JEE Main 2025 Question Papers With Solutions 23 Jan 2025 Shift 1 PDF Download
JEE Main 2025 Question Papers With Solutions 23 Jan 2025 Shift 1 PDF Download
Morning
Memory Based
Answers & Solutions
Time : 3 hrs. for M.M. : 300
IMPORTANT INSTRUCTIONS:
(2) This test paper consists of 75 questions. Each subject (PCM) has 25 questions. The maximum marks
are 300.
(3) This question paper contains Three Parts. Part-A is Physics, Part-B is Chemistry and Part-C is
Mathematics. Each part has only two sections: Section-A and Section-B.
(6) Section - A (01 – 20) contains 20 multiple choice questions which have only one correct answer.
Each question carries +4 marks for correct answer and –1 mark for wrong answer.
(7) Section - B (21 – 25) contains 5 Numerical value based questions. The answer to each question
should be rounded off to the nearest integer. Each question carries +4 marks for correct answer and
–1 mark for wrong answer.
PHYSICS
SECTION - A 3. The displacement of a particle as function of time is
Multiple Choice Questions: This section contains 20 x(t) = A sin(t) + B cos2(t) + Ct2 + D. Find dimension of
multiple choice questions. Each question has 4 choices
(1), (2), (3) and (4), out of which ONLY ONE is correct. ABC
D
Choose the correct answer:
1. Electric flux is related with linear charge density (1) L2 (2) L2T–2
q1q2r 4 q1q2
(3) (4)
(1) 125 m (2) 112.5 m 40Gm1m2 40Gm1m2
5. Match the column appropriately regarding 7. Statement-I : Hot water is less viscous than of cold
thermodynamic process. water.
(4) P(ii), Q(iii), R(i), S(iv) (1) Current in the circuit is zero
Sol. Volume change is zero → isochoric → W = 0 (3) Current in the circuit is maximum
(4) Voltage across resistance is maximum
Isobaric P = 0
Answer (1)
No heat exchange (adiabatic) Q = 0
Sol. Immediately after closing the key the capacitor acts
Heat given = W u = 0 T = 0
as a short circuit i.e. path of zero resistance. Hence,
6. In given DC circuit, find current for R = 12 in current is maximum at t = 0.
steady state.
9. A uniform solid sphere of mass m rolls down from rest
to achieve speed v1 on an inclined plane of 30°.
Sphere achieves speed v2 on an inclined plane of 45°
v12
when released from same height then is
v 22
(assume no slipping)
(1) 2 A (2) 1 A 5
(1) 1 (2)
(3) 3 A (4) 4 A 2
Answer (2) 2 3
(3) (4)
V 12 5 2
Sol. i = = =1A
R 12 Answer (1)
(2) B =
E0
C
( )
−3iˆ − 4 jˆ cos ( t − kz )
E
( )
(3) B = 0 3iˆ − 4 ˆj sin ( t − kz )
C
E
( )
(4) B = 0 −3iˆ − 4 jˆ sin ( t − kz )
C
Answer (1)
(A) Current in ammeter is 2 A
Sol. Phase difference of magnetic field with electric field
is zero. (B) Net resistance is 8
B=
(
5 E 0 3iˆ + 4 ˆj ) cos(t − kz) i=
12 V
=2A
C 5 6
E iAB = 1 A
B = 0 (3iˆ + 4 ˆj )cos(t − kz )
C VBC = 4 V
13. Find the time period of a cube of side length 10 cm Sol. TVY – 1 = constant
and mass 10 g oscillating in water. (density of Y −1
V
water = 103 kg/m3 and g = 10 m/s2) 273V Y −1 = T
4
1
(1) second V 2
1/2
25 273V =T
1
4 2
(2) second
50 T = 2 × 273 = 546 K
(3) R
2 3 3 2 –2 3
(10 cm) x (10 kg/m )(10 m/s ) 10 10 10
=– =– x R
(10 g) 10–2 (4)
+1
a = –104x Answer (2)
= 100 rad/s
2
T = = s Sol.
50
3
14. Adiabatic constant of a gas is . If volume of gas 2 1 2 − 1
2 − =
v u R
initially at 0°C is reduced to one fourth of the original
volume then new temperature is After first refraction the ray must become parallel to
the line joining two objects.
(1) 0 K
So v =
(2) 273 K
1 ( − 1)
(3) 546°C 0− =
u R
(4) 546 K
R
|u |=
Answer (4) −1
18. 23.
19. 24.
20. 25.
CHEMISTRY
SECTION - A
Multiple Choice Questions: This section contains 20 Sol. Only is aromatic in the given options
multiple choice questions. Each question has 4 choices
hence most stable.
(1), (2), (3) and (4), out of which ONLY ONE is correct.
3. Which of the following compound can show fac-mer
Choose the correct answer : isomerism?
1. Which of the following compound can react with (1) [Co(NH3)6]Cl3
Hinsberg reagent? (2) [Co(NH3)3Cl3]
(A) Aniline (3) [Co(en)2(NH3)2]Cl3
(B) N,N-Dimethyl aniline (4) [Co(H2O)6]Cl3
(1) Sol.
(2)
6. Identify the product formed in the following reaction 8. Consider the following sequence of reactions and
−
find the molecular mass of the final product (A)
CH3 − CH2 − CHO + HCHO ⎯⎯⎯⎯
OH
→
Reflux
Excess formed in g mol–1.
(1) (2)
Column I Column II
• CCl4, CO2 8e– in central atom Complete 11. Co2+ is forming an octahedral complex with spin
octet only magnetic moment 3.83 BM. The correct
• PCl5 10e– in central atom, BrF5 12e– in electronic configuration for cobalt in the complex is?
(4) (A) – (P), (B) – (Q), (C) – (R), (D) – (S) (2) S-I is incorrect, S-II is correct
reaction)
CH3 – Cl + AgF → CH3F (Swarts reaction) Both S-I and S-II are correct.
13. A(g) → 2B(g) Sol. Fructose has -hydroxy ketone group which
For the given reaction, initial pressure was 0.6 atm tautomerises to aldehyde group in presence of
and rate constant is 4.606 × 10–2 sec–1. Find the base. Therefore, it reduces Tollen’s reagent.
pressure at 100 sec
(1) 0.6 atm (2) 1.194 atm
(3) 0.594 atm (4) 0.006 atm
Answer (2)
A(g) → 2B(g) Sucrose is non reducing sugar because the
Sol. t = 0 0.6 aldehyde group of glucose and ketonic group of
t = 100 sec. 0.6 − p 2p function are bounded. Maltose and Lactose are
Answer (1)
Total pressure = 0.6 + p
= 0.6 + 0.594 1 1 1
Sol. = RH z2 2 − 2
= 1.194 atm n1 n2
14. Consider the following statements and choose the
1 1 1
= 109677 (1) 2 − 2 cm–1
2
correct option. −7
656 10 2 n2
Statement-I: Fructose does not contain aldehyde
group but it gives Tollen's test. 1
0.139 = 0.25 −
Statement-II: In disaccharides, if the reducing n22
groups are bonded, these are non-reducing sugar
1
e.g., sucrose. If these functional groups are free = 0.111
n22
then they are reducing sugar e.g. maltose and
Lactose. n2 = 3
(1) Statement-I and Statement-II are correct
16.
(2) Statement-I is correct and Statement-II is
17.
incorrect
18.
(3) Statement-I in incorrect Statement-II is correct
(4) Statement-I and Statement-II both are incorrect 19.
G = G1 + G2
–4 × F × E0 = –3 × F × 2 + (–F × 0.8)
3 moles Br2 will be required to react with 1 mole
–4E = –6.8
phenol.
E = 1.7 V
2
Br2 required for 2 g phenol = 160 3 24. Consider the given values :
94
H = 55 kJ mol–1
= 10.2 g S = 175 J mol–1 K–1
22. When 1021 molecules are removed from x mg of T = 25°C
CO2(g), then 2.4 × 10–3 moles of CO2 are left. Calculate the value of Gibbs free energy change
Calculate the value of x. [Take NA = 6 × 1023] (G) in J mol–1.
Answer (2850)
Answer (179)
Sol. G = H – TS
Sol. Number of moles of CO2 removed
G = 55000 – 298 × 175 J mol–1
21
10 G = 55000 – 52150
=
6 1023
G = 2850 J mol–1
= 0.167 × 10–2 mol 25. In estimation of sulphur by Carius method, 160 g of
Number of moles of CO2 left = 2.4 × 10–3 mol organic compound gives 466 g of Barium sulphate.
% of sulphur in the organic compound is _____.
Total moles = 2.4 × 10–3 + 1.67 × 10–3
Answer (40)
= 4.07 × 10–3 mol
Sol. 233 g of BaSO4 contains 32 g of sulphur.
Mass of CO2 present = 4.07 × 44 × 10–3 466 g of BaSO4 will have 64 g of sulphur.
= 179 × 10–3 g 64
% sulphur = 100 = 40%
= 179 mg 160
MATHEMATICS
12 5 5 Term
Sol. cos x + sin x; Let tan = , 0,
13 13 12 2
0 0 6 1·33 = 27
5 12
sin = ,cos = 0 2 4 15·3 = 45
13 13
12 5 0 4 2 15·32 = 135
cos x + sin x = cos cos x + sin sin x
13 13 0 6 0 1·33 = 27
= cos(x – ) 3 0 3 20·2 = 40
cos–1[cos(x – )] = x –
3 2 1 60·2·3 = 360
5
= x − tan−1 6 0 0 1·4 = 4
12
5. A relation defined on set A = {1, 2, 3, 4}, then how Sum of the rational term
many ordered pairs are added to = 27 + 45 + 135 + 27 + 40 + 360 + 4 = 638
R = {(1, 2), (2, 3), (3, 3)} so that it becomes z
equivalence relation? 7. If = 2 represents a circle with centre P then
z+i
(1) 10
distance of P from D is (where D : (1, 5) and i = −1 )
(2) 9
360
(3) 7 (1)
9
(4) 8
370
Answer (3) (2)
9
Sol. Ordered pairs to be added be
370
{(1, 1), (2, 2), (4, 4), (2, 1), (3, 2), (3, 1), (1, 3)} (3)
9
So total 7 ordered pairs to be added.
360
6. The sum of all rational terms in the expansion of (4)
9
6
1 1
1 + 2 3 + 3 2 is Answer (2)
Sol. Let z = x + iy
(1) 638 z =2 z+i
(2) 728
x 2 + y 2 = 2 x 2 + ( y + 1)
2
(3) 528
(4) 729 x2 +y2 = 4(x2 + (y + 1)2)
C: 3x2 + 3y2 + 8y + 4 = 0
Answer (1)
−4
Sol. The general term of multinomial expansion is P 0,
3
( )( )
6!
(1) 21/3 31/2
! ! ! 2
4 361 370
Now PD : 12 + 5 + = 1 + =
For terms to be rational 3| and 2| 3 9 9
= ( A A−1) (B B −1) | A | | B | = | A | | B | l n .
ex
= eln|1+e |
= 1 + e2 x
6 −16dx
y (1 + e2 x ) = (1 + e2 x )dx = dy
(1+ e ) 2x
( x − 1)2
y(1 +e2x) = 6x + c 1
− dy
Passes through (0, 0) I (x) =
16
15
c=0 y 13
6x − 15 + 1
y= 1 y 13
1 + e2 x =− +C
16 −15
Now if passes through (ln2, k) + 1
13
6 ln2 6
k= = ln2 13 − 13
2
1+ 4 5 = y +C
32
dx
12. Let I = , then I is 2
11 15
13 x − 1 13
( x − 1) 13 ( x + 15 ) 13 = +C
32 x + 15
2
13 x − 1 13 13.
(1) +C 14.
32 x + 15
15.
2
32 x − 1 13 16.
(2) +C
13 x + 15 17.
2 18.
1 x + 15 13 20.
(3) +C
32 x − 1
SECTION - B
15 Numerical Value Type Questions: This section
13 x + 15 13 contains 5 Numerical based questions. The answer to
(4) +C
32 x − 1 each question should be rounded-off to the nearest
integer.
Answer (1)
21. If f(x) is continuous at x = 0, where
dx
Sol. I ( x ) = 2
( sin( k1 + 1) x + sin( k2 + 1) x ) x0
11 15
( x − 1)13 ( x + 15 )13 x
dx f ( x ) = 4 x =0
= 15
2 log k2 x + 1
x + 15 13
( x − 1)2
x k1x + 1 x 0
x −1
Then k12 + k 22 is
x + 15
Let =y Answer (2)
x −1
Sol. f(x) is continuous at x = 0
( x − 1) − ( x + 15 ) dy
= Then lim f ( x ) = f (0) = lim f ( x )
( x − 1)2 dx x →0 − x →0 +
( )
4
2 3 5 =0
A = 25 − 25 − x 2 − | x − 1| dx
1 2 6 −3
2 – 18 = 0 4
1 25 −1 x 9
=9 = 25 − x 25 − x 2 + sin + 8 +
2 2 5 3 2
Now 2 + = 92 + 9 = 81 + 9 = 90
23. If the equation a(b – c)x2 + b(c – a)x + c(a – b) = 0 25 25 −1 4 25 −1 3
= 25 + − 6 + sin +6+ sin
16 2 2 5 2 5
has equal roots and if a + c = 5 and b = , then
5 25 25 75 1
the value of a2 + c2 is equal to = 25 + − 12 − = +
2 4 4 2
Answer (9) 1
Sol. Clearly 1 satisfy other root is also 1. = (75 + 2)
4
c (a − b )
=1 (using product of roots) = 75, = 2
a(b − c )
+ = 77
c(a – b) = a(b – c) 25.