AQw Wxve U7 Agj 0 N 9 KK Ozx
AQw Wxve U7 Agj 0 N 9 KK Ozx
JEE (Main)-2022
TEST DATE: 06-02-2022
Time Allotted: 3 Hours Maximum Marks: 300
General Instructions:
Section-A (01 – 20, 31 – 50, 61 – 80) contains 60 multiple choice questions which have only one
correct answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
Section-B (21 – 30, 51 – 60, 81 – 90) contains 30 Numerical answer type questions with answer
XXXXX.XX and each question carries +4 marks for correct answer. There is no negative marking.
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Physics PART – A
SECTION – A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
1. If E (x, t) = E0 sin (t kx) ĵ and B (x,t) = B0 sin (tkx) k̂ are the electric field and magnetic field
vectors respectively in an electromagnetic wave. What would be the direction of propagation of
the EM Wave?
(A) î
(B) ˆi ˆj
(C) k̂
(D) ˆj kˆ
2. The percentage modulation in AM Wave is 60% and the peak value of information voltage is 18
Volt. Then the sum of maximum voltage Vmax and minimum voltage Vmin is
(A) 36 V
(B) 60 V
(C) 30 V
(D) 72 V
3. If the radiation of highest wavelength in the ultraviolet region of hydrogen spectrum is just able to
eject photoelectrons from a metal. The value of threshold frequency for the given metal is:
(A) 3.83 1015 Hz
(B) 4.33 1014 Hz
(C) 2.46 1015 Hz
(D) 7.83 1014 Hz
4. A particle is projected with speed u at an angle with horizontal. Which of the following is the
correct representation of kinetic energy of the particle with respect to time? (Take g = 10 m/s2)
(A) KE (B) KE
t t
(C) KE (D) KE
t t
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6. In a composite slab as shown, the temperature at the interface between two materials is equal to
the average of the temperature at the two ends. Assuming steady heat flow through conduction,
choose the correct option.
Interface T0
Thermal Qout
Qin Temperature T2
Temperature T1 conductivity k1
2b b
Thermal
conductivity k2
(A) 2k1 = k2
(B) k1 = k2
(C) 2k1 = 3k2
(D) k1 = 2k2
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9. Two smooth spheres of radii R and 2R, specific gravity 0.1 and 0.2 respectively are released from
the bottom of a sufficiently deep-water tank (coefficient of viscosity 10 poise). The spheres travel
all the way to the surface of tank, emerges out and goes up to height H1 and H2 respectively in
air. Then,
(A) H1 = H2
(B) H1> H2
(C) H1< H2
(D) can’t be determined
10. Arrange the following telescopes, in order of decreasing resolving power: (where D is the
telescope diameter and is the wavelength)
(I) D = 100 m, = 21 cm
(II) D = 2 m, = 500nm
(III) D = 1 m, = 100 nm
(IV) D = 2 m, = 10 mm
(A) (III), (II), (IV), (I)
(B) (II), (III), (I), (IV)
(C) (IV), (III), (II), (I)
(D) (III), (II), (I), (IV)
11. For a gas under isothermal conditions its pressure P varies with volume V as P V2/3. Then the
bulk modulus B will be proportional to
(A) V 2/3
(B) V 5/3
(C) V 2
2
(D) V 5
12. When a liquid is placed in vacuum (e.g. a leak from a space vehicle) it evaporates very fast and
can lead to rapid cooling. A water droplet at 10 °C escapes into space and begins to evaporate.
Find its temperature when it has lost 1% of its mass. (To heat 1 kg of water by 1 °C requires 4.2
kJ of energy; to evaporate 1 kg of water requires 2.26 MJ of energy)
(A) 5.6 °C
(B) 4.6 °C
(C) 4.2 °C
(D) 5.4 °C
13. Three infinitely long wires, each carrying equal current are placed in the xy-plane along x = 0, +d
and d. On the xy-plane, the magnetic field vanishes at
d
(A) x
2
1
(B) x d 1
3
1
(C) x d 1
3
d
(D) x
3
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x
14. The velocity v(x) of a particle moving in one dimension is given by v(x) v 0 sin , where V0
x0
x
and X0 are positive constants of appropriate dimensions. If the particle is initially at , where
x0
|| <<1, then in the long time, it
(A) Executes an oscillatory motion around x = 0
(B) Tends towards x = 0
(C) tends towards x = x0
(D) executes an oscillatory motion around x = x 0
15. Two electric dipoles P1 and P2 are placed at (0, 0, 0) and (1, 0, 0) respectively with both of them
pointing in the +z direction. Without changing the orientations of the dipoles P1 is moved to (0, 2,
0). The ratio of the electrostatic potential energy of the dipoles after moving to that before moving
is
1
(A)
16
1
(B)
2
1
(C)
4
1
(D)
8
16. A light rigid rod with two equal masses m at the ends, is held with
one end on a horizontal surface. The other end rests on a circular
curve of radius 3.4 m, at a distance from the horizontal
corresponding to 1/8th of the circumference of a circle, as shown
in Figure. If the surface is frictionless, what is the speed of the rod
and masses when released and both masses slide on the flat
surface? The masses remain in the same vertical plane.
(A) 2.1 m/s
(B) 3.1 m/s
(C) 4.1 m/s
(D) 5.1 m/s
18. A spherical capacitor consists of two concentric conducting spheres of radii a and b (a>b). The
outer sphere is grounded and a charge Q is placed on the inner sphere. The outer conductor then
contracts from radius a to radius a. Find the work done by the electric force.
Q2 (a a)
(A)
80 aa
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Q2 (a a)
(B)
60 aa
Q2 (a a)
(C)
40aa
Q2 (a a)
(D)
20 aa
20. The phase difference () between input Vi and output voltage V0 for the following circuit (i) and
(ii) will be
C R
C V0 C V0
Vi Vi
(i) (ii)
(A) 0 and 0
(B) /2 and 0 < < respectively
2
(C) and
2 2
(D) 0 and 0 < < respectively
2
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SECTION – B
(Numerical Answer Type)
This section contains 10 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the second
decimal place; e.g. XXXXX.XX).
36 V 3 3 3 3
1 6 6 6
23. The voltage on a capacitor in a certain circuit is given by V(t) = V0et/RC. If R = 50 k 5% and
C = 0.01 F 10% and the fractional error in the voltage at t = 50 s is N. Find the value of 100N.
24. An alternating current is expressed as i 2cos t 2 sin t . The RMS value of current is N. Find
the value of N?
26. Two transverse waves y1 = 5 cos(kxt) cm, and y2 = 5 cos (kx + t) cm, travel on a string along
x-axis. If the speed of a point at x = 0 is zero at t = 0 s, 0.25 s and 0.5 s, then the minimum
frequency (in Hz) of the waves is
27. Consider N1 number of ideal gas particles enclosed in a volume V1. If the volume is changed to
V2 and the number of particles is reduced by half then the mean free path becomes four times of
V
its initial value. The value of 1 is X. Find the value of X?
V2
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28. A ball is thrown from a height h = 0.5m above the ground. The
ball leaves the point located at distance d = 10m from the wall at y
45 to the horizontal with velocity u = 20m/s. How far from the
wall (in horizontal direction) does the ball hit the ground,
assuming collision from the wall to be elastic? (Take g= 10m/s2) O
h
O x
30. A body slides down a rough plane inclined to the horizontal at 30. If 70% of the initial potential
energy is dissipated during the descent, then the coefficient of sliding friction is N . Find the value
of 10N ? (Take root 3 as 1.73)
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Chemistry PART – B
SECTION – A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
31. Permagnate ion oxidizes H2O2 in acidic solution according to the following equation
2MnO 4 aq 5H2 O 2 aq 6H aq 2Mn2 aq 5O 2 g 8H2 O
If 35.0 ml of an acidic 0.150 M KMnO 4 solution is required to consume all the H2O2 in 50.0 ml of
a disinfectant solution, what is the concentration of H2O2 in the disinfectant?
(A) 0.042 M
(B) 0.105 M
(C) 0.263 M
(D) 0.368 M
32. Decomposition of 1 gm of which of the following compounds into its constituent elements gives
the greatest amount of N2 gas?
(A) NO
(B) NO 2
(C) N2O4
(D) NH3
33. The natural logarithm of the vapour pressure (in bar) of HCN (s) as a function of the reciprocal of
the absolute temperature is plotted below:
- 2.0
y 4544x 15.864
- 3.0
- 4.0
nP
- 5.0
- 6.0
- 7.0
0 0.0038 0.0040 0.0042 0.0044 0.0046 0.0048 0.0050
1 1
k
T
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34. Which changes to this galvanic cell increase the measured potential?
Cu s / Cu2 aq , 0.10M || Ag aq , 1.0 M / Ag s
I. Increasing Cu2 in the Cu / Cu2 half-cell to 0.5 M.
35. Rank the element Si, P, Ge, and As in increasing order of their first ionization energy
(A) Si < P < Ge < As
(B) As < Ge < P < Si
(C) Ge < Si < As < P
(D) Ge < As < Si < P
36. The isoelectric point of a protein is the pH at which it is electrically neutral. Which mutation of an
amino acid NH2 CH COOH in the protein would have the greatest effect
|
R
on its isoelectric point, assuming that the mutation does not significantly affect the protein’s
overall structure?
(A) Serine R CH2 OH Ly sine R CH2 CH2 CH2 CH2 NH2
(B) Glutamine R CH2 CH2 CONH2 Methionine R CH2 CH2 S CH3
CH3
(C)
Isoleucine R CH CH3 CH2 CH3 Valine R = HC
CH3
37. The melting point of silicon dioxide is (1713oC) is higher than the melting point of silicon (1414oC).
What is the best explanation for this difference?
(A) Silicon – oxygen bond are stronger than Silicon – Silicon bonds.
(B) Silicon – dioxide is an ionic solid while Silicon is metallic solid.
(C) Silicon – dioxide is polar while Silicon is non-polar.
(D) Silicon – dioxide forms tetragonal crystal while Silicon forms cubic crystals.
38. Metallic gold will not dissolve in nitric acid alone, but will dissolve in aqua regia. Which is the best
explanation for this observation?
(A) Chloride ion complexes gold (III), stabilizing it as AuCl4 .
(B) Nitric acid is a stronger oxidant in more acidic solution.
(C) Nitric acid and hydrochloric acid react to form NO2 Cl, which react readily with metallic
gold.
(D) Nitric and hydrochloric acid react to form Cl2 , which react readily with metallic gold.
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39. Guanine is one of the bases in DNA, is susceptible to attack by alkylating agents. Which nitrogen
in guanine is most prone to alkylation?
O
B
H N C
N
H2N N N D
A DNA
(A) A
(B) B
(C) C
(D) D
40. Sodium halide crystallize in the rock salt structure, which has a cubic unit cell with 4 formula units
per unit cell. If sodium halide has density of 2.83 g / cm 3 and a unit cell edge length of 462 pm.
Which compound is it?
(A) NaF
(B) NaCl
(C) NaBr
(D) NaI
41. The degree of hydrolysis of a salt of weak acid and weak base in its 0.1 M solution is found to be
50%. If the molarity of the solution is 0.2 M, the percentage hydrolysis of the salt should be:
(A) 100%
(B) 50%
(C) 25%
(D) None of these
42. Solution of chemical compound x react with AgNO3 solution to form white ppt. ‘Y’, which
dissolves in NH4OH to give a compound ‘Z’. When ‘Z’ is treated with dil, HNO3 , ‘Y’ reappears.
The chemical compound ‘X’ can be
(A) NaCl
(B) CH3 Cl
(C) NaBr
(D) NaI
43.
The n2 n1 and n22 n12 for He ion in atomic spectrum are 4 and 8 respectively. The wave
length of emitted photon when electron jump from n2 to n1 is
32
(A) RH
9
9
(B) RH
32
9
(C)
32RH
32
(D)
9RH
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44. The vapour pressure of a saturated solution of sparingly soluble salt XCl3 was 17.20 mm of Hg
at 27o C . If the vapour pressure of pure H2 O is 17.25 mm of Hg at 300 K, what is the solubility of
sparingly soluble salt XCl3 in mole/lit?
(A) 4.04 102
(B) 4.08 102
(C) 2.02 102
(D) 4.04 103
45. O O O
C C C
H OH H OH H OH
I II III
Among these canonical structure, the correct order of stability is
(A) I > II > III
(B) III > II > I
(C) I > III > II
(D) II > I > III
47. n. moles of ‘He’ gas are placed in a vessel of volume V lit. At TK, if V1 is free volume of ‘He’ then
diameter of ‘He’ atom is
1/3
3 V1
(A)
2 NA n
1/3
3 V V1
(B)
2NA n
1/3
6 V V1
(C)
2NA n
1/3
3V1
(D)
N A n
48. Blister copper is refined by stirring molten impure metal with green logs of wood because such a
wood liberates hydrocarbon gases. This process X is called____________and the metal contains
impurities of Y is___________
(A) X Cupellation; Y CuO2
(B) X Polling; Y Cu2O
(C) X Polling; Y CuO
(D) X Cupellation; Y CuO
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49. 0.001 mole of Co NH3 5 NO3 SO4 was passed through a cation exchanger and the acid
coming out of it required 20 ml of 0.1 M NaOH for neutralization. Hence, the complex is:
(A) Co SO 4 NH3 NO3
5
50. First generation automobile air bags were inflated by decomposition of Barium azide. What mass
of barium azide would be required to inflate a 20 L air bag to a pressure of 1.23 atm at 27o C ?
(Given at. Mass of Ba = 137.327 and N = 14).
(A) 78.6 gm
(B) 74 gm
(C) 157 gm
(D) 52.4 gm
SECTION – B
(Numerical Answer Type)
This section contains 10 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the second
decimal place; e.g. XXXXX.XX).
51. The specific heat capacity of iron is 0.461 J g1 k 1 and that of titanium is 0.544 J g1 k 1 . A
sample consisting of 10.0 g Fe and 10 g of titanium at 100.0o C losses 200 J of heat to the
environment. What is the final temperature of the sample?
53. Sulphur trioxide is formed from the reaction of sulphur dioxide and oxygen
1
SO2 g O2 g SO2 g
2
At 1000 K, an equilibrium mixture has partial pressure of 0.562 bar
SO 2 , 0.101 bar O2 and 0.332 bar SO3 . What is the equilibrium constant KP for this reaction at
this temperature.
54. In an amino acid, the carboxylic group ionizes at pK a1 2.34 and ammonium ion at pK a2 9.60 .
The isoelectric point of the amino acid is at pH?
yz
55. If the following molecule undergo dimerization then find the value of .
x
ClO3 ,OF, GaH3 , AlCl3 , ICl3 , BeH2 , NO2
Where x = Number of molecules which are hypervalent in dimeric form.
y = Number of molecule which complete octet in dimer form.
z = number of molecule which are hypovalent in dimeric form.
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56. Find the number of basic radicals among the following cations, which can form soluble complex
on adding excess of NH3 .
Cd2 aq ,Pb2 aq ,Ni2 aq ,Mn2 aq ,Zn2 aq ,Ag aq ,Hg2 aq ,Fe 3 aq ,Mg2 aq
57. Find the total number of electron of Co2 ion which are present in non axial-d-orbitals in the
complex compound Co dmg2
o o
58. Calculate the I – I distance in A for given compound H2CCI2 if C – I bond length is 2.35 A
sin60 o
0.866
59. At constant temperature and pressure, 5.0 L of SO 2 is combined with 3.0 L of O 2 according to
the equation
2SO2 g O2 g 2SO3 g
After SO 3 formation is complete, what is the volume of the mixture?
60. An element ‘E’ has electronic configuration of ‘K’ shell is n 5 s2 and it has total number of
electron in its outer most shell is 2, in penultimate shell is 8 and in anti penultimate shell is 25.
Find the total number of unpaired electron in element ‘E’ in their ground state.
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Mathematics PART – C
SECTION – A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
61. Many states use a sequence of three letters followed by a sequence of three digits as their
standard license-plate pattern. Given that each three-letter three-digit arrangement is equally
likely, the probability that such a license plate will contain at least one palindrome (a three-letter
arrangement or a three-digit arrangement that reads the same left-to-right as it does right-to-left)
m
is , where m and n are relatively prime positive integers, then the value of m + n
n
(A) 58
(B) 59
(C) 60
(D) 63
62. There are 20 students participating in an after-school program offering classes in yoga, bridge,
and painting. Each student must take at least one of these three classes, but may take two or all
three. There are 10 students taking yoga, 13 taking bridge, and 9 taking paining. There are 9
students taking at least two classes, then number of students who are taking all three classes?
(A) 1
(B) 2
(C) 3
(D) 4
63. Right triangle ABC has right angle at C and BAC = ; the point D is chosen on AB so that
|AC| = |AD| = 1; the point E is chosen on BC so that CDE = . The perpendicular to BC at E
meets AB at F, then lim EF is equal to
0
1
(A)
2
1
(B)
3
1
(C)
4
1
(D)
5
64. All values of the real parameter ‘a’ such that the nonnegative solutions of the equation
(2a – 1) sin x + (2 – a) sin 2x = sin 3x form an infinite arithmetic progression are
(A) a < –2 or a > 2 {0}
(B) a < –3 or a > 3 {0}
(C) a < –5 or a > 5 {0}
13 13
(D) a< or a > {0}
2 2
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1
65. If z ei /13 , then is equal to (where i 1 )
1 z
(A) 1 z 2 z 4 z 6 z 8 z10 z12
(B) 1 z 2 z 4 z 6 z8 z10 z14
(C) z z 3 z 5 z7 z9 z11
(D) z z 3 z5 z7 z9 z11
66. If |z1| = 1, |z2 – 2| = 3 and |z3 – 5| = 6, then maximum value of |2z1 – 3z2 – 4z3| is
(where z1, z2 and z3 are complex numbers)
(A) 43
(B) 44
(C) 45
(D) 61
Px
67. Let P(x) be a polynomial of degree 4 having a local maximum at x = 2 and lim 3 27 . If
x 0 x
P(1) = –9 and P(x) has a local minimum at x = 2. If global maximum value of y = P(x) on the set
A x : x 2 12 7x is 4M, then the value of M is
(A) 6
(B) 7
(C) 9
(D) 13
68. The parabola y2 = x – y divides the triangle formed by the tangent to it at the origin and the
A p
straight line x + y = 0 and y = –1 into two parts whose areas are A1 and A2. If 1 where p, q
A2 q
p
N and is in simplest form, then the value of (p + q)
q
(A) 3
(B) 4
(C) 5
(D) 6
–x
(A) x + 2e – 1
(B) x – 2e–x + 1
(C) x + 2e–x + 1
(D) –x – 2e–x + 1
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71. The largest perfect square that divides 20143 – 20133 + 20123 – 20113 + ..... + 23 – 13 is
2
(A) 1
2
(B) 2
(C) 10072
(D) 20142
73. If a, b are positive real numbers such that the lines ax + 9y = 5 and 4x + by = 3 are parallel, then
the lest possible value of a + b is
(A) 13
(B) 12
(C) 8
(D) 6
x
t
74. For real x with –10 x 10 define f x 2 dt (where [.] denotes greatest integer function).
10
The number of points of discontinuity of f(x) in the interval (–10, 10) is
(A) 0
(B) 10
(C) 18
(D) 19
n n
3n 2r
75. If 1 x 3 a x 1 x
r
r
, then ar is (where n N natural number)
r 0
n r
(A) Cr 3
r
n 1
(B) Cr
3
n
(C) C2r 3r
(D) None of these
3
76. Number of solution of the equation sin1 sinx x ; x , is
2 2
(A) 0
(B) 1
(C) 2
(D) 3
77. Let S = {1, 2, 3, 4, 5, 6, 7} P is a subset of S. After replacing back in S the elements of P, again
subset Q is selected. The number of ways such that n(P Q) = 2, n(P Q) = 4 is
(A) 810
(B) 820
(C) 830
(D) 840
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dy 4x 5y 3
78. The general solution of is
dx 5x 6y 2
(A) 2x2 – 5xy – 3y2 + 3x + 2y + c = 0
2 2
(B) 2x + 5xy + 3y + 3x + 2y = c
2 2
(C) 3x – 5xy + 2y + 2x + 3y = c
(D) 4x2 – 5xy + 6y2 + 3x – 2y = c
79. “If you are born in India then you are citizen of India” contrapositive of this statement is
(A) if you are born in India then you are not citizen of India
(B) if you are not citizen of India then you are not born in India
(C) if you are citizen of India then you are not born in India
(D) if you are citizen of India then you are born in India
80. The angle between the lines whose direction cosines are given by l + m + n = 0 and 2l2 + 2m2 –
n2 = 0
1
(A) cos1
3
1
(B) cos 1
4
1
(C) cos 1
4
(D)
3
SECTION – B
(Numerical Answer Type)
This section contains 10 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the second
decimal place; e.g. XXXXX.XX).
9x 2 sin2 x 4
81. The minimum value of for 0 < x <
x sin x
82. A triangle has vertices P = (–8, 5), Q = (–15, –19) and R = (1, –7). The equation of the bisector of
P can be written in the form ax + 2y + c = 0, then the value of a + c
83. Let a, b, c be the three sides of a triangle, and let , , be the angles opposite them.
2 2 2 cot
If a + b = 1989c , then the value of is equal to
cot cot
84. Let f(x) = |x – p| + |x – 15| + |x – p – 15|, where 0 < p < 15. Then the minimum value taken by f(x)
for x in the interval p x 15 is equal to
85. For any integer n 5, let there are two n n invertible matrices with real entries A. B satisfy the
equation A–1 + B–1 = (A + B)–1. If |A| = 3, then the value of |B|
86. The number of 2 2 matrices A with elements from the set {–1, 0, 1} such that A2 = I is
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19 AITS-FT-V-PCM-JEE(Main)/22
88. Number of common tangents with finite slope to the curve (x – 1)(y + 2) = 9 and (y + 2)2 = 8(x – 1)
is
89. Let r be a variable vector and a ˆi ˆj kˆ such that the scalars r ˆi , r ˆj , r kˆ are positive
integers. If r a is not greater than 10, then total number of possible vectors r is given by
90. A student obtained the mean and standard deviation of 100 observations as 40 and 5.1
respectively. It was later found that he had wrongly copied down an observation as 50 instead of
40. The correct standard deviation is
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FIITJEE
ALL INDIA TEST SERIES
FULL TEST – V
JEE (Main)-2022
TEST DATE: 06-02-2022
SECTION – A
1. A
Sol. Direction of propagation is E B
2. B
Sol. Peak value of information voltage = 18 V
modulation percentage peak carring voltage
18 =
100
VC = 30 V
V Vmin
Peak carrier voltage VC max
2
Vmax + Vmin = 60 V
3. C
Sol. Lyman series UV region
Highest n = 2 n = 1
E2 E1 = 10.2 eV
kmax 10.2 eV
0 = 10.2 eV (just able to eject)
10.2 eV
v th 2.46 1015 Hz
h h
4. C
Sol. v x ucos , v y usin gt
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AITS-FT-V-PCM(Sol.)-JEE(Main)/22 2
1 1
K.E. mv 2 m u2 cos2 (usin gt)2
2 2
As v(t) ucos ˆi (u sin gt)jˆ
K.E. t 2 parabola
and K.E. 0 in projectile
5. A
Sol. KCL at x 50 V x
(100x)V
x 50 x (100 x) x
0
R R R i1
75
x= V i2
2
and KCL at y
100 V 0V
y 50 y 50 y (100y) y
R R R i1
100
y V (100x)V 50 V
3 x
2(x) y 325 5
Current = 2i1 + i2 = amp
R R 3R 3
6. D
d d
Sol. in out
dt dt
k1A 1(T1 T0 ) k 2 A 2 (T0 T2 )
2b b
T1 T2
T0 and A1 = A2
2
We get k1 = 2k2
7. D
I0 I I
Sol. I1 , I2 0 cos2 30, I3 I2 cos 2 30 0 cos 4 30
2 2 2
6
I I 3 27
I4 I3 cos 30 2 cos6 30 0
2
I0
2
2 2 128
8. A
V t/R2 C V
Sol.
R2
e
R1
1 eR1t/L constant
V t/R2C V R1t/L
e e R1 R2
R2 R1
R1 1
L R2C
L
R1R 2
C
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3 AITS-FT-V-PCM(Sol.)-JEE(Main)/22
9. C
Sol. As the tank is sufficiently deep, the ball will attain terminal velocity Fb
v
2( b )R2g
vT
9
Fv
= density liquid
b = density body
T ( b )R2
mg
T(2) T(1)
H2> H1
10. D
Sol. d 1.22
d
dI 2.56 103
dII 3.05 107
dIII 1.22 107
dIV 6.1 103
1
Resolving power =
d
RPIII RPII RPI RPIV
11. A
Sol. For isothermal Bulk modulus Pressure
12. B
Sol. Using Principle of calorimetry
mc T = 0.01 mL
hence T = 0.01 L/c = 0.01 × 2.26 × 106/4200 = 5.4°C F.
New temperature (assuming no other losses) is 4.6°C.
13. D
Sol. B1 + B2 = B3 y
0I I 0I
0
2(d x) 2x 2(d x) 1 2 3
1 1 1 x d x 1
d x x d x x(d x) (d x) x
x
(d + 2x) (d x) = dx +x 2 d d
d2xd + 2xd 2x2 = dx + x2
d2 + xd 2x2 = dx + x2
d
3x2 = d2 x =
3
14. C
x
Sol. v(x) v 0 sin
x0
x dx x x
a(x) v 0 cos v 0 cos v0 sin
x0 x0 dt x0 x 0 x0
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AITS-FT-V-PCM(Sol.)-JEE(Main)/22 4
15. D
1 U2 r13 1
Sol. Electrostatic potential energy U 3
r U1 r23 8
16. B
Sol. h = r – rcos
r 45°
= r(1 – cos )
h
= 3.4 (1 – cos 45°) r
1.7 2 2 m
1
and from energy conservation, mgh = 2m v 2
2
Hence, v gh 9.81 1.7 2 2 3.1 ms1
17. D
k 640
Sol. 1600
m m 0.38 0.02
= 40 rad/s
Let v be the velocity acquired by the block m where bullet m strikes it and comes to rest in it.
By conservation of momentum
m 0.02 0.02
(m m)v mv v v 200 200 10 m/s
m m 0.38 0.02 0.4
The block is set in oscillation about it mean position with maximum amplitude A
dx
x A sin t A cos t
dt
In the mean position, the velocity is maximum
10 10
A = 10 A 0.25
40
x = 0.25 sin(40t)
18. A
Sol. The electric fields at r < b and r > a are both zero. At b < r <a the electric field is
Q
E er
40r 2
Hence the field energy is
a 2
1 Q 2 Q2 1 1
W
b
0 4r dr
2 40r 2
80 b a
When the outer spherical surface contracts from r – a to r = a, the work done by the electric force
is equal to the decrease of the electric field energy
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5 AITS-FT-V-PCM(Sol.)-JEE(Main)/22
Q2 2
1 1 Q (a a)
Wa Wa
80 a a 80 aa
19. C
Sol. C is the point of contact around which the masses M and m rotate. As it is the instantaneous
center of zero velocity, the equation of motion is of the form C = IC, where IC is the moment of
inertia of masses M and m with respect to point C. Now
1
IC MR2 MR2 md2 …(i)
2
Where d2 L2 R2 2RL cos …(ii)
For small oscillation, sin , cos 1 and
3MR 2
IC m(L R)2
2
Therefore, the equation of motion become
3MR 2
m(L R)2 mgL sin mgL
2
mgL
Or 2
0
3MR 2
m(L R)
2
mgL
2
rad/s
3MR 2
m(L R)
2
20. D
XC v 1
Sol. (i) v0 v i 0 , phase difference () is 0
XC XC vi 2
XC v 1 1 1
(ii) v 0 vi 0 eiCR phase difference () is 0
R XC vi R 1 iCR 1 ( CR)2
1
XC
Phase difference () is 0 < <
2
SECTION – B
21. 00005.00
sini
Sol. 2 i 45
sinr
Total deviation 30
= (45 30) + 1802(30) + (45 30) 30
= 30 + 120
= 150 = 30x 30
x=5
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AITS-FT-V-PCM(Sol.)-JEE(Main)/22 6
22. 00009.00
Sol. Equivalent circuit can be drawn as following 1 6
Req = 4
So, I = 9A
36 V 3
1
23. 00001.50
t
Sol. In V = nV0
RC
V t d 1 t d 1
0 R C
V C dR R R dC C
t R C 50 106 5 10
8 4
0.015 =N
CR R C 10 5 10 100 100
24. 00001.73
i
Sol. i 2sin t 2 sin t 2
2
i (2)2 ( 2 )2 6
i 6
iRMS 3
2 2 2
25. 00006.00
Sol. UAB = 0, UDE = 0 P
(U)cycle = 0
A
UBC + UCD + UEA = 0 Isothermal
Adiabatic B Adiabatic
10 + UCD + 16 = 0
U = 16J = 10
UCD = 6
E
C
D Isobaric
Isothermal V
26. 00002.00
Sol. Time difference (Separation) between two zero velocities
T
0.25 s, T 0.5 s
2
1 1
So, frequency f 2 Hz
T 0.5
27. 00000.50
1 V
Sol.
2nd2 2Nd2
V
V N
N
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7 AITS-FT-V-PCM(Sol.)-JEE(Main)/22
V1 1N1 1N1
0.5
V2 2N2 N
(41 ) 1
2
28. 00014.14
gx 2
Sol. y x tan
2u2 cos2
y=5m y
velocity just before collision v 10iˆ 0ˆj
O
Apply elastic collision, velocity v x 10( ˆi) m/s
5m
vy 0
1 2 10 m
s ut at in y-axis
2
1
(y 5) 0 (10)t 2
2
10
10 t 2
2
t 2 sec
Range after collision in x-axis (v x)t = 10 2 14.14 m
29. 00001.60
Sol. dm rdr cr 2 rdr cr 3dr y-axis
2r
dm
y cm
dr
dm
R
2r 2 r 4 dr 2 R5 r
c 3
r dr O x
y cm 0
R
45
3 2r R
cr dr 2 r dr 4
3
8R
y cm
5 5
30. 00004.04
Sol. Let the body travel a distance s on the incline and come down through a height h.
Potential energy lost = mgh = mgs sin
Work done against friction W = fs = mg cos.s
70
By problem mg cos s = mgs sin
100
= 0.70 tan = 0.7 tan30 = 0.404
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AITS-FT-V-PCM(Sol.)-JEE(Main)/22 8
Chemistry PART – B
SECTION – A
31. C
Sol. From the chemical equation, we can have
1 1
0.15 35 10 3 L H2O2 50 103 L
2 5
H2 O 2 0.263 M
32. D
Sol. The mass% of nitrogen is higher in their compound hence gives greatest amount of N2 gas.
33. B
Sol. As we know that
G H TS RT nk
Here the reaction is vapourisation, therefore, the equilibrium constant equal to vapour pressure of
the liquid
H S
Thus, nP
RT R
H
Slope of the graph in the question is equal to
R
H 4544 8.314
= 37.8 kJ/mol.
34. D
Sol. Cu s 2Ag aq Cu2 aq 2Ag s
By Nernst equation
RT
E Eo nQ
nF
Cu2
Q
2
Ag
Increasing Q will decrease E.
Hence, I is incorrect and by adding Cl to the Ag .
Cell precipitate
Ag es hence Q is es
And II is also incorrect.
35. C
Sol. Ge < Si < As < P
Si = 786 kJ/mole; P = 1012 kJ/mole; Ge = 761 kJ/mole; As = 947 kJ/mole.
36. A
Sol. Isoelectric point is significantly determined by its amine and carboxylic acid functinalities.
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9 AITS-FT-V-PCM(Sol.)-JEE(Main)/22
37. A
Sol. Si – O bond require more energy becomes it is stronger than Si – Si bond, as ‘O’ atom is smaller
than Si.
Si is not a metal and SIO2 is not a ionic compound and also not polar but Si and SiO2 forms 3D
network covalent solid.
38. A
Sol. Conc. HNO3 or HCl cannot oxidize Au to Au3 because standard reduction potential
3
Au 3e Au is too high.
But Cl in aqua regia complex with Au3 , lowering down the reduction potential throuh stabilizing
it as AuCl4 .
39. C
Sol. Most basic, hence easily alkylation.
40. A
1
4 23 4x
Sol. 6.023 1023 2.83 g / cm3
3
1 cm
462 pm
1010 Pm
92 4x 3
6.023 10 23
2.83 462 10 10
92 4x 168
168 92 76
x 19
4 4
NaF
41. B
Sol. % hydrolysis does not depend on the concentration, in case of weak acid + weak base; salt.
42. A
Sol. NaCl AgNO3 AgCl NaNO3
Withe ppt.
AgCl NH4 OH Ag NH3 2 Cl
Ag NH3 2 Cl 2HNO3 AgCl NH4NO3
43. C
Sol. n22 n12 8
n2 n1 n2 n1 8
8
n2 n1 2
4
n2 n1 4
n2 3
n1 1
1 1
RH 4 1
9
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AITS-FT-V-PCM(Sol.)-JEE(Main)/22 10
9
32RH
44. A
Po Ps
Sol. m mol. wt. of solution
Ps
Po Ps 1000
m
Ps 18
17.25 17.20 1000
m 0.1615
17.20 18
If m = M = 0.1615.
xCl3 x 3Cl
Mtotal s 3s 4s 0.1615
0.1615
s 0.04 102
4
4.037 102
45. C
Sol. Neutral species is more stable than charged and complete octet resonance is more stable than
incomplete octet resonance.
46. D
Sol. Sulphuric acid does not show efflorescent.
47. B
Sol. b 4Vm
4 3
4 NA r
3
V1 V nb
nb V V1
V V1 4
b 4.NA r 3
n 3
1/3
3 V V1
r
16NA n
1/3
3 V V1
D 2 3
2 2 NA n
1/3
3 V V1
D
2NA n
48. B
Sol. The refining process of blister copper is known as polling and Cu2O impurities are present in the
Cu metal.
49. B
Sol. Meq. of complex = Meq. Of acid = Meq. of NaOH
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11 AITS-FT-V-PCM(Sol.)-JEE(Main)/22
W
1000 N V
E
0.1 20
W 0.1 20
nf
M 1000
0.1 20
n nf
1000
0.1 20
nf 2
0.001 1000
50. B
Sol. PV = nRT
RV 1.23 20
n 1
RT 0.0821 300
Ba N3 2
B 3N2
1 3
1
Number of moles Ba N3 2 required for 1 mole of N2 mole
3
1
137.327 84
3
221.327
74
3
SECTION – B
51. 00080.10
Sol. By law of conservation of environment
t 1 2
200 10 0.461 T 100 10 0.544 T 100
T 100 0.461 0.544 10
T 80.1o C
52. 00008.44
Sol. The dissociation reaction of Ca OH2 is
Ca OH2 s Ca2 aq 2OH aq
Eo E ocal E oanode
3.02 V 2.87 V 0.15
From Nernst equation
RT
E Eo nQ
nF
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AITS-FT-V-PCM(Sol.)-JEE(Main)/22 12
At equilibrium E = 0
RT
Eo nK sp
nF
Eo .nF
nK sp
RT
E o .nF 0.15 2 96500
logK sp
2.303RT 2.303 8.314 298
28950
logK sp 5.0737
5705.848
logK sp 5.0737
K sp Anti log 5.0737
Antilog 6.9263
K sp 8.44 10 6
53. 00001.86
1
PSO 0.332
Sol. KP 2 1.86
1/2 1/2
PSO PO2 0.562 0.101
2
54. 00005.97
pK a1 pK a2 2.34 9.60 11.94
Sol. PI 5.97
2 2 2
55. 00003.00
Sol. 2ClO3 Cl2 O6 hyper valent
2OF O2F2 complete octet
2GaH3 Ga 2H6 hypovalent
AlCl3 Al2Cl6 complete octet
2ICl3 I2Cl6 hyper valent
2BeH2 be2H4 hypovalent
2NO2 N2O 4 complete octet
x 2| y 3| z 2
yz 3x2
3
x 2
56. 00004.00
Sol. Soluble in excess of NH3 sol.
Cd2 aq ,Ni2 aq ,Zn2 aq ,Ag aq
57. 00005.00
Sol. Number of electron in non-axial d-orbital
dxy ,dyz ,dxz 2 2 1 5
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13 AITS-FT-V-PCM(Sol.)-JEE(Main)/22
58. 00004.07
Sol. H I
o
60
C C O
H I
IO C I sin 60 o 4.07
I I 2 IO
2 2.035 4.07
59. 00005.50
Sol. 2 SO 2 g O 2 g 2SO 3 g
5 3
Limiting reagent is SO2, hence total volume of gas after complete formation of SO3 = 5 L SO3 +
0.5 L O2 = 5.5 L.
60. 00007.00
Sol. K n 5 s2
6
Outer most shell = 2
Penultimate shell = 8
Anti penultimate shell = 2
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f 7
25 8 2
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AITS-FT-V-PCM(Sol.)-JEE(Main)/22 14
Mathematics PART – C
SECTION – A
61. B
Sol. Consider the three-digit arrangement, aba. There are 10 choices for a and 10 choices for b (since
10 10 1
it is possible for a = b), and so the probability of picking the palindrome is 3
10 10
1
Similarly, there is a probability of picking the three-letter palindrome
26
1 1 1 35 7
By the Principle of inclusion-exclusion, the total probability is
26 10 260 260 52
7 + 52
62. C
Sol. By property of inclusion/exclusion, we have A1 A 2 A 3 A A
i i Aj A
Number of people in at least two sets is A A i j 2 A1 A 2 A 3 9
So, 20 = (10 + 13 + 9) – (9 – 2x) + x, which gives x
63. B
Sol. Let G be the point obtained by reflecting C about the line AB. Since ADC = ,
2
we find that BDE ADC ADC BDC BDC
2
sin
BE BE 2 where we have used the law of sines in BDG. But by L’Hospital’s
EF
BC BG 3
sin
2
Rule
sin cos
lim 2 lim 2 1
0 3
0 3 3
sin cos
2 2
64. A
Sol. Since sin 2x = 2 sin x cos x and sin 3x = sin x (4 cos2 x – 1), we may write the equation in the
2 a
form sin x (2 cos x – (2 – a) cos x – a) = 0. Thus sin x = 0, cos x = 1 or cos x = . The
2
nonnegative solutions of the equations sin x = 0 and cos x = 1 are x = k and x = 2 k, k = 0, 1, 2,
a
.... respectively. Let |a| > 2. In this case the equation cos x = has no solution and therefore
2
the nonnegative solutions of the initial equation are 0, , 2, ....., which form an arithmetic
a
progression. Let now |a| 2 and let x0 be the only solution of the equation cos x = in the
2
interval [0, ]. In this case the nonnegative solutions of the last equation are x = x0 + 2k and x =
2 – x0 + 2k. It is clear now that the nonnegative solutions form an arithmetic progression only
when x0 = 0, x0 = and x0 = , so giving a = –2, a = 0 and a = 2. The values of a are a = 0 and
2
|a| > 2.
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15 AITS-FT-V-PCM(Sol.)-JEE(Main)/22
65. D
1 z13
Sol. z ei /13 z13 1 ; z13 1 0 0
1 z
2 3 12
1 – z + z – z + ..... + z = 0 ..... (1)
1 z13 2
1 z 1 z
2
1 + z + z2 + z3 + ..... + z12 = ..... (2)
1 z
From equation (1) and (2), we get
1 1
1 + z2 + z4 + z6 + z8 + z12 = and z + z3 + z5 + ..... + z11 =
1 z 1 z
66. D
Sol. |2z1 – 3z2 – 4z3| = |2z1 = 3(z2 – 2) – 4(z3 – 5) – 26| 2|z1| + 3|z2 – 2| + 4|z3 – 5| + 26 = 61
67. A
Px 4 3 2
Sol. lim 3 27 P(x) has no constant term let P(x) = ax + bx + cx + dx
x 0 x
3 – d = 27 d = –24
P(x) = ax4 + bx3 + cx2 – 24x ; P(2) = 0, p(1) = –9, p(2) = 0
P(x) = 4ax3 + 3bx2 + 2cx – 24 ; P(x) = 12ax2 + 6bx + 2c
P(x) = 24ax + 6b ; a + b + c – 24 = –9
a + b + c = 15 ..... (1)
P(2) = 0
4a(8) + 3b(4) + 2c(2) – 24 = 0
8a + 3b + c = 6 ..... (2)
P(2) = 0
24a(2) + 6(b) = 0 8a + b = 0 ..... (3)
Solving (1), (2) and (3)
a = 1, b = –8, c = 22
P(x) = x4 – 8x3 + 22x2 – 24x ; P(x) = 4x3 – 24x2 + 44x – 24 = 4[x3 – 6x2 + 11x – 6]
P(x) = 4[(x – 1)(x – 2)(x – 3)]
P(x) = 4[3x 2 – 12x + 11] > 0 x [3, 4] = 4[(3) (2) (1)] = 24 = 4M M = 6
68. A
Sol. Tangent to parabola at origin is x – y = 0 y = –x y=x
2
2 1 1 O
y + y = x ; y x
2 4
Let A be the shaded area
0 0
y3 y 2
A y y dx
2
3 2 1 (0, –1) B(1, –1)
1 y = –1
1 1 1 A(1, –1)
=
3 2 6
1 1 1 1
1 A1 A 1 2 p 1 2
Area of OAB = 1 2 1 ; 2 6 or 2 6 1 or or p+q=3
2 A2 1 1 1 1 A2 2 1 q 2 1
2 6 2 6
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AITS-FT-V-PCM(Sol.)-JEE(Main)/22 16
69. B
Sol.
Equation of AB y = r : A R R2 r 2 , r using R2 = 2r2
B R R2 r 2 , r point A(R – r, r) B(R + r, r) slope OA
r
Rr
m1
r m m2
Slope OB m2 ; tan 1 1 ; 45
Rr 1 m2m2 4
70. A
x
Sol. e1 x t dt e1 t x dt e1 x t dt apply integration by parts
II I II I
0 0 x
x
= x t e1 1 e t 0 x t e t e t x = x + 2e – 1
–x
71. C
3 3 3 3 3 3 3
Sol. –(1 + 2 + 3 + ...... + 2014) + 2(2 + 4 + ..... + 2014 )
2 2
2014 2015 3 1007 1008 2 2 2 2
= 22 = –(1007) (2015) + 4(1007) (1008)
2 2
= –(1007)2 [(2016)2 – (2015)2] = (1007)2 4031
72. C
Sol. f(x) = x3 + 3x2 + 3x + 3 = 0 ; f(x) = 3x2 + 6x + 3 = 3(x + 1)2 0 ; f(x) is increasing function
Now f(–3) = –6 < 0 ; f(–2) = 1 > 0
real root lies between –3 and –2
+ + = –3 ; –3 < < –2 ; + – 3 < + + < + – 2
+ – 3 < –3 < + – 2 –1 < + < 0
73. B
a 9
Sol. ab = 36 using AM GM
4 b
ab
ab a + b 12
2
74. A
Sol. Let r be an integer in (–10, 10)
x 9 8 r h
Now, LHL = lim 2 t dx = lim 2 t dt 2 t dt ..... 2 t dt
x r h0
10 10 9 r 1
= lim 210 2 9 ..... 2r 1
1 h
h 0
10
= 2 29 ..... 2r 1 ..... (1)
x 9 8 r h
lim 2 t dt = lim 2 t dt 2 t dt ..... 2 t dt
x r h0
10 102 9 r
= 2 10 29 ..... 2r 1 ..... (2)
r
t
f r 2 dt = 2 10 29 ..... 2r 1 ..... (3)
10
From equation (1), (2) and (3), we get f(x) is continuous at all integers
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17 AITS-FT-V-PCM(Sol.)-JEE(Main)/22
75. A
n n n r
1 x 2 3x
a x 1 x
r 2
Sol. r
r 0
n r n n r
n
Cr 1 x
2
3x 2
a r x r 1 x
2
r 0
2n 2r r
Compare the coefficients of x 1 x
76. B
x ; x
2 2
Sol. sin1 sin x
x ; 3
x
2 2
77. D
Sol. R.N.W = 7 C2 5 C2 22 840
78. A
Sol. –4xdx + 6ydy + 5(xdy + ydx) – 3dx – 2dy = 0
Integrating –2x2 + 3y2 + 5xy – 3x – 2y = c
79. B
Sol. pq
Contrapositive ~p ~q
80. A
Sol. l2 + m2 + n2 = 1 ; l + m + n = 0 ; 2l2 + 2m2 – n2 = 0
1 1 2 1 1 2
Solving above equations, we get the direction cosines as , , and , ,
6 6 3 6 6 3
1 1 2 1 1 2
or , , and , ,
6 6 3 6 6 3
1
The angle between these lines in both the cases is cos1
3
SECTION – B
81. 00012.00
9y 2 4 4
Sol. Let y = x sin x. We can rewrite the expression as 9y
y y
Since, x > 0 and sin x > 0 because 0 < x < , we have y > 0. So we can apply AM – GM
4 4 4 4 2
9y 2 9y 12 . The equality holds when 9y y 2 y
y y y 9 3
Therefore, the minimum value is 012.
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AITS-FT-V-PCM(Sol.)-JEE(Main)/22 18
82. 00089.00
Sol. Use the angle bisector theorem to the angle bisector of P divides QR into segments of length
25 15 25 15 QP 5
x , . It follows that and so
x 20 x 2 2 RP 3
5x 3x Q 5yR 3y Q 23
P R , 5,
8 8 2
11
The desired answer is the equation of the line PP·PP has slope , from which the equation
2
to be 11x + 2y + 78 = 0. Therefore, a + c = 089
83. 00994.00
2 2 2 2 2
Sol. a + b – 2ab cos = c = 1989c – 2ab cos ab cos = 994c
cot cos sin sin cos sin sin ab ab 99c 2
Now, cos = 994
cot cot sin sin2 c2 c 2 ab
84. 00015.00
Sol. It is best to get rid of the absolute values first. Under the given circumstance, we notice that
|x – p| = x – p, |x – 15| = 15 – x, and |x – p – 15| = 15 + p – x
Adding these together, we find that the sum is equal to 2\30 – x, which attains its minimum value
(on the given interval p x 15) when x = 15, giving a minimum of 015
85. 00003.00
Sol. A–1 + B–1 = (A + B)–1 (A–1 + B–1)(A + B) = (A + B)–1(A + B)
2I + A–1B + B–1A = I A–1B + B–1A = –I
Let A–1B = P
P + P–1 = –I P2 + I + –P P2 + I = –P P2 + P + I = 0
(P – I)(P2 + P + I) = 0 P3 = I
|B| = 1 |A–1| |B| = 1 |A| = |B|
86. 00016.00
a b a2 bc a d b 1 0
Sol. A2
c d c a d bc d2 0 1
If a + d = 0, a2 + bc = 1, b = 0, c = 0, d = 1, –1, a = 1, –1
or c = 0, b = 1, –1, a = 1, –1
If b = 0, c = 0, a = 1, –1, d = 1, –1
Number of quadruples (a, b, c, d) = 16
87. 00016.43
2
Sol. 3 3 5 8 7 1 3 6 3 30
30 30 30
88. 00001.00
4 1
Sol. m3
49 9
89. 00120.00
Sol. x + y + z 10 R.N.W = 9 C2 8 C2 ..... 2 C2 = 36 + 28 + 21 + 15 + 10 + 6 + 3 + 1 = 120
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19 AITS-FT-V-PCM(Sol.)-JEE(Main)/22
90. 00005.00
Sol. Let the variable be x. Here n = 100, incorrect A = 40, incorrect = 5.1
From formula A
x
x nA
n
Incorrect x = 100 40 = 4000
Correct x = incorrect x – 50 + 40 = 4000 – 50 + 40 = 3990
2 2 x2 2 2 2
Again, from A , we get x = n( + A )
n
2 2 2
Incorrect x = 100{(5.1) + (40) } = 100 (26.01 + 1600) = 162601
Correct x = incorrect x – 50 + 402 = 162601 – 2500 + 1600 = 161701
2 2 2
Correct mean A
x 3900
39.9
n 100
x 2 161701
Correct 2 A 2 1617.01
n 100
Correct 2 = 1617.01 – (correct A2) = 1617.01 – (39.9)2 = 1617.01 – 1592.01 = 25
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