepositedaftera certainperiodoftime.
Caleulatethe quantity requiredin
ofelectricity coloumb,/Molarmass of Ag is107.9g mot"]
[Ans.626.1coulomb] (March 2013) (2)
(4) Write electrode
reactionand net cellreaction
for fuelcell.
Caleulatee.m.f.
of the folowing
cellat 25° C:
Zn|Zn2na(0.I
M) ||Cu°g)(0.5 M)|Cu
Standard (SRP) of Zn and Cu are-0.76
reductionpotential V and 0.334V respectively.
[Ans.Eel=1.114 V] (Oct.2013) (2
(5) State and explainFaraday's
second law of clectrolysis. (Oct.2013) (2)
(6) Resistanceand conductivityof a cellcontaining
0.001M KCl solution
at 298K are 1500 2
and 1.46x 104 S.cm- respectively. constant?[Ans.0.219cm-.]
What isthe cell (March 2014) (2)
(7) Statethefirst
and second law of electrolysis. (March2014) (2)
(8) Write any four'
applications
ofelectrochemical
series. (Oct.2014) (2)
(9) With the helpof the equation,AGO = -nFE° Cxplainthatcellpotential
isan intensive
property. (Oct.2014) (2)
(10)How much electricity intermsofFaradayisrequiredto produce:
(a)20 g ofCa from moltenCaCl, (b)40 g of Al from moltenAl,0,
(Given:Molarmass ofCalciumand Aluminiumare 40g.mot' and 27g.mot'respectively.)
[Ans.(a) 1F(b) 4.4F) (Oct.2014) (2)
(11)Draw neat and labelled diagramof drycell. (March 2015) (2)
(12)Arrange the followingreducingagentsinthe orderof increasing
strengthunderstandardstate
conditions.
Justifythe answer.

Element Al Cu Cagl Ni
1.66V 0.34V 1.36V -0.26
V
(March 2015) (2)
(13)CalculateEeland AG forthe followingat 28°C:
Mg,,+ Sn2* (0.04M) +Mg? (0.06M) + Sn E =2.23
V.
Isthe reactionspontaneous? [Ans.Egell 2.224V;G -429.2
kJ] (March 2015) (3)
(14)Can coppersulphatesolution be stored inan iron vessel? Explain.
(15)Resistanceof conductivitycellfilled (Oct.2015) (2)
with 0.1M KCl solution is100ohms, calculatetheconductivityand molar
conductivity of 0.02M KCl solution.(Given:Conductivity 0.1 is1.29Sm
MKCl solution
k
of
[Ans. = 0.00248S-cm-,A- 124
S.cm² mol-1.] (Oct.2015) (3)
(16) Define 'Molarconductivity.
(17) Define cell (March 2016) (1)
constant. Draw a neatand welllabelled diagramof primary reference
electrode. (March2016) (3)

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(18)
a solution
Conductivity of is6.23 105 'cm and itsresistance is 13710S. Ifthe electrodes
are 0.7cm
apart, (March 2016) (3)
calculate thecrOSS-sectional areaofelectrode.[Ans.a -0.82cm"1
(July2016)
(2)
19) Write Nernst equation and explain the terms involved.
201 The conductivity of0.02M AgN0, at25°C is 2.428x 103 2- cm-!.
July2016) (2)
2!
What isitsmolarconductivity? [Ans.A = 121.4 cm² mol-]
n What arefuclcells? Writecathode and anode reactionina fuelccll. (March 2017) (2)
221 0.05M NaOH solution offereda resistance of3 1.6W ina conductivity cellat 298 h
Ifthe cellconstantof the cellis0.367cm-!,Calculatethe molarconductivity of NaOH soluton.
2017) (3)
[Ans.A = 232.2 ' cm² mol -!] (March
(23) StateFaraday's firstlaw of electrolysis. (March 2017) (1)
124) Construct a labelleddiagramforthefollowingcell:
(July2017) (2)
Zn| Zn2° (1M) ||H° (1 M)|H,lg, 1 atm) |
Pt

(25) Writethe cellrepresentation and calculate equilibriumconstantfor the followingredox reaction:

Ni,+ 2Ag'a(1 M) Nia(l
M) +2Ag,, at 25'C; =-0.25 and E
0.799V V E°=2017) (3)
(July
[Ans.k= 2.754x 1035]
(March 2018) (2)
(26) Draw a neatand labclled diagramofleadstorage battery. (March 2018) (1)
(27) Define: Referenceelectrode.
chloride
ofelectricityarerequiredto produce 13 gram of aluminiumfrom aluminium 2018) (3)
(28) How many faradays (March
solution? (Given:molarmass of Al= 27.0 gram mot) [Ans.1.444 F]
Mg?|Mg halfcell and writethe cellreaction.
and Ag'|Ag half cell
(29) Represent a cell
c onsistingof
July2018) (2)
(E° 0.799V, E°M-2.37 V)

(30) How much quantity

incoulomb is requiredto deposit 1.346x 10-3kg of Ag in3.5minutes
of electricity
(Given: Molar mass Ag is108 x 1o kg mot)
from AgNO, solution? (July2018) (3)
of
[Ans.Q - 1214 coulomb)
(July2018) (1)
(31) Define resistivity. [Ans.0.50F|(March2019) (2)
arerequiredto produce 6g of Mg from MgCl,?
ofelectricity
(32) How many faradays
of 0.05M BaCL, solutionat 25°C is 2239- cm-!.
(33) The molarconductivity [Ans.k = 0.01152-'cm-] (March 2019) (2)
What isitsconductivity? (March2019) (3)
series. Write itsapplications.
(34) Defineelectrochemical cm² mol- at 25°C.Calculateitsconductivity.
0.02M is407.2
HCl solution
(35) The molarconductivity (July2019) (2)
of

[Ans.8.144x 10-3 glcm-!]

(July2019) (2)
diagram of H,-O,Fuel cell.
(36) Draw a neatlabelled hydrogen electrode.
(July2019) (2)
diagramof standard
(37) Draw a neatlabelled 0.463 V
of thefollowingcellis
(38) The standarde.m.f.
Cu,|Cu"eg (IM) l|
Ag(sg) lAgy
of Cu electrode2
potential
(1M)
is0.800 V,what isthe standard
of Ag electrode
Ifthe standardpotential [Ans. 0.337 V] Eu (March 2020) (1)
electrochemicalcell:
the following
cell and calculateE° cellof
reaction
(39) Writethe
Zn2*
||
Al,JA1(aq (IM)
(1M) [Ans. Eel 0.90 V] (March 2020) (2)
-1.66 Ez-0.76
V.
V,
E'A series (b) Corrosion.
terms:(a)Electrochemical series. (March 2020) (3)
(40) Define ofelectrochemical
Writetwo applications RT 2021)
(Sept. (1)
2.303 in Nernstequation.
(41) Write the value
of
F at 25°C is 18 N-! cm² mol!, in
Calculateitsdegree of dissociation
0.01 aceticacidthe molarconductivityofaceticacid atzeroconcentration
of M

(42) The molar conductivity constant,if

and dissociation [Ans.a = 0.015;K,=2.025x10-5](Sept.2021) (2)
0.01M solution of
is400 2 cm² mol-!. oIions.W te and explaintwo applications
independentmigration
(43) StateKohlrausch
law of
constant (Sept.2021) (4)
series. Writeunitofcell Zn 2* to Zn 2
electrochemical of 2 moles of
are requiredforreduction (March2022) (2)
(44) How many
moles of electrons be required
will ? [Ans.4 moles;4 faraday]
of electricity
How many faraday ofsaltb ridge.
Writethefunctions electrode (SHE).
(45) Definereference
electrode. hydrogen (March2022) (4)
diagram of standard
Draw neat,labelled and conductivity solution.
of (July2022) (1)
between molarconductivity
(46) Write relation Rk Free Booles
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284
(July2022) (1)
(47) Write cellrepresentationof standardhydrogen electrode.

.
of
application
Law of independent migration of ions. Write one
(48) State Kohlraush (July2022)
Kohlraush Law ofindependentmigration of ions. (1)
(March2023) (1)
isreference
electrode?
at 298 K is0.012cm!.
(49) What
the molar conductivityfor0.5M BaCl,ifits
conductivity
(50) Calculate
JAns.A 20 7 cm molI (March 2023)
enerevchange at25°C
(50) CalculatestandardGibb's forthe cellreaction:
E°.-0.136 V. [Ans.AGO--51.53
kJJ(March2023/|2)
Cd,
+ Sn20 Cdao + Sn,; E -0.403V,
(52) Draw labelled of fuelcell. (March 2023) (3)
diagram of H,-0, Write two applications
fuelcell.

6 CHEMICAL KINETICS
(1)Distinguish
between molecularity
and orderof the reaction.

(a)
(n)

-d[1]
g)t
(2) Considerthe reaction:

S0
(March 2008,2009,2011,

(b)
2
2020;Oct. 2008,2009,2010,2013,2014)

SO,-atparticular
What are the valuesof the followingatthe same time?
-a|s,o,?1
time

(c
t,2.2
-d[L1
dt
x 10-2M/s.
(2)

dt dt dt
|Ans.(a)3.3x 10-² M/s (b) 1.1x 10-2M/s (e) 1.1x 10-2M/s] (March2013) (3)
(3) Defineactivation
energy.Calculate energyfora reaction
activation ofwhich rateconstantbecomes
fourtimeswhen temperaturechanges from 30°C to 50°C.(GivenR 8.314JK-'mot').
[Ans.E,- 56.4 kJmol-!.] (Oct.2013) (3)
(4) Writemolecularity
of thefollowingreaction:
2NO+Oals -+ 2NOg) (March2014)(1)
(5) The decomposition ofN,Osg at320K accordingtothe followingequationfollows ârstorderreaction:

N,Osiel
Theinitial
Calculate
concentration
of N,Ostis1.24x
the rateconstant of thereaction
10² mol.L- and after60 minutes,
at320K.
0.20x 10-²mol. L'.
[Ans.k 0.0304min-"] (March2014) (3)
(6) Derivethe relation between half-life
period and rateconstantforfirst orderreaction.
(7) Sucrose decomposes inacidsolutionto give
(March 2014) (2)
glucose and fructoseaccordingto the first
orderratelaw.
The halflifeof the reaction
is3 hours.Calculatefractionof sucrose vhichwillremain after8 hours.
(8) Derivethe relation
[Ans.0.1576] (Oct.2014;March 2015) (3)
between halflife
and rateconstantfora first
(9) Define:
orderreaction. (March2015, 2017) (2)
(a)Averagerateofreaction(b)
Instantaneous
rateof reaction.
(10)Anmonia and oxygen reactat high (Oct.2015) (2)
temperature as:
4NHt 502 4NO6H,0
Inan experiment, of NO, is3.6x 10-mol L-!,
rateofformation s-l
Calculate:
(a)Rateof disappearance
of ammonia. (b) Rateofformationofwater.
[Ans.(a)3.6 x 10 mol-L-l.s-
(11)DefineZero orderreaction'. (b)5.4x 10 mol-L-l.
]
(Oct.2015) (3)
(12)Explain graphical method to determine activation (March2016) (1)
(13)Ina first energy of a reaction.
orderreaction x y,40% of the (March2016) (2)
Calculate rateconstantofthe reaction. given sample of compound remainsunreactedin45
minutes.
(14) The rateconstantof a firstorder reaction [Ans. 0.02036min-'] (March 2016) (2)
er
are0.58 s at313K and
What isthe energyof activation1for the reaction? 0.045s- at293 K.
(15)Write the Nernstequationand [Ans.96.85kJmol-] 2016) (3)
explainthe terms involve, (July
(16) Inthe Arrhenius
equationfora first order reaction, (July 2016) (2)
and 98.6kJ mol respectively. the valuesof 'A'
Atwhat temperaturewill and E.'
are 4 x 1013sec-l
R8.314JK- mot!] its
halflife periodbe 10 minutes?
(17) The ratelaw for the reaction [Ans.T =311.5
2H2g + 2NO,
The reaction
+Nae + 2H,O isgiven by rate
occursinthefollowingtwo steps:
K|H,][No?
K] (March 2017) (3)

(a)Hae + 2NO,@ N,OtH,O

ORR Free Boolks
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285
(b) N,O + Ha)
What istherateof N,O inthe
mechanism? What (2)
18) From thefollowing
rateconstant:
dataforthe liquid
phase
is the

reactionA - molecularityof theelementarysteps?(uy

B. determinethe orderofreactionand
caleuae
t/s 600 1200
[AJ/molL1 1800
0.624 0.446 0.318 (3)
19) A certain
reaction
0.226 J[Ans.Firstorder;5.6x 10-4s-] (July2017)
occursinthefollowingsteps:
CltOsie)
(i)
CIO,O2l0
(ii)CIO,+Ou C+Oz10
(a)What isthemolecularity
of each of theelementarysteps?
(b) Identify
thereactionintermediate and writethe chemicalequationfor overall
reaction. (March2018)
(2)
(20) The reaction A + B +
productsisfirst orderineachof the reactants.
(a)How does the rateof reactionchange if the concentration
of A isincreasedby factor3?
(b) What isthechange intherate of reactionifthe concentrationof A ishalvedand concentration
of B isdoubled? [Ans.(a)The rateof
reactionisincreased by factor3
(b)The rateof reaction remains unchanged.] (March 2018) (2)
(21)Definetheorderofchemical reaction.
Findtheoverall orderof thefollowingreactions:
(a)CHCIe) + Clag +
CCl + HCl Rate k[CHCI,)[CI,]
(b) 2NO, +Ogie) + 2NO,ely Rate - k[NO [O,] [Ans.(a)2 (b)3] 2018)
(July (2)

(22)Ina first
orderreaction
A- +
product,80% ofthegivensampleofcompound decomposes
(July2018) (3)
in40 min.What isthe half lifeperiodof the reaction? [Ans.17.22 min-!]
(23) WriteArrhenius equation.Derivean expression fortemperaturevariations. (March 2019) (3)
(24) The rateofa firstorderreaction, A + Bis5.4 x 10-6 Ms- when JAJ is0.3M.
Calculatethe rateconstant of the reaction. [Ans.1.8x 10-5s-] (March2019) (1
(25) The halflifeperiod orderreactionis6.0h.Calculatethe rateconstant.
of a fîrst (March2019) (1)
(26) The halflifeof frstorderreactionis6.0hours.How long itwill takeforthe concentration of
reactantto decreasefrom 0.8M to 0.25M. [Ans.t 10.07hours] (July2019) (3)
is
energy of activation 240 kJ mol-1,Calculatei ts
rate constant
(27) For a certainsecond orderreaction
at 1023 Kiftherate constant at923 is 0.0113m-l s-.
(R 8.314JK- mot)
[Ans.0.24 M- s-] (uly2019) (3)
(28) Defineelementaryreaction. (July2019) (1)
mechanism:
(29) A reactionoccurs by the following
NO2) Fa

(i)
Fe + NO210 +
NO,F
and write net reaction.
the intermediate
July2019) (1)
Identify
lifcof zeroorder reactionand itsrate (March
constant. 20o0
(30) Writethemathematicalrelation between half
pseudo orderreaction
first with
rate of Explain
reaction.
(31) Define instantaneous (March2020) (3)
suitable example.
law expressionforfirstorder reaction. 2021) (4)
(Sept.
Deriveintegrated
(32) Define isomorphism. with suitableexample.
orderreaction? Explain (Sept. 2021) (2)
(33) What ispseudo-first
2.303RT in Nernst equation. (Sept. 2021) (2)
(34) Write the valueof F
for halflifeand
Obtainthe expression
of first
order reaction.
(35) Definehalflife (March2022) (3)
orderreaction.
of the first
rate constant reaction:
the molecularityof followingelementary
(36) ldentify (September2021)(1)
NOtOe + NO3) +Og is three timesthe time requiredoro00
Show that timerequiredfor99,9 % completion o1 a nrstorder reacton
(37) (July2022) (1)
completion.
occursinthe followingsteps:
(38) A chemicalreaction (slow)
(6) NO + Fate + NO,Fg+ Fe (fast)
(ii) F + NOgNO,F reaction.
overall
(a) Writethe equation
of
ratelaw.
(b) Write down July2022)
reactionintermediate. (3)
(c) ldentifythe
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UTTAM'S XIl
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286
(March 202342
? DeriveinteeratedrateJaw equationfor zero orderrcaction.
(39) What isPseudo orderreaction
first times the time for Gos
required
completion orderreactionis three
of a frst
for
that timerequired 99.9% (March 2023) (2)
(90) Show
completion.

7 ELEMENTS OF GROUPS 16,

17 AND 18
(1)What isthe actionof the followingreagentsonammonia? (March 2013) (3)
(a) Excessof air (b) Excessofchlorine (c) Na mnetal
properties
withreference to group 16:
(2) Explainthe trendsinthe following
(a) Atomic radii
and ionicradii (b) Density
(March 2013) (4)
(c) lonisation
enthalpy (d) Electronegativity
(3) What isthe actionofchlorine(Cl)on the following:
causticsoda.
(a)Cold and dilutecausticsoda. (b) Hot and concentrated
(Oct.2013) (3)
(c) Potassiumbromide solution.
(Oct. 2013) (2)
(4) Writeelectronic and two usesof neon (Z - 10).
configuration
(5) Writeresonatingstructures
ofozone. (March2014) (1)
(6) Describeanomalous behaviourof fuorinewith theotherelements of group 17 with referenceto:
(a)Hydrogen bonding (March2014) (3)
(b)Oxidationstate(e) Polyhalideions.
(7) Describeanomalousbehaviourof oxygen as comparedwithotherelementsofgroup 16 with reference to
(a) Magneticproperty (b) Oxidationstate (e)Hydrides (Oct. 2014) (3)
(8) Draw the structure of:
(a) Orthophosphoricacid acid (Oct.2014) (2
(b) Pyrophosphoric

(9) Explain the structure of sulphur dioxide. (March2015) (2)

(10) Writemolecularformulaeand structures ofthe followingcompounds:
(a)Dithionic acid (b) Peroxy monosulphuricacid
(c)Pyrosulphuric acid (d)Dithionous acid (March2015) (4)
(11)Draw structures of: (a)Chlorine trifluoride (b) Chlorine pentafluoride. (2)
(12) What isthe actionof dioxygenon :
(a)Calcium (b) Iron (c) Carbon disulphide? (Oct.2015) (3)
(13) Writefour' usesof hydrochloric acid.
Writechemicalformula of the followingoxoacidsof chlorine:
(a)Hypochlorousacid (b) Chlorous acid (e)Chloric acid (d) Perchloric
acid. (Oct.2015) (4)
(14) What happens when dilute sulphuricacidis treatedwith (a) Fe (b) CaF, ? (July2016) (2)
(15) What happens when thin copperleavesarethrown injarcontainingchlorine? (July2016) (2)
(16) H,0 isliquidwhile H,S isgas at room temperature. Explain. (July 2016) (2)
(17) Writethe electronic configuration of the followingelements:
(a) Sulphur(Z = 16) (b) Krypton(2 36)
(March2017) (2)
(18) Writeany two'usesofeach ofthe following: (a) H,SO, (b) Chlorine
(19) What isthe actionof concentrated (March 2017) (2)
sulphuricacidon the following:
(a)Phosphorous pentachloride(b) Copper (c) Potassiumchlorate.
(20)Arrangethefollowingoxyacidsof chlorine: (July2017) (3)
HCIo,HCIO,, H CIO,and HCl0,with respect t o:
(a)Increasing orderof thermal stability (b) Increasingorderof oxidisingpower.
(21)Writebalancedchemicalequationsforthe following: July2017) (2)
Actionofozone on hydrogenperoxide.
(22) Writethe molecularand structural formulaeof: (March 2018) (1)
(a)Thiosulphuric acid (b) Dithionous acid
(23) Draw the structure IF,
of Writeits geometry and the typeof hybridization.
(March2018) (2)
(24) Explain thefollowing with the helpofbalanced chemicalequation: (March2018) (2)
(a) Bleachingaction ofSO,.
(b) Dehydrationofformicacidby concentratedH,So,
(c) Burningof benzene inpresenceof excessof
dioxygen.
(25) Writestructure (July 2018) (3)
and molecularformulafor sulphurous acid.
(26) Writeany fourpoints (July2018) (1)
of difference
between ffuorine and otherhalogens,
(July2018) (2
(27) Explainthe followingpropertiesof group 16 elements:
(i)Electronegativity (1)Meltng and boiling
points
(iii)
Metallic
character (iv)
Allotropy
(March2019) (4)
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(28) What are oxides?Write (4)

different
typesof oxideswith one example each. (March 2019)
129) Write the name of an inertgas
elementused inthe treatment of cancerby radiotherapy (July2019) (1)
ng The layerof 0zone acts asa protective (July 201 9) (2)
umbrella.,Explain.
33 Wite two uSes of cach of the following: (2)
(a)Helium (b) Neon. (March 2020)
22) Draw the structure of sulphurous acid.
Explain why nitrogen does not form
pentahalides, (March 2020) (3)
(33) Explain interhalogen
compounds.
How isoxygen preparedfrom the
following compounds ?
(a)KCIO, (b) PbO,. (March2020) (4)
(34) Write thenane ofinterhalogen compound of chlorine which has squarepyramidal
structure. 2021)
(Sept. (1)
(35) Draw the structureof sulphurous acid.Write two usesof helium. (Sept.2021) (2)
(36) Writechemicalequations duringmanufactureof sulphuric
involved acidby
contact process.
Writetwo usesof sulphur dioxide. (Sept.2021) (3)
(37) What isthe actionof concentrated H,SO,on:(i)CaF, (i)Cane sugar.
2021) (4)
What isnucleotide? Writereactionforthe preparation (Sept.
of polyacrylonitrile
(PAN):
(38) What isthe actionof seleniumon magnesium metal? (March 2022) (1)
(39) Explain thetrendsinthe followingatomicpropertics ofgroup 16elements:
(0)Atornicradii(ii)lonisation enthalpy (i)Electronegativity gainenthalpy.(March 2022) 14
(iv)Electron
(40) Writechemicalcompositionof haematite.Write the names and electronic
configurations
of firsttwo elementsofgroup 17. (March 2022) (3)
(41) Writechemicalequationfor preparation of sulphurdioxide from sulphur.
Writeusesof sulphur. (March 2022) (2)
(42) What isthe actionofchlorine
on the following:
) NH, (excess)(ii)
phosphorus?
(43) What happens when:
(July2022) (2)

()Ethenereactswith iodine
monochloride
(ii)
Sulphurdioxideisoxidisedinpresenceof V,0,
(li)Cu heatedwith concentrated H,S0 (July2022) (3)

(44) What compounds ? Writetwo uses ofneon.

are interhalogen (July2022) (2)
(March2023) (1)
(45) Write the chemicalcompositionof cryolite.
(46) Give reason: Group 16thelementshave lower ionisationenthalpy compared togroup 15h elements.
(March 2023) (2)
Write twousesof dioxygen.
dry bleach.
Bleachingaction of ozone is alsocalled (March2023) (1)
(47) Given reason:
Draw structuresof the followingcompounds:
(48)
acid (b)Peroxy disulphuricacid. (March2023) (2)
(a)Chloric
Explaina nomalous behaviour ofoxygen ingroup 16 with respectto:
(49)
Magnetic property(iüi)Oxidation state. (March2023) (3)
()Atomicity(ii)
TRANSITION AND INNER TRANSITION ELEMENTS
stateof manganese
(1) Writethe diferent oxidationstatesof manganese. Why +2 oxidation
(March 2013) (3)
is more stable?
terms:(1)Smelting(ii)Flux. (March 2013) (2)
(2) Explain the following
ofelements from first serieshaving
transition
Writeobserved electronicconfiguration
(3)
d-orbitals. (Oct.2013) (2)
halfflled contractien
of lanthanoid
contraction? Explain the cause and effects (Oct.2013) (3)
(4) What islanthanoid
What is the position of actinoidsinperiodictable? (March 2014) (2)
(5) What are lanthanoids? '?
'? How does itdiffer from 'roasting (March 2014) (2)
(6) What is 'calcination
formulaofthe following ores:
(7) Writechemical (d) Corundum.
(b) Haematite (c) Magnetite (Oct.2014) (2)
(a) Calamine meltingpoints
Why do these compounds have higher
(8) What areinterstitialcompounds?
puremetals? (March 2015) (2)
thancorresponding Explain its effects.
contraction. (March 2015) (3)
(9) Definelanthanoid
in the zone of reduction in blast furnaceduringextraction
(10) Writethe reactions involved
of iron. (March 2015) (2)
(Z= 26) inperiodic table?
of iron
(11)What isthe position JoinTelegram:- @NOTESPROVIDER12TH BOARD
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(Oct.2015)
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(3)
stable than Fe*?
2010;Oet. 2015;July 2016,
Explainwhy isFemore 2019) (2)
Lanthanoides and Actinoides. (March 2008,
(12) Distinguishbetween (Oet 2015) (2

(13)Define:(a)Hydrometallury(b) Electrometallurgy. (Murch 2016) (2)

ore of ironand zine ench.
(14) Write the names and chemicalformulaeof any one (Mareh 2016) (2
while Ti coloured?(Atomic number
Se-21, - 22).
T

(3
(15) Why is colourless (March2016)
Se
between lanthanoids and actinoids.
(16) What are (-blockelements?Distinguish (March2o16) (1|
(17) Explainthe term Interstitial
- compounds. (March2017) (2)
which are relatedto the colourof transitionmetal ions.
(18)Writethe factors stable?
oxidation statesof iron,Why oxidationstateofmanganese ismore
(19) Write the different (March2017) (3)
(Given:Z of Mn 25.)
why lanthanum (Z 57) forms La ion,
Explain,
contraction?
while
(20) What islanthanoid (July2017) (3)
cerium (2 58) forms Ce* ion?
(2)
of pure metalsfrom their
in the extraction
ores.July2017)
(21) Mention the names ofvarioussteps involved
(22) What isthe action ofcarbon on the followingmetaloxicde: (March 20 18) (1)
Fe,0,in blastfurnace. (July2018) (2)
(23) What are 'd'and T blockelements?
(24) What isthe action of the followingon lanthanoids?
(July2018) (3)
(a)Water (b) Sulphur,
heat (c) Nitrogen,heat.
What is the action of sulphur
(25) Explainthe positionof actinoidsinthe periodictable.
on lanthanoids?Calculate the magncticmoment of divalention in aqueous solutionif
itsatomicnumber is 24. (March2019) (4)
(26) Write note on Lanthanoidcontraction.Writetwo uses of KMIO, (July2019) (3)
(27) Explain Bessermization process. (July2019) (3)
(28)What is electrometallurgy? (March2020) (1)
(29)Writethe nane and chemicalformulaof one ore of zinc. (March2020) (2)
(30) Define flux.Writea note on leachingprocess. (March 2020) (3)

(31)Write the generalelectronic configurationoflanthanoids.Why are most of the

compounds of transition metalscoloured ? (March 2020) (3)
(32)Ironexhibits +2 and +3 oxidation states.Write their
electronic
configuration.
Which willbe more stable? Why? (Sept.2021) (2)
(33) Why La(OH),isthe strongestbase,while Lu(OH),is the weakestbase?
Write two applicationsofcatalyticpropertiesof transition
metalsand compounds. (Sept.2021) (3)
(34) Write the chemicalformulaofHaematite. (Sept.2021) (1)
(35) Define mineral. (Sept.2021) (1)
(36) Calculate spinonlymagneticmoment of divalent cationof transition
metalwith
atomicnumber25.SaltsofTi*arecolourless. Give reason.
(March 2022) (4)
(37) What is a Lanthanoidcontraction?
(March 2022) (1)
(38) Write the molecularformulaof the followingminerals:
() (i)
Chalcopyrite Calamine. (July2022) (2)
(39) What isa Lanthanoidcontraction? Write similarities
between lanthanoids
and actinojds. (July2022) (3)
(40) Give clectronicconfigurationofGd (Z - 64).
(March2023) (1)
(41) Distinguish between lanthanides and actinides.
(42) What areinterstitial
(March2023) (2)
compounds ? Give the classification
ofalloyswithexamples,
(March2023) (3)

COORDINATION COMPOUNDS
(1)Write theformulae of the followingcompounds:
(a)Sodium hexanitro-N-cobaltate
(l1)
(1)chloride.
(b)Tetraaquodichlorochromium
(e)Potassiumtetracyanoaurate
(2)Write applications
of co-ordination
()ion.
(March2013) (3)
compounds inmedicineand electroplating.
(Oct.2013) (2)
(3) What iseffectiveatomicnumber (EAN)?
Calculate
EAN of (Z -27) in(Co(NHJ
cobalt and zinc(230)in[Zn(NH,),l
of So,. (March2014) (3)
(4) Classifythe followingligandsinto monodentate and polydentate
(a) Amnonia (b)Carbon monoxide
(e)Ethylenediamine (d)Ethylenediaminetetra
acetateion.
(Oct. 2014) (2)

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Summary ofBoard Questions 289
(5) On the basisof
Witethe IUPACvalence bond theory explainthe nature of
name of bonding in(CoF 1on.
(March 2015) (3)
(6) Explaincationic |Co(NO,),NH),)
complexesand anioniccomplexes of (Oct. 2015) (2)
(7) nlustrate co-ordinationationcompounas.
withexample,the differencebetween a double saltand a co-ordination compound.men
(8) Explainthe terms-Ligand.
(March 2016)
1
(1
(9) Write the formula ofTetraminodichloroplatinum (1)
(V) chloride. (March 2016)
(10)Define ligand. Writefourpostulates of Werner'stheory. July 2016) (3)
(11) What is'effective
atomicnumber' (EAN)?
Calculatethe effective atornicnumber thecentralmetalatom inthe followingcompounds

of
(a)K,Fe(CN), (b)Cr(CO)6
Fe (Z 26) Cr (Z 24) (March 2017) (3)
(12)How ligands areclassified?Explain with suitableexamples. July2017) (3)
(13)Explain the geometry of[Co(NH,)3*on the basisof hybridisation. (March 2018) (2)
(Zof Co = 27)
(14) Write theformula
ofthecomplex Copper(I) (March 2018) (1)
hexacyanoferrate(1).
(15) Writethe formulafor pentaammine
chlorocobalt() (July2018) (2)
sulphate.
July 2018) (2)
(16) Explain the geometry of [CuNHJ|?*on the basis of hybridisation
[At.No. Cu= 29].
(17) What iseffective atomicnumber? Calculateeffectiveatomic number of
-
copper(Z 29) in[Cu(NH,),?*. (March 2019) (3)
(18) What isNesslert's reagent. (March 2019) (1)
2019) (1)
(19) Write IUPAC name of ([Pt(en),C1,)?
complex.
(July
(March 2020) (2)
(20) Calculatethe effective
atomicnumber (E.A.N.)ofcopper in [Cu(NH,J|2*. (Z ofCu = 29)
(21)What arebidentateLigands?Giveone example. (Sept.2021) (2)

(22) Writetwo applicationsofcoordinatecompounds. (Sept.2021) (1)

(23)Write IUPACname of(Fe(CO)]complex. 2021)

(Sept. (1)

(24) Writethe name of isomerisminthe followingcomplexes:

(March 2022) (1)
[Cu(NH,).[PrCI,]and Pr|(NHJ),|[CuCl,]
(March 2022) (2)
(25) Explainmonodentate and ambidentate ligands with example.
(March 2022) (3)
(26) Explaincationic,anionicand neutralsphere complexes with example.
(July
2022) (1)
(27) Calculate atomicnumber of Co* in(Co(NH,)JP* comple.
effective
complexes with examples.
2022)
(July (2
(28) Explainhomolepticand heteroleptic (2)
of Werner theory of coordinatecomplexes. (July2022)
(29) Writetwo postulates
used in the treatmentofcancer. (March 2023) (1
(30) Write the name of platinumcomplex
(March 2023) (1)
(31) Defne:Distereoisomers.
respectto:
formnationof[CoF]3complex with
(32) Explain
(i)
(1)Hybridisation Magnetic properties (i)
Inner/
outer complex (iv)Geometry. (March 2023) (3)
of (Co(NH),CL,. (March 2023) (2)
(33) Give cisand trans
isomers

10 HALOGEN DERIVATIVES
reactionsreadilywith attackof
(1) Why does p-nitrochlorobenzeneundergo displacement (March2013) (2)
nucleophilicOH- ion? of
chemicalequationsforthe action
(2) Write balanced
on propan-2-ol.
trichloride
(a)Phosphorus a peroxide.
(b)Hydrogen bromide
on styrene inthe presence of
propanoate. (March 2013) (3)
on silver
(c)Methylbromide profle diagrom
a ctivityo f acid.Draw a neat,labelledenergy
lactic
(3) Explainoptical (Oct.2013) (4)
forSN!reaction mechanism.
of lacticacid. (March 2014) (3)
the optical activity
(4) Discuss SN² mechanisms. (March 2014) (2)
between SN' and
(5) Distinguish
of -
(6) Writethe structures 2014 (3)
(b) 1-lodo-2,3-dimethylbutane(c)1,3,5-Tribromobenzene.(0ct,
fa)3-Chloro-3-ethylhex-1-ene effects.
environmental (March 2015) (2)
of DDT. Write its
(7) Draw structure reaction:
'A'and B'inthe following B'
(8) Identify
CH, -CHCH,
HBr A' alc. KOH (Oct.2015) (2)
of bromomethane.
hydrolysis (Oct.2015) (4)
the mechanism ofalkaline
(9) Discuss
from How
aniline? is chlorobenzene converted intodiphenvl?(Mareh 201E (2)
(10) How is chlorobezene prepared

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290

(11)Explainthe term - Optical

activity.
(March 2016) 1)
and 2-bromnopropane? (March2016) (2)
(12) How is propeneconvertedinto 1-bromopropane (July2016,2018)
(13) Write a note on Sandmeyer'sreaction. (2)

'A'
(14)ldentify and 'B'and rewritethe reactions.
CH,

(a NaNO,
HBr,273K
(A) Cu,Br,
(B) + N,t

(b) H,C-CH,- CH-CH, AlcoholicKOH (A)+ (B) 2KBr + 2H,O (July

2016) (2)
Br
(15)Define racemicmixture. (March2017) (1)
(16)Explainthe mechanism ofalkaline
hydrolysisoftert-butyl
bromide with energy profilediagram.
(March2017) (3)
(17) Define opticalactivity.
Explainopticalactivity
of lactic
acid. (July2017) (4)
(18) ldentifyA and B inthe followingreaction:

-
CH, Br + Mg dry etherA
+Co,
dryether
H"/H,0
+ B+ Mg(Br)OH (July
2017) (2)

(19) Explainonly reaction

mechanism foralkaline hydrolysisof tert-butylbromide. (March2018) (2)
(20) Tdentify'A'
and 'B'inthe followingreactionand rewritethe complete reaction:
CH, -CH,-Br+ AgCN
Na
-A -+B (March2018) (2)
(21) Identify
A and B from the followingreaction
and rewritecompletereaction:

-CH,CI+ Mg
dry ether
AH,O,B MgCl(OH) + (July2018) (2)
(22) Complete and rewritethe followingchemicalreaction:
1-Chloro -2,4-dinitrobenzene 49 alkal
368 K,H (July2018) (1)
(23) What isthe action ofthe followingon ethylbromide:
() Alcoholicsolutionof potassiumhydroxide
Moist silver
(ii) oxide
(iüi)Silveracetate?
(24) Define Enantiomers. (March2019) (3)
(25) What isGrignardreagent? (March2019) (1)
(26) Explain the roleof iodic (March2019) (1)
acidinthe preparation of ethyl
iodide from ethane.
Dilacticacidisopticallyinactive. Why?
(27) Writethe reaction for preparation
(July2019) (3)
of Grignard'sreagent.
(28) Writeconversionof 2-bromobutane into (July2019) (1)
unsaturatedhydrocarbonby using alcoholic
(29) Defineoptical KOH. (July2019) (1)
activity.How many optical isomersare possibleforglucose?
(30) Writethe chemicalreactions of chlorobenzene with respectto:
(March2020) (2)
(a)Sulphonation (b)Acetylation (c) Nitration.
(31)What isthe action ofthe followingon chlorobenzene? (March 2020) (3)
(i)Methylchloride inpresence ofanhydrousAlCL,
(ii)Fuming H,SO,
(32)Explain SN² reactionmechanismn foralkaline (Sept.2021) (2)
hydrolysisof bromomethane.
(33) Write the productformed when alkyl (Sept.2021) (3
halidereactswith silver
nitrite.
(34) What isthe action of the followingon ethylbromide? (March 2022) (1)
() Na indry ether(i)Mg indry ether.
(35) Writechemicalreactions forthe followingconversions: (March 2022) (2)
()
Ethylbromide to ethylmethylether (iü)Ethyl
bromide to ethene
(iti)Bromobenzene to touene. (iv)
Chlorobenzeneto
(36) Convertethylbromide to:(i)Ethyliodide(iil) biphenyl. (March 2022) (4
Ethyl fluoride.
LI37)Write four salientfeatures
of S,l mechanism. July 2022) (21
(38) Write thestructure
of the product
formedwhen chlorobenzene is July2022) (2)
inthe presenceofdry ether. treatedwith sodiummetal
(March 2023) (1)
RR FreeBools
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Summary ofBoard Questions
291
(291 Writethe
chemicalreactionsforthefollowing:
(a)Chlorobenzene isheatedwith
(b) Ethyl fumingH,SO,
bromideisheatedwith (2)
(40)
silveracetate. (March 2023)
Explain dehydrohalogenation
Writeuse reaction of2-chlorobutane.
and environmental
effectof CFC. (March 2023) (3)

11ALCOHOLS, PHENOLS AND ETHERS

(1)How isethanolpreparedfrom
methanal by usingGrignard (March 2013) (2)
(2)Explainthe mechanism of actionof reagent?
(March 2013) (3)
(3)How isphenolconvertedintothe hydroiodicacidon 3-methylbutan-2-ol.
following?
(a) Benzene (b) Benzoquinone (c) Picric
acid. (Oct.2013) (3)
(4) How ismethoxy benzene (Oct. 2013) (2)
preparedfrom carbolic
acid?
(5) Writethestructural
formulaand IUPACnames of allpossibleisomersof the
withmolecularformulaCH,0. compoud (4)
Writetwo' uses of phenol. (March 2014)
(6) How ismethoxyethane preparedfrom methyliodide. (March 2014) (1)
(7) What isthe actionof the following
reagentson phenol-
(a) BromineinCs,at low temperature (b) Conc. H,S0,
at room temperature. (Oct. 2014) (2)

(S) Wite the structureand IUPACname ofall the metamerism representedby formulaC,H,o.(0ct. 2014) (3)
(9) How iscarbolicacidpreparedfrom the followingcompounds:
()Aniline(ii)
Chlorobenzeneand steam at69SK? (March2015) (2)
(10)Mentiontwo'physicalproperties ofcarbolicacid. (March 2015) (1)
(11) How arethefollowing compunds prepared?
(a)Benzyl alcoholfrom benzylchloride. (b) Propan -1-ol
from propanal. (Oct.2015) (2)
(12)How iscarbolic
acidpreparedfrom chlorobenzene? What isthe actionofbrominewater on
carbolic
acids?Writechemicaltestto distinguishbetween carbolicacidand alcohol. (Oct. 2015) (3)
(13)Writethe reactionsinvolvedindehydrationof 1,2° and 3 alcohols. (March2016) (2)
(14)What ismetamerism? Explainmetamerism withsuitable examplesofethers. (March 2016) (2)
(15)What ismetamerism? Writethe structureandIUPACname of 'methyl-n-propyl ether.
What istheactionof hot HIon it? (July2016) (3)
(16)How are the followingconversions
carricdout?
acid.
into2-methylbutanoic
(4) 2-Methylbutan-1-ol
PhenyletheneintoBenzoicacid
(ii)
acid.
Benzoic acidintometanitrobenzoic
(iüi) (July2016) (3)

(17) Definecarbolic acid.How carbolic acidispreparedfrom benzene sulphonicacid? (March 2017) (2)
etherpreparedby continuousesterification process? (March 2017) (2)
(18) How isdiethyl
propan-2-ol and 2-methylpropan-2-olfrom Grignard'sreagent?(July2017 (3
(19) How willyou prepareethanol,
cumene? (July 2017) (2)
(20) How is phenol preparedfrom
a cidfrom benzene acid?
sulphonic Write a chemicalequation forthe
(21)How will you prepare carbolic
actionof neutral ferricchlorideon phenol. (March 2018) (3)
boilingpoint than ethane? (March 2018) (2)
(22) Why ethanol has higher
from cumene? What happens when phenol is heated
(23)Write a preparation ofphenol
(July2018) (3)
with zincdust?
on isopropylmethylether? (a)cold HI (b)hot HI (July2018) (2)
(24) What isthe actionof the following
(March 2019) (1)
(25) What are ethers?
chemical equations forthe following:
26) Write balanced
metal on ethanol
(a)Actionof sodium
of zincdust on phenol. (March2019) (2)
(b) Action
OH

of(CH,),CCH- C,H,.
- (July
2019) (1)
(27) GiveIUPAC name
Ethoxyethaneintoethanol. (July 2019) (1)
(28) Writethe followingconversion:
ofethanol. (July2019) (1)
(29) Give two uses
IUPAC name of pyrogallol. (July
2019) (1)
(30) Write when acetaldehvde is
structuralformula of the alcohol thatresults
(31)Write etherand the productishydrolvsed.
reactedwith CH,MgBr in the presence of dry (March2020) (1)

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TTAM's XItCheimisthy Papers Solution
292
(March 2020) (2)
of diethyl
process for the preparation ether.
(32) Explainthe continuousetherification
(33) How is ethanolpreparedfronthe followingcompounds: (March 2020)
(a)Ethanal (b)Ethene (c)Bromoethane. (3)
(Sept. 202 1) (2)
(34) Write a note on Kolbe reactíon.
(35) Convertthe following:
) Chlorobenzene to phenol (u) Ethanalto ethanol
(36) Write the preparation of phenolfrom aniline.
(iil lodomethane to methoxy methane. (Sept.2021)
(March 2022)
(a1

(2)

(37) Write chemicalreactions of followingreagents on methoxyethane: (March 2022)

(u) Hot HI () PCI, (ii)
(3)
Dilute H,SO4
(July2022) (1)
(38) Write the name of reaction duringconversionof phenol to salicyclic
acid.
(39) Writebalancedchemicalreactions of the followingreagentson carbolicacid:
(July2022) (2)
(i)Br,water(i)Concentrated HNO,.
(July2022) (2)
(40) What happens when vapoursof 1' and 2' alcoholsare passed overhot Cu metal?
Aceticacidintoethylalcohol. (March2023) (1)
(92)Write chemicalreactionsforthe followingconversion:
(42))Convertthe following:
(1)Ethylalcoholintoethylacetate
(u) Phenol into
benzene
(i)
Diethyl
etherintoethylchloride. (March2023) (3)
ofPhenol.What isthe action of bromine wateron phenol?/March2023) (2)
(43) WriteDow process forpreparation

12 ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

(1)How is4-methylpent-3-en-2-one
obtained from propan-2-one? (March2013) (2)
(2) How arethe followingcompounds prepared?
(a)Benzaldehydefrom benzene.
(b)Acetophenone from benzene.
(e)Benzaldehydefrom benzoyl chloride. (March2013) (3)
(3) Mention 'two'uses of propan-2-one. (March2013) (1
(4) Explainthe mechanism of aldolcondensation. (Oct.2013;March 2015) (3
(5) How isbenzophenone preparedfrom benzonitrile? (Oct.2013;July2016;Mareh 2018) (2
(6) Write a note on aldolcondensation. (March2014,2017;July 2022) (2)
(7) Write a note on self
oxidation-reduction
reaction
of aldehyde withsuitable
example. (March2014) (2)
(8) Identify'A'
and B'inthe followingreaction :CH,MgBr + Co,
Dry ether
A' B' (0ct.2014) (2)
(9) Writethe structure
and IUPACnames of all
the metamers represented C,H,0.
by formula (Oct.2014) (3)
(10) Writebalancedchemicalequationsforaction of ammonia on -
(a)Formaldehyde (b)Acetaldehyde (c)Acetone.
(Oct.2014) (3)
(11) Write a note on Friedel
Craft's
acylation. (March2015) (2)
(12)Explain,why are boiling pointsof carboxylic
acidshigherthan correspondingalcohols.
(13) Writethe structures (March2015) (2)
and IUPACnames of the followingcompounds:
(a)Adipicacid (b)a-methylbutyraldehyde
(March2015) (2)
(14) What isStephenreaction?
(15) Writethestructureand IUPAC (Oct.2015) (2)
names of isomeric
aldehydeshavingmolecularformulaC.H.,,0.(Oct.
(16) What areketones?How are ketonesclassiñied?
2015) (4)
(17) Explainthemechanism ofesterification.
(March2016) (2)

(18)WriteIUPACnames ofthe followingcompounds : (March 2016) (4)

(a) CH, (b)CH,– -- CH,

July2016) (2)
(19) How isethanoicacidpreparedfrom dryice?
(20) GiveIUPAC name of CH-CH,-CH-CHO. (March 2017) (2)
(21) What isthe action of the followingreagentson (March 2017) (1)
prepanone?
(a)Phenylhydrazine (b)
(22) Writea note on self
Zn-Hg/conc. HCI ()Sodium bisulphite. July2017) (3)
oxidation-reduction reaction
ofaldehydewith suitable
example. July 2017) (2)

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Summary of Board Questions 293

(23)Complete and rewritethe balanced
chemicalequations:
(a)Chlorobcnzene NaCN CuCN
473K, pressure ?
50%
(b) Isobutyraldehyde KOH ?
(c)Butanone+2,4-dinitro-phenyl (3)
hydrazine h ? (March 2018)
(24) What isthe action ofthefollowingreagentson
ethanoicacid?
/
(a)LiAlH,E,0* b) PCI,,
(c) P,0,,
heat heat. (March 2018) (3)
(25) Conpleteand rewritethebalancedchemicalequationforthe
followingreactions:
(a)Benzaldehvde s0% KOH

(b) Acetone + phenylhydrazineH +? 2018)

(July (2)

(26) Writebalanced equations

forthe following conversions:
(a)Cyclopropane carboxylic
acidtocyclopropylmethanol.
(b)Acetylchloride
to benzylmethylketone usingdialkyl
cadmium. (July2018) (2)
(27),Writechemicalcquationforthe following:
Fischeresterification. (March 2019) (3)
(i)Gatterman-Koch formylation(ii)
Rosenmund reduction (ii)
(28) How willyou convert:
()Calciumacetateto acetaldehyde (i)Acetone to acetone cyanohydrin
(iii)
Sodium acetateto methane (iv)Benzoic acidto m-bromobenzoic acid? (March2019) (4)

(29) Convert thefollowing:

(i)
Ethanalintoethanal cyanohydrin
(July2019) (2)
(ii)
3,5-Dinitorbenzoic acidinto3,5-dinitrobenzoyl
chloride.
(30) How are thefollowingconversioncarried
out?
2019) (1)
(July
Dry ice intoethanoicacid.
2019) (2)
(July
(31)Writealdolcondensationreactionbetween ethanaland propanal.
anhydrideusingaceticacid. (March 2020) (1)
(32) Write balancedchemical reactionforpreparation
of acetic

(33) ldentify'A'and 'B'in thefollowingreaction:

Zn-Hg (March 2020)(1)
A HCL.
B + H,0
+ CH,COCi Conc.
A
- HCI

additionreaction. Mention two usesofcarboxylic acids. (March2020) (4)

(34) Explainthe mechanism of aldol
conversion ofacetaldehyde to
(35) Write the name ofreagentused during (Sept.2021) (1)
acetaldehyde cyanohydrin.
? (Sept.2021) (2)
from benzonitrile
(36) How isbenzophenone prepared Write chemical
of ethanal.
(37) Writea note on 'aldol'condensationreaction
istreatedwith concentrated causticpotash. (Sept.2021) (4)
reactioninvolvedwhen benzaldehyde
is treatedwith 2,4-dinitrophenyl (March
hydrazine. 2022)(11
(38) Writethe name of productformed,when acetone
reaction:
(39) IdentifyA and B from thefollowing
CH,
2CH,- -0
Ba (O), A A+B+ H,0 (March 2022) (2)
:
of aceticacidfrom
(40) Writepreparation (Mareh 2022) (2)
Acetylchloride.
() Dry ice(ii) isthe action of
of aliphaticketoneswith example.What
(41)Writethe classification (March 2022) (2)
on acetone?
sodiumhypoidite acid. July2022) (1)
1UPAC name of a-methylpropionic
(42) Writethe on carboxylicacid:
of thefollowing
(43) What istheaction July2022) (2)
() (i)
soCl, P,0,?
acidsto: (i) Acidamide.
Ester(ii) July2022) (2)
(44) Convert carboxylic ofethanal. (March 2023) (3)
condensation
(45) ExplainAldol reaction. (March 2023) (2)
on Haloform
46) Writea
note

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294 Join Telearam:-GUTTAM's XIh ChemistryPapcrs Solution

13 AMINES
(1)What istheactionof bromine inalkaline
medium on:
(a) CH,CH,NO, (b) CH,-CH- NO, (March2013) (2)

CH,
(2) Writea shortnote on Hoffmann bromamide degradation. (March2013) (3)
(3)How isnitromethane prepared from the following?
(a)Alkylhalide (b)a-Halogen carboxylic acid (e)a-Nitroalkene. (Oct.2013) (3)
(4) Explain Hoffmann bromamide degradationreaction. March 2017,2018)
(Oct.2013; (21
(5) What isthe actionof the following
reagentson aniline?
(a)Brominewater (b) Aceticanhydride(c)Hot and conc. sulphuricacid. (March 2014) (3)
(6) ldentifythe compound 'A' and B' inthefollowingequation:
-
CH, CH,+ HNO,
423-600K
+
'A'Sn/conc.HCI B'+ H,0 (March 2014) (2)

() What will
be theactionof the mixture
ofsodiumnitrite
and dilute
hydrochloric
acidon:
(a)Ethyl
amine (b)Aniline(c)Triethyl
amine? (Oct.20O14) (3)
(8) How are propan-1-amine and propan-2-amine prepared from oxime? (Oct.2014) (2)
(9) How isethylamine preparedfrom methyl iodide? (March 2015) (2)
(10) Writea note on Gabrielphthalimide (March 2015)
synthesis. (3)
(11) What isthe actionofaceticanhydrideon:
(a)Ethylamine (b)Diethyl amine. (Oct 2015) (2)
(12) What isthe actionof nitrous acidon:
(a)Primarynitroalkane (b) Secondary nitroalkane (c)Tertiarynitroalkane. (Oct.2015) (3)
(13) How are:(a) 1-Nitropropane and
(b)2-Nitropropane preparedfrom suitableoxime? (March 2016) (2)
(14)How are1-nitropropane, 2-nitropropane and 2-methyl-2-nitropropane
are distinguished
from each otherusingnitrous acid? (March 2016) (3)
(15) What isthe actionofbenzene diazonium chloride on:
(a)Phenolinalkaline medium (b)Aniline. (July 2016) (2)
(16) Identify'A'
and 'B'and rewritethe reactions:
Ag,0/H,0
C,H,-
N(CHJ),I" A
A
H

+ B+ (CH),N+ H,0 (July2016) (1)

(17) What isthe actionof mixtureof NaNO, and dil.HCI
on:
(a)Ethylamine(b)Aniline(e)Diethylamine (March 2017) (3)
(18)How isnitroenthane convertedinto:
(a)Ethylamine (b)N-ethylhydroxylamine (e)Aceticacid? (July2017) (3)
(19)How isethylaminepreparedfrom (a)Nitro-alkane(b)Oxime?
Explainbasicnatureofamines. (March2010;Oct. 2009;July2017) (4)
(20) What istheactionof p-toluenesulphonyl on cthylamineand diethylamine?
chloride (March 2018) (2)
(21) What istheactionof lithium
aluminiumhydrideinthepresenceofetheron the followingcompounds?
(a) Nitroethane(b)2-Methyl-1-nitropropane.
(July
2018) (2)
(22) Write resonance structures
of aniline.
What isthe actionofbenzene diaozonium chloride
on ethanol?
(July2018) (2)
(23) Writethestructure ofPhenylmethanamine. (March 2019) (1)
(24) Writea shortnote on Hoffmann elimination. (March 2019) (3
(25) What areamines?
(March 2019) (1)
(26)Writethefollowingconversion: Acetaldoximeintoethylamine. (July 2019) (1)
(27) Amines are basicinnature. Explain.
(July2019) (2)
(28) Convert benzene diazoniumhalide intoaryliodide. (July2019) (1)
(29) What istheactionofbenzene sulphonylchloride on ethanamine?
(July2019) (1)
(30) Define:Quaternary ammonium salt.
(March 2020) (1)
(31)Writethe chemical reactioninvolvedinthe formationofethylamine using acetaldoxime.
(March 2020) (3)
(32) Writereactions to prepare ethanaminefrom:
()
(33) How will
()
Acetonitrile Nitroethane (ii) Propionamide. (Sept. 2021) (3)
you convert
(4)Methyliodide to methyl isocyanide.
(iü)Methyl cyanide toethanoic acid? ORR FreeBools (Sept. 2021) (3)
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Summary of Board Questions 295

(34) Write chemicalreactions to prepareethananinefromn:
(i)
Acetonitrile Nitroethane. (March 2022) (2)
(35) Writetheformulaof Hinsberg's reagent. (July2022) (1)
(36) Writechemicalreactionfor carbylaminetest. (July2022) (1)
(37) Complete the followingreactionand identify
A and B.
PBr,
Isopropylalcohol NH,B
excess
(July2022) (2)

(38) Writethe name the product formed by the action of LiAIH, (March 2023) (1)
/ether
on acetamide.
of
(39) Writechemical reactionsfor the followingconversion:
Aceticacidintoaceticanhydride. (March 2023) (1)
(40)WriteIUPAC name and structure ofmethylphenylaminc. (March 2023) (1)
(41)What isthe actionof the followingreagerntson ethyl
amine.
(i)Chloroformand causticpotash(i) (March 2023) (3)
Nitrous
acid.

14 BIOMOLECULES
(1)Writethestructures
of nucleotideand nucleoside. (March 2013) (2)

(2) Enlist
theproperties
ofglucose thatcannotbe explained
on the basis
of open chain
of it.
structure (Oct.2013) (3)

(3) What happenswhen glucose istreatedwith

(a) Bromine water (b)Dilute nitricacid (c)Hydrogen cyanide (HCN). (March 2014) (3)

(4) Describelaboratory method for preparation of glucose.Write the reactionthatindicates

-
thepresenceof CHO group inglucose. (Oct. 2014)
(Oct.2014)
(3)
(2)
(5) Draw thesimpleFischerprojection formulae of D-(+)-glucoseand D-(-fructose.
(March 2015) (2)
(6) How areproteinsclassifed on the basisof molecularshapes?
(7) Definecarbohydrates. What are reducingand non-reducing sugars? (March 2015) (3)
(Oct.2015) (2)
(8) What aremonosaccharides?Draw ring structure of a-D- (+)-glucopyranose ?
(9) What ispeptide linkage?How istripeptideformed? (Oct.2015) (3)

What arecarbohydrates? (March 2016) (1)

(10)
(11)What isthe actionof followingreagentson glucose?
(a)Bromnine water (b)Dilute HNO, (c)Hydroxylamine. (July2016,2018) (3)

(12) How isthe glucose preparedfrom sucrose ?

(March 2009, 2017; July2022) (2)

(13)Defineenzymes. How is peptide linkage formed? (July2017) (3)

is treatedwith:
(14) What happens when glucose
(July2017) (2)
(a)Hydroxylamine (b)Hydrogen cyanide.
suger? (March 2018) (2)
(15) How glucose isprepared fromn cane
forformation ofpeptidebond between
(16) What areamino acids?Writethe correctreaction
amino acids. (March2018) (2)
from starch? (July2018) (2)
(17) How isglucose prepared
the structureof Thymine. (July2018) (1)
(18) Draw
Write the number hydroxyl groups present ina-D-(+) – Glucopyranose (trans). (March2019) (1)
(19) of

method? How is peptide linkage formed? (March2019) (3)

(20) How isglucose preparedby commercial
(July2019) (3)
(21) Define enzyme.
carriedout?
(22) How are the followingconversion
-hexane (i) G lucose intoglucoxime? (Juty2019) (21
(4)Glucose into n

formulaof a-D-(+)-glucopyranose. Define hormones (March 2020) (2

(23) Write Haworth projection
Explain denaturationof proteins. (March 2020) (3)
(24) What aremonosaccharides?
the name of sugar presentinRNA. (Sept. 2021) (1
(25) Write
(26) Writeclassification of proteinson the basis of molecularshapeswith examples. (Sept. 2021) (2)

of linkage in proteinwith an example. (March 2022) (2)

(27) Explainformation peptide
(28) Write commercial method of preparation f glucose.Write structureofadipicacid. (March 2022) (3)

of protein? (July
2022) (1)
(29) What isdenaturation
of glucose from sucrose.
forthe preparation
(30) Write chemicalreaction
o f D -ribose. (March 2023) (2)
Write structure
(March 2023) (1)
(31) What is peptide bond.

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 15 INTRODUCTION TO POLYMER CHEMISTRY
(1)Explainthe following
terms:
()Homopolymers (ii)
Elastomers. (March 2013) (2)
(2) Writethechemicalreaction
to preparenovolacpolymer. (March2013) (2)
(3) How are polymersclassified
on the basisofpolymerisation
process? (Oct.2013) (2)
(4) Writethe structure
of melamine. (Oct.2013) (1)
(5)Writenames andchemicalformulaeofmonomers used inpreparingBuna-S. (March 2014) (2)
(6) What arethemoplasticpolymers? (March 2014) (1
(7) How isNylon6,6prepared? Writeany "two'uses of terylene. (Oct.2014) (3)
(8) Explainwithexamples,branchedand linear polymers. (March 2015) (2)
(9) What arebiodegradablepolymers and non-biodegradablepolymers?Write'one example'of cach.
(March2015) (2)
(10)Writethereactionsinvolvedinthepreparation of - (a)Teflon
(b) Orlon(e)PVC. (Oct.2015) (3)
(11)Writethereaction
forthe preparationof Nylon-6. (March 2016) (1
(12) How arepolytheneand neoprene prepared? (March 2016) (2
(13) Writethe formulaeoftheraw materials ofBuna-S.
used forpreparation (July 20o16) (1)
(14) How arethefollowing polymersprepared?
(a)Orlon (b)Teflon (July20O16) (2)
(15) Explaintheterm:Homopolymers (March 2017) (2
(16) How isnylon 6,6prepared? (March2017) (1)
(17) How isTeryleneprepared? July 2017) (2)
(18) Writethe names and chemicalformulaeof monomers used inpreparing Buna-N. July 2017) (2)
(19)Explainthepreparation andusesofnylon-2-nylon-6. (March2018) (3)
(20) What areelastomers?
Distinguishbetween thermoplasticpolymersand thermosetting
polymers. (July2018) (3)
(21) Writechemicalreactions to preparethefollowing
polymers:
() Teflon (i) Nylon-6 (March2019) (3)
(22)Writethe reactions of polymersby using
forthe preparation thefollowing
monomers:
(i) (i)
Vinylchloride Tetrafiuoroethane. Juty2019) (2)
(23) Define:(i)Condensationpolymer (i)Homopolymer. (July 2019)(2)
(24) Define non-biodegradable
polymer.Writethe preparation
of terelyne. (March2020) (2)
(25)Writenames and structure
of monomers used inthepreparation
ofNylon6,6 polymer. (Sept.2021) (2)
(26) Writeclassification
of polymerson the basisofstructure. (March2022) (3)
(27) Writethename ofbiodegradablepolyamidecopolymer. (March 2022) (1)
(28) Writethe name of monomer used forpreparationofNylon 6. (July2022) (1)
(29) Writechemicalcomposition
ofZieglar-
Nattacatalyst. (July2022) (1)
(30) Define:Elastomer.
(July2022) (1)
(31)Writethereactionsfortheformationofnylon6,6 polymer. (March2023) (3)
(32) Define:Vulcanization. (March 2023) (1)
16 GREEN CHEMISTRY AND NANOCHEMISTRY
(1) Writethename ofnanostructural material
used intyrestoincreasetheirlife. (Sept.2021) (1)
(2) Explainthreeprinciplesofgreen chemistry. (Sept.2021) (2)
(3) Writethe name of thealloyusedinFischerTropschprocess inthe synthesisofgasoline. (March2022) (1)
(4) Definegreenchemistry. Writetwo disadvantagesof nanotechnology. (March2022) (2)
(5) Define: Nanochemistry. (July2022) (1)
(6) Define:Nanotechnology. (July2022) (1)
(7) Define:Green chemistry. (July2022) (1)
(8) Writethename ofthetechniqueusedto know geometry ofnanoparticles. (March 2023) (1)
(9) Define:Green chemistry.Writetwo advantages of nanoparticle
and nanotechnology. (March 2023) (2)
(10)Writethe namne ofnano structuredmaterialusedincartyrestoincreasethelife of tyres. (March 2023) (1)