Claire - Vandal Mark Remover
Claire - Vandal Mark Remover
0
Revision Date: 09/27/2019
Recommended restrictions
Restrictions on use: Not known.
Manufacturer/Importer/Distributor Information
Manufacturer
2. Hazard(s) identification
Hazard Classification
Physical Hazards
Flammable aerosol Category 1
Health Hazards
Skin Corrosion/Irritation Category 2
Serious Eye Damage/Eye Irritation Category 2A
Toxic to reproduction Category 2
Aspiration Hazard Category 1
Environmental Hazards
Acute hazards to the aquatic Category 3
environment
Label Elements
Hazard Symbol:
Precautionary
Statements
Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Do not spray on an open flame or other ignition
source. Do not pierce or burn, even after use. Wash thoroughly after
handling. Wear protective gloves/protective clothing/eye protection/face
protection. Obtain special instructions before use. Do not handle until all
safety precautions have been read and understood. Use personal protective
equipment as required. Avoid release to the environment.
Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of
water If skin irritation occurs: Get medical advice/attention. IF
SWALLOWED: Immediately call a POISON CENTER/doctor Do NOT
induce vomiting. IF exposed or concerned: Get medical advice/attention.
Specific treatment (see on this label). Take off contaminated clothing.
3. Composition/information on ingredients
Mixtures
4. First-aid measures
Ingestion: Call a physician or poison control center immediately. Rinse mouth. Never
give liquid to an unconscious person. If vomiting occurs, keep head low so
that stomach content doesn't get into the lungs.
Skin Contact: Immediately flush with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Wash contaminated clothing
before reuse. Get medical attention.
Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do,
remove contact lenses. Get medical attention.
5. Fire-fighting measures
General Fire Hazards: Use water spray to keep fire-exposed containers cool. Fight fire from a
protected location. Move containers from fire area if you can do so without
risk.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media:
Specific hazards arising from Vapors may travel considerable distance to a source of ignition and flash
the chemical: back.
Special protective equipment Firefighters must use standard protective equipment including flame
for fire-fighters: retardant coat, helmet with face shield, gloves, rubber boots, and in
enclosed spaces, SCBA.
Personal precautions, Ventilate closed spaces before entering them. ELIMINATE all ignition
protective equipment and sources (no smoking, flares, sparks or flames in immediate area). Keep
emergency procedures: upwind. See Section 8 of the SDS for Personal Protective Equipment. Do
not touch damaged containers or spilled material unless wearing
appropriate protective clothing. Keep unauthorized personnel away.
Methods and material for Absorb spill with vermiculite or other inert material, then place in a container
containment and cleaning for chemical waste.
up:
Notification Procedures: Prevent entry into waterways, sewer, basements or confined areas. Stop
the flow of material, if this is without risk. ELIMINATE all ignition sources
(no smoking, flares, sparks or flames in immediate area). Stop leak if you
can do so without risk.
Environmental Precautions: Avoid release to the environment. Prevent further leakage or spillage if safe
to do so. Do not contaminate water sources or sewer.
Precautions for safe handling: Avoid contact with eyes. Wash hands thoroughly after handling. Keep away
from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Do not spray on an open flame or other ignition source. Do not
pierce or burn, even after use. Do not handle until all safety precautions
have been read and understood. Obtain special instructions before use.
Use personal protective equipment as required. Avoid contact with skin.
Conditions for safe storage, Store locked up. Pressurized container: protect from sunlight and do not
including any expose to temperatures exceeding 50°C. Do not pierce or burn, even after
incompatibilities: use. Aerosol Level 2
Control Parameters
Occupational Exposure Limits
Chemical Identity Type Exposure Limit Values Source
Benzene, methyl- STEL 150 ppm 560 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
REL 100 ppm 375 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
TWA 100 ppm 375 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
Ceiling 300 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02 2006)
TWA 20 ppm US. ACGIH Threshold Limit Values (2008)
TWA 200 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02 2006)
MAX. 500 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02 2006)
CONC
STEL 150 ppm 560 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
Propane REL 1,000 ppm 1,800 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
PEL 1,000 ppm 1,800 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
CFR 1910.1000) (02 2006)
TWA 1,000 ppm 1,800 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
2-Propanone STEL 1,000 ppm 2,400 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
PEL 1,000 ppm 2,400 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
CFR 1910.1000) (02 2006)
TWA 250 ppm US. ACGIH Threshold Limit Values (03 2015)
TWA 750 ppm 1,800 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
STEL 500 ppm US. ACGIH Threshold Limit Values (03 2015)
REL 250 ppm 590 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
Butane REL 800 ppm 1,900 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
STEL 1,000 ppm US. ACGIH Threshold Limit Values (03 2018)
TWA 800 ppm 1,900 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
Ethanol, 2-butoxy- TWA 20 ppm US. ACGIH Threshold Limit Values (2008)
TWA 25 ppm 120 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
REL 5 ppm 24 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
PEL 50 ppm 240 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
CFR 1910.1000) (02 2006)
Ethanol, 2-(2-butoxyethoxy)- TWA 10 ppm US. ACGIH Threshold Limit Values (03 2013)
- Inhalable fraction and
vapor.
Sodium hydroxide (Na(OH)) Ceiling 2 mg/m3 US. ACGIH Threshold Limit Values (2008)
Ceiling 2 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
Ceil_T 2 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
ime
PEL 2 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
CFR 1910.1000) (02 2006)
Morpholine REL 20 ppm 70 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
STEL 30 ppm 105 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
TWA 20 ppm US. ACGIH Threshold Limit Values (2008)
TWA 20 ppm 70 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
STEL 30 ppm 105 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
PEL 20 ppm 70 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
CFR 1910.1000) (02 2006)
Quartz (SiO2) - Respirable REL 0.05 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
dust.
Quartz (SiO2) - Respirable. TWA 2.4 millions of US. OSHA Table Z-3 (29 CFR 1910.1000) (2000)
particles per
cubic foot of
air
TWA 0.1 mg/m3 US. OSHA Table Z-3 (29 CFR 1910.1000) (2000)
Quartz (SiO2) - Respirable TWA 0.025 mg/m3 US. ACGIH Threshold Limit Values (2008)
fraction.
Quartz (SiO2) - Respirable TWA 0.1 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
dust.
Quartz (SiO2) - Respirable TWA 0.05 mg/m3 US. OSHA Specifically Regulated Substances (29 CFR
dust. 1910.1001-1053) (03 2016)
Quartz (SiO2) - Respirable PEL 0.05 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
dust. CFR 1910.1000) (03 2016)
Quartz (SiO2) - Respirable OSHA 0.025 mg/m3 US. OSHA Specifically Regulated Substances (29 CFR
dust. _ACT 1910.1001-1053) (03 2016)
Ethanol, 2-methoxy- TWA 0.1 ppm US. ACGIH Threshold Limit Values (2008)
REL 0.1 ppm 0.3 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
TWA 25 ppm 80 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
PEL 25 ppm 80 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
CFR 1910.1000) (02 2006)
1,2-Ethanediamine TWA 10 ppm US. ACGIH Threshold Limit Values (2008)
PEL 10 ppm 25 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29
CFR 1910.1000) (02 2006)
TWA 10 ppm 25 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989)
REL 10 ppm 25 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards (2005)
General information: Provide easy access to water supply and eye wash facilities. Good general
ventilation (typically 10 air changes per hour) should be used. Ventilation
rates should be matched to conditions. If applicable, use process
enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure
limits have not been established, maintain airborne levels to an acceptable
level. If exposure limits have not been established, maintain airborne levels
to an acceptable level.
Eye/face protection: Wear safety glasses with side shields (or goggles).
Skin Protection
Hand Protection: No data available.
Respiratory Protection: In case of inadequate ventilation use suitable respirator. Seek advice from
local supervisor.
Hygiene measures: Avoid contact with eyes. Observe good industrial hygiene practices. When
using do not smoke. Do not handle until all safety precautions have been
read and understood. Obtain special instructions before use. Wash
contaminated clothing before reuse. Avoid contact with skin. Wash hands
before breaks and immediately after handling the product.
Appearance
Physical state: liquid
Form: Spray Aerosol
Color: No data available.
Odor: No data available.
Odor threshold: No data available.
pH: No data available.
Melting point/freezing point: No data available.
Initial boiling point and boiling range: No data available.
Flash Point: -104.44 °C
Evaporation rate: No data available.
Flammability (solid, gas): No data available.
Upper/lower limit on flammability or explosive limits
Flammability limit - upper (%): No data available.
Flammability limit - lower (%): No data available.
Explosive limit - upper (%): No data available.
Explosive limit - lower (%): No data available.
Vapor pressure: 413.682 - 517.1025 hPa (20 °C)
689.47 - 827.364 hPa (50 °C)
Oral
Product: ATEmix: 33,509.32 mg/kg
Dermal
Product: ATEmix: 11,647.52 mg/kg
Inhalation
Product: ATEmix: 496.89 mg/l
ATEmix : 82.82 mg/l
SDS_US - RE1000010419 7/13
Version: 1.0
Revision Date: 09/27/2019
Skin Corrosion/Irritation
Product: No data available.
Carcinogenicity
Product: No data available.
In vitro
Product: No data available.
In vivo
Product: No data available.
Reproductive toxicity
Product: No data available.
Aspiration Hazard
Product: No data available.
Ecotoxicity:
Fish
Product: No data available.
Aquatic Invertebrates
Product: No data available.
Fish
Product: No data available.
Aquatic Invertebrates
Product: No data available.
Biodegradation
Product: No data available.
BOD/COD Ratio
Product: No data available.
Bioaccumulative potential
Bioconcentration Factor (BCF)
Product: No data available.
Disposal instructions: Discharge, treatment, or disposal may be subject to national, state, or local
laws.
DOT
UN Number: UN 1950
UN Proper Shipping Name: Aerosols, flammable
Transport Hazard Class(es)
Class: 2.1
Label(s): –
Packing Group: II
Marine Pollutant: No
Environmental Hazards: No
Marine Pollutant No
IMDG
UN Number: UN 1950
UN Proper Shipping Name: Aerosols, flammable
Transport Hazard Class(es)
Class: 2
Label(s): –
EmS No.:
Packing Group: –
Environmental Hazards: No
Marine Pollutant No
IATA
UN Number: UN 1950
Proper Shipping Name: Aerosols, flammable
Transport Hazard Class(es):
Class: 2.1
Label(s): –
Packing Group: –
Environmental Hazards: No
Marine Pollutant No
US Federal Regulations
alkyl)dimethylammonium
salt with b
Sodium hydroxide 10000 lbs
(Na(OH))
Morpholine 10000 lbs
Quartz (SiO2) 10000 lbs
Ethanol, 2-methoxy- 10000 lbs
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130):
Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)
US State Regulations
US. California Proposition 65
This product contains chemical(s) known to the State of California to cause cancer and/or to cause birth
defects or other reproductive harm.
Benzene, methyl- Developmental toxin. 03 2008
Quartz (SiO2) Carcinogenic. 05 2011
Ethanol, 2-methoxy- Developmental toxin. 03 2008
Ethanol, 2-methoxy- Male reproductive toxin. 03 2008
US. New Jersey Worker and Community Right-to-Know Act
Chemical Identity
Water
Benzene, methyl-
Propane
2-Propanone
Butane
Ethanol, 2-butoxy-
Ethanol, 2-(2-butoxyethoxy)-
US. Massachusetts RTK - Substance List
Chemical Identity
Quartz (SiO2)
1,2-Ethanediamine
US. Pennsylvania RTK - Hazardous Substances
Chemical Identity
Benzene, methyl-
Propane
2-Propanone
Butane
Ethanol, 2-butoxy-
Ethanol, 2-(2-butoxyethoxy)-
9-Octadecenoic acid (9Z)-
US. Rhode Island RTK
No ingredient regulated by RI Right-to-Know Law present.
International regulations
Montreal protocol
2-Propanone
SDS_US - RE1000010419 12/13
Version: 1.0
Revision Date: 09/27/2019
Stockholm convention
2-Propanone
Rotterdam convention
2-Propanone
Kyoto protocol
Inventory Status:
Australia AICS: On or in compliance with the inventory
Korea Existing Chemicals Inv. (KECI): Not in compliance with the inventory.
China Inv. Existing Chemical Substances: Not in compliance with the inventory.
Version #: 1.0