CHEMISTRY

Q.1 Which of the following gives a suffocating gas Q.11 An alkaline solution of potassium mercuric
when treated with dilute HCl - iodide is known as -
(A) carbonate (B) sulphite (A) Nessler’s reagent(B) Lassaigne’s reagent
(C) sulphate (D) borate [B] (C) Fenton’s reagent(D) None of the above [A]
Q.2 The mixture when rubbed with organic acid Q.12 A solution on treatment with aqueous ammonia
smells like vinegar obtain. It contains -
turns blue. It contains - [A]
(A) sulphur (B) nitrate
(A) Cu2+ (B) Ni2+
(C) nitrite (D) acetate [D]
Q.3 The type of analysis that deals with the (C) Co2+ (D) Mn2+
methods which are used to determine the Q.13 The sulphide which is insoluble in 30% HNO3
constituents of a compound is - [A] is - (A) HgS (B) CuS (C) PbS (D) CdS[A]
(A)Qualitative analysis (B) Titrametric analysis Q.14 The group reagent for the V group radicals
(C) Volumetric analysis (D) None of the above is - (A) (NH4)2CO3 (B) (NH4)2SO4
Q.4 The chromyl chloride test is meant for which of
(C) NH4Cl (D) (NH4)2C2O4 [A]
the following ions ?
(A) Cl– ions (B) both Cl– and Br– ions Q.15 K2HgI4 Is useful for detecting - [D]
(C) I– ions (D) Cl– and CrO42– ions [A] (A) NO3– (B) PO4–3 (C) Cl– (D) NH4+
Q.5 Violet vapours are given out when ........... is Q.16 A Black sulphide is formed by the action of H2S
treated with conc. H2SO4 - on - [A]
(A) bromide (B) iodide (A) CuCl2 (B) CdCl2 (C) ZnCl2 (D) None
(C) chloride (D) nitrate [B]
Q.17 Which of the following sulphides has the
Q.6 AgCl react with NH3 forms a complex -
maximum solubility product - [D]
(A) AgNO3 (B) Ag NH2Cl (A) HgS (B) PbS (C) CuS (D) MnS
(C) Ag (NH3)2 Cl (D) Ag mirror [C] Q.18 Which sulphides are soluble only in aqua-regia -
Q.7 For the test of oxalates, the soda extract is (A) NiS (B) HgS [D]
acidified with -
(C) CoS (D) All of these
(A) dil H2SO4 (B) dil HNO3
Q.19 Which of the sulphides is yellow - [B]
(C) CH3COOH (D) None [C]
(A) ZnS (B) CdS (C) NiS (D) PbS
Q.8 Sodium carbonate extract is a mixture of - Q.20 In qualitative analysis Cd is under - [B]
(A) [Salt + Na2CO3 + HCl] (A) I group (B) II group
(B) [Salt + Na2CO3 + H2O] (C) III group (D) IV group
(C) [Salt + CaCO3 + HCl] Q.21 In the II A group basic radical, the ions are
present - [A]
(D) [Salt + Na2CO3 + HNO3] [B]
(A) Cu+2, Cd+2 (B) Ni+2, Zn+2
Q.9 For the test of sulphite, the soda extract is
acidified with - [A] (C) Pb+2, Al+3 (D) Cr+3, Cu+2

(A) dil HCl (B) dil HNO3 Q.22 The ion which is not precipitated by H2S in the
presence of HCl is - [D]
(C) CH3COOH (D) None of these
(A) Cu+2 (B) cd+2 (C) Pb+2 (D) Al+3
Q.10 Lead sulphate is soluble in which solvent
(A) Ammonium acetate (B) Conc. HNO3 Q.23 CoCl2 is - [A]
(C) Ammonium hydroxide (D) Conc. HCl [A] (A) pink (B) black
(C) green (D) colourless
1
 Q.35 In the detection of nitrogen in sodalime test , the
Q.24 Addition of KI to lead saturated in water gives evolved gas is - [C]
precipitate, the colour is - [A]
(A) N2 (B) NO (C) NH3 (D) NO2
(A) yellow (B) black (C) white (D) red
Q.36 Beilstein test for organic compounds in used to
Q.25 What is green vitriol ?
detect -(A) nitrogen (B) halogen
(A) FeSO4.7H2O (B)(NH4)2 SO4.6H2O
(C) sulphur (D) carbon[B]
(C) K2SO4 (D) Na2SO4 [A] Q.37 In Lassaigne’s test for N, S and halogens, the
Q.26 Aqueous solution of Potash Alum is - [A] organic compound is -
(A) Acidic (B) Basic (A) Fused with sodium
(C) Neutral (D) Amphoteric (B) Dissolved with sodamide
Q.27 The purpose of carrying out crystallization is- (C) Extracted with sodamide
(A) To prepare a substance in solid state (D) Fused with calcium[A]
only Q.38 In Lasaigne’s test for nitrogen, the blue colour
(B) To.prepare a substance in state of purity is due to the formation of -
(C) To prepare a substance in hydrated state (A) Ferric ferrocyanide
(D) None of the above [B] (B) Potassium ferrocyanide
Q.28 Colour of potash alum Crystals - [C] (C) Sodium ferrocyanide
(A) Green (B) Blue (D) Sodium cyanide [A]
(C) Colourless (D) Black Q.39 Positive Beilstein test shows that -
Q.29 Sodium extract of an organic substance gives a (A) Halogens are surely present
blood red colour with FeCl3. It contains the (B) Halogens are absent
elements - [C] (C) Halogens may be present
(A) N (B) S (C) N & S both (D) N or S (D) None of the above [C]
Q.30 Copper wire test of halogens is known as - Q.40 In Lassaigne’s test sodium metal is used
(A) Beilstein test (B) Liebig test because -(A) it is very reactive
(C) Lassaigne test (D) fusion test [A] (B) its melting point is low
Q.31 Violet colouration in Lassaigne test with (C) its compounds are soluble in water
sodium nitroprusside, indicates the presence of - (D) all of the above [D]
(A) N (B) S (C) halogen (D) O [B] Q.41 For the detection of halogen in lassaigne’s test,
Q.32 Sodium nitroprusside gives violet colour of the light yellow ppt indicate the presence of -
........ with aqueous solution of Na2S - (A) Cl (B) Br (C) I (D) None[B]
(A) Na4[Fe(CN)5NOS] (B) Na3[Fe(CN)5NOS] Q.42 Carboxylic group changes the blue litmus to -
(C) Na2[Fe(H2O)5NOS] (D) Na4[Fe(H2O)5NOS][A] (A) Black (B) Red (C) White (D) Green[B]
Q.43 Fehling solution ‘B’ consists of -
Q.33 Prussian blue is -
(A) NaOH + potassium tartarate
(A) Na4Fe (CN)6 (B) Na3Fe(CN)6
(B) NaOH + Sodium tartarate
(C) Fe4[Fe(CN)6]3 (D) None of these [C]
(C) CuSO4 + CH3COOH
Q.34 When sodium extract is prepared, generally the
(D) NaOH + Sodium potassium tartarate [D]
substance ignites - [B]
Q.44 Which test is used to distinguish aldehydes from
(A) Na (B) H2
Ketones ? [C]
(C) Organic compound (D) O2 (A) Tollen’s test (B) Fehlling’s test
(C) Both (A) & (B) (D) None of the above

2
Q.45 Liebermann’s test is used for which class of
compounds - [B] Q.55 In iodoform reaction acetone is treated with-

(A) Alcohols (B) Phenols (A)Sodium iodide (B) Sodium hypoiodide

(C) Aldehydes (D) Ketones (C) Iodine (D) None of the above[B]
Q.46 Sodalime test for the detection of nitrogen is not Q.56 The IUPAC name of iodoform is -
reliable for the group - [D] (A) Methyl iodide (B) Methyl triiodide
(A) – CHO (B) – NO2 (C) Triiodo methane (D) None of the above[C]
Q.57 The IUPAC name of acetanilide is -
(C) – N = N – (D) Both (B) and (C)
(A) Aniline methyl Ketone
Q.47 In the Xanthate test for the detection of alcohol,
(B) Methyl benzamide
which colour ppt. is obtained - [C]
(C) Phenylethanamide
(A) Green (B) Red (D) All [C]
(C) Yellow (D) Brown Q.58 The size of the colloidal particles is -
(A) Between 100 nm to 1000 nm.
Q.48 For detection of alcohol group in the Victor
(B) Between 10 nm to 100 nm.
meyer’s test, 2º Alcohol give colour - [B]
(C) Between 1 nm to 100 nm.
(A) Red (B) Blue
(D) Between 500 nm to 1000 nm. [C]
(C) Black (D) Colourless
Q.59 The pH range of phenol red is - [A]
Q.49 Lucas reagent is - [B] (A) 6.3 - 8.4 (B) 4.8 - 6
(A) Ag + Conc.HCl (B) Zn + Conc. HCl (C) 3.2 - 4.4 (D) 8.2 - 10
(C) Cd + Conc. H2SO4 (D) Zn + Conc. HNO3 Q.60 In the titration of strong acid and weak base
suitable indicator is - [B]
Q.50 Tollen’s reagent is - [A]
(A) phenolphthalein (B) methyl orange
(A) [Ag(NH3)2]OH (B) [Ag(H2O)2]OH
(C) No indicator used (D) Thymol blue
(C) [Ag(NH3)4]Cl (D) None
Q.61 Greater is the protective power of lyophilic
Q.51 In the detection of ketones which test is colloid - [A]
used - (A) leasser is its gold number
(A) Libermann’s test (B) Lassaigne test (B) greater is its gold number
(C) either of the above
(C) Nitroprusside test (D) None [C]
(D) none
Q.52 Benedict’s solution provides : [B]
Q.62 The molarity of water is - [C]
(A) Ag+ (B) Cu2+ (C) Ba2+ (D) Li+
(A) 5.55 mol/L (B) 18.0 mol/L
Q.53 The formation of aniline yellow from
(C) 55.55 mol/L (D) 10 mol/L
benzenediazonium chloride and aniline in acidic
Q.63 Enthalpy of neutralisation of strong acid and
medium is known as-
strong base are - [A]
(A) Coupling Reaction
(A) – 13.7 Kcal (B) – 57.1 Kcal
(B) Gomberg,s Reaction (C) + 13.7 Kcal (D) + 57.1 Kcal
(C) Gattermann Reaction Q.64 Solvent loving colloids are - [B]
(D) Sandmeyer Reaction [A] (A) lyophobic colloid (B) lyophilic colloid
Q.54 Preparation of acetanilide involves the reagents (C) hydrophobic colloid (D) none
aniline, glacial acetic acid and - [C] Q.65 Solvent hating colloids are - [A]
(A) Acetone (B) Acetophenone (A) lyophobic (B) hydrophilic
(C) Acetic anhydride (D) Phenol (C) lyophilic (D) none

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 Q.83 Mixing of SnCl2 to HgCl2 Solutions gives ppt.
Q.74 Brown ring test is made for - [A]
which is -(A)white turning to grey
(A) (B) Cl
(B)black turning to white
(C) I¯ (D) Br¯
(C) white turning to red(D) red turning to white [A]
Q.76 In Lassaingne’s test for deteraction of nitrogen,
Q.84 Soda extract of the salt is prepared by - [D]
the blue colour is due to the compound - [D]
(A) Fusing mixture of baking soda and salt
(A) Na4[Fe(CN)6] (B) NaCN
and then extracting with water
(C) Na3[Fe(CN)6]4 (D) Fe4[Fe(CN)6]3 (B) Dissolving NaHCO3 and salt in dil. HCl
Q.77 For deteraction of sulphur in an organic (C) Boiling Na2 CO3 and salt in dil. HCl
compound, the Lassaigne’s extract is acidified
(D) Boiling Na2CO3 and salt in distilled water
with dilute acetic acid and lead acetate is the
added to it. The black ppt. is obtained which is Q.85 When H2S is passed through Hg22+, we
due to the formation of - [A] get -(A) HgS (B) HgS + Hg2S
(A) PbS (B) Na2S
(C) HgS + Hg (D) Hg2S[C]
(C) PbSO4 (D) PbS2O3
Q.86 In the second group of qualitative analysis, H2S
Q.78 A compound which does not give a positive test is passed through a solution acidified with HCl
in the Lassaigne’s test for nitrogen is [B] in order to -
(A) Urea (B) Hydroxl amine (A) Limit the concentration of S2– ions
(C) Glycine (D) Phenylhydrazine (B) Increase the solubility of H2S
Q.79 An aqueous solution contains SO42– and Cl–
(C) Increase the concentration of S2– ions
ions. Which of the following aqueous solutions
(D) Add the Cl– ions. [A]
will precipitate only SO42– ion but not Cl– ion ?
Q.87 In the Lassaigne’s test the sulphur present in the
(A) NaOH (B) KOH [C] organic compound first changes into - [D]
(C) BaCl2 (D) BaSO4 (A) Na2SO4 (B) CS2
Q.80 When concentrated H2SO4 is added to dry (C) Na2SO4 (D) Na2S
KNO3, brown fumes are evolved. These fumes
Q.88 Ferric ion forms a prussian blue coloured
are due to - [D] precipitate with K4[Fe(CN)6] due to the
(A) SO2 (B) SO2 + SO3 formation of - [B]
(C) NO (D) NO2 (A) K3Fe(CN)6 (B) Fe4[Fe(CN)6]3
Q.81 In order to prevent the hydrolysis of ferrous (C) Fe(OH)3 (D) KFe[(CN)6]
sulphate in the preparation of Mohr’s salt what
Q.89 Manganese salt + PbO2 + conc.HNO3  The
is added - [B]
solution acquires purple colour. The colour is
(A) Con.H2SO4 (B) Dil. H2SO4
due to -(A) HMnO4 (B) a lead salt
(C) Water (D) Conc. HNO3
(C) Mn(NO3)2 (D) H2MnO4[A]
Q.82 Freshly prepared chlorine water is added to the
Q.90 In Victor meyer test reactant in the reaction
aqueous solution of some halide salt containing
follow the order - [B]
some CS2. After shaking the contents, a violet
(A) AgNO2, HNO2, NaOH, (Red P + I2)
colour is appeared in CS2 layer. The halide ion
in solution is - (B) (Red P + I2), AgNO2, HNO2, NaOH

(A) Iodide (B) Bromide (C) AgNO2, NaOH, (Red P + I2), HNO2
(C) Chloride (D) Iodide as well as bromide[A] (D) (Red P + I2), AgNO2, NaOH, HNO2

4
Q.91 Which of the following indicators is used in the Q.101 If ‘a’ is the initial conc. of a substance which
titration of oxalic acid with sodium hydroxide reacts according to zero order kinetic and k is
solution - [D] rate constant, the time for the reaction to go to
completion is(A)a/k (B)2/ka (C)k/a(D)2k/a-[A]
(A) Bromophenol blue (B) Methyl red Q.102 The term-dc/dt in a rate equation referes to -
(C) Methyl orange (D) Phenophthalein (A) the conc. of a reactant [C]
Q.92 Which of the following indicators is used in the (B) the decrease in conc. of the reactant with time
titration of KMnO4 against sodium oxalate in an
(C) the velocity constant of reaction (D) none
acidic medium -
Q.103 The temperature coefficient of a reaction is-
(A) Phenolphthalein (B)Eriochrome black T (A) the rate constt. at a fixed temperature
(C) No indicator is necessary [A] (B) the ratio of rate constt. at two temperatures
(D) Starch (C) the ratio of rate const. differing by10o
Q.93 Ca, Ba and Sr ions are precipitated in fifth (K35/K25) (D) none [C]
group as their - [C] Q.104 The metal ion which is precipitated when H2S is
(A) Oxides (B) Sulphates passed with HCl - [C]
(C) Carbonates (D) Sulphides (A) Zn (B) Ni
2+ 2+ (C) Cd 2+ (D) Mn2+
Q.105 In Nesseler’s reagent for detection of ammonia,
Q.94 AgNO3 gives yellow ppt with - [B] the active speies is - [D]
(A) KIO3 (B) KI (C) CHI3 (D) CH2I2 (A) Hg2Cl2 (B) Hg 2+ (C) Hg2I2 (D) HgI42–
Q.95 Which can be used in place of NH4Cl in III Q.106 Which of the following metal sulphides has
group precipitation - [A] maximum solubility in water - [C]
(A) NH4 NO3 (B) (NH4)2CrO4 (A) HgS,Ksp = 10–54 (B) CdS,Ksp = 10 –30

(C) (NH4)2SO4 (D) NaCl (C) FeS,Ksp = 10–20 (D) ZnS,Ksp = 10–22
Q.23 Which on mixing gives deep brown colour - Q.107 When H2S gas is passed in a metal sulphate
(A) N2O + O2 (B) NO + O2 solution in presence of NH4OH, a white
precipitate is produced. The metal is identified
(C) N2O3 + O2 (D) None [B] as - (A) Zn (B) Fe (C) Pb (D) Hg[A]
Q.96 Redish brown (chocolate) ppt are formed with- Q. 108 When H2S is passed through an ammonical salt
(A) Cu2+ and [Fe(CN)6]2– (B) Ba2+ and SO42– solution X, a white precipitate is obtained. Then
X can be a - [D]
(C) Pb2+ and I– (D) none [A] (A) Co2+ solution (B) Mn2+ solution
Q.97 On passing H2S in II group, sometimes a white (C) Ni2+ solution (D) Zn2+ solution
Q.109 In third group, bromine water is used to test-
turbidity is formed. This is due to - [A]
(A) colloidal sulphur (B) SnS2 (A) Fe3+ ions (B) Cr3+ ions [B]
(C) Al3+ ions (D) All of these
(C) Bi2S3 (D) ZnS
Q.110 In IV group analysis NH4OH is added before
Q.98 For the tests of halides, the soda extract is
acidified with - [B] passing H2S gas because - [C]
(A) dil. H2SO4 (B) dil. HNO3 (A) The sulphides of IV group are insoluble in
(C) dil. HCl (D) any of the three NH4OH
Q.99 The colour developed when sodium sulphide is (B) The sulphides of other metals are soluble in
added to sodium nitroprusside is - [A] NH4OH
(A) violet (B) yellow
(C) red (D) black (C) The concentration of S2- ions is increased
Q.100 All ammonium salts liberate ammonia when-[B] (D) The sulphides of second group are soluble
(A) heated (B) heated with caustic soda in NH4OH
(C) heated with H2SO4(D) heated with NaNO2

5
Q.111 An aq. solution containing Hg; Hg2+, Pb2+ and
Q.120 Which gives blood red colour with ammonium
Cd2+ ions is mixed with dil. HCl. Which will be
thiocyanate - [A]
precipitated - [C]
(A) Hg2Cl2 (B) PbCl2 (A) Fe3+ (B) Fe2+ (C) Cu2+ (D) Cd2+

(C) Both (A) and (B) (D) None of these Q.121 Which combines with Fe2+ to form brown
Q.112 Disodium hydrogen phoshate is used to test - complex - [B]
(A) Mg2+ (B) Na+ [A] (A) N2O (B) NO (C) N2O3 (D) N2O5
(C) Ca2+ (D) All Q.122 In III group precipitation NH4Cl is added before
Q.113 In inorganic salt solution on treatment with HCl adding NH4OH due to - [A]
gives a white precipitate of which metal ions -
(A) Hg (B) Hg2+ [A] (A) decreasing conc. of OH–
(C) Zn 2+ (D) Cd 2+ (B) prevent interference of PO43–
Q.114 An inorganic salt solution gives a yellow (C) increase in conc. of Cl–
preceipte with silver nitrate. The precipitate
(D) increase in conc. of OH– ions
dissolves in dilute nitric acid as well as in
Q.123 Few drops of HNO3 are added to II group
ammonium hydroxide. The solution contains -
(A) Bromide (B) Iodide [A] filtrate before proceeding to III group in order to -

(C) Phosphate (D) Chromate (A) convert Fe2+ to Fe3+ (B) convert Fe3+ to Fe2+
Q.115 Which of the following salts will turn water (C) ppt III group (D) none [A]
coloured when fumes evolved on treatment with Q.127 The heats of neutralisation of four acids A,
conc. H2SO4 are passed in water - [B] B,C,D are – 13.7, – 9.4, – 11.2 and – 12.4 kcal
respectively when they are neutralised by a
(A) Nitrate (B) Bromide
common base. The acidic character obeys the
(C) Both (D) None order -
Q.116 A salt which gives CO2 with hot conc. H2SO4 (A) A > B > C > D (B) A > D > C > B
and also decolourizes acidified KMnO4 on (C) D > C > B > A (D) D > B > C > A [B]
warming is - [C] Q.128 The heat of neutralization of one mole of a
(A) HCO3 (B) CO 32 strong acid (in dilute solution) with one mole of
(C) Oxalate (D) Acetate a strong base is - [D]
Q.117 Sodium extract is heated with conc. HNO3 (A) 24.6 k cal (B) 13.7 k cal
(A) silver halides are insoluble in HNO3 (C) dependent on the acid
(D) dependent on both the acid and the base
(B) Na2S and NaCN are decomposed by HNO3
Q.129 The sulphides of which one of the following
(C) Ag2S is soluble in HNO3
groups of elements are soluble in yellow
(D) AgCN is soluble in HNO3 [B] ammonium sulphide - [A]
Q.118 In the brown ring test for the nitrate ion, (A) As, Sb and Sn (B) As, Cd and Sn
[Fe(H2O)5NO]+2 imparts the colour due to - (C) Cd, Cu and Bi (D) Hg, Cu and Cd
(A)  * Transition Q.130 How do we differentiate between Fe3+ and Cr3+
(B) Charge transfer transition in group III - [D]
(C) d-d transition (D) *  * transition [B] (A) By adding excess of NH4OH solution
Q.119 Na2CO3 cannot be used in place of (NH4)2 CO3 (B) By increasing NH4+ ion concentration
for the precipitation of V group,because -
(C) By decreasing OH– ion concentration
(A) Na+ interferes in the detection of V group (D) Both (B) and (C)
(B) conc.of CO32– is very low
(C) Na will react with acid radicals
(D) Mg will be precipitated [D]
6
Q.131 salt X  Y (gas)
NaOH
[A] Q.136 How do we differentiate between Fe3+ and Cr3+
Heat in qualitative analysis gp. III :
(A) By taking excess of NH4OH
(B) By increasing ion concentration
    (C) By decreasing OH– ion concentration
(D) Both (B) and (C) [D]
Gives brown (Mg3N2 + H2O)
Q.137 Which statement is correct : [D]
ring test (A) Fe3+ ions give deep green precipitate with
K4[Fe(CN)6] solution
Salt X is -
(B) On heating K+, Ca2+ and ions, we get a
(A) NH4NO3 (B) NH4Cl precipitate of K2[Ca(CO3)2]
(C) Manganess salts give a violet borax bead
(C) KNO3 (D) Ba(NO3)2 test in the reducing flame
Heat (D) From a mixed precipitate of AgCl and AgI
Q.132 (KCl + K2 Cr2O 7 + H 2SO4 ) Red Gas
ammonia solution dissolves only AgCl
dil NaOH Q.138 Which compound does not dissolve in hot,
Pb(Ac)2 Yellow
X
Solution dilute HNO3 - [A]
(A) HgS (B) PbS
The formula and colour of X are respectively- (C) CuS (D) CdS
(A) CrO2Cl2, red colour Q.139 An aqueous solution contains Hg2+, Hg22+ ,
Pb2+ and Cd2+. The addition of HCl will
(B) PbCrO4, yellow colour precipitate : [C]
(A) Hg2Cl2 only (B) PbCl2 only
(C) BaCrO4, Green Colour
(C) PbCl2 and Hg2Cl2 (D) PbCl2 and HgCl2
(D) Cr2(SO4)3, Green Colour [B]
Q.140 Which of the following statement is incorrect
Q.133 A substance on treatment with dil H2SO4 when a mixture of NaCl and K2Cr2O7 is gently
liberates a colourless gas which produces warmed with conc. H2SO4 .
(i) Turbidity with baryta water and (A) A deep red vapour is evolved.
(ii) Turns acidified dichromate solution green (B) The vapour when passed into NaOH solution
The reaction indicates the presence of - gives a yellow solution of Na2CrO4.
(A) CO3–2 (B) S–2 (C) Chlorine gas is evolved .
(C) SO3–2 (D) NO2– [C] (D) Chromyl chloride is formed. [C]

Q.134 Match the following : [B] Q.141 Which of the Following statement is incorrect
with reference to the ferrous and ferric ions - [C]
(a) White crystalline ppt (i) Sb2S3
(A) Fe3+ gives brown colour with potassium
(b) Reddish brown ppt (ii) Cr (OH)3 ferricyanide.
(c) orange ppt (iii) PbCl2 (B) Fe3+ gives blue precipitate with potassium
ferrocyanide.
(d) yellow ppt. (iv) Fe (OH)3
(C) Fe3+ gives red colour with potassium
(e) Green ppt. (v) K3 [Co(NO2)6] thiocyanate.
(D) Fe3+ gives brown colour with ammonium
(A) (a – i), (b – Iii), (c – ii), (d – v), (e – iv)
thiocyanate.
(B) (a – iii), (b – iv), (c – i), (d – v), (e – ii) Q.142 Identify the correct order of solubility of Na2S,
(C) (a – iii), (b – iv) , (c – v), (d – i), (e – ii) CuS and ZnS in aqueous medium -
(D) (a – ii), (b – iv), (c – iii), (d – v), (e – i) (A) CuS > ZnS > Na2S
(B) ZnS > Na2S > CuS
Q.135 HgCl2 on passing H2S gives - [A]
(A) HgS (B) Hg2S (C) Na2S > CuS > ZnS
(C) Hg + HgS (D) HgS + H2S (D) Na2S > ZnS > CuS [D]
7
Q.143 An aqueous solution of a substance gives white yellow and finally black precipitate of 'Y' is
precipitate on treatment with dilute hydrochloric formed. Which is correct pair ? [B]
acid, which dissolves on heating . When (A) X is Ag2S and Y is Na3 [Ag(S2O3)2]
hydrogen sulfide is passed through the hot (B) X is Na3[Ag(S2O3)2] and Y is Ag2S
acidic solution, a black precipitate is obtained. (C) X is Ag2S2O3 and Y is Ag2S
The substance is – [D]
(D) X is Ag2S2O3 and Y is Na3[Ag(S2O3)2]
(A) Hg2 salt
2+ (B) Cu salt
2+
Q.150 If NaOH is added to an aqueous solution of
(C) Ag+ salt (D) Pb2+ salt Zn2+ ions, a white precipitate appears and on
Q.144 A gas 'x' is passed through water to form a adding excess of NaOH, the precipitate
saturated solution . The aqueous solution on
dissolves. In this solution, zinc exists in the
treatment with silve rnitrate gives a white
(A) Anionic part (B) Cationic part
precipitate. The saturated aqueous solution also
dissolves magnesium ribbon with evolution of (C) Both in anionic and cationic part
colourless gas 'y'. Identify 'x' and 'y' [C] (D) Colloidal form [A]
(A) x=CO2 , y = Cl2 (B) x= Cl2 , y = CO2 Q.151 Identify A, B and C [B]
 A   B(Purple)
Na2SO4 + Carbon 
Sodium
(C) x= Cl2, y=H2 (D) x = H2, y = Cl2
nitroprusside
Q.145 [X] + H2SO4  [Y] a colourless gas with
irritating smell, CdCO3

[Y] + K2Cr2O7 + H2SO4  green solution. C (yellow ppt)

[X] and [Y] is [A] (A) Na 2 S 2 O 3 , Na 2 [Fe(CN) 5 NOS], CdSO 4
(A) SO32–, SO2 (B) Cl– , HCl respectively
(B) Na2S, Na4[Fe(CN)5NOS], CdS respectively
(C) S2–, H2S (D) CO32–, CO2
(C) Na2S, Na2[Fe(CN)5NOS], CdS respectively
Q. 146 A solution which is 10–3 M each in Mn2+, Fe2+, (D) Na2S, [Fe(H2O)5NO] SO4, CdS respectively.
Zn2+ and Hg2+ is treated with 10–16 M sulphide Q.152 Zinc sulphate solution on mixing with sodium
ion, If KSP of MnS, FeS, ZnS and HgS are carbonate solution give precipitates of A which
10–13, 10–18 , 10–24 and 10–53 respectively, on heating give another solid compound B.
Compound B on heating with cobalt nitrate give
which one will precipitate first : [C]
(A) FeS (B) MgS (C) HgS (D) ZnS a green mass of compound 'C'. 'C' is [D]
Q.147 An aqueous solution of a substance gives a (A) Guigret's green (B) Chinese white
white precipitate on treatment with dil. HCl, (C) Melachite green (D) Rinmann's green
which dissolves on heating. When H2S is passes Q.153 A black compound (X) in solid state is fused
through the hot acidic solution, a black with KOH and KClO3. The aqueous extract is
precipitate is obtained. The substance is a: green colour solution (Y). On passing CO2 gas
(A) Hg 22  salt (B) Cu2+ salt [D] through it pink colour of (Z) is noticed along
(C) Ag salt
+
(D) Pb salt
2+ with some black insoluble mass of X. The pink
Q.148 A gas X is passed through water to form a coloured solution is decolorised by Fe2+ in
saturated solution. The equeous solution on acidic medium. What are (X) (Y) and (Z).
treatment with silvernitratre gives a white (A) MnO2, K2MnO4, MnO4–
precipitate. The saturated aqueous solution also (B) MnO4–, K2MnO4, MnO2
dissolves magnesium ribbon with evolution of (C) MnO4–, MnO2, MnO
colour less gas Y. 'X' and 'Y' are respectively : (D) None of the above [A]
(A) CO2, Cl2 (B) Cl2, CO2 Q.154 A metal nitrate reacts with KI to gives a black
(C) Cl2, H2 (D) H2, Cl2 [C] precipitate which on addition of excess of KI
Q.149 When excess of Na2S2O3 is added to dil. converts into orange colour solution. The cation
AgNO3, a soluble compound 'X' is formed. of metal nitrate is : [B]
However, when dil. Na2S2O3 is added to conc. (A) Hg2+ (B) Bi3+ (C) Pb2+ (D) Cu+
AgNO3 solution, a white precipitate, turning Q.155 An aqueous solution containing a mixture of
copper (II), iron (II) and lead (II) ions was
8
 treated with an excess of aqueous ammonia. (C) nitrates (D) Phosphates
What precipitate was left by this reaction: Sol.[C] [Fe(H2O)5NO] SO4 In the test of nitrate brown
(A) Copper (II) hydroxide only [B] Brown ring. ring is obtained.
(B) Iron (II) hydroxide only Q.163In qualitative analysis Cd is under:
(C) Lead (II) hydroxide only (A) I group (B) II group
(D) Lead (II) hydroxide and iron (II) hydroxide (C) III group (D) IV group
Sol.[B] II Group Basic Radicals. Pb+2 , Cu+2 , Bi+3 , Hg+2 Cd+2
Q.156 [X] + H2SO4   [Y] a colourless gas with
Q.164 Which of the sulphides is yellow ?
irritating smell, (A) ZnS (B) CdS
(C) NiS (D) PbS
[Y] + K2Cr2O7 + H2SO4 
 Green solution,
Sol.[B] CdS is a yellow colour ppt.
[X] and [Y] is : [A] Q.165 Soda extract is prepared by:
(A) SO 32 , SO 2 (B) Cl–, HCl (A) fusing soda and mixture and then extracting
(C) S2–, H2S (D) CO32  , CO 2 with water
Q.157 Flame test is not given by : [A] (B) dissolving NaHCO3 and mixture in dil. HCl
(A) Be2+ ions (B) Ba2+ ions (C) boiling Na2CO3 and mixture in dil. HCl
(C) Ca2+ ions (D) none of these (D) boiling Na2CO3 and mixture of salt in
Q.158 Four test tubes contain four different powered distilled water
substances as :
I [copper (II) oxide]; II [Iron (III) oxide]; Sol.[D] Mixture  Na 2CO 3  water 
of salt  Test tube
III(Silver); IV (Iron). Heat

The addition of which of the following Q.166 On heating a mixture of NaCl, K2Cr2O7 and
reagents can achieve distinction between them ? conc. H2SO4 which of the following is formed ?
(A) NaOH (B) HCl (A) CrO2Cl (B) CrO2Cl2
(C) H2O (D) Na2CO3 [B] (C) CrOCl2 (D) NaClO2
Sol.[B] 4 NaCl + 3H2SO4 + K2Cr2O7 – CrO2Cl2
Q.159 A metal salt solution forms a yellow Chromyl
precipitate with potassium chromate in acetic Chloride
acid, a white precipitate with dilute sulphuric (deep red colour vapour)
acid but gave no precipitate with sodium Q.167 In the test of basic radical group reagent is used
chloride or iodide. The white precipitate in IVth group
obtained when sodium carbonate is added to
(A) (H2S + HCl)
the metal salt solution will consist of -
(A) Lead carbonate (B) NH4OH + NH4Cl
(B) Basic lead carbonate (C) NH4OH + NH4Cl + H2S gas
(C) Barium carbonate (D) NH4OH + NH4Cl + (NH4)2CO3
(D) Strontium carbonate [C] Sol.[C] IV Group reagent  ( NH4OH +NH4Cl + H2S Gas)
Q.160 An orange precipitate of group II is dissolved Q.168 In the test of phosphate, canary yellow
in conc. HCl; the solution when treated with
precipitate is obtained due to formation of
excess water turns milky. The milkiness is
due to formation of - [C] (A) (NH4)2PO4. 12MoO3
(A) Sn(OH)Cl (B) Sb(OH)Cl2 (B) (NH4)3PO4 . 12MoO3
(C) SbOCl (D) Sb(OH)2Cl. (C) (NH4)3PO4.21MoO4
Q.161 A potassium chromate solution is added to (D) (NH4)3PO3.21 MoO3
aqueous solution of metal chloride. The
Sol.[B] (NH4)3PO4. 12 MoO3 . Canary yellow ppt.
precipitate formed in the process is insoluble
(Ammonium phospho molybdate)
in acetic acid. Its flame test is performed. The
Q.169 In the test of acetate when neutral solution of
colour of the flame is - [B]
(A) Lilac (B) Apple green FeCl3 add then which colour solution is formed
(C) Crimson red (D) Golden yellow (A) Blue colour (B) Green colour
Q.162 The brown ring test is performed for the (C) Blood red colour (D) Colourless
qualitative detection of: Sol.[C] 3 CH3COONa + FeCl3 – Fe (CH3COO)3 + 3 NaCl
(A) bromides (B) iodides (Blood red colour)
(Ferric acetate)
9
Q.170 When a substance A reacts with water it (C) CH3CONH2 (D) C6H5NO2 [B]

produces a combustible gas B and a solution of Q.174 Which of following, gives black colour in
a substance C in water. When another substance lassaigne's test –
D reacts with this solution of C, it also produces
(A) C6H5CN (B) H2N COOH
the same gas B even on reaction with dilute
sulphuric acid at room temperature. A imparts a
deep golden yellow colour to a smokeless flame (C) NH2CONH2 (D) H2N SO3Na
of Bunsen burner. A, B, C and D respectively [D]
are - Q.175 When 20 g of a compound [A] (M.F. = C4H10O4)
(A) Na, H2, NaOH and Zn reacts with excess of MeMgBr, 14.6 L of CH4 is
(B) K, H2, KOH and Al obtained at STP. Structural fomula of (A) is -
(C) Ca, H2, Ca(OH)2 and Sn (A) HOH2C(CHOH)2CH2OH
(D) CaC2, C2H2, Ca(OH)2 and Fe
Sol.[A]Na imparts a Golden yellow colour to the flame
HO OH
Q.171 A colourless salt. (A)   
 decolouries
MnO 4– / H 
(B)
Heat HO OH
H2O
X+Y+Z;Z B
gases (C) C(CH2OH)4
Gas Y + B  milkiness. (D) Both A & C [A]
Gas X burns with blue flame. Mark the correct
Q.176 A bottle containing two immiscible liquids is
choices - given to you. These may be separated by-
A X Y Z B (A) Fractionating column
(A) CaCO3 CaO CO CO2 H2CO3 (B) Separating funnel
(B) CaC2O4 CO CO2 CaO Ca(OH)2 (C) Fractional distillation
(D) Steam distillation [B]
(C) CaC2O4 CO2 CO CaO Ca(OH)2
Q.177 Sublimation is process where a solid-
(D) CaOCl2 Cl2 O2 CaO Ca(OH)2
(A) Melts
Sol.[B] CaCO4 
CO + CO2 + CaO (B) Changes into liquid form
(A) (X) (Y) (Z) (C) Boils
CaO + H2O  Ca(OH)2 ; (D) Changes into vapour form directly [D]
Ca(OH)2 + CO2  milikiness Q.178 A mixture contains four solid organic
compounds, A, B, C and D. On heating only C
Q.172 If the temporary hardness of water is measured changes from solid to vapour state. C can be
by the titration against HCl which of the separated from the rest in the mixture by-
(A) Distillation (B) Sublimation
following indicators should we use ?
(C) Fractional distillation (D) Crystallisation [B]
(A) Methyl orange Q.179 A mixture of acetone and methanol can be
separated by-
(B) Phenolphthalein (A) Vaccum distillation (B) Steam distillation
(C) Fractional distillation (D) None [C]
(C) Bromothymol blue Q.180 The best method to separate the mixture of
ortho and para nitrophenol (1:1) is-
(D) No indicators is required [A] (A) Steam distillation (B) Crystallization
Q.173 In which of following N cannot be tested by (C) Vapourisation (D) Colour spectrum[A]
lassaigne's test – Q.181 Turpentine oil can be purified by-
(A)Vaccum distillation(B)Fractional distilliation
(A) C6H5NH2 (B) N2H4 (C) Steam distillation(D) Simple distillation [C]
10
Q.182 Chromatography is used for the purification of- Q.194 In Kjeldahl’s method, CuSO4 acts as-
(A) Solids (B) Gases
(A) Oxidising agent (B) Catalytic agent
(C) Liquids (D) All [D]
(C) Reducing agent (D) Hydrolysing agent[B]
Q.183 The separation of mixture of two compounds by
chromatographic technique is based upon- Q.195 Nitrogen in an organic compound can be
(A) Differential solubilities estimated by-
(B) Different densities (A) Kjeldahl’s method only
(C) Different absorption (B) Duma’s method only
(D) Differential adsorption [D] (C) Both method (D) None of these [C]
Q.184 Which of the following technique is most Q.196 0.2 g of an organic compounds on complete
suitable for purification of cyclohexanone from
combustion produces 0.44 g of CO2, then the
a mixture containing benzoic acid , isoamyl
alcohol, cylclohaxane and cyclohexanone – percentage of carbon in it is-
(A) Crystallisation (B) IR spectroscopy (A) 50 (B) 60 (C) 70 (D) 80 [B]
(C) Sublimation (D) Gas chromatography [D] Q.197 Which is useful for separating benzoic acid
Q.185 The compound that does not give a blue colour from a mixture of benzoic acid and methyl
in Lassaigne’s test is- benzoate-
(A) Aniline (B) Glycine (A) Aq. NaHCO3 (B) Dil.HCI [A]
(C) Hydrazine (D) Urea [C] (C) Dil.H2 SO4 (D) Dil. HNO3
Q.186 In Lassaigne’s test, the organic compound is
fused with sodium metal so as to- Q.198 The process of differential extraction is based
(A) Burn the compound upon-
(B) Form a sodium derivative (A) Differential solubilities
(C) Convert N, S, or halogen into soluble ionic (B) Differential molecular masses
compound (C) Different boiling points
(D) None of these [C] (D) Different chemical properties [A]
Q.199 0.2 g of an organic compound on complete
Q.187 Which of the following compound will give
combustion produces 0.18 g of water, then the
blood red colour while doing the Lassaigne’s
test for N. percentage of hydrogen in it is-
(A) (NH2)2C=O (B) H2N (C6H4)SO3H (A) 5 (B) 10 (C) 15 (D) 20 [B]
Q.200 In column chromatography the MOVING
(C) C6H5 SO3H (D) CHCI3 [B] PHASE is constituted by - [D]
Q.188 In Lassaigne test thiourea is converted into - (A) A substance which have to be separated
(A) NaCNS (B) Na2S (C) NaCN (D) Na2SO4[A] (B) Eluent (C) Adsorbent
Q.189 In a Lassaignes’s test for sulphur in the organic (D) Mixture of eluent and substances to be
compound with sodium nitroprusside solution separated
the purple colour formed is due to- Q.201 Silica gel is used for keeping away the moisture
(A) Na4 [Fe(CN)5 NOS] because it-
(B) Na3 [Fe(CN)5 S] (A) Absorbs H2O (B) Adsorbs H2O
(C) Na2 [Fe(CN)5 NOS] (C) Reacts with H2O (D) None [B]
(D) Na3 [Fe(CN)6 ] [A] Q202 Which process is suitable for the purification of
aniline-
Q.190 If 0.32 gm of an organic compound containing
sulphur produces 0.233g of BaSO4 Then the (A) Simple distillation (B) Steam distillation
(C) Fractional distillation
percentage of sulphur in it is-
(D) Fractional crystallization [B]
(A) 10 (B) 15 (C) 20 (D) 25[B]
Q.191 Carbon and Hydrogen are estimated by- [A] Q.203 Steam distillation is a better method of
purification for...........compounds-
(A) Liebig’s method (B) Duma’s method
(A) Liquids (B) Steam volatile
(C) Carius method (D)Kjeldahl’s method
(C) Non-volatile (D)Miscible with water [B]
Q.192 Duma’s method involves the determination of
content of nitrogen in the organic compound in Q.204 In steam distillation the vapour pressure of the
volatile organic compound is-
the form of-(A) Gaseous NH3 (B) Gaseous N2
(A) Equal to atmospheric pressure
(C) NaCN (D)(NH4)2SO4[B] (B) Less than the atmospheric pressure
Q.193 In Duma’smethod, the gas which is collected in (C) More than the atmospheric pressure
Nitrometer is-(A) N2 (B) NO(C) NH3 (D) H2[A] (D) Just double the atmospheric pressure [B]

11
Q.205 Ellution is the process for- Q.216 To detect iodine in presence of bromine,
(A) Crystallization of compound the sodium extract is treated with
(B) Separation of compound NaNO2 + glacial acetic acid + CCl4. Iodine is
(C) Extraction of compound detected by the appearance of:
(D) Distillation of compound [B]
(A) yellow colour of CCl4 layer
Q.206 Boiling point of a liquid can be increased by-
(A) Increasing the pressure (B) purple colour of CCl4
(B) Decreasing the pressure (C) brown colour in the organic layer of CCl4
(C) Purifying the liquid
(D) Adding water to it [A] (D) deep blue colour in CCl4 [B]
Q.207 0.59 g of an organic substance when treated Q.217 In steam distillation the vapour pressure of
with caustic soda evolved ammonia, which volatile organic compound is:
required 20 c.c. of N/2 sulphuric acid for (A) equal to atmospheric pressure
neutralization. The percentage of nitrogen is- (B) double the atmospheric pressure
(A) 40% (B) 53.6% (C) 63.6% (D) 23.73%[D] (C) less than atmospheric pressure
Q.208 In organic compounds P is estimated as- (D) more than atmospheric pressure [D]
(A) H3PO4 (B) P2O5 Q.218 The sodium extract prepared from sulphanilic
(C) Mg3(PO4)2(D) (NH4)3 PO4 .12MoO3 [D] acid, contains SCN–. It gives blood red
Q.209 Which statement apply best to vacuum colouration with:
distillation- (A) a mixture of Na2S and CS2 (B) FeCl3
(A) Distil liquids quickly with decomposition (C) FeSO4 (D) Na2SO3[B]
(B) It is very easy to distill Q.219 Before testing halogens the sodium extract is
(C) Distil liquid to avoid decomposition boiled with conc. HNO3 to:
(D) None [C] (A) bring common ion effect(B) make solution clear
Q.210 A mixture of naphthalene and benzoic acid can (C) destroy CN– and S– – ions
be separated by-
(D) make the solution acidic [C]
(A) Extraction with solvent (B) Sublimation
Q.220 Kjeldahl’s method cannot be used for the
(C) Fractional crystallisation (D) Distillation[A] estimation of nitrogen in : [D]
Q.211 If on adding FeCl3 solution to acidified (A) Pyridine (B) Nitrocompounds
Lassaigne’s solution, a blood red colouration is (C) Azo compounds (D) All
produced, it indicates the presence of- Q.221 The latest technique used for purification of
(A) S (B) N (C) N and S (D) S and Cl [C] organic compounds is:
Q.212 In carius tube the compound ClCH2–COOH (A) Chromatography (B) Vacuum distillation
(C) Fractional distillation (D) Crystallization[A]
was heated with fuming HNO3 and AgNO3.
Q.222 If 0.2 gram of an organic compound containing
After filteration and washing, a white ppt. was carbon, Hydrogen and oxygen on combustion,
formed. The ppt is- [A] yielded 0.147 gram carbon dioxide and 0.12
(A) AgCl (B) AgNO3(C) Ag2SO4(D) CH2(ClCOOAg gram water. What will be the content of oxygen
in the substance ?
Q.213 Leibig method is used for the estimation of-
(A) 73.29 % (B) 78.45 % (C) 83.23 %(D) 89.50 %[A]
(A) Nitrogen (B) Sulphur Q.223 0.765 g of an acid gives 0.535 g of CO2 and
(C) Carbon and hydrogen (D) Halogens [C]
0.138 g of H2O. Then the ratio of the
Q.214 During Lassaigne’s test, N and S present in an
organic compound changes into- percentage of carbon and hydrogen is:
(A) Na2S and NaCN (B) NaSCN (A) 19 : 2 (B) 18 : 11 (C) 20 : 17 (D) 1 : 7[A]
Q.224 2.79 g of an organic compound when heated in
(C) Na2SO4 and NaCN(D) Na2S and NaCNO [A]
Carius tube with conc. HNO3 and H3PO4
Q.215 Two solids A and B have appreciable different
formed converted into MgNH4.PO4 ppt. The
solubilities in water but their melting points are
very close. The mixture of A and B can be ppt. on heating gave 1.332 g of Mg2P2O7. The
separated by- percentage of P in the compound is
(A) Sublimation(B) Fractional crystallisation (A) 23.33 (B) 13.33 (C) 33.33 (D) 26.66[B]
(C) Distillation(D) Specific method [B]

12
Q.225 Which of the following compounds will give (A) the solid has a positive enthalpy of solution
silver mirror test-(A) CH3COOH (B) HCOOH (B) the solid has a negative enthalpy of solution
(C) CH3CO.COOH (D) None[B] (C) solvent has evaporated
Q.226 In a compound C, H and N atoms are present in (D) the solute is volatile
9 : 1 : 35 by weight. Molecular weight of Q.235 A dibasic acid containing C, H and O, on
compound is 108. Molecular formula of análysis was found to contain C = 26.7% and
compound is:(A) C2H6N2 (B) C3H4N H = 2.2%. The vapour density of its diethyl
(C) C6H8N2 (D) C9H12N3 [C] ester was found to be 73. The molecular
formula of the acid is : [A]
Q.227 The compound formed in the positive test for
(A) C2H2O4 (B) C4H4O4
nitrogen with the Lassaigne solution of an
(C) C3H3O4 (D) None of these
organic compound is:
Q.236 Chloroplatinate of a diacidic base contains 39%
(A) Fe4[Fe(CN)6]3 (B) Na3[Fe(CN)6]
of platinum. Find out equivalent weight and
(C) Fe(CN)3 (D) Na4[Fe(CN)5NOS] [A] molecular weight of the base [B]
(A) 90 (B) 45 (C) 180 (D) 22.5
Q.228 The ammonia evolved from the treatment of
Q.237 In Kjeldahls method the gas evolved from 1.325
0.30 g of an organic compound for the gm sample of a fertilizer is passed into 50 ml of
estimation of nitrogen was passed in 100 mL of 0.203 N H2SO4. 25.32 ml of 0.1980 N NaOH
0.1 M sulphuric acid. The excess of acid are required for the titration of unused acid.
required 20mL of 0.5 M sodium hydroxide Calculate the % of nitrogen in the fertilizer [A]
solution for complete neutralization. The (A) 5.43% (B) 6.83% (C) 8.87% (D) 9.32%
organic compound is : [A] Q.238 In carius method for estimation of P which
(A) urea(B) benzamide(C) acetamide(D) thiourea precipitate are finally obtained ? [B]
(A) Mg NH4PO4 (B) Mg2P2O7
Q.229 Red colour complex ion formed on adding
(C) H3PO4 (D) P2O5
FeCl3 to sodium extract when N and S both are Q.239 For detection of sulphur in an organic
present in organic compound is : [B] compound, sodium nitroprusside is added to the
(A) [Fe(CN)6] 4–
(B) [Fe(CNS)] 2+ sodium extract. A violet colour is obtained due
(C) [Fe(CNS)2]+ (D) [Fe(CN)6]3– to the formation of : [C]
(A) Fe(CN)2 (B) K3Fe(CN)5NS
Q.230 Detection of sulphur in sodium extract is done
(C) Na4[Fe(CN)5NOS] (D) Na4Fe(CN)6
by: (A) lead acetate (B) sodium nitroprusside Q.240 An organic compound is fused with fusion
(C) both (A) and (B) (D) none of these [C] mixture an extracted with HNO3. The extract
Q.231 In an estimation of sulphur by the Carius gives yellow precipitate with ammonium
method 0.2175g of the substance gave 0.5825 g molybdate. It shows the presence of which
element ? (A) P (B) As
of BaSO4. What is the percentage of sulphur in
(C) Both P and As (D) May be P or As or both [D]
the substance ? Q.241 Refining of petroleum involves the process of
(A) 36.78% (B) 20.58% (C) 52.08%(D) 45.52% [A] (A) Simple distillation
Q.232 The best method for the separation of naphthalene (B) Fractional distillation
and benzoic acid from their mixture is : [B] (C) Distillation under reduced pressure
(D) Destructive distillation [B]
(A) chromatography (B) crystallisation
Q.242 A substance which decomposes below its
(C) distillation (D) sublimation boiling point can be best purified by
Q.233 Detection of phosphorus in the compound can (A) Steam distillation
be done by its conversión into phosphate. (B) Simple distillation
Reagent to identify phosphate ion is: (C) Fractional distillation
(D) Distillation under reduced pressure [D]
(A) sodium nitroprusside
Q.243 The non existence of PbI4 is due to :
(B) ammonium molybdate (A) small size of Pb4+ ions and large size of I–
(C) potassium ferrocyanide ions (B) highly oxidizing power of Pb4+ ions
(D) potassium ferricyanide [B] (C) highly reducing power of I– ions
Q.234 A clear solution is heated in a china dish where (D) both (B) and (C) [D]
upon a solid separates from the hot solution. It
is due to the fact that [A]
13