Engineering Materials

Engineering materials refers to the group of materials that are used in the construction of manmade
structures and components. The primary function of an engineering material is to withstand applied loading
without breaking and without exhibiting excessive deflection. The major classifications of engineering
materials include metals, polymers, ceramics, and composites. The important characteristics of the materials
within each of these classes are discussed on this page, and tables of material properties are also provided.

 Metals
o Ferrous Alloys
 Carbon Steel
 Low-Alloy Steel
 Tool Steel
 Stainless Steel
 Cast Iron
o Aluminum Alloys
o Nickel Alloys
o Copper Alloys
o Titanium Alloys

 Polymers
o Thermoplastic Polymers
o Thermosetting Polymers
o Elastomers
 Ceramics
o Glass
o Cements
o Clay Products
o Refractories
o Abrasives
 Composites
o Particulate Composites
o Fibrous Composites
o Laminated Composites

Metals
Metals are the most commonly used class of engineering material. Metal alloys are especially common, and
they are formed by combining a metal with one or more other metallic and/or non-metallic materials. The
combination usually occurs through a process of melting, mixing, and cooling. The goal of alloying is to
improve the properties of the base material in some desirable way. Metal alloy compositions are described in
terms of the percentages of the various elements in the alloy, where the percentages are measured by weight.

Ferrous Alloys

Ferrous alloys have iron as the base element. These alloys and include steels and cast irons. Ferrous alloys
are the most common metal alloys in use due to the abundance of iron, ease of production, and high
versatility of the material. The biggest disadvantage of many ferrous alloys is low corrosion resistance.
Carbon is an important alloying element in all ferrous alloys., higher levels of carbon increase strength and
hardness, and decrease ductility and weldability.
Carbon Steel

Carbon steels are basically just mixtures of iron and carbon. They may contain small amounts of other
elements, but carbon is the primary alloying ingredient. The effect of adding carbon is an increase in
strength and hardness.

Most carbon steels are plain carbon steels, of which there are several types.

Low-Carbon Steel

Low-carbon steel has less than about 0.30% carbon. It is characterized by low strength but high ductility.
Some strengthening can be achieved through cold working, but it does not respond well to heat treatment.
Low-carbon steel is very weldable and is inexpensive to produce. Common uses for low-carbon steel include
wire, structural shapes, machine parts, and sheet metal.

Medium-Carbon Steel

Medium-carbon steel contains between about 0.30% to 0.70% carbon. It can be heat treated to increase
strength, especially with the higher carbon contents. Medium-carbon steel is frequently used for axles, gears,
shafts, and machine parts.

High-Carbon Steel

High-carbon steel contains between about 0.70% to 1.40% carbon. It has high strength but low ductility.
Common uses include drills, cutting tools, knives, and springs.

Low-Alloy Steel

Low-alloy steels, also commonly called alloy steels, contain less than about 8% total alloying ingredients.
Low-alloy steels are typically stronger than carbon steels and have better corrosion resistance.

Some low-alloy steels are designated as high-strength low-alloy (HSLA) steels. What sets HSLA steels apart
from other low-alloy steels is that they are designed to achieve specific mechanical properties rather than to
meet a specific chemical composition.

Tool Steel

Tool steels are primarily used to make tooling for use in manufacturing, for example cutting tools, drill bits,
punches, dies, and chisels. Alloying elements are typically chosen to optimize hardness, wear resistance, and
toughness.

Stainless Steel

Stainless steels have good corrosion resistance, mostly due to the addition of chromium as an alloying
ingredient. Stainless steels have a chromium composition of at least 11%. Passivation occurs with chromium
content at or above 12%, in which case a protective inert film of chromic oxide forms over the material and
prevents oxidation. The corrosion resistance of stainless steel is a result of this passivation.

The table below shows the typical compositions of stainless steels:

Element Austenitic Ferritic Martensitic

Carbon 0.03 - 0.25% 0.08 - 0.20% 0.15 - 1.2%
Chromium 16 - 26% 11 - 27% 11.5 - 18%
Nickel 3.5 - 22% --- ---
Manganese 2% 1 - 1.5% 1%
Silicon 1 - 2% 1% 1%

Austenitic Stainless Steel

Austenitic stainless steel is the most common form of stainless steel. It has the highest general corrosion
resistance among stainless steels. It is also the most weldable of the stainless steels due to its low carbon
content. It can only be strengthened through cold work. Austenitic stainless steels are generally more
expensive than other stainless steels due to nickel content. Austenitic stainless steels are not magnetic,
although ferritic and martensitic stainless steels are. Common applications include fasteners, pressure
vessels, and piping.

Ferritic Stainless Steel

Ferritic stainless steel has high chromium content and medium carbon content. It has good corrosion
resistance rather than high strength. It generally cannot be strengthened through heat treatment, and can only
be strengthened via cold work.

Martensitic Stainless Steel

Martensitic stainless steel has high carbon content (up to 2%) and low chromium content. This higher
carbon content is the primary difference between ferritic and martensitic stainless steels. Due to the high
carbon content, it is difficult to weld. It can be strengthened through heat treatment. Common applications
include cutlery and surgical instruments.

Duplex Stainless Steel

Duplex stainless steel contains both austenitic and ferritic phases. It can have up to twice the strength of
austenitic stainless steel. It also has a high toughness, corrosion resistance, and wear resistance. Duplex
stainless steel is generally as weldable as austenitic, but it has a temperature limit.

Precipitation-Hardenable Stainless Steel

Precipitation-hardened stainless steel can be strengthened through precipitation hardening, which is an age
hardening process. These materials have high strength as well as high resistance to corrosion and
temperature.

Stainless Steel Materials Table

Cast Iron

Cast iron is a ferrous alloy containing high levels of carbon, generally greater than 2%. The carbon present
in the cast iron can take the form of graphite or carbide. Cast irons have a low melting temperature which
makes them well suited to casting.

Gray Cast Iron

Gray cast iron is the most common type. The carbon is in the form of graphite flakes. Gray cast iron is a
brittle material, and its compressive strength is much higher than its tensile strength. The fracture surface of
gray cast iron has a gray color, which is how it got its name.

Ductile Cast Iron (Nodular Cast Iron)

The addition of magnesium to gray cast iron improves the ductility of the material. The resulting material is
called nodular cast iron because the magnesium causes the graphite flakes to form into spherical nodules. It
is also called ductile cast iron. Nodular cast iron has good strength, ductility, and machinability. Common
uses include crankshafts, gears, pump bodies, valves, and machine parts.

White Cast Iron

White cast iron has carbon in the form of carbide, which makes the material hard, brittle, and difficult to
machine. White cast iron is primarily used for wear-resisting components as well as for the production of
malleable cast iron.

Malleable Cast Iron

Malleable cast iron is produced by heat treating white cast iron. The heat treatment improves the ductility of
the material while maintaining its high strength.

Aluminium Alloys

Pure aluminium is soft and weak, but it can be alloyed to increase strength. Pure aluminium has good
corrosion resistance due to an oxide coating those forms over the material and prevents oxidation. Alloying
the aluminium tends to reduce its corrosion resistance.

Aluminium is a widely used material, particularly in the aerospace industry, due to its light weight and
corrosion resistance. Despite the fact that aluminium alloys are generally not as strong as steels, they
nevertheless have a good strength-to-weight ratio.

Aluminium alloys are named according to a 4-digit number, where the first number indicates the major
alloying element. A processing code follows the 4-digit number, which indicates the condition and treatment
of the material.

Series Major Alloying Element Heat Treatable

1XXX None (commercially pure) No
2XXX Copper Yes
3XXX Manganese No
4XXX Silicon No (mostly)
5XXX Magnesium No
6XXX Magnesium and Silicon Yes
7XXX Zinc Yes
Suffix Treatment
-F As fabricated
-O Annealed
-HX Cold worked (strain hardened)
-TX Solution heat treated; precipitation hardened

Nickel Alloys

Nickel alloys have high temperature and corrosion resistance. Common alloying ingredients include copper,
chromium, and iron. Common nickel alloys include Monel, K-Monel, Inconel, and Hastelloy.

The table below provides representative mechanical properties for several common nickel alloys.

Copper Alloys

Copper alloys are generally characterized as being electrically conductive, having good corrosion resistance,
and being relatively easy to form and cast. While they are a useful engineering material, copper alloys are
also very attractive and are commonly used in decorative applications.
Copper alloys primarily consist of brasses and bronzes. Zinc is the major alloying ingredient in brass. Tin is
a major alloying element in most bronzes. Bronzes may also contain aluminum, nickel, zinc, silicon, and
other elements. The bronzes are typically stronger than the brasses while still maintaining good corrosion
resistance.

The aluminium bronze alloys are very hard and have good wearing properties, and so are commonly used in
bearing applications. The beryllium copper alloys have good strength and fatigue properties, and good wear
resistance when lubricated properly. Beryllium copper is commonly used for springs, bearings, and
bushings.

Titanium Alloys

Titanium alloys are light, strong, and have high corrosion resistance. Their density is much lower than steel,
and their strength-to-weight ratio is excellent. For this reason, titanium alloys are used fairly commonly,
especially in the aerospace industry. One primary downside of titanium alloys is the high cost.

There are three categories of titanium alloys: alpha alloys, beta alloys, and alpha-beta alloys. Alpha alloys
do not respond to heat treatment and are instead strengthened through solid-solution strengthening
processes. The beta and alpha-beta alloys can be strengthened by heat treatment, primarily through
precipitation hardening. Titanium alloys are identified using the percentages of alloying elements, for
example Ti-6Al-4V. Polymers

Polymers are materials that consist of molecules formed by long chains of repeating units. They may be
natural or synthetic. Many useful engineering materials are polymers, such as plastics, rubbers, fibers,
adhesives, and coatings. Polymers are classified as thermoplastic polymers, thermosetting polymers
(thermosets), and elastomers.

Thermoplastic Polymers

The classification of thermoplastics and thermosets is based on their response to heat. If heat is applied to a
thermoplastic, it will soften and melt. Once it is cooled, it will return to solid form. Thermoplastics do not
experience any chemical change through repeated heating and cooling (unless the temperature is high
enough to break the molecular bonds). They are therefore very well suited to injection moulding.

Thermosetting Polymers

Thermosets are typically heated during initial processing, after which they become permanently hard.
Thermosets will not melt upon reheating. If the applied heat becomes extreme however, the thermoset will
degrade due to breaking of the molecular bonds. Thermosets typically have greater hardness and strength
than thermoplastics. They also typically have better dimensional stability than thermoplastics, meaning that
they are better at maintaining their original dimensions when subjected to temperature and moisture
changes.

Elastomers

Elastomers are highly elastic polymers with mechanical properties similar to rubber. Elastomers are
commonly used for seals, adhesives, hoses, belts, and other flexible parts. The strength and stiffness of
rubber can be increased through a process called vulcanization, which involves adding sulphur and
subjecting the material to high temperature and pressure. This process causes cross-links to form between
the polymer chains.

Ceramics
Ceramics are solid compounds that may consist of metallic or non-metallic elements. The primary
classifications of ceramics include glasses, cements, clay products, refractories, and abrasives.

Ceramics generally have excellent corrosion and wear resistance, high melting temperature, high stiffness,
and low electrical and thermal conductivity. Ceramics are also very brittle materials.

Glass

Glasses are common materials and are seen in applications including windows, lenses, and containers.
Glasses are amorphous, whereas the other ceramics are mainly crystalline. Primary advantages of glasses
include transparency and ease of fabrication. The base element of most glasses is silica, and other
components can be added to modify its properties. Common processes used to form glass include:

 heating until melting, then pouring into Molds to cast into useful shapes
 heating until soft, then rolling
 heating until soft, then blowing into desired shapes

Cements

Cements are materials that, after mixing with water, form a paste that then hardens. Because of this
characteristic, cements can be formed into useful shapes while in paste form before they harden into rigid
structures. Plaster of Paris is one common cement. The most common cement is called Portland cement,
which is made by mixing clay and limestone and then firing at high temperature. Portland cement is used to
form concrete, which is made by mixing it with sand, gravel, and water. It can also be mixed with sand and
water to form mortar. Like other ceramics, cements are weak in tension but strong in compression. Cement
is very inexpensive to produce, and it is used widely in the construction of buildings, bridges, and other
large structures.

Clay Products

Clay is a very common ceramic material. It can be mixed with water, shaped, and then hardened through
firing at high temperature. The two primary classifications of clay products include structural clay products
and whitewares. Structural clay products see applications including bricks, tiles, and piping. Whitewares see
applications including pottery and plumbing fixtures.

Refractories

Refractory ceramics can withstand high temperatures and extreme environments. They can also provide
thermal insulation. Brick is the most common refractory ceramic.

Abrasives

Abrasive ceramics are hard materials that are used to cut, grind, and wear away other softer materials.
Typical properties of abrasives include high hardness, wear resistance, and temperature resistance.
Abrasives can either be bonded to a surface (e.g., grinding wheels and sandpaper), or can be used as loose
grains (e.g., sand blasting). Common abrasives include cemented carbide, silicon carbide, tungsten carbide,
aluminium oxide, and silica sand. Diamond is also an excellent abrasive, but it is expensive.

Composites
A composite material is a material in which one or more mutually insoluble materials are mixed or bonded
together. The primary classes of composites are particulate composites, fibrous composites, and laminated
composites.
Particulate Composites

Particulate composites are created by adding particles of one material to a matrix (the filler material). The
particles will typically account for less than 15% of the total material volume. The particles are added to
improve upon some shortcoming of the matrix material.

Fibrous Composites

A fibrous composite is a material in which Fibers of one material are embedded within a matrix. The fibres
carry most of the stress, and the matrix serves to hold the Fibers in place and to transmit stress between the
Fibers. The Fibers can be short and randomly oriented, or they can be long and continuous.

Laminated Composites

Laminated composites are created by combining layers of composite materials. The layers will typically
differ in the orientation of the Fibers, or they will differ in the material itself. Sandwich materials are
common, in which a lightweight material (such as foam or a honeycomb) will be placed in between layers of
a strong, stiff material.