SANGATHAN, BHUBANESWAR REGION

VIDYALAYA
KENDRIYA PREBOARD EXAMINATION CLASS-XII
SET-1
SUB:CHEMISTRY TIME: 3HRS

MAX MARK 70

GeneralInstruction: paper withinternal choice

There are 33 questions in this question questIons carrying 1 mark each.
choice
(a)Section A consists of 16 multiple
questons carrying 2 marks each
(b)Section B consists of 5 short answer carrying 3marks each
(C)SectionC consists of 7 short answer questions
carrying 4 marks each
(a)Section D consists of 2 case based questions
marks each
(e)Section E consists of 3 long answer questions carrying 5
All questions are compulsory
MARKS
Q QUESTION
NO
SECTIONA 1

constant (K) will be

Irmolality of dilute solution is doubled. the value of molal depression
1

(c) unchanged (d) doutbled

(a) halved (b) tripled
1
standard conditions
2 If M, N, O, P andQare in the increasing order of their standard potentials in
of their standard half cells, then by combination of which two half cells maximum cell potential
will be obtained?
(a) M and N (b) M and O (c) M and P (d) M and Q
The rate of first order reaction is 0.04 mol L-1 s- at 10 sec. and 0.03 mol L-1 s-' at 20 seconds 1
3
after initiation of the reaction. tuz of reaction is
(a) 44.1 s (b) 54.1s (c) 24.1s (d) 34.1s
4 1
Which of the following willshow maximum paramagnetic nature?
(a)[Cr(H,0)6" (b)[Fe(CN)e]+ (c) [Fe(CN)6J (d)[Cu(H,0).P*
5 Which of the following reactionconfirms the presence of carbonylgroup in glucose? 1
(a) Reaction with HI (b) Reaction with NH,OH
(c) Reaction with HCN (d) both (b) and (c)
Which of the following pairs has the similar ionic size? 1
(a) Zr, HE (b) Zn?*, H (c) Fe?, Ni2* (d) Zr, Ti4
7 Which of the following is the correct order of decreasing SN' reactivity? 1
(a) RCH2X>R,CHX>R3CX (b) RsCX>R,CHX>RCH,X
(c) R2CHX>R,CX>RCH;X (d) RCH2X>RsCX>R2CHX
8 Which ofthe following haloalkane is optically active? 1
(a) 2-Chloropropane (b) 2-Bromobutane (c) 3-lodopentane (d) 1-Fluorobutane
Which one is anexample of allylic alcohol?
(a) Prop-2-en-1-ol (b) but-2-en-2-ol (c) Prop-1-en-1-ol (d) Prop-1-en-2-ol
10 Which of the following will not give iodoform test?
(a) Ethanol (b) Ethanal (c) Pentan-3-one (d) Pentan-2-one
 The correct order of Compoundis:
basiC strength for the following
NH, NH,
NH,
() (ii)
(ü)
CH.
(a) i<i<l NO (d) ii<i<ii
12 (b) ii<i<ii (c)ii<ij<i
A' Reduction "B' HNO,
The compound A' is CH,CH,0H
(a) propane nitrile (c) nitro methane (d) methyl isocyanate
(b) ethane nitrile
wng questions a statement of assertion followed by a statement of reason is gvel.
Choose the correct answer out of the following choices. (Q.13 to Q. to)
(a) Assertion and reason both are corect statements and reason is correct explanauon
assertion.
(b) Assertion and reason both are correct statements but reason is not correct explanation o
assertion.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion is wrong statement but reason is correct statement.

13 Assertion: Pulses are cooked faster in pressure cooker

Reason: Boiling point of water is less than 100°C.
3.
14 Assertion: The total number of isomers shown by [Co(en);CIL]' complex ion is
Reason: (Co(en)2Cl2]' complex ion has an octahedral geometry. 1
chlorobenzene in comparison to that in
15 Assertion: It is difficult to replace chlorine by-OH in
chloro ethane.
benzene has a partial double bond character
Reason: Chlorine-carbon(CCI) bond in chloro 23
due to resonance.
prepared by Gabriel phthalimide synthesis
16 Assertion (A): Aromatic 1° amine can be nucieophilic substitution reaction with anion
undergoes
Reason (R): Primary Alkyl halide
formed by phthalimide. 24
SECTION B
2
17 = 60 g/ mol), calculate the osmotic pressure at 300 K
5% solution of urea (Molar mass
For a
K- mo)
[R =0.0821 L atm
2
each of the following:
18 Assign reasons for generally form coloured compounds.
metals oxidation state of +7 amongthe 3d series of
()Transition exhibitsthe highest
transition (a)
()) Manganese (b)
elements. OR
(c)
Explain the following
observations densityof elements
increase in elements
from titanium (Z = 22) to copper 25 Give
there is an transition
() Generally
29) in the first series
Of
ccompounds are generally found to be good (a) n
(Z =
elements and their catalysts in (b) Ra
(1) Transition
chemical reactions (c) The
toward
 compounds
of
following pairs
betweenthe
distinguish 2
chemicaltesteachto boiling points
19 Giveone and Benzoicacid orderoftheir
Phenol 2-Propanol compounds in the increasing
(0)
1-Propanoland following acid strength
(i) the
CzH:0C;Hs, CaHsCOOH, CAHsOH of their
20
Arrange
the
increasingorder 3,4-Dinitro Benzoic
compoundsin 4-Methoxy Benzoic acid,
the following acid
() Arrange acid, 4-Nitrobenzoic 2
Benzoic
acid vitamin causes
vitamins? Deficiency of which
21 What are
()PernicIOus anemia?
l )Convulsions?
SECTION C 3
diluted
used by scuba divers filled with air
tanks
law and explain why are the
22 (a) State Henry's helium, 56.2% nitrogen and 32.1% oxygen)?
with helium (11.7%
gas in
of 6 bar. Calculate the solubility of argon
(b)Assume that argon exerts a partial pressure
water, KH = 40 kbar)
water. (Given: Henry's law constant for argon dissolved in
OR
Give reasons for the following:
(a) Measurement of osmotic pressure method is preferred for the determination of molar
masses of macromolecules such as proteins and polymers.
(b) Aquatic animals are more comfortable in cold water than in warm water.
1 (c) Elevation of boiling point of 1MKCI solution is nearly double than that of1 Msugar
solution

23 Conductivity of 2.5 x 104 M methanoic acid is 5.25 x 10-5 S cm-'.

Calculate its molar 3
conductivity and degree of dissociation.
Given: Ao (H*) = 349.5 S cm' mol' and Ao (HCO0) = 50.5 S cm2
mol.
24 For the reaction 2NO (g) + Clh (g) ’ 2NOCI (a).
the following data were collected. Allthe 3
2 Expt no [NOJM
measurements were taken at 263 K.
[CI-]M Rate Of disappearance(M/min)
0.15 0.15
2 0,60
0.15 0.30
3 1.20
0.30 0.15
4 2.40
2 0.25
0.25
(a) Write the
(b) Calculate expression for rate law.
the value of rate
(c) What is the
initial rate of constant and specifv its units.
25 Giye reasons: disappearance
of Cl, in experiment no. 4?
(a) n-Butyl
(b)Racemicbromide has higher
(c) The mixture is optically boling
inactive.point than
bromide. 3

towards presence of nitro

group t-buty'
nucleophilic (-NO2) o/o Positions increases the
at
substitution reactions reactivity of
haloarenes
 3
26
(a) Write the
mechanism of the following reaction:
CH,CH;0CH,CH3
2CH3CH,OH H*
of Salicylic acid.
(b)Write the
equation involved in the acetylation 3
27 Give the structures of A, B followingreactions:
(i) CH,CHl NaCN and C in the NaOH +Br2
A OH
NHJA
(1)CsHsN,CI CuCN A HzO/H+
B

50.14 kJ 3
28 The the absence of a catalyst and
activation energy of a reaction is 75.24IkJ mol- inreaction grow in the presence of the
mol with a catalyst. How many of
will the rate JK-1 mol-') [Antilog 4.40 = 2.512 x 104]
catalyst if the reaction proceeds times
at 25 °C? (R =8.314
SECTION D
4
29 Tne transition elements have incomnietaly filled d-subshells in their ground State a
0ccupy position in between s- and p-blOCKS In
n Addlon states. The transition elemate elements consIst of rour
transition
groups 3-12 of the Periodic table Startino from fourth period.
Cn. In general, the electronlG
Complete series: Sc to Zn, Y to Cd and I Hf to Hg and Ac. Rf to
electronic
Configuration of outer orbitals of these elements is (n-1) d1-10 ns12, The
general formula (n -
Contigurations of outer orbitals of Zn. Cd Ha are represented by the
properties such as high tensile
1)d nS. Allthe transition elements have typical metallic
room temperature, other
strength, ductility, malleability. Except mercury, which is liquid at metals and their compounds
transition
transition elements have typical metallic structures. The
behaviour. Transition metal also forms alloys.
also exhibit catalytic property and paramagnetic
An alloy is a blend of metals preparedby
mixing the components. Aloys may be homogeneous
one metal are distributed randomly among the atoms of
solid solutions in which the atoms of
the other.
Answer the following question: enthalpy of atomisation? In 3d series
(Scto 7n)
transition metals have higher
(i) Why do the why?
enthalpy of atomisation and
which element has lowest OR
series (Sc to Zn) whuch
Why do transition elements Show vallaie oxdation states? In 3d
(i) of states and why?
maximum number oxidation
element shows the following outer orbital configurations may exhibit the largest
Which one of the states? 32
(i) number of
oxidation
(b)3d94s? (c) 3d2 4s? (d) 3d° 4s?
(a) 3d54s!
lanthanoid series which is well known to
memberof the exhibit +4 oxidation
Name a
(i) state. (c) La (d) Gd
(b)Eu
(a) Ce linear sequenCe amino acids in a peptide or protein. In
of
structure istheregular, contrast,
Protein primary to recurrin9 arrangements in the space of adjacent amino
refers chain. It Is
maintained by hydrogen bonds between amide
30 Secondary structurepolypeptide
residues in a ofthe peptide back bone. The major secondary structures are
acid carbonyloxygens The tertiary Structure of
hydrogens and pleated structures. molecular protein represents overall folding of
B-
a-helix andstructure. Two major
type Snapes which are found naturally are fibrous and
biologicalsystem with a unique
secondary foundin a native proein When a three-dimensional structure and
globular
Protein called a protein in its native form, is
subjected tO
activítyis
biological
 physical changes like change in temperature or
hydrogen bonds are disturbed. Due to this, globules chemical changes
loses its biological activity. This is called denaturation unfold
like
and helix gets change in pH, the
of
in secondary and tertiary structures but primary protein, The
uncoiled and protein
denaturation of protein are coagulation of e99 white on Structures denaturation
remain intact. causes change
Examples
cheese when an acid is added to milk. boiling.
curding of milk, and formation ofof
Answer following questions:
(A) Give two differences
between globular and fibrous
protein. (2)
(A) What is meant by a peptide linkage? Explain wwith one
(B) What type of bonding helps in example.
stabilizing the a-helix structure of proteins? (1)
(C)Where does the water present in egg go
ater boiling the egg? (1)

SECTION E
31 (i) What type of isomerism is shown by the
(ü) On the basis of crystal field theory, write complex
[Cr (H2O)]CI,? 5
the electronic configuration for da ion if Ao >P.
(ii) Write the hybridization and shape of [CoFej.
(IV) State a reason for each of the following
situations:
(a)CO is a stronger complexing reagent than NH3.
(b) The molecular shape of Ni(CO)4 is not the same as that of
[Ni(CN)4.
OR

() Draw the geometrical isomers of complex [Pt(NH3)2C12]

(ii) On the basis of crystal field theony write the electronic configuration for d" ion if Ao <
P
(ii) Write the hybridization and magnetic behaviour ofthe complex [Ni(COa).
(iv) Name the following coordination compounds
(a) [CoCl2(en)a]CI
(b) [P(NHs)2CI(NO)]
32 (a) Although phenoxide ion has more number of resonating structuresthan Carboxylate 5

ion, Carboxylic acid is a stronger acid than phenol. Give twO reasons.
(b) How will you bring about the following conversions?
() Propanone to
propane
(i) Benzoylchloride to
(ii)Ethanal to but-2-enalbenzaldehyde

(a) Account for the OR

() CH:CHO is following: towardsreactionwith HCN.
more reactive than oneis involvedinthe formation
(i) There aretwo
-NH2 groups in
CH:COCH, However, only
of semicarbazones. semicarbazide. reactions:
(b) Write the chemical following name
equations to illustrate the
 (i) Wolff-Kishner reduction
(ii) 5
33 Clemmensen's
a) Define the reduction (i) Cannizzaro reactio
following
(i) Limiting molar terms: is 100 Q. Ifthe
conductivity (i) Fuel cell molL-1 KCI solution
(b) Resistance ofa with 0.1 L-1 KCI solution is 520 Q, calculate
conductivity cel filled
resistance of the same cell when filled with 0.02 molL-t KCI solution. The conductivity of
the conductivity of0.02 mol
0.1 mol L-1 KCI and molar conductivity
solutions is 1.29 x 10-2 Q-'cm-!.
OR
a) Define the term conductivity and molar Conductivity of the solution of. an electrolyte.
Comment on its variation with
(b) The
measured resistance temperature.
of cell was 100ohms. If
f7.45 g of KCI is dissolved per
litre of solution. Calculate conductivity
(i) specific conductance () molar conductance. [ G* =1.25 cm-1
Molar mass of KCI is 74.5 g
mol]