.
SI.No. Total No. of Pages : 3
(Scheme: CBCS) (Old)
CHEMISTRY
Organic Chemistry -II
Time: 2 Hours Max. Marks : 50
Instruction: Answer all the questions in brief.
1. a) Predict the product of the reaction, [4]
of-f
~~
1
'"'
~
}f
b) Predict the product and suggest a plausible mechanism for. [6]
)
~
o-tCJ
oJf OH
OR
2. a) Find the product in the reaction. [4]
b) Find the product and give the mechanism for. [6]
+
(.n-/~
l
G
~~
+Hc..r.f 1..J1).-"D
P.7:0.
3. Discuss Knoevenagel condensation with suitable mechanism and its synthetic
application. [10]
OR
4. Write a note on the following [10]
a) Esterification and hydrolysis
b) Hydroxy acids.
5. a) How will you synthesisAdipic acid from acetoacetic enter. [5]
b) Discuss Keto-Enol tautomerism in ethylaceto acetate. [5]
OR
6. a) Write the synthesis of cinnamic acid from malonic enter. [5]
b) How do you effect the conversion qf cyclolexaone to -methyl
\
cyclolexanone via enamine. \\ [5]
7 a) Describe the synthesis of picnic acid from chlorobenzene. [5]
b) What are the user ofHinsberg reagent. [5]
OR
8. a) How will you distinguish between three classesof nitro compounds using
HNO2. [5]
b) Arrange the following in increasing order ofbasicity and give reason.[5]
i) Methylamine
ii) Aniline
iii) Triphenylamine
9. Write a note on any five of the following : [5 x Z
10]
a) Reimer -Tiemann reaction.
b) Oxidation with mo 4.
c) NaBH4
d) Nitrile Hydrolysis.
e) Charge transfer complexe,
t) Enamine.
g) Ketonic hydrolysis.
h) Gabriel phthalimide synthesis.
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