SRI CHAITANYA IIT ACADEMY, INDIA 19-01-25_ Sr.

S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-19/14_KEY &SOL’S

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.S60_Elite, Target & LIIT-BTs JEE-MAIN Date: 19-01-2025
Time: 09.00Am to 12.00Pm GTM-19/14 Max. Marks: 300!
KEY SHEET
MATHEMATICS
1 2 2 1 3 2 4 1 5 2
6 1 7 3 8 1 9 1 10 1
11 3 12 4 13 2 14 2 15 1
16 4 17 4 18 3 19 4 20 1
21 26 22 25 23 35 24 1 25 7

PHYSICS
26 3 27 3 28 2 29 3 30 2
31 2 32 3 33 3 34 2 35 3
36 2 37 1 38 2 39 2 40 3
41 3 42 1 43 1 44 4 45 2
46 30 47 30 48 35 49 25 50 3

CHEMISTRY
51 1 52 1 53 1 54 2 55 1
56 1 57 2 58 1 59 3 60 1
61 1 62 3 63 1 64 1 65 1
66 2 67 4 68 3 69 2 70 4
71 0 72 9 73 3 74 7 75 8

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 SRI CHAITANYA IIT ACADEMY, INDIA 19-01-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-19/14_KEY &SOL’S

SOLUTION
MATHEMATICS

1.
2. Observe that R1 = { (1, 2), (3,2), (1, 1), (2, 2), (3, 3), (2, 1), (2,3 ) } is the only relation on
{1, 2, 3} which is reflexive, symmetric but not transitive and is such that (2, 1), (2, 3) 
R1.  (A) is the correct alternative.
2 2
ïì 3 x , x < 1
3. f1 =í 2
Not differentiable at x = 1, - 1
ïî 1, x > 1
4. Let E1  Event of selecting a coin with both sides & E2 –ve event of selecting P(E1) =
40  31
20/51, P(E2) = 31/51 Req. event, P(E) = 20/51 × 1+ 31/51 × ½ = = 71/102
102
5. use cot  - tan  = 2cot 2
dx =  sec x  sec x  tan3x dx   dt3 (t = sec x + tan x)=   sec x  tan x  2  C
1
6. (A)  sec x
 sec x  tan x 
2
 sec x  tan x  t 2

(B)
(C)  1  2 tan x (tan x  sec x )dx   (sec x  tan x ) dx

(D) Let
dy
yx dy 1
7. xe dx
 ln x  xy   ydy   ln xdx
dx x
y 2  ln x 
2

ln x 
2
 k  y   C
2 2
2 a 2 a
8. f (2 – ) = f (2+)function is symmetric about the line x = 2. 
2a
f(x) dx  2 
2
f(x) dx .

9. Maximum value of 4sin2x + 3cos2 x is 4 and that of sin x + cos x is 2 ,

2 2
both attained at x = /2. hence the given function has maximum value 4 + 2 .
1 n x  n2 x2
10. 2  [ n1 ( 12  d12 )  n2 ( 22  d 22 )] , where d1  x1  x , d 2  x2  x and x  1 1
n1  n2 n1  n2
   
11. a = 4 , b = 5, a ´ b = 10 , Use Lagrange’s identity

6 15 3
3 1 1
3 2 4 270
12. S.D.    270 = 3 30 .
(4  2) 2  (12  3)2  (6  3) 2 270
13. 599  (5) (52 )49  5(25)49  5(26  1) 49

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 SRI CHAITANYA IIT ACADEMY, INDIA 19-01-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-19/14_KEY &SOL’S
= 5  (26)  (Positive terms)–5, So, when it is divided by 13 it gives the remainder – 5 or
(13 – 5) i.e., 8.
14. f (x ) = 3x 7 + 4 x3 + 9 x + 109 = 0
f ' (x ) = 21x6 + 12 x 2 + 9 > 0" x.
\ f is an increasing function
\ Only one real root
15.
S1 : 3, 7, 11, 15, ……, 399 with common difference 4 = d1
S2 : 2, 5, 8, 11, ……, 359 with common difference 3 = d2
Common difference of A.P. formed by common terms of S1, S2 is
D = L.C.M. of (4, 3) = 12
So series 11,23,….
30
 Sum of common terms of S is (11  359)  5550
2
16. Since y-axis is major axis  f(4a) < f(a2 – 5)
 4a > a2 – 5 ( f is decreasing)
 a2 – 4a – 5 < 0  a  (–1, 5)
17. Let a, b, e1 be the semi major axis, semi minor axis and eccentricity of ellipse.
a1,b1,e2 be the semi transverse axis, semi conjugate axis and eccentricity of Hyperbola.
a 1
Given (a e1,0)  (a1, 0)  1

a e1
a
(a, 0) = (a1e2 ,0)   e2  e1e 2  1
a1
18. Diagonals are passing through A and parallel to the angular bisectors of the given lines
19. G.E = 6 - 2 + 12 - 4 = 18 - 6
20. Characteristicequation of Ais given by A  l  0
4 2
 0   2   4       4   2   0
  
So, A2   4    A   4  2  I  0, A  4   2  18
21. C   2,1 , P= 14,6  , r=5,max= CP+r, min = CP-r
22. Given  ,  are roots of the equation x 2  2 x  5  0
 2  2  5  0   n 2  2 n1.  5 n  0 & n2  2 n1.  5 n  0
P15 P16  2 P14 P16  2 P152  4 P14 P15  P  2 P14  P16  2 P15 
=  15
P13 P14 P13 P14
23. Rank of the word when letters are repeated

24. f(x)
8
a  4
2
25.  5a  64  0  16  a  3  probability  2/9
36

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 SRI CHAITANYA IIT ACADEMY, INDIA 19-01-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-19/14_KEY &SOL’S

PHYSICS
26. Charge on capacitor CV = capacitance x (voltage across it)
In steady state, there will be no current through capacitor.

E R2
Voltage across capacitor V = iR2 =
R2 + r
C E R2
Charge on capacitor = CiR2 =
R2 + r
27.

1 2
mgR 1  cos    mv
2
m v 2  2 g R 1  cos      1 
2
mv
m g co s   N 
R
a t tim e o f le a v in g N  0
mv2
so m g co s  
R
2 g R 1  c o s  
g co s  
R
3 cos   2
2
co s  
3
 2
v  2 g R 1  c o s   2 gR 1  
 3
2
 gR
3
28.

GM 2
Fn et 
4R2
1 2 2  
M  2R 
GM 2
4R2
2 2 1  
 
GM
4R2
2 2 1  
3
4 R 2

GM 2 2  1 
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 SRI CHAITANYA IIT ACADEMY, INDIA 19-01-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-19/14_KEY &SOL’S
29. Q-value Final binding energy Initial binding energy =E2N2+ E3N3-EN1
30. In case of pure rolling a can be obtained about bottommost point, about which torque of
friction is zero

F (2R) 4 F
 2

3/2 mR 3 mR
4F
a  R 
3m
31. First process is constant pressure
Hence W1 = nR(2T0 - T0 ) = nRT0
c
Equation of second process is T =
V
nRT nR c
Hence, P =  2
V v

2V0
nRT0 W1
 W2 =  Pd v= , =2:1
V0
2 W2
32. BOD  0
BOB  0
0 I  I
BAB 
4 a 2   8 a 
cos 450  iˆ   cos 450 kˆ   0 iˆ  kˆ 

33. Conceptual
34. Conceptual
35. In a pressure cooker the water is brought to boil, if temperature is 100°C. When the lid of
cooker is opened, pressure is lowered so that boiling point decreases and water boils
again. Generally, impurities increase the boiling point.

36.

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 SRI CHAITANYA IIT ACADEMY, INDIA 19-01-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-19/14_KEY &SOL’S

di di
VA  5V ,VC  20v  L  Va  VC  ir  16v   1.6 A / s
dt dt
37. Conceptual

38. When light ray is going from rarer to denser medium at polarising angle
i  
p D  tan i p
R
39. Conceptual
40. Conceptual
41. Conceptual.
KQ KQ
42. E 3
r  2 at r  R
R 4r
dE KQ KQ
At r  R, E is min imum when 0 3 r 2 0
dr R 8r
E   at r  0and E  0 at r  
These variations are best represented by point 1
 R R2  2
2  
43. R   12  2
 R1 R2 
 0.2 0.1  2
2  
R   2   2
  6  3  
 
 0.07 ohm
R   2  0.07  ohm
44. If Assertion is false but the Reason is true.
45. Conceptual
46. by lami’s theorem
z0 3g

sin g 0  
sin    
2 
20 3  10 3
 cos     300
1   2
sin    
2 

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 SRI CHAITANYA IIT ACADEMY, INDIA 19-01-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-19/14_KEY &SOL’S

47.
12 75
i 
8R R
5
R  750 300
i1  
3R R R
R
2
300
TP  TQ   R  300
R
48. Applying conservation of linear momentum at the time of collision or at t = 1 s,
mv  m (0)  2m (20î  10 j )
 v  40î  20 ˆj
At 1 s, masses will be at height
1
h1 = u y t + vy t 2  (20)(1) + ( - 10)(1)2 = 15 m
2
After explosion other mass will further rise to a
height:
u y2 (20)2
h2  =
2 g 2 × 10
 20 m
u y  20 m/s just after collision.

 Total height h  h1  h2  35 m

49. Conceptual

50. Conceptual

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 SRI CHAITANYA IIT ACADEMY, INDIA 19-01-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-19/14_KEY &SOL’S

CHEMISTRY
10xd
51. M
M2
d  1.22 g / ml
 w
x%  
 w
10  4.9  1.22
M
98
 0.61M
52. Conceptual
53. Due to boiling denaturation of protein take place.
54. Inter halogen compounds are more reactive
55. For strong acids in aqueous solution
  100%
K a  It is difficult todetermine K a valueacid
56. Factual (see graph)
57. Only in
CH Br

(Compound)
C2 H 5
Both the direction in cyclic ring are different.
58.
Br

H 2O
 NaOH 
  NaBr 

OH

(Major) 
OH 


59. Hint: This one is hell -Volhard Zelinsky reaction so here halogen substitutional is at
  position
60.
NH 3 NH 3

NH 3

en C0 en C0
en

en (Cis-form) NH 3 (Trans-form)

61. Two enantiomers from cis-form and one transform only so total 3 stereo isomers
A(q);B(s);C(p);D(r)
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 SRI CHAITANYA IIT ACADEMY, INDIA 19-01-25_ Sr.S60_Elite, Target & LIIT-BTs _Jee-Main_GTM-19/14_KEY &SOL’S
No. of C-atoms in 1 g molecule of CO 2 = N 0
48
(B) No. of molecules in 48 g of O 2 =  N 0  1.5N 0
32
N
(C) No. of molecules in 11.2 L H 2 at STP = 0  0.5N 0
2
(D) No. of H-atoms in 1 mole of NH3 = 3 x No = 3N 0
62. Due to its shape.
63. Conceptual
64. s electrons are closer to nucleus than p electrons, hence ionisation energy of s electrons is
higher than p electrons
65. x-y = 8-2 = 6
M
Eq.wt of Potash alum =
8
M
Eq.wt of Gypsum =
2
66. (2)
Due to weakest back bonding strength BI3 is the strongest Lewis acid.
67. Conceptual.
68. Conceptual.
69. A is phenol So D.O.U.S = 3+1=4
70. (Ans:4) Conceptual (fact)
71. (Zero) Conceptual – Slater scheme
72. U will be same for both the paths as U is a state function
O

Stucture H O P O H

O H
73.

74. (Ans:7) Gd=  X e  4f 7 ,5d1 ,6s 2

75. (Ans:8)
O
O

H O Cl O

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