Sec: JR.

IIT_*COSC(MODEL-A) CAT-15 Date: 12-11-23

Time: 3 Hrs 2018_P2 Max. Marks: 180
KEY SHEET
MATHEMATICS
1 ABCD 2 BC 3 ABCD 4 CD 5 ABD
6 BD 7 1 8 3 9 7 10 7
11 6 12 2 13 1 14 5 15 B
16 A 17 D 18 B

PHYSICS
19 ABCD 20 ACD 21 ABD 22 ABCD 23 AC

24 BCD 25 2 26 2 27 0.5 28 60

29 5 30 100 31 5 32 3.17 33 B

34 A 35 D 36 C

CHEMISTRY
37 ACD 38 ABCD 39 BCD 40 CD 41 ABC

42 ABCD 43 62 44 2 45 2 46 13

47 0 48 15 49 94 50 2 51 A

52 A 53 A 54 D
Narayana IIT Academy 12-11-23_JR.IIT_*CO SC(MODEL-A)_JEE-ADV_CAT-15_KEY&SOL
SOLUTIONS
MATHS
3 9
1. f  
2 4
  3  3
f f   
  2  2
   3  9
f f f   
   2  4
5
f  2
2
  5 
f f   1
  2 
   5 
ff f   1
   2 
1
lim ( p tan qx 2 3cos2 x 3)
x0 3 x 2
2. e
pq 3(1 cos 2 x )
lim 
e x0 3 3 x2

pq 5
  1  ; pq  2
3 3
3. Differentiable w.r.t. ' x '
2 f ( x ) f '( x)  2 y  2 f ( x  y ) f '( x  y )
Put x  0
k  y  f '( y ) f ( y )
y2 f 2 ( y)
Integrate on both sides, ky   c
2 2
Put x  y  0 in given equation, we get f 2 (0)  2
f (0)  2 as  f ( x)  0 
Put y  0 in (1)
1  c  0  c  1
Also put y  2
4
k 2 1  1
2
k 2 0
k 0
y 2 f 2 ( y)
  1
2 2
f 2 ( y)  y 2  2
f ( y)  y2  2

f ( x)  x 2  2

JR.*CO SC Pg.No: 2
Narayana IIT Academy 12-11-23_JR.IIT_*CO SC(MODEL-A)_JEE-ADV_CAT-15_KEY&SOL
Hence, we can answer.
4. Equation of tangent to y  x3
y  x13  3 x12 ( x  x1 )
Equation of tangent to y  x1/ 3 is
1
y  x1/2 3  ( x  x2 )
3 x22 / 3
1 9 x12 x22 / 3 2 x13 1
If these tangents represent same line    x1  
2 1 2 1/ 3 3
x2
3
5. Conceptual
1 3 
6. 2  sin   cos    ( x  3) 2  2
2 2 
7.
10
8. 2a
3

9. x 2  1  6 log 4 y
y 2  2 x y  2 x 1  0
 y  2 x 1 and y  2 x
If y  2 x (not possible, because y  0 )
x 1
If y  2
 log 2 y  x  1
x 2  1  3 log 2 y
 x 2  1  3( x  1)
x 2  3x  4  0
 ( x  4) ( x  1)  0
x1  4
 y1  25  32
x2  1
 y2  2 0  1
JR.*CO SC Pg.No: 3
Narayana IIT Academy 12-11-23_JR.IIT_*CO SC(MODEL-A)_JEE-ADV_CAT-15_KEY&SOL
log 2 x1 x2 y1 y2  log 2 128  7
10. If a, x, y, z , b A.P.
3a  b ab a  3b
x ,y and z 
4 2 4
If a, x, y, z , b H.P.
4ab 2ab 4ab
x ,y and z 
3b  a ab 3a  b
 3a  b   a  b   a  3b   4ab   2ab   4ab  343
If      55 and      ab  7
 4  2  4   3b  a   a  b   3a  b  55
11. P ( x)   x 4  x 3  x 2  1  x 2  1   x 2  x  1

P ( )  P (  )  P ( )  P ( )   2    1    2    1    2    1   2    1  6

2sin 400  sin 200 2sin  60  20   sin 20

0 0 0

12. 
cos 200 cos 300 cos 200 cos 300
 1 

 2    
13.  2 tan 1  2    2 tan  2
 n  n  4  n0
1 2 
n 0  n  n  1 
 4 4 
 n 1 n 
  2  2 2 
  2 tan  
1  
n 0     1
n n 1
 22 2 
   

 n 1  n 
  2  tan 1     tan 1   
n 0  2 2  2 
14. Let sin x  1  a, cos x  1  b, sin x  c
 a 3  b3  c 3  ( a  b  c )3
 a  b  0 or b  c  0 or c  a  0
1
sin x  cos x  2 or sin x  cos x  1 or sin x 
2
 Total solution = 5
15. Conceptual
16. (A) Since A is idempotent, A2  A3  A4  ..........  A .
Now, ( A  I ) n  I  nC1 A  nC2 A2  ........  n Cn An
 I  nC1 A  n C2 A  ..........  nCn A
 I   n C1  nC2  ........  n Cn  A

 I   2n  1 A
 2n  1  127  n  7
(B) We have,
 I  A   I  A  A2  ........  A7 

JR.*CO SC Pg.No: 4
Narayana IIT Academy 12-11-23_JR.IIT_*CO SC(MODEL-A)_JEE-ADV_CAT-15_KEY&SOL
 I  A  A  .........  A    A  A2  A3  A4 ...........  A8 
2 7

 I  A8
I  if A8  0 

Here matrix A is skew-symmetric and since A  AT   1 A , so A 1  (1) n   0

n
(C)
As n is odd, hence A  0 . Hence A is singular.
(D) If A is symmetric, A1 is also symmetric for matrix of any order
17. Conceptual
18. (A) f ( x)  2sin 2 x  sin x  6
ymin  9 at sin x  1
47 1
ymax   at sin x 
8 4
(B) f ( x)  2 cos x  6
2

ymin  6; ymax  8
1
(C) f ( x)   4sin 2 x  1  cos 2 x  3 (1  cos 2 x)
2
1
  2  4 sin 2 x  4 cos 2 x 
2
 1  2  sin 2 x  cos 2 x 
ymax  1  2 2; ymin  1  2 2
 
(D) f ( x)  2 sin   sin x 
4 

PHYSICS
19.

CHEMISTRY
37. Copper SRP value is +ve, while Na, K and Mg value is –ve
38. Half life (t1/2 ) (initial conc)1n
Rate of reaction  (conc. of reactant)n
39. Tartaric acid has two similar chiral carbons
42.

43. X  180(anti staggered)

Y  60(SKEW )

JR.*CO SC Pg.No: 5
Narayana IIT Academy 12-11-23_JR.IIT_*CO SC(MODEL-A)_JEE-ADV_CAT-15_KEY&SOL
44.
 Ag    CN
AgCN 
K sp  [ Ag  ][CN  ]
2.2 1016  x[CN  ] 
(1)
 HCN
H   CN  
x x

1 [ HCN ]

Ka [ H  ][CN  ]
1 x
  (2)
6.2  1010 103 [CN  ]
1 x.x
10

6.2  10 2.2  1016 103
2.2  1019
x2 
6.2  1010
2.2
x2  109
6.2
x 2  0.354 109
x  1.88 105
 2 105 mole / litre
45.

‘B’ is the only stereo center to exhibit geometrical isomerism

46.

47. Bridge bond in Al2Cl6is formed by 3-centre 4-e-bond.

JR.*CO SC Pg.No: 6
Narayana IIT Academy 12-11-23_JR.IIT_*CO SC(MODEL-A)_JEE-ADV_CAT-15_KEY&SOL
48.
  CST
WST

MV
1.46  0.083  300
M
2.42 103  0.1
1.46  0.083  300 104

2.42
 15.02 104 gm
49.
H 2O2 K 2Cr2O7
N1V1 = N 2V2
0.7  6  120
N1  30 =
30
 24  0.7
VS  N  5.6  24  0.7  5.6
 94.08
50. NaHCO3; KHCO3
molecular wt (or) formula wt
51. Eq.wt 
no. of e  transferred per mole of substance
52. H ( neu ) of WA + WB = H ( neu ) of SA + SB  Hionisation of WA + WB
53.

54. Diamond, graphite and SiO2 has dangling bonds.

Graphite is a good conductor of electricity

JR.*CO SC Pg.No: 7