ALPHORES IIT ACADEMY

TELANGANA :: MAHARASTRA

JEE Main - 23-01-2025 (Shift-1)

[Memory Based Questions]

PHYSICS
1. If angles of projection for two projectiles are 30∘ and 60∘ then the ratio of velocities
at maximum height is? (Assume initial velocities of both projectiles is same).
a) √3 b) 2 c) 1/ √3 d) 1/2
Ans: (a)
2. Statement 1: Hot water moves faster than cold water.
Statement 2: Soap water have higher surface tension than fresh water.
a) Statement 1 is false and statement 2 is true
b) Both statement 1 and statement 2 are true
c) Both statement 1 and statement 2 are false
d) Statement 1 is true and statement 2 is false
Ans: (d)
3. Electric flux 𝜙 is related with linear charge density 𝜆. and surface charge density
𝛽
𝜎 as 𝜙 = 𝛼𝜆 + 𝛽𝜎. where 𝛼, and 𝛽 are of appropriate dimension of (𝑎 ) is

a) Area b) Displacement c) Electric field d) Velocity

Ans: (b)
4. Two particles are located at equal distance from origin. The position vectors of
those are represented by 𝐴‾ = 2𝑖ˆ + 3𝑛𝑗ˆ + 2𝑘ˆ and 𝐵‾ = 2𝑖ˆ − 2𝑗ˆ + 4𝑝𝑘ˆ respectively. If
both the vectors are at right angle to each other, the value of 𝑛−1 is.
a) 4 b) 5 c) 3 d) 2
Ans: (c)
5. 𝐹 = 𝑥 2 𝑦𝑖 + 𝑦 2 𝑗, on line 𝑥 + 𝑦 = 10. work done from (0, 0) to (4, 2).
a) 152 b) 162 c) 150 d) 160
Ans: (a)

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6. A positive ion 𝐴 and a negative ion 𝐵 have charges 6.67 × 10−19 C and 9.6 × 10−10 C
and mass 19.2 × 10−27 kg and 9 × 10−27 kg respectively at an instant, the ions are
separated by a certain distance 𝑟. At that instant the ratio of the magnitudes of
electrostatic force to gravitational force 𝑃 × 1043 , where value of 𝑃 is
1
Take = 9 × 109 Wm2 C−1 and universal gravitational constant as
4𝜋𝜀0
6.67 × 10 −11
Nm−2 kg −2.
Ans: 50
7. A gas at 0∘ C, is reduced to 1/4 of its volume adiabatically. Change in temperature
is 𝑘. (𝛾 = 3/2).
a) 546 b) 273 c) 100 d) 200
Ans: (b)
𝐴𝐵𝐶
8. 𝑥(𝑡) = 𝐴sin⁡𝑡 + 𝐵cos 2 ⁡𝑡 + 𝐶𝑡 2 + 𝐷 Dimension of =
𝐷

a) L2 T −2 b) 𝐿2 c) 𝐿3 𝑇 −2 d) L
Ans: (a)
9. Given a convex lense of refractive index 𝜇2 in a liquid of refractive index 𝜇1 , 𝜇1 <
𝜇2 having radii of curvature 𝑅1 𝑅2 the 𝑅2 surface a silver polished. Where should
an object be placed on the optic axis so that the real and inverted image is formed
at the same place.
(𝜇2 +𝜇1 )|𝑅1 | 𝜇1 |𝑅1 |⋅|𝑅2 |
a) (𝜇2 −𝜇1 )
b) 𝜇2 (|𝑅1 |+|𝑅1 |−𝜇1 |𝑅2 |
𝜇1 |𝑅1 ||𝑅2 | 𝜇1 |𝑅1 |⋅|𝑅2 |
c) d)
𝜇2 (2|𝑅1 |+|𝑅2 |)−𝜇1 √|𝑅1 |⋅𝑅2 ∣ 𝜇2 (|𝑅1 |+|𝑅2 |)−𝜇1 |𝑅1 |)

Ans: (b)
10. From velocity v/s time graph find distance covered by aeroplane in 30.5 sec

a) 15 km b) 12 km c) 10 km d) 20 km
Ans: (b)

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11. Infrared light of wavelength 900 nm used for muscle pain. Which of the following
transition in H -atom can be used?
a) Lyman: 3 → 1 b) Balmer: 5 → 2 c) Paschen: 5 → 3 d) Paschen: ∞ → 3
Ans: (d)
12. Given mass 𝑚 = 10gm. Density of water = 103 kg/m3 . Side length of cube=
10 m/s2 . If the cube is pushed slightly into the water from equilibrium then time
period of SHM T = Y𝜋 × 10−2 then find x
Ans: 2
13. The same solid sphere is rolled from rest from 2 inclined planes. Assume pure
rolling. Find v2/v1

a) 21/2 b) 21/4 c) 2-1/2 d) 2

Ans: (b)

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 CHEMISTRY
1. Which of the following element doesn't lie on the same period?
a) Osmium b) Iridium c) Palladium d) Platinum
Ans: (c)
2. Which of the following can show fac-mer isomers?
a)⁡Co[(en)2 Cl2 ] b)⁡[Co(NH3 )4 Cl2 ] c)⁡[Co(H2 O)6 ] d) [Co(NH3 )3 Cl3 ]
Ans: (d)
3. Which of the following react with Hinsberg reagent?
(A) Aniline (B) N,N-Dimethyl aniline
(C) Methyl amine (D) C6 H5 NHC6 H5
a) A only b) A and C only c) A, C and D d) A and B only
Ans: (c)
4. Statement 1: Fructose can give Tollens test even though it does not have
aldehyde group.
Statement 2: When reacted with base fructose can undergo rearrangement to
produce aldehyde group.
a) Statement 1 is correct but Statement 2 is incorrect.
b) Both Statement 1 and Statement 2 are correct.
c) Both Statement 1 and Statement 2 are incorrect.
d) Statement 1 is incorrect but Statement 2 is correct.
Ans: (b)
5. Which of the following pair of ions are same coloured?
a)⁡Ti4+ , V 3+ b)⁡Cr 2+ , Cu2+ c)⁡Cr 3+ , Ni2+ d) Mn3+ , Fe2+
Ans: (b)
6. If 2g phenol is allowed to react with Br2 /H2 O. How much Br2 will be required to
produce 2,4,6-tribromophenol (Rounded off to nearest integer).
a) 8 b) 14 c) 10 d) 12
Ans: (c)

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7. Among the following the most stable Carbanion

a) b) c) d)
Ans: (b)
8. Co(NH3 )x Cl3 has 0.1 molal. 100% dissociation ΔTf = 0.558 (k f = 1.86). Then formula
of compound is
a)⁡[Co(NH3 )4 Cl2 ] b)⁡[Co(NH3 )2 Cl4 ] c)⁡[Co(NH3 )5 Cl ]Cl2 d) [Co(NH3 )4 Cl2 ]Cl2
Ans: (c)
9. In estimation of Sulphur by Carius method, 160 gm of organic compound gives
466 gm of Barium sulphate. % of Sulphur in the organic compound is.
a) 60% b) 55% c) 40% d) 70%
Ans: (c)
10. 4 -nitrotoluene is treated with Br2 to get compound P which is reduced with Sn
and HCl to get Compound Q, then Q is diazotized and product is treated with
phosphinic acid to get R is oxidised with alkaline KMnO4 to get final product.
a) 2-Bromo 4 hydroxy Benzoic acid b) Benzoic acid
c) 4-Bromo Benzoic acid d) 3-Bromo Benzoic acid
Ans: (b)
11. If 1021 molecules are removed from x mg of CO2 (g), then 2.4 × 10−3 moles are left.
Calculate the value of x.
a) 156 b) 179 c) 187 d) 165
Ans: (b)
12. Incorrect statement among the following is
a)⁡SO2 acts as oxidizing agent but not reducing agent
b)⁡NO2 exists as dimer
c)⁡PF5 exists but NF5 does not
d) PH3 has lower proton affinity than NH3
Ans: (a)

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13. The d-electronic configuration of an octahedral Co (II) complex having magnetic
moment of. 3.95 BM is :
a)⁡t 2 g 5 eg 2 b)⁡eg 4 t 32 c)⁡t 2 g 3 eg ∘ d) t 2 g 6 eg1
Ans: (a)
14. Match the column appropriately regarding thermodynamic process.

Column I Column II
(P) When volume change is zero (i) ΔW = 0
(Q) When volume is constant (ii) ΔQ = 0
(R) When no heat is exchanged (iii) Isochoric
Work done by the gas is equal to
(S) (iv) Isothermal
heat given to the gas
a)⁡P(iv), Q(iii), R(i), S(ii) b)⁡P(i), Q(iii), R(ii), S(iv)
c)⁡P(ii), Q(iii), R(iv), S(i) d) P(ii), Q(iii), R(i), S(iv)
Ans: (b)
2.0V 0.8V −0.5V
15. Consider the following FeO2−
4 → Fe3+ → Fe2+ → Fe0 .
0
Find EFeO 2− /Fe
2+
4

a) 8 b) 2 c) 4 d) 6
Ans: (b)
16. Consider the given values :
ΔH = 55 kJ mol−1, ΔS = 175 J mol−1 K −1, T = 25∘ C
Calculate the value of Gibbs free energy charge (ΔG) in Jmol−1.
a) 1780 b) 2570 c) 1570 d) 2850
Ans: (d)
17. Given below are two statements :
Statement-I : During Lassaigne's test, covalent compound is converted to ionic
compound.
Statement-II : Na4 [Fe(CN)6 ] gives Prussian blue colour on reaction with
Fe2 (SO4 )3

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 a) S-I is correct, S-II is incorrect b) S-I is incorrect, S-II is correct
c) Both S-I and S-II are correct d) Both S-I and S-II are incorrect
Ans: (c)
18. Correct order of stability

a) (i) > (ii) > (iii) b) (ii) > (iii) > (i) c) (ii) > (i) > (iii) d) (iii) > (i) > (ii)
Ans: (b)

19.

a) b) c) d)
Ans: (a)

20. Name Reaction Product

a) Sandmeyer's p) Cyano Benzene

b) Swarts q) Ethyl Fluoride

c) Wurtz-Fittig r) Ethyl Benzene

d) Finkelstein s) Ethyl Iodide

a) a(p), b(q), c(r), d(s) b)⁡a(q), b(r), c(p), d(r)

c)⁡a(q), b(p), c(s), d(r) d)⁡a(r), b(p), c(q), d(s)
Ans: (a)

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21. Consider the following sequence of reactions and find the molecular mass of the
final product (A) formed in gmol−1 .

a) 108 b) 216 c) 171 d) 186

Ans: (c)
22. Match the Column I with Column II and choose the correct option.

Column I Column II
A. BF3 (i) Odd e⁡− species
B. CCl4 , CO2 (ii) Expanded octet
C. PCl5 , BrF5 (iii) Complete octet
D. NO (iv) Electron deficient

a)⁡A - (iii), B - (iv), C - (i), D - (ii) b)⁡A - (iv), B - (ii), C - (iii), D - (i)
c)⁡A - (iv), B - (iii), C - (ii), D - (i) d)⁡A - (i), B - (ii), C - (iii), D - (iv)
Ans: (c)

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 MATHEMATICS
1. Find the area bounded between two curves 𝑥 2 + 𝑦 2 = 25 and y = |x − 1|.
25 1 25 1 21 1 7 2
a)  b)  c)  d) 
4 2 4 3 3 5 3 5
Ans: (a)
2. The value of 𝑎 = 3, the sum of first 4 terms is equal to the one fifth of sum of next
4 terms in A.P. then find the sum of first 20 terms?
a) -1080 b) -2016 c) 512 d) 128
Ans: (a)
3. 2 biased dice are rolled. Die one has 1 on 2 faces, 2 on 2 faces, 3 and 4 on other
faces. Die two has 2 on 2 faces, 4 on 2 faces, 1 and 3 on other faces. Then the
probability of getting sum as 4 or 5 is
a) 0.25 b) 0.5 c) 1.2 d) 2.5
Ans: (b)
4. Let 𝑅: 𝐴 → 𝐴 be a relation where A = {1, 2, 3, 4}. Find the minimum number of
elements added to the set to make it equivalence relation.
a) 7 b) 9 c) 3 d) 5
Ans: (a)
5. The total number of ways the word 'DAUGHTER' can be arranged so that all
vowels doesn't occur together.
a) 36000 b) 37000 c) 35000 d) 38000
Ans: (a)
6. A quadratic equation 𝑎(𝑏 − 𝑐)𝑥 2 + 𝑏(𝑐 − 𝑎)𝑥 + 𝑐(𝑎 − 𝑏) = 0 has equal roots, where
36
𝑎 + 𝑐 = 15 and 𝑏 = then find 𝑎2 + 𝑐 2 is equal to
5

a) 117 b) 216 c) 512 d) 120

Ans: (a)
1 1 6
7. Sum of rational terms in expansion (1 + 23 + 32 ) is _________.

a) 172 b) 215 c) 156 d) 160

Ans: (a)

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8. Let 𝑓(𝑥) be a continuous function at 𝑥 = 0, where
2
(sin⁡(𝑘1 + 1)𝑥 + sin⁡(𝑘2 + 𝑥)); 𝑥 < 0
𝑥

𝑓(𝑥) = 2 𝑘 𝑥+1
(log⁡(𝑘1 𝑥+1)) ; 𝑥>0
𝑥 2

{ 4 𝑥=0
Then find 𝐾12 + 𝐾22 .
a) 3 b) 5 c) 2 d) 7
Ans: (c)
𝑑𝑥 1 1 1
9. Let 𝐼(𝑥) = ∫ 11 15 . If I(37) − I(24) = 4 (𝑏1/3 − 𝑐 1/3 ) Then 3(𝑏 + 𝑐) is equal to
(𝑥−11)13 (𝑥+15)13

a) 37 b) 39 c) 21 d) 45
Ans: (b)
10. Area of the triangle with the vertices 𝑃(5,4), 𝑄(−2,4), 𝑅(𝑎, 𝑏) is 35 square units. If
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orthocentre of this triangle is O (2, 5 ) and centroid is C(c, d) then (c + 2d) is equal
to
a) 3 b) 7/3 c) 2 d) 8/3
Ans: (a)
𝑥 4 −2𝑥 3 +3𝑥 2 −2𝑥+2
11. If 𝑓(𝑥) = log⁡𝑥 and 𝑔(𝑥) = . Then find domain of 𝑓(𝑔(𝑥)).
2𝑥 2 −2𝑥+1

a) (1, 2) b)  ,   c)  0,  d)  ,1

Ans: (b)
12. Let a curve y = f(x) passes through the points (0, 5) and (log 𝑒 ⁡2, k). If the curve
satisfies the differential equation 2(3 + y)𝑒 2𝑥 𝑑𝑥 − (7 + 𝑒 2𝑥 )𝑑𝑦 = 0. Then k is equal
to
a) 4 b) 2 c) 5 d) 8
Ans: (d)

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13. If 𝐴, 𝐵 and (adj⁡(𝐴−1 ) + adj⁡(𝐵−1 )) are non - singular matrices of same order then
−1
the inverse of A(adj⁡(A−1 ) + adj⁡(B−1 )) B is equal to
1
a) (adj⁡𝐵 + adj⁡𝐴) b) 𝐴𝐵 −1 + 𝐴−1 𝐵
|𝐴𝐵|
𝐴𝐵−1 𝐵𝐴−1
c) adj⁡𝐵 −1 + adj⁡𝐴−1 d) +
|𝐴| |𝐵|

Ans: (a)
14. Marks obtained by all the students of class 12th are in a frequency distribution
with classes of equal width. Let the median of the group data be 14 with median
class interval 12-18 and the median class frequency is 12. If the number of
students who secures marks below 12 is 18 then the total number of students is
a) 48 b) 52 c) 44 d) 40
Ans: (c)
15. If the system of equation
(𝜆 − 1)𝑥 + (𝜆 − 4)𝑦 + 𝜆𝑍 = 5
(𝜆𝑥 + (𝜆 − 1)𝑦 + (𝜆 − 4)𝑍 = 7
(𝜆 + 1)𝑥 + (𝜆 + 2)𝑦 − (𝜆 + 2)𝑧 = 9
Has infinitly many solutions then 𝜆2 + 𝜆 is equal to
a) 20 b) 10 c) 12 d) 6
Ans: (c)
𝜋 3𝜋 12 5
16. If ≤𝑥≤ . Then cos −1 ⁡[13 cos⁡𝑥 + 13 sin⁡𝑥] is equal to
2 4
5 1 5 4
a) 𝑥 + tan−1 ⁡12 b) 𝑥 − tan−1 ⁡3 c) 𝑥 − tan−1 ⁡12 d) 𝑥 + tan−1 ⁡5
Ans: (c)
17. Value of sin70∘ (cot⁡10∘ cot⁡70∘ − 1) is
a) 3 b) 5 c) 7 d) 1
Ans: (d)

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