Sudip Ghosh
Sudip Ghosh
EXERCISES ON EXERGY
by
SUDIP GHOSH
Prob.1 A fixed mass of gas expands frictionlessly at a constant pressure of 100 kPa from
0.15 m3 to 0.3 m3. If the total internal energy increases by 25kJ and the temperature
change in the process is 40oC, estimate:
(i) mass of gas,
(ii) enthalpy change in the process and
(iii) heat supplied
Assume cv = 0.72.
Do you find any inconsistency in the problem data?
Prob.2 In an expander, air expands adiabatically from initial conditions of p1=0.4 MPa,
V1=3 m3, T1=200oC to the final pressure of p2=0.1 MPa. Estimate the technical work
Wt, change in U and the air mass flow rate assuming the expander as a steady flow
device, cp=1.005 kJ/kg-K and =1.41.
Also estimate the technical work if the expansion is considered polytropic having n=1.25.
Prob.3 Water at 25oC is converted to saturated steam under atmospheric pressure of 101
kPa. Calculate the change in entropy per kg of water.
If the conversion takes place in a recovery boiler, having water mass flow rate of 5 kg/s
and gas flow rate of 60kg/s, calculate the net change in entropy in the recovery boiler and
the associated irreversibility, assuming an inlet temperature of 400oC for the gas, its cp
being 1.125 kJ/kg-K. Neglect any heat loss or pressure loss in the system.
Prob.4 For the above problem (Prob.3), calculate Exergy Factors for the gas and the
water streams, exergy efficiency of the recovery boiler, assuming T0 as 25oC.
Prob.5 The rear wheels of an auto are braked using friction shoes. The braking force is
10kN, applied normal to the rear wheel of 210 mm diameter. The co-efficient of friction
is 0.25. The brake is applied when the rear wheel are rotating at 1800 rpm and the brake
shoes reach a temperature of 127oC. Estimate the braking power and the instantaneous
entropy generation due to braking? If all the due to braking is eventually lost to the
environment at 270C, what is the total entropy generation?
10 kN
steam out water in
210
mm
water
@ 60oC
vapor @
pr. reducing 60oC
valve collector 2
Fig. Prob. 6
Solutions to exercises:
1. Given:
ΔU = 25 kJ, ΔT = 40oC
Calculate:
pΔV=100 (0.3-0.15)=15 kJ
ΔH= ΔU + p ΔV=25 + 15 = 40 kJ
Qp = ΔH=40 kJ
m= ΔU/cv ΔT=25/(0.72x40)=0.868
ΔT data therefore seems erroneous. ΔT could have been calculated from other given data.
2. Given:
p1 = 0.4 MPa, V1 = 3 m3, T1 = 200oC = 473 K
p2 = 0.1 MPa,
Calculate:
V2 from P1V1= P2V2; V2 = 8 m3 approx.
T2 from T2/T1= (V2/V1) ; T2 = 316 K approx.
Technical work, Wt = ( P1V1 - P2V2)/(-1) = 1375 kJ
Again, Wt = m cp ΔT m = 1375/(1.005x(473 – 316) = 8.72 kg approx.
ΔU = m cv ΔT = 8.72 x (cp /) x (473 – 316) = 975.8 kJ
Similarly calculate technical work for polytropic expansion using n=1.25 instead of .
3. Water is first heated sensibly from 25oC to 100oC, the saturation temperature @
101 kPa. Then evaporation occurs @ the constant saturation temperature of 100oC. Total
change in entropy Δs per kg of water is thus given by:
Exergy flows:
Exergetic efficiency:
So, the second collector, which only evaporates water from and at a fixed temperature of
60oC, has a greater exergetic efficiency (more than double compared to the exergetic
efficiency of the first collector), even though both the collectors have the same energy
efficiency of 64.1%.