•"IVIARY OF QUES TION S ASKE D IN PREV IOUS BOAR D EXAM S

stJJ.Y~

[ 1 SOLID STATE .
. guish between crystalli ne solid and am h
5tl11
Oi curs as face centered cube and has :rp ~us soli d • (March 2013, 2014, 2017)
(l-l aold 0 ~ass of Au= 197) (2)
a ensity of l9.30 kg dm-3 . Calculat e atomic radius of gold.
1il (M : te the number of atoms present in
01
lAna. r = 144 pm}
2 (March 20131 (2}
(SI cal~ aedge length of 100 pm and density f ~ ~ f cry stal
1 which has face-cen tered cubic (£cc) crystal lattice
bfl";;~e Schottky defect and Frenkel defect? • lAna. 8 x 1023 atoms] (Oct. 2013} (3}
(4-) Wb ntered cubic crystal lattice of copper h d .
(5) Face c~t cell. Given molar mass of copper is 63.t=-~~ ~:ty of 8
(Oct. 2013) (2)
-966 g•cm-3 . Calculat e the volume of
tbe un ° and Avogadro number N.., is 6.022 x 1023 .
. 11 of iron crystal has edge length [Ans. 4.702 x 10-23 cm3)
288 (March 2014) (3)
(6) A unit ~etype of the crystal lattice. {Given: Mol:~and de?sity
cell an , r-rumber N = 6.022 x 1 ()23] 7 .86 g.cm-3 . Find the number of atoms per unit
ogadro s l " A
ass of iron= 56 g- mot- 1 •
, •
AV lain impurity defect in stainles s steel with diagram {An8 '
•
2 , Type-bee } (Oct. 2014) (3)
(1) E~ . m crystalli ses as body centered cube (BCC d• .
(8) Niob:ate the atomic radius of niobium . (Given. jt an. has dens1ty of 8. 55 kg/ dm-3 .
calc rystallise s in F.C.C. (face-ce ntered b.' omtc mass of niobium = 93).
(March 2015} (2)

silver c {Ans. 0.143 nrn](Ma rch 2015) (3)

(9) ·t cell is found to be 408.7 pm. Calculatcu ic crystal)
e density 0 f thstructu . re.
Th d 1
e e ge ength
un_i n. Molar mass of silver is 108 g. moZ-1] of the
e unit cell.
[Give •
W}lat is ferromag netism? Iron (Z = 26) is strongly •
ferrom
(Ans 10 51
: • ~-cm
-31 (3)
(10) tallises in FCC structur e If d (Oct. 2015}
. . agnetic. Explain. (March 2016) \2)
(11) silver ~:ass of silver (Ag) = 108 g . •moZ-~~sity of silver is
10.51 g.cm-3 • calculate the volume of unit cell.
[Atomic . (Ans. 68.24 x 10-24 cm3}
face centered cube (FCC) consists of how many atoms? E .
(March 2016) \3)
(12) A . f .
Determin e the density o Cesium chloride which crystalli z . BCC • xp 1 am. (July 2016) \2)
(13) The atomic masses of Cs and Cl es in type structur e with the edge length
41;•.1 Pr:;· + = 1.69 A and= r _ = 133
Cs 10n res 1 • 81 A are and 35.5 respectiv ely. Predict the co-ordin ation number of
. Cl •. . (Ans. 4 gcm-3 ; C.N. = 81 (July 2016) \3\
114 calculate the percenta ge efficie~c y of packing in case of simple cubic cell. (Ans. 52.4%1
)
alculate the number of atoms 1n
(March 2017} \2\
(15) C a unit cell of a metal crystalli • • f
sing 1n ace centered cub.1c structur e.
. .
(l 6) Classify the followin g molecul ar solids into different types:(Ans. 4 atoms1 \March 201 7) \2\
(a) Ammon ium phosph ate (b) Brass {c) S molecul e (d) Diamon d.
8 (Jut 20171 \2 \
(17) A metal cI?'stalli ses into two cubic faces namely face centered (FCC) and
body centered (BCC), y
whose urut cell edge lengths are 3.5 A and 3.0 A respectiv ely. Find the ratio
of the densitie s of
FCC and BCC. [Ans. d 1 :d2 = 1.261 (July 2017} \3\
(lS) Ionic solids are hard and brittle. Explain .
(March 2018) \2\
119) The density of iron crystal is 8.54 gram cm-3 . If the edge length of unit cell is 2.8 A. and
atomic mass is 56 gram mo1- , find the number of atoms in the unit cell.
1

[Given: Avogadr o's number = 6.022 x 1023 , 1 A= 1 x 10-8 cm1 [Ans. z = 2.017z
21 (March 2018) \3\
(20) Classify the followin g molecul ar solids into differen t types:
(a) HCl (b) CO 2 (c) Solid ice (d) SO2
(21) The density of silver having atomic mass 107 .8 gram moi- 1 is 10.8
(July 2018) \2\
gram cm- 3 . If the edge
length of cubic unit
cell is 4.05 x 10-8 cm, find the number of silver atoms in the unit cell.
(NA= 6.022 x 1023 , IA =1CJ8 cm)
(Ans. Z = 4.009;:s 41 (July 2018) \3\
(22) What is the ratio of octahed ral holes to the number of anions in
hexagon al closed packed structur e?
(Ans. 1: ll (March 2019) \1\
(23) Define Anisotro py. Disting uish between crystalli ne solids and amorph
ous solids. (March 2019) \3\
(24) Give the relation between radius of atom and edge length in body
centered cubic crystal. (July 2019) \1\
(25) Classify the followin g solids: (i) Diamon d (ii) NaCl (iii) P molecul
4 e (iv) Brass.
What is Schottk y defect?
(July 2019) \3\
{26) Classify the followin g into differen t types: (a) Silver (b) P (c) Diamon
4 d (d) NaCl (March 2020) \2\
(27) Unit cell of a metal has edge length of 288 pm and density of 7 .86
g cm- 3 • Determi ne the type
of crystal lattice. (Atomic mass of metal = 56 g moz- 1) (Ans. heel (March 2020) \3\
(28 ) What is the coordin ation numbe r of atoms in simple cubic crystal
lattice? (Sept. 2021) \1\
(291 A compou nd forms hexago nal close packed (hep) structur e. What
is the number of
(i) Octahed ral voids (ii) Tetrahe dral voids (iii) Total voids formed in 0.4
mol of it?
[Ans. {i) 2.4098 x 1023; (ii) 4.818 x 1023; (iii) 7 .227 x 1023 ;}
(Sept. 2021) \3'
(277)
 .;:;.27,;..;8:._._ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _V_rt_T._~_•_Xll
__ C_he_m_ist--...iryl..:Pi:..::a~p
ers So,ufi...._
(30) W • th
nte e consequences of Schottky defect with reasons. . x _
(M arch 2022,
(2)
8
(3 lJ Gold crystallises into face-centred cubic cells. The edge length of urut cell is 4.os-3 IO ~m.
1 19 27
Calculate the density of gold.(Molar mass of gold• 197 gmo1- ] [Ana. - ,c lO kg·dm 1(March 2022]
2
<32) Explain metal deficiency defect with example. (March 2022J ( )
33 2
( ) Distinguish between Schottky and Frenkel defect. (July 2 022] ( )
34 2
( ) Calculate the number of atoms and unit cell present in 0.5 g of Niobium if it forms . . ()
body centred cubic structure. The density of Niobium is 8.55 g cm-3 and edge len~ 1of urut cell 19 330.6 Pm.
[Ana.No. of atoms • 3.25 x 1021 , No. of unit cells • 1,62 ,c 1O I (July 2022] ( )
2
(35) Explain the following terms:
(a) Substitutional impurity defect (b) Interstitial impurity defect. (March 2023] (2)
(36) Silver crystallizes in fee structure. If edge length of unit cell is 400 pm, calculate density of silver.
I (Atomic mass ofAg • 108). [Ans.Density of silver (p) = 11.20 g•cm- 3• J (March 2023] (2)
It
j II SOLUTIONS
(1) Derive the relationship between relative lowering of vapour pressure and molar mass of
._ non-volatile solute. (March 2013, 20l 7J (2)
(2J Define osmosis. (March 2013} (1)
(3J What is boiling point? . . (March 2013} (l)
(4J State Henry's law. How does solubility of a gas in water varies with the temperature?{Oct. 2013; July 2017J(2)
(5) De~e 1sotonic solution'. • (March 2009, Oct. 2013) (l)
(6) Calculate the amount of CaC½ (van't Hoff factor, i = 2.47) dissolved in 2.5 L solution so that
its osmotic pressure at 300K is 0. 75 atmosphere.
(Giuen: Molar mass o/Ca~ is 111 g. moz-1,R = 0.082 L. atm K-1 moz-1.) [Ans. W = 3.425 g] (March 2014} (3)
(7) Explain, why do aquatic animals prefer to stay at lower level of water during summer? (March 20l 4) (2)
(8) A solution containing 0.73 g of camphor (molar'mass 152 g.mol-1) in 36.8 g of
acetone (boiling point 56.3°C) - , : · ·- boils at 56.55°C. A solution of 0.564 g of
unlmown compound in the same weight of acetone boils at 56.46°C. Calculate the molar mass
of the unlmown compound. • .- . :,i • 1 • •. [Ans.183.5 g•mo1- 1 ] (Oct. 2014) (3)
(9) Define van't Hoff factor. How is it. related to the degree of dissociation? (Oct. 2014) (2)
(10) Define: Ciyoscopic constant. (Oct. 2014, July 2018) (1)
(11) Derive van't Hoff general solution equation. -·· : '. • • (March 2015, 2019; July 2011) (2)
a
(12) 1.0 x 10-3 kg of urea when dissolved in 0.0985 kg of solvent, decreases freezing point
of the solvent by 0.211 K.' 1.6 x 10-3 kg of another non-electrolyte solute when dissolved
in 0.086 g of the same solvent depresses the freezing point by 0.34 K. Calculate the
molar mass of the another solute. [Given: Molar mass of urea= 60) [Ans.68.28 g-mo1- 1] (March 2015) (3)
(13) Define ebullioscopic' constant. Write·its t'..tnit. _:: (Oct 201 SJ (2)
f14) . What is the effect of temperature .
on solubility of gas in a
.
liquid?. (Oct 20 l SJ (2)
(15) Define boiling point. Write the formula to determine molar mass of a solute using freezing point
depression method. - • (March 2016) (2)
(16) The vapour pressure of pure benzene is 640 mm of Hg. 2.175 x 10-3 kg of non-volatile
solute is added to 39 gram of benzene, the vapour pressure of solution is 600 mm of Hg.
. , Calculate molar mass of solute. (C • 12, H = 1]. • [Ans.69.6 x 10-3 kg] (March 2016) (3)
(17) Why is molality of a solution independent of temperature? . _ (March 2016) (1)
. (18) Define; (a) Osmosis (b) Freezing point. .
• . I
(July 2016) (2)
, {19) 3.795 gof sulphur is dissolved in 100 g ofCS2 • This solution boils at 319.81 K. What is the molecular
•. , .form~ of sulphur in solution? The boiling point of CS2 is 319.45 K. .
(Given that Kt, for CS2 = 2.42 K kg mo1-1 and atomic mass of S-= 32.) (Ans.S8 ] (July 2016) (3)
(20) State Hemy's law. (July 2016) (1)
f21) Leolutionof a substance having mass 1.8 x lo-3 kg has the osmotic pressure
of 0.52 atm at 280K. Calculate the molar mass of the substance used. _
•.J. qm.3, R • 8.314 JK-1 moZ-1) • (Ana. 79.49 g-mol- 1) (March 2017} (2)
1
'lftll ft0'.point of benzene is 353.23 K. When 1.80 gram of non-volatile solute was dissolved in
benz.ene. The boiling point is raised to 354.11 K. Calculate the molar mass of solute.
• 2.53 Kmot-1] • (Ana.57.5 g•mol- 1) (March 2017} (2)
w. How does solubility of a gas in water varies with temperature? (July 2017} (2)
·ty (b) Osmotic pressure. (July 2017} (2)
 n.,estions 279
,J_f300.~d ~-
(J.r!i.
0
bstance (M • 169 gram mol- 1) is d • .
rga.ruc 5 ~ound to be 0.54 atm. If R • 0 0821 ssolved in1 2000 cm3 of water. Its osmotic pressure
1
S'!,ffl.ffl
S) AP oc was
0
• L atrn. K- mo1- 1 , calculate the mass of (2)
,i ~t 120 1ote. . (Ana. 7.796 g) {July 2017}
t;11e s relation between elevation of boiling point d h 20181 (2)
Jive tbe . able membrane I
an mo ar mass of solute. (Marc
) pe.,;,..,e: SeitllPe~e • (March 2018} (1)
(i6 pev>~ J-IenIY s law
,,1) (a&) state of urea was dissolved in 300
,is) (b) 22.22 ~~ea and molality of the urea so~= of water. Calculate the number of
moles z mass of urea = 60 gra z-1)
[Ana.0.3703 mol; 0.1234 mot kg-•] (March 2018} (2)
,aiven: Mo ar . m_mo
, an't Hoff general solution equation for 'n' moles of 1 t .. h 20 19} (2)
Jive v . t f li •d? Th f sou e. (July 2018; .... arc
(:Z9) ~at is fre~zin~ ri:iso~u:o::1iien 2 ~ ;;:!ngfpointl of pure_ benzene is 278.4 K. Calculate the
o) zillg point O O
a so ute having molecular weight 100 gram is
(3 fte~ed to 100 gr8:°1 of be°2'.ene. (K,for benzene= 5.12 kg moZ-1] {Ana.T • 277.376 K] (July 2018} (3)
e.d tbe following terms.
121) pefitlet ..,;c solution (ii) Hypertonic
W .
solution (iii) Hypotonic soluti·on. (.March 2019)
(3)
(., i) Jso o ...,..
( smotic pressure. nte mathematical expression between cryoscop1c . d
pefitle O f lute constant an
32) mass o so • (July 2019} (2)
( molar (2)
. e 1t::::: CRT. (July 2019}
(3 3) pertV the following: (i) Molality (ii) Mole fraction. (July 2019} (2)
(124) pefitl~1s the concentration of dissolved oxygen at 50°c un d er pressure of one atmosphere
., dn-.at •
: .i~artial pressure of oxygen at 50 C 1s O .14 atm.
O
(35)
if~nry's law constant/or oxygen= 1 •3 x l0- mol dm- 3 atm-1) [Ans.1.82 x 10- 4 mol•dm- 3 1 (March 2020}
3 (1l
fH' .,;, ..... (a) Molality (b) Osmotic pressure. (March 2020} (""')
.,
ve~&e ·
(36) rive the mathemati~al expression between molar mass of a non -volatile solute and
(31) De ation of boiling point. State and explain van't Hoff-Avogadro's law. (March 2020} (4)
elev • t t ' D • h
Define 'Cryoscop1c cons an • enve t e relation between elevation of boiling point and
(38) lar mass of solute. .
(Sept. 2021} (3)
II10 .
What is the molar mass of a so~ute if a solution prepared by dissolving 0.822 g of it in
(39) 0 _3
drn3 of water ~as an osmotic pressure of 0.196 atm. at 298 K? [Ans. 341.9 g· mo1-11 (Sept. 2021}
Derive an expression to calculate molar mass of non volatile solute by osmotic pressure
(40) llleasurement. (March 2022) (2l
Henry's law c~1?°stant for CH3 1:3r(g) is 0.159 mol dm-3 bar-1 at 25°c.
(4 l) What is solubility of CH3Br(g) 1n water at same temperature and partial pressure of 0.164 bar?
[Ans.0.026 mol dm- 3 } (March 2022) (2)
( ) Define the following terms: (i) Isotonic solution (ii) Osmosis. (March 2022) (2\
42
( Define: (i) Osmotic pressure (ii) Ebullioscopic constant. (July 2022) (2)
431
(44-) 5 % aqueous solution of cane sugar has freezing point of 271 K. Calculate freezing point of
5% glucose solution. {Molar mass of cane sugar= 342 g mol-1 ] {Ans.269.2 K} (July 2022) \2)
(4S) The normal boiling point of ethyl acetate is 77.06 °C. A solution of 50 g of non-volatile solute
in 150 g of ethyl acetate boils at 84.27 °C. Evaluate the molar mass of solute if Kb for ethyl acetate is
2.77 K kg mo1- 1 . {Ans.128 g mol-1} (July 2022) \2)
(46) Write the SI unit of cryoscopic constant. (March 2023) lll
(47) Calculate the mole fraction of solute, if the vapour pressure of pure benzene at certain temperature is
640 mmHg and vapour pressure of solution of a solute in benzene is 600 mm Hg. [Ans.Mole fraction= 0.062}
(March 2023)
(48) Define osmosis. How will you determine molar mass of non -volatile solute by elevation of
boiling point. (March 2023) \3)

- IONIC EQUILIBRIA
(1) Derive the relationship between pH and pOH. (Sept. 2021, March 2022) \2)
(2) Define 'Solubility product'. Derive the relationship between solubility and
solubility product for Pbl2 . (Sept. 2021) \3}
(3) Calculate the pH of buffer solution composed of 0.01 M weak base BOH and
0.02 M of its salt BA. [Kb= 1.8 x 10-5 for weak base] [Ans.pH= 13.95] (March 2022) \3
4
14) The pH of solution is 3.12. Calculate the concentration of H 3O+ ion. {Ans.7.568 x 10- Ml (July 2022) \~
IS) Derive an expression of Ostwald's dilution law for weak acid. (July 2022) \~
IDefine: Acidic buffer solution. Write the relationship between solubility and solubility product
far PbC~ (March 2023) \
Woakmonobasic acid is 10% dissociated in 0.05 M solution. What is percent dissociation in 0.15 M solutior
(Ans.% dissociation= 5.74% l (March 2023)
 280

II CHEMICAL THERMODYNAMICS
-
UTTAM's XII Chemistry Papers Solution

(l) Prove that Ml• .1U + .1 nRT. What is the condition under which llU • AH? {March 2013) (2)
12 ) JOO mo) of perfect gas occupies l 3L at 320 K. Calculate the work done in joules when the gas expands-
(a) isothermally against a constant external pressure of 0.20 atm.
(b) isothermal and reversible process.
1 1
(c) into vacuum until the volume of gas is increased by 3L. (R • 8.314 J mot- K· I
(Ana. (a)-60.78 J (b)-165.8 J (c) OJ (March 2013) (2)

(3) Explain with reason sign conventions of AS in the following reactions:

(i) N2181 + 3H2181 - + 2NH31g)
(ii) CO2(g) co2191 (March 2013) (2)

(4) Calculate .1H° for the following reaction:

2H3 BO3faq)-+ B2O3181 + 3H2O1~
Given that: (a) H3 BO3(aq)-+ HBO21aq) + H2 O111 , AH 1 = - 0.02 kJ
0

(b) H2B4O7(sl-+ 2B2O3 (sl + H2 O111, AH 2 = 17.3 kJ

0

+ H2O(~ - + 4HBO2(aq)' AHo3 = - 11 •58 kJ [Ans. 6H = + 14.40 kJJ(Oct. 2013)

0 (3)
(c} H2 BO
4 7(s)
(5) What are the conditions for spontaneous and non -spontaneous reactions in terms of
free energy change? Define entropy. (Oct. 2013) (2)
(6) Derive the relation .1H - AU= ruiRT. (Oct. 2013) (2)
(7) Derive a relation between .1H and .1U for a chemical reaction. (March 2014) (2)
(8) One mole of a gas expands by 3L against a constant pressure of 3 atmosphere. Calculate the work done in -
(a) L. atmosphere (b) Joules (c) Calories. [Ans, (a)- 90 L-atm (b)-911.7 J (c)- 217.98 cal. J (March 2014) (3)
(9) Derive the relation between .1G0 and equilibrium constant (K) for the reaction-
aA + bB cC + dD (March 2014) (2)

(10) What is the value of .1Ssurr for the following reaction at 298K?
6CO2(g) + 6H2O1~ C6H 12O6(sl + 6O2(g).
Given that, aG0 = 2879 kJ mol- 1 .1S = -210 J moi-1. [Ans. -9.451 kJ]
K"1 (Oct. 2014) (3)
State and explain Hess's law of constant heat summation. (Oct. 2014; July 2018; March 2020) (2)
(11)
Derive the equation: W = - pext ·Av. (March 2015) (3)
(12)
(13) Define the following terms: (a) Enthalpy of fusion (b) Enthalpy of atomization. (March 2015) (2)
(14) Determine whether the reactions with the following AH and AS values are spontaneous or non-spontaneous.
State whether the reactions are exothermic or endothermic.
(a)AH= -110 kJ, .1S= +40 JK- 1 at 400 K (b)AH= + 40 kJ, AS= -120 JK- at 250 K.
1

[Ans. (a) spontaneous and exothermic (b) non-spontane ous and endothermic] (March 2015) (3)
(15) Write one statement of first law of thermodynam ics and its mathematical expression. (March 2015) (2)
(16) Derive an expression for maximum work in isothermal reversible expansion of two moles of an ideal gas.
(Oct. 20 l SJ (2)

(17) The equilibrium constant~ for the reaction

H21g) + ½(g) 2HI(g) is 130 at 510 K. Calculate 6G0 for the following reaction at the same temperature.
2HI H (g) + I (g). /Given: R = 8.314 JK- 1 mot- 1.J [Ans. 6cJJ = 20490 J) (Oct. 2015) (3)
2 2
(18) State: (a) Second law of thermodynamics in terms of entropy
(b) Third law of thermodynamics. (Oct. 2015) (2)
(19) Write mathematical equations of first law of thermodynam ics for the following processes:
(a) Adiabatic process (b} Isochoric process. (March 2016) (3)
(20) Define Enthalpy of sublimation. How is it related to enthalpy of fusion and enthalpy of vaporization?
(March 2016) (2)
(21) Calculate C - Cl bond enthaply from following reaction:
CH3 C~ + C~(g) ,- CH2C½(g) + HCI1g); 4"0 = -104 kJ if C - H, Cl - Cl and H - Cl bond enthalpies
are 414,243 and 431 kJ-mo1-1 respectively. [Ans. 330 kJ moJ- 1 ) (March 2016) (3)
) ki>Wn the relationship between Gibb's standard energy change of the reaction and equilibrium constant.
(July 2016) (2)
te the standard enthalpy of the reaction,
3H2(g) JJ C2H6(g) ; m0 = ? from the following m 0 values :
7
-02(11 ,- 2C02(g) + 3H20u1 ; Ml°= -1560 kJ
 rd ouestions
0~
1
t1 + -2 02(g) H201n
281
; AlfO • -285 .8 kJ
p,J P2~ ) + 02(g)
_ _.
co2(g )
• A/fO
J C(gt8pbitC
alpy '. ' • - 393.s kJ. I
I' the term 'enth Aila. 4JIO •-84.4 kJJ
pe6'1e,vill happen to the internal ener . (July 2016/ 131
by the
(1'l ¢11l~te AH' for the reaction betwee~e~:ork is done r to fi systcrn;,
ne Elnd Wate
6) cs1c C ff OH~,= - 1368 kJ; AcHo C H /March 2017} 121
• -14 IO kJ 0rrn ethyl alcohoU
2 :a1culated ,I.I{O represent th 2 rorn the foUow ing data :
poes the [An AHO - e enthalpy of fi • .
s. - -42 kJ is orrna tton or Ii .
of fi ~d ethanol?
. an expression for maximum Work• not enthalpy orrnation of Ii .d
perive ti al C!Ui ethanol.) /March 2017} 131
~6) rite the rnathema ex~ression of the first law
i . /March 2017} 121
,,11 \\'J Jsothertllal (bJAdiabatic alpy (cJ Isochoric IdJls o/~ therrnodYnlunics for the oUowmg processes
of comb . anc.
(• u}ate the standard enth Ustion of CH C
ca1c kJ 11 ~ from the foll . (July 2017 } (2)
('S) • rJO (CO2) = 393.3 mo - ; .•flrHO (~O) == - 285 8 k a OOH, 0 wmg data:
• • J rno1-1 . ~]-JO
1¥" (CHaCOOH) == -483 2 kJ mot-• .
[Ans. MfO == -s75 kJ •
• : '
• tinguish between isothermal process and
.
. adiabatic Process. moi-i.J (July 2017) (3)
(,9J pis ..i...,.d law of thermodynamics • a·ive its two us (Jul 20
Y 17) (2)
51:ate UUI> for the fo e~.
(30) culate the internal energy at 298K h 2018/ 121
mo1•1. (Given· R l'lllation of one mole of anun . if (Marc
(Sll cal tant pressure is -42.0 kJ • • == 8,314 JK-I _ ) orua, the entha lpy chang e at
cons al f za::
1 1
kJJ (Marc h 2018) 131
ofvapori [Ans. -39.5 23
321 pefine: fa) En~ PY o ato ~tio n (bJ Enthalpy • (March 2018 / (21
nd isoth enna ny rever sibl 6
I 5111oles of helium expa and
nal ener y rom a pressure 40 x 10-s Nm·2 to 4 x 1o-s Nm·2 at 300 K.
1SSJ calculate the work done, change in inter sion.
[Ans. W • == - : ~at absorbed during the expan
{R = 8.314 J K-1 moZ-1) (July 2018) (3)
' 6 U == O, q == 287.720 kJ]
""te and explain Hess's law of constant h~; summation.
• . 'Jul
(34) S •
r Y 2018 ; Marc h 2020; 2022) (2)
Write the features of reversible process.
•
l,c;L

/July 2018 / (21

fSSI Write the cond itions for maximum work done by th st (Marc h 2019) (2)
36 ing re ti e sy em.
( ) Calcula~ the work done in. the follow h
ac on at 50°C•State whet er wor 1s one k · d
(37)
on the system or by the system.
- .
1 -- (31
3
SOJ(g)· [Ans. W = + 1. 43 kJ; Work
is done on the system. J (March 2019 /
so
2111 + 2°21 g1
(3SJ The standard en~a lpy of comb~stio
n of formaldehyde !!.ell°==_ 571 kJ.
(March 2019) (3)
of 22 g of CO2? [Ans. 285.5 kJ]
How much ~eat will be evolved m the formation (July 2019) (1)
de c~ not perform the work. Give reason.
(39) Conversion of carbon into carbo_n dioxi
alpy . Classify the followmg properties into intensive and extensive properties:
(40) Define the term enth (July 2019) (3
(i) Pressure (ii) Density (iii) Work (iv) Heat.
(41) Calculate the work done by the follow
ing chemical reaction:
373K
2NH N0 (s)
4 3
2N20(g) + 4H20(g)
or by the system.
State whether the work is done on the system (July 2019) (~
[Ans. W = -18. 62 kJ, work is done by the
system.}
L\H0 == +57.24 kJ, 6S0 = 175.8 JK-1.
(42) For the reaction: N20 4(g) 2N02 (g) ;

• "1tt what temp erature the reaction will be spontaneous?

(March 2020) (~
(Ans. T > 325.6 K, the reaction will be spon
taneous.]
•
(43) Defihe: (a) Reversible process (b) Stan
dard enthalpy of combustion.
2NH3(g) •
Calculate the enthalpy change for the reaction: 2
N (g) + 3 H21g1

The bond enthalpies are:

l!i:in lr.J moJ-l I ~== I ~;: I ~;:

(44) In a particular reaction, 2 kJ of heat is
3
'[Ans. : : = 6 of work is
released by the sy [Ans. /l U =+4 kJ]
.:;! (March
20201

(Sept. 2021)
(:

· NH
d()ne on the system. Calculate llU• 2
of -1 ~(N -N) = 159 kJ mo1-1.
) CaJc ulate the stan dard enthalpy N2H4(8) + H2(g)
i AuO(ff ff) = 435 kJ mol , (Sept. 2021)
[Ans._ 184 kJ]
6ffO(N-H) • 389 kJ moI- , un -
· 00 K
of sublimation. sibly from 20 L to 30 L at
E th. aJnv and rever 3 •
M~ v e property (ii) n rJ all (Sept. 2021)
enn [Ans J]
kleal gas are expanded 1soth Y 2023
. (R • 8.314 JK"1 mo,1) •
work done
 282 UTTAM'.t XII Chemistry Pa
(47) One mole or an ideal gas is expanded isothennally and reversibly fonn IO L to 15 L at 300 K.
Calculate the work done in the process. (Ana. -l.Ol lS kJ] (March 2022,
(48) Calculate the standard enthalpy of formation of CH 0Hlll
3 from the following data: (2)
1
(l) CH3OH + ~O ., CO + 2H o , • Mio• - 726 kJ mo1-
(l) 2 2(g) 2(11) 2 (fl '
1
(Ii) c,., + 021£1 co2(g) ; Mio. - 393 kJ mo1-
1
(ill) H2111 + 202111 H201fl ; 6Ho. - 286 kJ mo1- 1.
[Ana. 6,Ho. -239 kJ mo1- 1.] (March 2022; July 2 022}
(49) Write the mathematical equation for the first law of thermodynamics for 3
I ()
(l) Isothermal process (ii) Adiabatic process. . (March 2022) ( )
(50) Define the relationship between 6H and 6U for gas phase reaction. 2
(July 2022) (
{51) Write the correct condition of spontaneity in terms of Gibb's energy. 2
(March 2023) ,/
(52) Define extensive property. Calculate the work done during the expansion 2 moles of an ideal gas °~
from 10 din!
to 20 dm3 at 298 Kin vacuum. [Ans. Work done= 0, Free expansion.] (March 2023) (
2
(53) 2000 mmol of an ideal gas expanded isothermally and reversibly from 20 L to 30 Lat 3 oo K, calculate the wok)
done in the process (R-= 8.314 JK-1 moZ-1). [Ans. Wmax = - 2023.08 J.] (March 2023) ; )
(54) Derive relationship between fl H and fl U for gaseous reaction. 3
(March 2023) )
II
12
ELECTROCHEMISTRY
(1) State Kohlrausch Law and write mathematical expression of molar conductivity of the given solution at
infinite dilution. (March 2013} (2)
2
( ) Write the cell reactions in lead storage battery during discharge. (March 2013) (2)
(3) In the electrolysis of AgNO3 solution 0.7 g of Ag is deposited after a certain period of time.
Calculate the quantity of electricity required in coloumb.[Molar mass ofAg is 107.9 g mot-1]
[Ans. 626.1 coulomb] (March 2013) (2)
(4) Write electrode reaction and net cell reaction for fuel cell. Calculate e.m.f. of the following cell at 25°C:
Zn,., Izn2$(aq) (0.1 M) II euE&2(aq) (0.5 M) ICu(s)
Standard reduction potential (SRP) of Zn and Cu are - 0. 76 V and 0.334 V respectively.
• [Ans. Ece11 = 1.114 V] (Oct. 2013} (2)
(5) State and explain Faraday's second law of electrolysis. (Oct. 2013} (2)
(6) Resistance and conductivity of a cell containing 0.001 M KCl solution at 298K are 1500 0
and 1.46 x 1~ S.cm-1 respectively. What is the cell constant? [Ans. 0.219 cm- 1.] (March 2014} (2)
(7) State the first and second law of electrolysis. (March 2014} (2)
(8) Write any 'four' applications of electrochemical series. (Oct. 2014} (2)
(9) With the help of the equation, aG0 = - nFE0cell explain that cell potential is an intensive
property. (Oct. 2014} , (2)
(10) How much electricity in terms of Faraday is required to produce:
(a) 20 g of Ca from molten CaC~ (b) 40 g of Al from molten ~ 03
(Giuen: Molar mass of Calcium and Aluminium are 40g.mot1 and 27g.mot"1 respectively.)
[Ans. (a) IF (b) 4.4F] (Oct. 2014) (2)
(11) Draw neat and labelled diagram of diy cell. (March 2015} (2)
(12) Arrange the following reducing agents in the order of increasing strength under standard state
conditions. Justify the answer.
Blemeat Al(sJ Cu(s) c11aq) Ni1,1
:
So -1.66 V 0.34 V 1.36 V -0.26 V (March 2015) (2)
(13) Calculate Ecell and .10 for the following at 28°C:
M~•) + Sn2+ (0.04M) Mg2+ (0.06M) + Sn1,1 E 0cell • 2.23 V.
Is the reaction spontaneous? [Ans. Ece11 • 2.224 V; G = -429.2 kJ] (March 2015) (3)
(14) Can copper sulphate solution be stored in an iron vessel? Explain. (Oct. 2015} (2)
(15) Resistance of conductivity cell filled with 0.1 M KCl solution is 100 ohms, calculate the conductivity and molar
conductivity of 0.02 M KCl solution. [ Giuen: Conductivity of 0.1 MKCl solution is 1.29 S m- 1.J
[Ans.~• 0.00248 S-cm- A= 124 S-cm mol- 1

,
(Oct. 2015)
2

(3)1

. ]

(16)1 Define 'Molar conductivity'. (March 2016} (1)

7) e cell constant Draw a neat and well labelled diagram of primary reference electrode. (March 2016} (3)
 28 3
rd ~e sti on s
-•
a fJ<!!!.. Ofa soluti on is 6.23 x 10-s o-•cm and its res • nce is 13710
. ista
·VltY cul a t e th e cro ss- sec tio nal ctro de [ • - - 0. If the electrodesarch 20 16 } (3)
art , cal th are a or ele a• 2 cm2J (M
otlc tt
.n d exp lain • 0.8
eoJJ 1 crtl ap
an ms involved •
.-u q.
e ter (July 201 6} (2)
O· rns t equatio0.02 M AgNO3 at 25 °c i 2
x 10"-3 0-1 cm-•.
•''
I ·te ~e . ·tyrof ? s .428
,, t/ltl c0ndllc tiV11a conductivity [ 2 mot-•J (July 2016] (2)
j 'li'e •ts rno de an d ariode reactio . Ana. A• 121.4 0-1 cm (Jl a.rch 20171 (2)
ite cat ho
~J ¢'' tis 1 'fllel cells'? Wr red_ a resistance of 31 _6 W : : a fuel ~II.'
¢' 't ~a OH sol ution offe t conductiV Jty cell at 298 K.
cel l is 0.367 cm-1. Calculate NaOH solution.
pjl o,05 ld constant of the he molar conductivity or rc h 2 0171 (3)
1 mo1-1 l '"a
f' Jftlle cell
of electrolysis.
[Ana. A • 232.2 0- cm2 ,.... , h 2011}
(M arc 1)(
day's first law ti th l:
fflf3 d'
ram or e following cel
5ts.te ct 8 labelled iag I H (g, 1 atm) IPt (Ju ly 20171 (2)
II He (1 M)
~J eonstrlznl 2(D (l M)
2
. culate equ ilib ri ll •
,4,J ,) I cell representati on an d cal um consta=rit for the fiO owmg redox reaction:
,.. Zfl( - - - N'2 (1 M + 2 A~ sl at 2so c . EO _
-ie tbe 1 + (aq) )
, Ni 0.2 5VaridE0Ag=0.799V
"'~J 'I/fl 21\f,+ sq) ( 1 M) 35 (July 20171 (3)
1r ~¼sl+ (
e b tt [A ns. k = 2.7 54 >< 10 ]
m of lead storag a ery. (M arc h 20 18 } (2)
eat and labelled diagra
\\1 an (M arc h 20 18 } (1)
~ 61 V~ e: Reference
electrode.. . d
icity are required top gram of alunuru • •um from alu mi niu m chloride
111) pef
ill y faradays Zof electr if m mo
ro
t-I)
uce 13
[ (M arc h 20 18 ) (3)
d \\1 rnan:
27 .0 gra 44 4 F]
'"' n? (Gi ven : mo ar ma ss o Al = d A An s. 1.
,s)
nsisting of Mg + I Mg ha
2 lf cell write the cell reaction.
riO . +

( solutIO ta cell co V) an g I Ag half cell and

-2 .37 (July 20 18 ) (2)
1"°) Represen 799 v,, Mg
Eo =
o ::= 0. b is re uir . minutes
ctricity in cou lom of in 3.5
osit 1.346 x 10-3 kg Ag
I"'
fE A9 uch quantity of ele n: Mo lar mass oif Ag . qlOBed to(r3dep mo t-I)
J{oW '!1,.,NO solution
? (G ive zs xJ kg
,~J f:rO b] (July 20 18 } (3)
..,-. Jil.tW' 3
[Ans. Q = 1214 coulom 20 18) ll)
. . ·ty (July
arch 20 19 ) (2)
De fine res1 stiV1 • d l [A ns. 0.S 0F ](M
faradays of electricity
are r •
eqU1re to produce is 6 g of Mg from Mg Cl
fSl) . . at 2so c 223n-1 -1 •
anY uti on
S2J J{o wrn
cti vit y of 0.05 M BaCl2 sol ~" cm (M arc h 20 19 } (2)
f The mo lar con du
d • ·ty ? [A ns. k = o.0 11 sn -1cm-1] (M h (a)
(33) . . . 20191
W}lat is its con uc~vi sen es. Wnte its applications. ar c
I)efine electrochem.1c al late its conductivity.
• ·ty Of 0 02
M HCI ution is 407.2 n-1cm2 mo1-i at 25°C. Calcu
fS4) d
i sol 3 1cm-1} (Ju ty2 01 9) (2)
fSS). The molar con uctiv (A ns .8. 14 4x 10 - n-
•
(Ju ly 20 l 9J (2)
. ,
• . cel l.
diagram of H2 - 0 2 Fuel (Ju ly 20 19 ) (2)
•(36) oraw a ne at labelled hydrogen electr od e.
ed diagram of sta nd ard
(S7) oraw a ne at labell ing cel l is 0.463 v
of the fol low
f3S) The standard e.m.f.
~a) 1eu ++ (aq ) 11
Ag+ (aq) IA~s)
l of Cu electrode?
is the standard potentia
(lM) (1 M)
0.8 00 wh at
is (March 20 20 ) (1)
od e V,
tial of Ag electr
' Jfthe sta nd ard poten (Ans. E eu = 0.337 V]
0

ochemical cell:
an d cal cu lat e E0
cel l of the following electr
on
(39) Write the cell reacti
2
Afr,) j Al +(aq) II Zn
3 + (aq) j Zn(aq)
(March 20 20 ) (2)
(lM) (lM)
[A ns. E\ eu = 0.90 V]
0 0.76 V.
E°Al = :...1.66 V, E Zn = - sion.
j ,

Ele ctr oc hemical series (b) Corro (March 20 20 ) l3)

(40) Define ter ms : (a) mi cal ser ies .
of electroche
Write two applications (Sept. 20 21 } ll)
. n.
2.3 03 RT . equatio
'..1) Wn·te the value of - - - m Nernst e of dis so cia tio n in
f., F n- 1 cm2 mo1-1. Ca lcu lat e its degre
°C is 18
tivity of 0.01 M acetic
acid at 25 zero co nc en tra tio n
(42) The molar conduc if the mo lar co nd uc tivity of acetic acid at 5 2021J (2)
t, 2.0 25 xi o- ] (Sept.
d dis soc iat ion co ns tan [Ans. a= 0.015; Ka=
• 0.01 M solution an 1
is 400 0- cm mol- .
1 2 o ap pli cat ion s of
de nt mi gra tio n of ion s. Write an d explain tw (Sept. 20 21 } (4)
law of ind ep en
f43) State Kohlrausch ns tan t
. Write un it of cell co of Zn + to Zn ?
electrochemical ser ies
2

s are req uir ed for red uc tio n of 2 moles (March 2022) l2)
ctr on ay ]
f44) How ma ny moles
of ele
req uir ed ? [Ans. 4 moles; 4 far ad
icity will be
How ma ny faraday of electr t bridge. (March 2022) l4l
rite the functions of sal
Define reference electrode.mWof sta nd ard hydroge n ele ctr od e (SH E).
(Ju ly 2022) ll'
Draw neat, labelled diagra uctiv ity an d co nd uc tiv ity of solution.
•a te relation between mo lar cond
 __C_he_m_~_·~t~it...:..:Pa~p~e~&.
~2.8~4!.,__ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _U_TT._~_~_Xll
- fl)
(47) Write cell representation of standard hydrogen electrode. (July ~022)
(48) State Kohlraush Law of independent migration of ions. Write one application of
Kohlraush Law of independent migration of ions. (July 2022) '1)
(49) What is reference electrode? (March 2023)
(50) Calculate the molar conductivity for 0.5 M BaC¼ if its conductivity at 298 K is 0.01 n- cm -I.
1
(l)
2
= 20 0- cm mo1-1] (March 20231
1
[Ans. A.m • (1) I
(50) Calculate standard Gibb's energy change at 25°C for the cell reaction:
0
Cd + sn2e cd2e + Sn .1 Eo = _ o•403 V' EoSn = -0.136 V. [Ans. ~G =- 51.53kJ](March 20231, (2)
(s) (aq) (aq) (s) Cd
(52) Draw labelled diagram of H -O fuel cell. Write two applications of fuel cell. (March 2023) (3)
2
II
2

CHEMICAL KINETICS
(1) Distinguish between molecularity and order of the reaction.
(March 2008, 2009, 2011, 2020; Oct. 2008, 2009, 2010, 2013, 2014} (2)
(2) Consider the reaction:
d[SO42 -J 2
31-(aq) + S2O82 - (aq) I3-(aq) + 2SO42-(aq) at particular time t ' dt = 2.2 x 10- M/s.

What are the values of the following at the same time?

d[I-J -d[S2O82-J -d[l3-J
(a) -dt (b) dt (c) dt
2 (3)
[Ans. (a) 3.3 x 10-2 M/s (b) 1.1 x 10-2 M/s (c) 1.1 x 10- M/s] (March 2013}
(3) Define activation energy. Calculate activation energy for a reaction of which rate constant becomes
1 1
four times when temperature changes from 30°C to 50°C. (Given R = 8.314 JK- mot- ).
[Ans. Ea= 56.4 kJmol- 1.] (Oct. 2013} (3)
(4) Write molecularity of the following reaction:
• 2NO(g) + O2(g 2NO21g1 (March 2014) (1)

(5) The decomposition of N2O5(g) at 320K according to the following equation follows first order reaction:
1
N2O5(g) 2NO2(g) + ~ 2(g)
1
The initial concentration ofN2O5(g) is 1.24 x 10-2 moI.1-1 and after 60 minutes, 0.20 x 10- mol. 1- .
2

[Ans. k = 0.0304 min- ] 1 (3)

Calculate the rate constant of the reaction at 320 K. (March 2014)
(6) . Derive the relation between half-life period and rate constant for first order reaction. (March 2014) (2)
. (7) Sucrose decomposes in acid solution to give glucose and fructose according to the first order rate law.
The half life of the reaction is 3 hours. Calculate fraction of sucrose which will remain after 8 hours.
[Ans. 0.1576) (Oct. 2014; March 2015) (3)
(8) Derive the relation between half life and rate constant for a first order reaction. (March 2015, 2017) (2)
(9) Define: (a) Average rate of reaction (b) Instantaneous rate of reaction. (Oct. 2015) (2)
(10) Ammonia and oxygen react at high temperature as:
4NH31g1 + 5O21g1 4NO1g1 + 6H2O1g1
In an experiment, rate of formation of NO(g) is 3.6 x 10-3 mol L- 1. s- 1
Calculate: (a) Rate of disappearance of ammonia. (b) Rate of formation of water.
[Ans. (a) 3.6 x 10-3 mol·L-1 • s- 1(b) 5.4 x 10-3 mol•L- 1 • s- 1] (Oct. 2015) (3)
(11) Define 'Zero order reaction'. (March 2016) (1)
(12) Explain graphical method to determine activation energy of a reaction. (March 2016) (2)
(13) In a first order reaction x-+ y, 40% of the given sample of compound remains unreacted in 45 minutes.
Calculate rate constant of the reaction. (Ans. 0.02036 min-1) (March 2016) (2)
(14) The rate constant of a first order reaction are 0.58 s- at 313 Kand 0.045 s-1 at 293 K.
1

What is the energy of activation for the reaction? [Ans. 96.85 kJmoI- 1 J (July 2016) (3)
(15) Write the Nemst equation and explain the terms involve. (July 2016} (2)
(16) In the Arrhenius equation for a first order reaction, the values of 'A' and 'E 'are 4 x 1013 sec-1
~~8,6kJ mo1-1 respectively. At what temperature will its half life period be 10 minutes?
1
,/R•B.314JE- mot" J
1
[Ans.T=311.5K] (March2017} (3)
~rate. law for the reaction
+ 2NOw, .. N2(g) + 2H2O(g) is given by rate= K[H2] (NO]2
n occurs in the following two steps:
Ow, .. N2O(g) + H2O1g1
 .r130 ard Questions
~OJ_~~-=---.:;::___
• .
m~" o +H218l
;r,, (171 r(z (g) 21g1 + Ii o
2
t is the rate of N 2 o in th 181
\Vb8 . e lllech .
tJl the following data for the li an.ism;> \Vh
,ssJ ; . constant: qUid Phase r-e at _is the fllol
0 60 0 action A ~lllrity '285
ti• - 8 d Of the
1
~:?-
' eter-rnine the elementary
/t11ol L-1 0.624 0.446 1200 ?
8
ertsin reaction occurs in th fi O•3 I 8
0
00 °t"dcr of (July 20 .t 7) '2)
,s9J AC (i) c1,g) + 03(g) .. ~l~lloWing Steps. -226 [Atta F· on llnd calcutate its
·ch (il) CIO(g) + o,g) • Cl (&I + 02(g) • • lt"St Order; 5.6 )! 10-<t
202.:11,2, l&J+o2 a-11
202.:11
) What is the molecularity of e~h~fu
(3J 1gJ (July 20171 t3 )
n.) Jdentif.Y the reaction intenned· e element
,., · A B ____ iate and • ary ste
fbe reaction + products is Write fue che _Ps?
110) (a) How does the rate of reaction h first Order in e htnica} equation fi
• h h . c ange if th ac of th or overall
,2, (b) What xs t e c ange m the rate of e concentr . e reactants reaction. (M
of Bis doubled? [Ans. (a) Th reaction if fu ation of A is. • «rch 2018} (~t
e rate f e concentr . Increased by r
(b) The rat o f reaction 18 • . ation of A • h •actor 3?
Incre is alved
order of chemical reac t·ion e O reaction rernains ased by factor 3 and concentration
,,1J Define the
find the overall order of the foll . • Unchanged.]
OWJ.ng rea ti
1
{aJ CHC13 (g) + Cl2(g) CCI + c ons: (March 2018) (~)
4(g) HCI(g), Rate == k[
3) 2NO2(g)' Rate == k[NO]2 CHCl3] [C½]
(3J {bJ 2NO(g) + 02(g)
-azJ In a first order reaction A ,. prod [02] (Ans. (a)
2 Cb) 3)
( • 40 min. What is the half lif; . uct,ao % of the •
U1 . e penod of the . given sample of c (July 2018) l~l
(3J ,,,31 Write Arrheruus equation. Derive an expression ~eaction ?
fi
[Ans °~P0 und decomposes
• 17 •22 nun-11
II
,,,41 The rate of a first order reaction A _ __,,__ or temperature Vari ti (July 2018} ta}
!J u1 th ' - B is 5 4 1 -6 a ons
(IJ II
Cale ate e rate constant of the reacti • x 0 Ms-1 when [A]. • (March 2019) l3}
1w • d f fi on. [ 1s 0.3M
25J The half e peno o a rst order reaction. 6 Ans. 1.8 x 10-s s-11·
t:l'. O ffir t • ls .Oh. CalcuI t th (March 2019) ll}
(26J
' The half J.Ue s ord er reaction is 6 0 h a e e rate constant
reactant to decrease from 0.8M to 0 25. M ours. How long it will take for the c • . (March 2019) (1)
. • . oncentration of
(2 7} For a certain second order reaction energy of t· . . [Ans. t = 10.07 hours] 'Jut )
th t ac ivation is 240 kJ 1-1 ,, Y 2019 (3)
(3J at 1023 K if era e constant at 923 is 0.011 3 -l _ 1 mo • Calculate its rate constant
_ m s • [R == 8.314 JK-1 moz--1}
r2,
[Ans. 0 •24 M-l s- 1
1
(2BJ Define elementary reaction. (July 2019) (3)
(291 A reaction occurs by the following mechanism: (July 2019) (1)
SJ (i) NO2 (gJ + F2 (g) NO2 F (&I + Ffgl
J (ii) F(g) + NO2 (&1 NO2 F(gJ
' Identify the intermediate and write net reaction. (July 2019} (1\
(30J Write the mathematical relation between half life of zero order reaction and its rate constant. (March 2020} \1\
(31J De.fine instantaneous rate of reaction. Explain pseudo first order reaction with
suitable example. (March 2020J \3\
(32J De.fine isomorphism. Derive integrated law expression for first order reaction. (Sept. 202 lJ \4\
(33J What is pseudo - first order reaction? Explain with suitable example. (Sept. 2021} \2\

(34J Write the value of

2.303RT
F . Nemst equat'10n.
1n (Sept. 2021} \2l \
\
(35J Define half life of first order reaction. Obtain the expression for half life and (March 2022) \3l
rate constant of the first order reaction.
(36) Identify the molecularity of following elementary reaction: (September 2021)\1\

NOlKJ + 03(g) N03(g) + O(g) . first order reaction is three times the time required for 90%
(37J Show that time required for 99.9% completion of a (July 2022) (1\
completion.
• steps·
(38J A chemical reaction occurs in the foIIowing •
-~NO F + F (slow)
:;n
•
(i) N02llJ + F2 (&1 2 (g) (g) (ft t)
(ii) FflJ + N02 (g) N02F(g)
fa) Write the equation of overall reac • (3)
(July 2022J
.J~J _Write down rate law. .
~ t i l y the reaction intermediate.
 UTTAM's XII Chemistry Papers So
286
. . . tegrated rate law equation for zero order reaction.(March 202
.
(39) What is Pseudo first order reaction? Denve_m fir rder reaction is three times the time required fi 3A3)
(40) Show that time required for 99.9% completion of a st o [March 20 or 90%
23
completion. ) (2)
• ELEMENTS OF GROUPS 16, 17 AND 18
(1) What is the action of the following reagents on ammonia?
. (b) Excess of chlorine (c) Na metal [March 2013) ( )
(a) Excess of ru.r 3
• d · the following properties with reference to group 16:
(2) Explain the tren s m .
· di· (b) Density
(a) Atomic radii and iomc ra 1 . .
. • thaJp,v (d) Electronegativtty (March 2013) (4)
(c) Iorusation en J •

(3) What is the action of chlorine (Cl) on the followmg: .

(a) Cold and dilute caustic soda. (b) Hot and concentrated caustic soda.
(c) Potassium bromide solution. (Oct. 2013) (3)
(4 ) Write electronic configuration and two uses of neon (Z = 10). (Oct. 2013) (2)
(5) Write resonating structures of ozone. . (March 2014) (1)
(6) Describe anomalous behaviour of fluorine with the other elements of group 17 with reference to:
(a) Hydrogen bonding (b) Oxidation state (c) Polyhalide ions. (March 2014) (3)
(7) Describe anomalous behaviour of oxygen as compared with other elements of group 16 with reference to-
(a) Magnetic property (b) Oxidation state (c) Hydrides (Oct. 2014) (3)
(8) Draw the structure of:
(a) Orthophosphoric acid (b) Pyrophosphoric acid (Oct. 2014) (2)
(9) Explain the structure of sulphur dioxide. (March 201 SJ (2)
(10) Write molecular formulae and structures of the following compounds:
(a) Dithionic acid (b) Peroxy monosulphuric acid
(c) Pyrosulphuric acid (d) Dithionous acid (March 2015) (4)
(11) Draw structures of: (a) Chlorine trifluoride (b) Chlorine pentafluoride. (2)
(12) What is the action of dioxygen on:
(a) Calcium (b) Iron (c) Carbon disulphide? (Oct. 2015) (3)
(13) Write 'four' uses of hydrochloric acid.
Write chemical formula of the following oxoacids of chlorine:
(a) Hypochlorous acid (b) Chlorous acid (c) Chloric acid (d) Perchloric acid. (Oct. 2015) (4)
(14) What happens when dilute sulphuric acid is treated with (a) Fe (b) CaF2 ? (July 2016) (2)
(15) What happens when thin copper leaves are thrown in jar containing chlorine? (July 2016) (2)
(16) H2O is liquid while H2 S is gas at room temperature. Explain. (July 2016) (2)
(17) Write the electronic configuration of the following elements:
(a) Sulphur (Z = 16) (b) Krypton (Z = 36) (March 2017) (2)
(18) Write any 'two' uses of each of the following: (a) H2 SO4 (b) Chlorine {March 2017) (2)
(19) What is the action of concentrated sulphuric acid on the following:
(a) Phosphorous pentachloride (b) Copper (c) Potassium chlorate. (July 2017) (3)
(20) Arrange the following oxyacids of chlorine: HClO, HC1O2 , HC1O3 and HC1O4 with respect to:
(a) Increasing order of thermal stability (b) Increasing order of oxidising power. {July 2017) (2)
(21) Write balanced chemical equations for the following:
Action of ozone on hydrogen peroxide. (March 2018) (1)
(22) Write the molecular and structural formulae of:
(aJ Thiosulphuric acid (b) Dithionous acid (March 2018) (2)
(23} Draw the structure of IF7_Write its geometry and the type of hybridization. (March 2018) (2)
(24} Explain the following with the help of balanced chemical equation:
(a) Bleaching action of SO2 .
(bJ Dehydration of formic acid by concentrated H2 SO
4.
(c) Burning of benzene in presence of excess of dioxygen. (July 2018) (3)
(25) Write structure and molecular formula for sulphurous acid. (July 2018) (1)
(26) Write any four points of difference between fluorine and other halogens. (July 2018) (2)
(~ Explain the following properties of group 16 elements:
o/ (i) E1ectronegativity (ii) Melting and boiling points
(ili) Metallic character (iv) Allotropy (March 2019) (4)
 of.So'}_
rd Questions
0 ,cides?
W · diffi
nt•e erent types of 0,0.dCS th
~=-=--------
in
With
on e eu un plc each _______
__±28~7

gas element used

__
t ts> - {K h 20 19 (4 )
~d
sJ the naJlle of an inert b Ila. e treatment of
can •
rapy. ar c )
on e ac ts as a pro tec tiv e urn cc r by rad iot he (Ju ly 20 l 9/ c1)
ye r of oz , re Ex pla in.
l
ch of the following.• (a, Helium. (b (Ju ly 20 19 } C2)
~J 'J/f 11 1 .
!:t,, flt~ _,0 us es of ea .
r, 'J/f lte f
s acid. Ex pl . ) Ne on (M arch 20 20 ] C2)
1 t ra'II the stn tct ur e o su lph ur ou
L'"

,si ain why nit rog en do es t fi

no onn
~J D ntahaJides. n co mp ou nd s. (March 20 20 } (3)
pe lain interhaloge low in
m th e fol
s3J is 0 x:ygen prepared fro g compounds?
1 f{oJ{ClO (b) Pb02.
4 . . (March 20 20 } (4)
,., erhalogen compound of chlonne Which has sq
Write the name of mt uarc PY Ta midal
13.JJ trUcture• tu f lphurous acid W . (Sept. 20 21 } (1)
s w the str uc re o su es of he lium.
pra :e two us (Sept. 20 21 / (2)
rite ch em ica l eq ua tions involved d ~ ctu re of su lph un 'd
(35) W of sulPhgur dio anura c ac1 by
(36) contact proc •
ess. Write two us es .
xid
e. (Sept. 20 21 } (3)
of co nc en tra ted H SO ne su
What is th e acti~ n aF2 (ll) Ca
ction ior 2 th4 on . (i)C gar.
(371 What is nucleoti. de? Write rea e prepar ti on of polyacrylonitrile (PAN).
. a (Sept. 20 21 , (4)
. len ium on ma gn
) What 1s th e ac tio
n of se (M arc h 20 22 } (1)
th e fol low ing at ~siurn metal ? :
38 nd s in eleme nts
( ) ExJ>lain th e tre ro)pEelrties of group 16
Ionisation enth:p~cJ(pW
(2)
39 ic rad ii (ii) ect ron eg ati ·ty ) Electron gain entha
lpy. (March 20 22 }
( (i) At om • VI (iv
• h •cal composition ?f haematite. W the names and electronic rite
(40) Wnte c e~ of (M arc h 20 22 } (3)
configuration s of first. two elements group 17.
. h . al ar ti ur.
equation for prep a on of sulphur dioxide from sulph
(4 l) Wnte c erruc r. (M arc h 2022J (2)
Write us es of su lp hu .
ine on the 1011owing·
is th e action of chlor
(42) What ph os ph or us ? • (Ju ly 20 22 ) (2)
(i) NH3 (ex c~ ss) (ii)
wh en :
(43) What ha pp en s
th iodine monochloride
(i) Et he ne re ac ts wi ce of V 0
(ii) Su lp hu r dioxid
e is oxidised in presen 2 5 (J ul y 20 22 } (3)
nc en tra ted H SO
(W) Cu he.ated wi th co 2 4• (Ju ly 20 22 } (2)
ou nd s? wn ·te two us ' es of neon.
n co mp ll)
(44) Wha t are mterh.aloge oli te. (March 20 23 )
. mp os itio n of cry me nts .
(45) Wnte thas e chemical co th lpy compared to group
15 ele
th

"•e re on .• Gro up 16 e1ements have Iower 1orusation entha

• • • (March 20 23} \2)
(46) n . G .
xygen. (M ar ch 20 23 } \1)
"W_nte two us es of dio ne is also cal led dr y ble ac h.
Bleaching action of ozo
(47) GJVen rea so n: ing co mp ounds: (M ar ch 20 23 } \2)
s of th e follow
(48) Draw str uc tu re d.
Peroxy disulphuric aci
(a) Chloric acid (b) 16 with respect to: \3)
om alo us be ha vio ur of oxygen in group (M ar ch 20 23 }
(49) Ex pl ain an ida tio n sta te.
netic property (iii) Ox
(i) Atomicity (li) Mag
O N EL EM EN TS
IN NE R TR AN SI TI
II TRANSITION AND
an es e. Why +2 oxidation
sta te of ma ng an es e
(M ar ch 20 13 } \3)
tes of ma ng
ferent oxidation sta \2)
, • (1) Write the dif (M ar ch 20 13 }
is mo re sta ble ?
elting (ii) Flux. ving
lowing terms: (i) Sm st tra ns iti on series ha (Oct. 20 13 } \2\
- (2 ) Ex pl ain th e fol co nfi gu rat ion of elements from fir
ic
(Oct. 20 13 } l3\
e ob ser ve d ele ctr on
(3) Writ
th an oi d contraction.
(M ar ch 20 14 } l2\
d- or bit als . an d eff ec ts of lan
ha lf fil led
contraction? Expla
in th e ca us e
an oid dic tab le?
(M ar ch 20 14 } l2l
(4) W ha t is lan th oid s in pe rio
e th an oid s? W ha t is th e position of actin
(S) What ar lan
n'? How do es it dif
fer from 'ro as tin g'?
(6) What is 'calcinatio e follow ing or es : (Oct. 20 14 ) l~
l for mu la of th
(7 ) Write cb em ice tite (d) Co ru nd um
.
mi ne fb) Ha ematite (c) Magne s ha ve hig he r me lti
ng po in ts
(a) Ce Ja W hy do th es e co mp ou nd (M ar ch 20 l SJ ,
(S) W ha t are int er sti tia l co mp ou nd s?
g pure me ta ls?
(M ar ch 20 15 )
than co rr esp on din
in its effects.
id contraction. Expla as t fu rn ac e du rin g
ex tra cti on
(t ) l)e in e Jantbano ne of re du cti on in bl (M ar ch 20 15 )
tio ns involved in th e zo
(IO) J,Vrite the re ac
11:,uonis. the position of iro n (Z • 26) in periodic table?
 UTTAM's XIl Chemistry Papers Sol .
2~8~8~-----------------------------~=-~.:...::..:::::~
2015
Explain why is Fe3 •more stable than Fe2•? (Oct. ) (3)
'd (.'March 2008, 2010; Oct. 2015; July 2016, 20191 ( )
(12) Distinguish between Lanthanoides and Actinot es. , 2
all gy (Oct 20 l S• (2)
(13) Define: (a)Hydrometa11ury (b) Electromet ur • . ,
(14) Write the names and chemical fonnulae of any one ore of iron and zmc each. (March 2016) (2)
(15) Why is Sc3• colourless while Ti3 • coloured? (Atomic numbe~ Sc• 211 • ~21• (March 2 016J (2)
(16) What are f-block elements? Distinguish between lanthano1ds and actino1ds. (March 2016) (3)
.. d (March 2016• (
(17) Explain the term - Interstitial compoun s. , 1)
(18) Write the factors which are related to the colour of transition metal ions. . (March 2017) 12)
( 19) Write the different oxidation states of iron. Why oxidation state of manganese 1s more stable?
.
(GJVen . z f M = 25 ) (March 2017) (3 )
. o n • . _ 3+ • hil
(20) What is lanthanoid contraction? Explain, why lanthanum (Z - 57) forms La 10n, w e
cerium (Z = 58) forms Ce4• ion? . . (July 2017) (3)
(2 l) Mention the names of various steps involved in the e~raction of pure metals from their ores. (July 2017) (2)
(22) What is the action of carbon on the following metal made:
Fe20 3 in blast furnace. (March 2018) (1)
(23) What are 'd' and 'f block elements? (July 2018) (2)
(24) What is the action of the following on lanthanoids?
(a) Water (b) Sulphur, heat (c) Nitrogen, heat. (July 2018) (3)
(25) Explain the position of actinoids in the periodic table. What is the action of sulphur
on Ianthanoids? Calculate the magnetic moment of divalent ion in aqueous solution if
its atomic number is 24. (March 2019) (4)
(26) Write a note on Lanthanoid contraction. Write two uses of KMDO4 . (July 2019) (3)
(27) Explain Bessermization process. (July 2019) (3)
(28) What is electrometallurgy? (March 2020) (1)
(29) Write the name and chemical formula of one ore of zinc. (March 2020) (2)
(30) Define flux. Write a note on leaching process. (March 2020) (3)
(31) Write the general electronic configuration of lanthanoids. Why are most of the
compounds of transition metals coloured? (March 2020) (3)
(32) Iron exhibits + 2 and + 3 oxidation states. Write their electronic configuration.
Which will be more stable? Why? (Sept. 2021) (2)
(33) Why La(OHb is the strongest base, while Lu(OHb is the weakest base?
Write two applications of catalytic properties of transition metals and compounds. (Sept. 2021) (3)
(34) Write the chemical formula of Haematite. (Sept. 2021) (1)
(35) Define mineral. (Sept. 2021) (1)
(36) Calculate spin only magnetic moment of divalent cation of transition metal with
atomic number 25. Salts of Ti 4 + are colourless. Give reason. (March 2022) (4)
(37) What is a Lanthanoid contraction? (March 2022) (1)
(38) Write the molecular formula of the following minerals:
(i) Chalcopyrite (ii) Calamine. (July 2022) (2)
(39) What is a Lanthanoid contraction? Write similarities between lanthanoids and actinoids. (July 2022) (3)
(40) Give electronic configuration of Gd (Z = 64). (March 2023) (1)
(41) Distinguish between lanthanides and actinides. (March 2023) (2)
(42) What are interstitial compounds? Give the classification of alloys with examples. (March 2023) (3)

II COORDINATION COMPOUNDS
(1) Write the formulae of the following compounds:
(a) Sodium hexanitro-N-cobaltate (III)
(b) Tetraaquodichlorochromium (III) chloride.
(c) Potassium tetracyanoaurate (III) ion. (March 2013) (3)
(2) Write applications of co-ordination compounds in medicine and electroplating. (Oct. 2013) (2)
(3) What is effective atomic number (EAN)?
Calculate EAN of cobalt (Z = 27) in [CO(NH3) 6j+3 and of zinc (Z = 30) in [Zn(NH ) ] SO . (March 2014) (3)
3 4 4
(4) Classify the following ligands into monodentate and polydentate _
(a) Ammonia (b) Carbon monoxide
(c) Ethylene diamine (d) Ethylene diamine tetra acetate ion. (Oct. 2014) (2)
..
, .reoa~,d~Qu~es_tt_o_ns_
(1/_ OL
.

len
_ _ _ _ __
in
ce bo nd theory expla th nature of bondi ~ -~ : ; ~ = - - -
-----~2~
8~ 9
e ba sis of va
((If;,()
C na m e of [Co(Nd0an 2)3(NH3)3
I e ng m ICoFJ3- ion.
oti . the JUPA lex es an io . • (March 20 15 }
(3)
161 writ . cationic
comp
le th . rue complexes f co-ordinationation co (O ct.
. ence between adou o . mpounds. 20
e,cP18Jll
16) 11lt.1strate with m s- Igand.
exarni- ' e differ bte salt and
ation compound.(M
arch 20 :: (2)
th e ter a co -or din (2)
) ta.ill platin (March 20 16 } (1)
11 th e fo rm ul ~ of Tetraminodichloro loride .
1s) :f te um (IV) ch (March 20 16 }
(1)
d. W nt e fo ur postulates of Werner's th )
19) 0 fine lig an
fti t· at ~m.ic nu m be r' (EAN)? eory. (July 20 , (3 16 '
e ec ive
(l0) wn at is 'e numb of the central
a.iculate th e effective atomic er U .
metal atom in the fio owmg compounds:
1j.l) C N) (b) Cr(CO)
(e.) K4 Fe(C 6 Cr (Z =6 24) (3)
Fe (Z == 26) (M ar ch 20 17 }
fie d? Ex pla in wi th s . (3)
ssi Uttable examples •
17 }
fioW ligands ar e cla of [Co(NH ) ]3+ (July 20
om etr y si f h n. (Z of Co = 2 } (2)
3 6 on thIIe ba
18
11i) e,cplain thfie ge u1 (Mar ch 20
mp lex Co pp er h so ybridisatio 7) 18 } (1)
113) m a of th e co yanoferrate(II) • (M ar ch 20
14) Write ~e or in hl ( ) ex ac
a for pentaamm e c orocobalt n,.1) sulphate. (July 20 18 ) (2)
I t!.) Write th ethformul •
(l"' explain e geometry of [Cu(NH3)412 on the basis Of hybnd . .
isation [At N Cu - 29).
_ (July 20 18 } (2)
) . l o.
(16 . fii tive atomic nu m be r? Ca
. c number ~f
(l 7) What IS e ec29) in [Cu(NH3)4]2+. culate effective atomi (March 20 19 } (3)
copper (Z ==
(M ar ch 20 19 } (1)
W ha t is Ne ss ler t's reagent.
(lS) (July 20 19 } (1)
rit e IU PA C na m e of [Pt(en) 2Cl2]2+ complex (2)
W • (March 20 20 }
(l9 ) th e eff ec
.
tive atomic nu mber (E.A N•) 0 f copper m [Cu(NH 3)4 ]2+ • (Z of cu 9
=2 )
Ca lcu lat e . • (Sep t. 20 21 } (2)
(20) e bi de nt at e Ligands? G"Ive one example (1)
(21 ) W ha t ar . • (S ep t. 20 21 )
. tio ns of coordinate compounds
e tw o ap pl ica 20 21 } (1)
(22) W nt • (C O) ] lex. • (S ep t.
IUPAC na m e of [Fe s comp
(23) W nt .e iso me rism in th fiollow.mg complexes • (1)
th e na m e of e (M ar ch 20 22 }
(24) W nt e H ) ][Pt ][C uC l ] •
(N H ) (2)
[Cu a 4 Cl4] an d Pt[(N 34 (M ar ch 20 22 }
4 d .
E 1. am bi de nt at Ii ple . (3 )
on od en ta te an d
)
e gan s Withlexexesam (M ar ch 20 22
(25) xp am m tionic an i • he re co mp wi th exam le 22 ) (1)
{26) Ex pl ain ca oruc an d neutrafl Csp+J. P • (J ul y 20
.' be r 3
lex . (2 )
ective atomic nu m 0
[Co(NH3)6] • co mp (J ul y 20 22 }
Ca lcu lat e eff m ple s
(2 7)
molepti dh es with exam (J ul y 20 22 )
(2 )
(28) Ex pl ain ho c an eteroleptic complex mp lex e~ .
. ordinate co (M ar ch 20 23 }
(1)
o po stu la te s of Werner theory of co of ca nc er .
(29) WW~te thtw pl ati nu m comp1ex us ed m the tre
• atment (M ar ch 20 23 )
(1 )
nt e e na m e of.
(3 0) .
reo1somers.
(3 1) Define: Diste th respect to: (M ar ch 20 23 )
(3)
ai n fo rm ati on of [CoF6]30complex wi co mp lex (iv ) Ge ometry. (2)
(3 2) Ex pl ne r/ ou ter (M ar ch 20 23 )
isa tio n (ii ) M ag ne tic properties (iii) In
(i~ Hy~rid [Co(NH3)4CliB•
(3 3) Give c1s an
d tra ns isomers of

mrg o
HALOGEN DERI
displacement reac
VATIVES
tions readily with
at ta ck of
(March 20 13 }
(2}
be nz en e un de
trochloro
(1) Why do es p-ni
op hi lic OH - io n?
nu cle th e action of-
ba la nc ed ch emical equations for
(2) Write -2-ol.
chloride on propan (March 20 13 )
(3
(a) Ph os ph or us tri ne in th e pr esence of a peroxid
e.
ide on sty re
(b) Hydrogen brom te.
e on silver propanoa gy profile di ag ra m (Oct. 20 13 )
(c) Methyl br om id
tic ac id. Dr aw a ne at , labelled ener
al activity of lac (M ar ch 20 14 }
(3) Explain optic
echanism. (M ar ch 20 14 )
for SN1 re ac tio n m lac tic acid.
optic al ac tiv ity of
(4) Di sc us s th e 2 ha ni sm s.
n SN an d SN m ec
1
ng ui sh be tw ee (Oct. 2014J
(5) Di sti
e (c) 1, 3, 5- Tr ibromobenzene.
tu re s of - m eth yl bu tan (M ar ch 20 15 )
(6) Write th e str uc-e th yl he x- l-e ne (b) l-Iodo-2, 3- di
(a) 3- Ch lo ro -3 ec ts.
en vi ro nm en tal eff
re of DDT. Write its
(7) Dr aw str uc tu ng re ac tio n :
(Oct. 20 15 ]
d '8 ' in th e fo llo wi
(8) Identify 'A' an 'A' ale. KOH
'8 ' (Oct. 2015)
HBr .
CH3 -C H • CH2 olysis of br om om et ha ne
ph en yl ? (March
20 l E
us s th e m ec ha ni sm of alk ali ne hydr is ch lo ro be nz en e co nv er te d in to di
Di sc an ili ne ? How
(9) ne pr ep ar ed from
How is chlorobeze
(10)
 290 UTTAM's XD Chemistry Papers Solutio,.
(11) Explain the term - Optical activity. (March 2016} (l)
(12) How is propene converted into 1-bromopropane and 2-bromopropane? (March 2016} (2)
(13) Write a note on Sandmeyer's reaction. (July 2016, 2018} (2)
(14) Identify 'A' and 'B' and rewrite the reactions.

(al ANH3
V NaNO,
HBr,273K
• (Al cu,Bra • (Bl + N, 1

Alcoholic KOH
H3C - CH 2 - CH - CH3
(b) (A) + (B) + 2KBr + 2H2O (July 2016} (2)
I tJ.
Br
(15) Define racemic mixture. (March 2017) (1)
(16) Explain the mechanism of alkaline hydrolysis of tert-butyl bromide with energy profile diagram.
(March 2017) (3)
(17) Define optical activity. Explain optical activity of lactic acid. (July 2017) (4)
(18) Identify A and Bin the following reaction:
CH - Br + Mg th
dry etber A + CO dry e er B + Mg(Br)OH (July 2017} (2)
3 2 W/H2O
(19) · Explain only reaction mechanism for alkaline hydrolysis of tert-butylbromide. (March 2018} (2)
(20) Identify 'A' and 'B' in the following reaction and rewrite the complete reaction:
fl Na
CH3 -CH2 -Br + AgCN - - - A _C_H_O_H_• B (March 2018} (2)
2 5
(21) Identify A and B from the following reaction and rewrite complete reaction:
OcH,CI + Mg dry etber A tt,o B + MgCl(0H) (July 2018} (2)

(22) Complete and rewrite the following chemical reaction:

1- Chloro -2, 4-dinitrobenzene ;~·
8
a:::~ ? (July 2018} (1)

(23) What is the action of the following on ethyl bromide:

• j

(i) Alcoholic solution of potassium hydroxide

(ii) Moist silver oxide
(iii) Silver acetate? (March 2019} (3)
(24) Define Enantiomers. (March 2019} (1)
(25) What is Grignard reagent? (March 2019} (1)
(26) Explain the role of iodic acid in the preparation of ethyl iodide from ethane.
Dilactic acid is optically inactive. Why? (July 2019} (3)
(27) Write the reaction for preparation of Grignard's reagent. (July 2019} (1)
(28) Write conversion of 2-bromobutane into unsaturated hydrocarbon by using alcoholic KOH. (July 2019} (1)
(29) Define optical activity. How many optical isomers are possible for glucose? (March 2020} (2)
(30) Write the chemical reactions of chlorobenzene with respect to:
(a) Sulphonation (b) Acetylation (c) Nitration. (March 2020} (3)
(31) What is the action of the following on chlorobenzene?
(i) Methyl chloride in presence of anhydrous AIC13
(ii) Fuming H2S04 . (Sept. 2021} (2)
(32) Explain SN2 reaction mechanism for alkaline hydrolysis of bromomethane. (Sept. 2021} (3)
(33) Write the product formed when alkyl halide reacts with silver nitrite. (March 2022} ( 1)
(34) What is the action of the following on ethyl bromide?
(i) Na in dry ether (ii) Mg in dry ether. (March 2022} (2)
(35) Write chemical reactions for the following conversions:
(i) Ethyl bromide to ethyl methyl ether (ii) Ethyl bromide to ethene
(iii) Bromobenzene to·toluene. (iv) Chlorobenzene to biphenyl. (March 2022} (4)
(36) Convert ethyl bromide to: (i) Ethyl iodide (ii) Ethyl fluoride. (July 2022} (2)
(37) Write four salient features of SN 1 mechanism. (July 2022} (2)
(38) Write the structure of the product formed when chlorobenzene is treated with sodium metal
in the presence of dry ether. (March 2023} (1)
 ns 291
, ~ m QuesM
for the followi ng..
et he che mi cal. rea cti ons
~r itvvrt
9)
( ) chl oro ben zen e •1s hhea
ted wit h fum ing H2so
(S .d
a
(b) Eth yl brom1 e 1s eat
ed wit h silv er ace tate . (M arc h 20 23 } (2)
h1
r:-~ lain deh ydr oha log ena tio n rea ctio n of 2 - c oro but ane •
d •
40) ~ ite use an env iro nm ent al
r eff ect of CF C. (M arc h 20 23 } (3)
( Wr

ed fro m me tha nal by . (M arc h 20 13 } (2)

l) How is eth ano l pre par . ud~mg ~ri gna rd rea gen t?
(
Ex pla in the me cha nis m of act ion of hyd r010 2 1
1c aci d on 3 -me thy lbu t an- -o • (M arc h 20 13 } (3)
(2) ted int o the following?
(3) How is phe nol con ver
non e (c) Picric acid. (Oct. 20 13 ) (3)
(a) Be nze ne (b) Be nzo qui d? (2)
Ho w is me tho xy ben zen e pre par ed from carbolic aci (Oct. 20 13 )
(4 )
(S) Write the str uctfor ura l for mu la and IUPAC 'tw n~ es of all possib le iso me rs of the com pou nd
mu la c H W .
O • nte o use s of phenol . (Ma rch 20 14 } (4)
wit h mo lec ula r a s
. (Ma rch 20 14 } (1)
w •~ me tho ~e tha ne pre par ed from me thy l iodide.
(6) Ho g t h
(7) Wh at 1s the act ion of the following rea en s on p enol - (2)
. . per atu re (b) Co nc. H2SO 4 at room tem per atu re.
(Oct. 20 14 )
ne m CS 2 at low tem
(a) Bro mi H 0. (Oct. 20 14 } (3)
w ·t the str u tu r~dand IUPAC nam e of all the me tam eri sm rep res ent ed by formula C4 10
(S) H n e_ bo lt owing com pou nds ·
ow is car c ac1 pre par ed from the foll • (Ma rch 20 15 } (2)
(9)
nze ne and ste am at 698 K?
(i) An ilin e (ii) Ch lor obe (Ma rch 20 15 } (1)
ties of carbolic acid.
(10 ) Me nti on 'tw o' phy sic al pro per
(11 ) Ho w are the following com
pun ds pre par ed? (Oct. 20 15 } (2)
(b) Pro pan -1-ol from pro
pan al.
l fro m ben zyl chl ori de. ter on
(a) Be nzy l alc oho ion of bro min e wa
(12 ) Ho w i~ car ~ol ic ac~d pre par ed from chl
orobenzene? Wh at is the act (Oct. 20 15 } (3)
gui sh bet we en car bol ic aci d and alcohol.
al tes t to dis tin (2)
car bol ic aci ds? Wn te che mic atio n of 1°, 2° and 3° alcohols. (Ma rch 20 16 }
deh ydr (2)
(13 ) Write the rea cti ons involved in le exa mp les of eth ~rs . (M arc h 20 16 }
eri sm wit h sui tab
(14 ) What is me tam eri sm ? Ex pla in me tam thyl-n-propyl eth er.
Wr ite the str uct ure and IUPAC nam e of 'me (Ju ly 20 16 } (3)
(15 ) Wh at is me tam eri sm ?
ion of ho t HI on it?
What is the act ?
(16 ) Ho w are the follow
ing con ver sio ns car rie d out
o 2-m eth ylb uta noi acid. c
(i) 2-M eth ylb uta n-1 -ol int
zoic aci d (Ju ly 20 16 ) (3)
(ii) Ph eny let hen e int o Ben
tan itro ben zoi c aci d. 17 ) (2)
(iii ) Be nzo ic aci d int o me
(M arc h 20
ic aci d is pre par ed fro m ben zen e sul pho nic aci d? ) (2)
(17 ) De fin e car bol ic aci d. How
carbol (M arc h 20 17
con tin uou s est erif ica tion pro ces s? (3)
(18 ) Ho w is die thy l eth er pre
par ed by gen t? (Ju ly 20 17 )
-2- ol and 2-m eth ylp rop an- 2-o l from Gri gna rd's rea
(19 ) How will yo u pre par e
eth ano l, pro pan (Ju ly 20 17 ) (2)

ed from cum ene ?

(20 ) How is phe nol pre par a che mic al equ ati on for the
e car bol ic aci d fro m ben zen e sul pho nic aci d? Write (M arc h 20 18 ) (3)
(21 ) Ho w will you pre par phe nol . • (2)
ori de on 20 18 )
act ion of neu tra l ferric chl
(M arc h
nt tha n eth ane ?
her boiling poi
(22 ) Wh y eth ano l has hig cum ene ? Wh at hap pen s wh en
phe nol is hea ted
(Ju ly 20 18 } (3)
ati on of phe nol fro m
(23 ) Wr ite a pre par (Ju ly 20 18 ) (2}
t HI
wit h zin c du st?
ing on iso pro pyl me thy l eth er? (a) col d HI (b) ho ) (1)
(24 ) Wh at is the act
ion of the follow (M arc h 20 19

(25 ) Wh at are eth ers

?
the following:
(26 ) Wr ite bal anc
ed che mic al equ ati ons for
(a) Action of sod ium me
tal on eth ano l (M arc h 20 19 } (2)

(b) Action of zin c du st

on phe nol .
OH (1)
I (Ju ly 20 19 )
nam e of (CH bC - CH - C2 H5 . (1)
Give IUPAC 3 (Ju ly 20 19 )
(27 ) ano l.
sion: Ethox:yethane int o eth (1)
(28 ) Write the following conver (Ju ly 20 19 )
Give two use s of eth ano l. (Ju ly 20 19 ) (1)
(29 ) llol.
Write IUPAC nam e of pyroga ace tald ehy de is
(30 )
la of the alc oho l tha t res ult s wh en (M arc h 20 20 } (1)
Wr ite str uct ura l for mu the pro duc t is hyd rol yse d.
(31 ) the pre sen ce of dry eth er and
rea cte d wit h CH3MgBr in
 ~ 2 9 ~ 2 ~ - - - - - - - - - - - - - - - - - - - - - - - - ~ - UTTAM's XI1 Chemistry Papers So'-- .
---~~::.:.:.::~~
(32) Explain the continuous etherification process for the preparation of diethyl e ther.
(March 2020) (2)
(33) How is ethanol prepared from the following compounds:
(a) Ethana l. (b) Ethene (c) Bromoethane. (March 2020) ( )
(34) Write a note on Kolbe reaction. 3
(Sept. 2021] (2 )
(35) Convert the following:
(i) Chlorobenzene to phenol (il) Ethana l to ethanol (ill) Iodome
thane to methoxy methane. (Sept. 2021) (3 )
(36) Write the preparation of phenol from anili~e. (March 2022} (2 )
(37) Write chemical reactions of following reagents on methox
yethane:
(i) Hot HI (ii) PC15 (lli) Dilute H S04 , (March 2022]
2 . . . (3)
(38) Write the name of reaction during conversion of phenol
to salicyclic acid. (July 2022) (l)
(39) Write balanced chemical reactions of the following reagent
s on carbolic acid:
(i) Br2 water (HJ Concentrated HN0 • (July 2022}
3 (2)
(40) What happen s when vapours of 1° and 2° alcohols are passed over
hot Cu metal? (July 2022) (2)
(41) Write chemical reactions for the following conversion: Acetic
acid into ethyl alcohol. (March 2023} (l)
(42) Convert the following:
(iJ Ethyl alcohol into ethyl acetate
(ilJ Phenol into benzene
(ill) Diethyl ether into ethyl chloride.
(March 2023) (3)
(43) Write Dow process for preparation of Phenol. What is the
action of bromine water on phenol ?(March 2023)

m
(2)

ALDEHYDES, KETO NES AND CARBOXYLIC ACIDS

(1) How is 4-methylpent-3-en-2-one obtained from propan-2-one?
(March 2013) (2)
(2) How are the following compounds prepared?
(a) Benzaldehyde from benzene.
(b) Acetophenone from benzene.
(c) Benzaldehyde from benzoyl chloride.
(3) Mention 'two' uses of propan-2-one.
(March 2013} (3)
(March 2013) (1)
(4) Explain the mechan ism of aldol condensation.
(Oct. 2013; March 2015} (3)
(5) How is benzophenone prepare d from benzonitrile?
(Oct. 2013; July 2016; March 2018} (2)
(6) Write a note on aldol condensation.
(March 2014, 2017; July 2022) (2)
(7) Write a note on self oxidation-reduction reaction of aldehyde with
suitable example. (March 2014) (2)
(8) Identify 'A' and 'B' in the following reaction : C H MgBr + CO
6 5 2 ., 'A' PCls ., 'B' (Oct. 2014) (2)
(9) Write the structu re and IUPAC names of all the metamers represe
nted by formula C4 H100. (Oct. 2014) (3)
(10) Write balance d chemical equatio ns for action of ammon ia
on -
(a) Formaldehyde (b) Acetaldehyde (c) Acetone.
(Oct. 2014) (3)
(11) Write a note on Friedel Craft's acylation.
(March 2015) (2)
(12) Explain, why are boiling points of carboxylic acids higher than corresp
onding alcohols. (March 2015) (2)
(13) Write the structu res and IUPAC names of the following compounds:
(a) Adipic acid (b) a-meth yl butyraldehyde
(March 201 SJ (2)
(14) What is Stephe n reactio n?
(Oct. 2015) (2)
(15) Write the structu re and IUPAC names of isomeric aldehyd
es having molecular formula C H 0.(0ct. 2015) (4)
5 10
(16) What are ketones ? How are ketones classified?
(March 2016) (2)
(17) Explain the mechan ism of esterification.
(March 2016) (4)
(18) Write IUPAC names of the following compo unds:
o o o
(a) CH3
-d II II
(b) CH3 - C - C - CH3

How is ethano ic acid prepare d from chy ice?

(July 2016)

(March 2017)
(2)

(2)
Give JUPAC name of CH3-CH -CH-CHO.
2 (March 2017) (1)
1) What is the action of the following reagen ts on prepan one?
(a) Phenyl hydraz ine (b) Zn-Hg/ cone. HCI (c) Sodium bisulph
ite. (July 2017) (3)
J Write a note on self oxidation-reduction reactio n of aldehyd e with suitabl
e example. (July 2017) (2)
 Board Questions 293
0
.
,n.f11.a mic al equa t·ion s:
plet e and rew nte the bala nce d che
corn NaCN + CuCN
(i3) rob enz ene ?
(a) ChiO 473 K, pres sure

50% KOH
?
(b) Jsob utyr alde hyd e
H•
hen yl hyd razi ne ? (Ma rch 201 8}
(c) suta non e +2, 4-d init ro-p (3)

g reag ents on etha noic acid ?

Wh at is the acti on of the followin
hea t. (Ma rch 201 8}
F O+ (b) PC1 hea t (c) P O
(3)
(a) LiA1H
,

for the following reac tion s·•

2 5

/ 3

the bala nce d che mic al equ atio n

3
4

com plet e and rew rite

W% WH
?
(a) Ben zald ehy de - - - -
H+ (Ju ly 201 8} (2)
(b) Ace tone + phe nylh ydr azin
e--- ?

following con vers ions :

Write bala nce d equ atio ns for the
(26) to cyc lopr opy lme than ol.
(a) Cyc lopr opa ne carb oxy lic acid (Ju ly 201 8} (2)
m.
hyl keto ne usin g dial kyl cad miu
(b) Acetyl chlo ride to ben zyl met
g:
(27) Write
che mic al equ atio n for the followin
her este rific atio n. (Ma rch 201 9} (3)
Gat term an-K och form ylat ion (ii) Ros enm und redu ctio n (iii) Fisc
(i)
(28) How will you
con vert :
ydr in
de (ii) Ace tone to ace tone cya noh
(i) Cal cium ace tate to ace tald ehy nzo ic acid ? (Ma rch 201 9) (4)
(iv) Ben zoic acid to m-b rom obe
(iii) Sod ium ace tate to met han e
(29) Con vert the following:
(i) Eth ana l into etha nal cya noh
ydr in (2)
(Ju ly 201 9)
3, 5-di nitr obe nzo yl chlo ride .
(ii) 3, 5-D init orb enz oic acid into
How are the following con vers
ion carr ied out ? (1)
(30) {Ju ly 201 9)
Dry ice into etha noic acid . (Ju ly 201 9) (2)
betw een etha nal and prop ana l.
(31) Write aldo l con den sati on reac tion usin g ace tic acid . (Ma rch 202 0) (1)
for prep arat ion of acet ic anh ydr ide
(32) Wri te bala nce d che mic al reac tion
g reac tion :
(33) Iden tify 'A' and 'B' in the followin
(Ma rch 202 0) (1)
Zn-H g ., B
,..,. I + CH3COCI AlCla
- HCI Con e. HCI, l:!.
A
0, , oxylic acid s. (Ma rch 202 0} (4)
the mec han ism of aldo l add itio n reaction. Mention two use s of carb
(34) Exp lain hyd e to
use d dur ing con vers ion of acet alde
(35) Wri te the nam e of reag ent (Se pt. 202 1) (1)
ace tald ehy de cya noh ydri n. (Se pt. 202 1) (2)
How is ben zop hen one prep ared from ben zon itril e?
(36)
Write che mic al
(37) Wri te a note on 'ald ol'
con den sati on reac tion of etha nal. sh. (Se pt. 202 1) (4)
lved whe n ben zald ehy de is trea ted with con cen trat ed cau stic pota
reac tion invo ne.( Mar ch 202 2) (1)
t form ed, whe n acet one is trea ted with 2,4- dini trop hen yl hyd razi
(38) Wri te the nam e of pro duc
(39) Iden tify A and B from the
following reac tion :
CH3 (Ma rch 202 2) (2)
I B + H 20
2 CH3 - C =- 0 ea (OHb A t. .,

(40 ) Wri te prep arat ion of acet

ic acid from: (Ma rch 202 2) (2)
(i) Dry ice (ii) Ace tyl chlo ride .
at is the acti on of
(41) Write the clas sific atio n of
alip hati c keto nes with example. Wh (Ma rch 202 2) (2)
sod ium hyp oidi te on ace tone ? (Ju ly 202 2) (1)
C nam e of a-m ethy lpro pion ic acid.
(42) Write the IUPA
(43) Wh at is the acti on of the
following on carboxylic acid : (Ju ly 202 2) (2)
(i) soc~ (ii) P2O5 ? (Ju ly 202 2) (2)
Con vert carb oxy lic acid s to: (i) Este r (ii) Acid ami de.
(44) (Ma rch 202 3) (3)
lain Aldo l con den sati on of etha nal.
(45) Exp (Ma rch 202 3) (2)
.
(46) Write a note on Haloform reaction

__ __J
 ?2-~-- -------- -------- ------= =---U= -T=-=- TAM'
__s_xn
__ C_he_m---=is_.:.;_try.sz...:..P.,.:::a~p~ers~Sol •
m
394
Summary of Board Qi
AMINES l34) Write chemica
(1) What is the action of bromine in alkaline medium on: \i) Acetonitril,
(35) Write the fon:
(a) CH3 CH 2 NO2 (b) CH - CH - NO2 (March 2013) ( )
2
3
I (36) Write chemic
CH3 . (371 Complete thi
(2) Write a short note on Hoffmann bromamide degradation. (March 2013} ( )
3 lsopropyl ale
(3) How is nitromethan e prepared from the following?
(a) Alkyl halide (b) a-Halogen carboxylic acid (c) cx-Nitroalkene. (Oct. 2013) ( ) \38) Write the m
3
(4) Explain Hoffmann bromamide degradation reaction. (Oct. 2013; March 2017, 2018) ( ) (39) Write chem
2
(5) What is the action of the following reagents on aniline? Acetic acid
(a) Bromine water (b) Acetic anhydride (c) Hot and cone. sulphuric acid. (March 2014) \40) Write IUPA
(3)
(6) Identify the compound 'A' and 'B' in the following equation: (41) What is th
CH _ CH + HNO 423-600 K (i) Chlorol
3 3
'A' Sn/conc.HCl 'B' + H2 O . . . (March 2014) (2)
3
(7) What will be the action of the mixture of sodium nitrite and dilute hydrochlon
c acid on.
(a) Ethyl amine (b) Aniline (c) Triethyl amine? (Oct. 2014) (3)
(8) How are propan-1-am ine and propan-2-am ine prepared from oxime? (Oct. 2014) (2) (1) Write the
(9) How is ethyl amine prepared from methyl iodide? (March 2015) (2) \2) Enlist th
(10) Write a note on Gabriel phthalimide synthesis. (March 2015} (3) structur,
(11) What is the action of acetic anhydride on: \3) What ha
(a) Ethyl amine (b) Diethyl amine. (Oct 2015} (2) \a) Bron
(12) What is the action of nitrous acid on: (4) Describ
(a) Primary nitroalkane (b) Secondary nitroalkane (c) Tertiary nitroalkane . (Oct. 2015} (3) the pre,
(13) How are: (a) 1-Nitroprop ane and ._ \5) Draw t:
(b) 2-Nitroprop ane prepared from suitable oxime? (March 2016} (2) (6) How ai
'-

(14) How are 1-nitroprop ane, 2-nitroprop ane and 2-methyl-2- nitropropan e are
distinguish ed \7) Define
from each other using nitrous acid? (March 2016} (3)
(15) What is the action of benzene diazonium chloride on: \8) What
(a) Phenol in alkaline medium (b) Aniline. (July 2016) (2) \9) What
(16) Identify 'A' and 'B' and rewrite the reactions: \10) What
Af½O/H2 O H+ (11) Wha1
C2 H5 - N+(CH3 ) 3 C A --- (July 2016) (1)
6
(17) What is the action of mixture of NaNO and dil.HCl on:
1· \a) B
\12) Ho\V
2
(a) Ethylamine (b) Aniline (c) Diethylami ne (March 2017} (3) \13) Den
(18) How is nitroenthan e converted into: \14) Wh
(a) Ethyl amine (b) N-ethylhydr oxyl amine (c) Acetic acid? (July 2017} \a)
(3)
(19) How is ethylamine prepared from (a) Nitro-alkan e (b) Oxime? I
\15) Ho
Explain basic nature of amines. (March 2010; Oct. 2009; July 2017} (4) \16) W1
(20) What is the action of p-toluenesu lphonyl chloride on ethylamine and diethylamin e?
(March 2018) l2) ar
(21) What is the action of lithium aluminium hydride in the presence of ether on the following compound
s? \17) H
(a) Nitroethane (b) 2-Methyl-1 -nitropropa ne.
(July 2018) (2) \18) I:
(22) Write resonance structures of aniline. What is the action of benzene diaozonium chloride
(19) '\J
on ethanol? (July 2018) (2}
(23) Write the structure of Phenylmeth anamine. \20) l
(March 2019) ll)
(24) Write a short note on Hoffmann elimination . \21) •
(March 2019) (3)
(25) What are amines? \22)
(March 2019) ll)
(26) Write the following conversion : Acetaldoxim e into ethylamine . (July 2019) ll)
(27) Amines are basic in nature. Explain. (July 2019) l2l \23)
(28) Convert benzene diazonium halide into aryl iodide. \24)
(July 2019) ll)
(29) What is the action of benzene sulphonyl chloride on ethanamin e? \25)
(July 2019) ll)
(30) Define : Quaternary ammonium salt. (March 2020) ll) \261
(31) Write the chemical reaction involved in the formation of ethyl amine using acetaldoxim
e. (March 2020) l3l \27
(32) Write reactions to prepare ethanamin e from:
\28
(i) Acetonitril e (ii) Nitroethan e (iii) Propionam ide. (Sept. 2021} l3l \2~
(33) How will you convert -
(i) Methyl iodide to methyl isocyanide . l \31

(ii) Methyl cyanide to ethanoic acid? (Sept. 2021) (3) \3

...
l
summa o Board Questions
I
(34) Write chemical reactions to prepare ethanamine from : 295
(i) Acetonitrile (ii) Nitroethane.
(35) Write the formula of Hinsberg's reagent. (March. 2022) (2)
(36) Write chemical reaction for carbylarnine test. (July 2022) (1)
(37) Complete the following reaction and identify A and B. (July 2022) (1)
Isopropyl alcohol PBr3 A NH a B
excess
(July 2022) (2)
(38) Write the name of the product formed by the action of LWH / ether on acetamide.
4 (March 2023)
(39) Write chemical reactions for the following conversion: (1)
Acetic acid into acetic anhydride.
(March 2023) (1)
(40) Write IUPAC name and structure of methylphenylamine.
(March 2023) (1)
(41) What is the action of the following reagents on ethyl amine.
(i) Chloroform and caustic potash (ii) Nitrous acid.
(March 2023) (3)

m BIOMOLECULES
(1) Write the structures of nucleotide and nucleoside.
(March 2013) (2)
(2) Enlist the properties of glucose that cannot be explained on the basis of open chain
structure of it.
(Oct. 2013) (3)
(3) What happens when glucose is treated with-
(a) Bromine water (b) Dilute nitric acid (c) Hydrogen cyanide (HCN). (March 2014) (3)
(4) Describe laboratory method for preparation of glucose. Write the reaction that indicates
the presence of- CHO group in glucose.
(Oct. 2014) (3)
(5) Draw the simple Fischer projection formulae of D-(+)-glucose and D-(-)- fructose.
(Oct. 2014) (2)
(6) How are proteins classified on the basis of molecular shapes?
(March 2015) (2)
(7) Define carbohydrates. What are reducing and non-reducing sugars?
(March 2015) (3)
(8) What are monosaccharides? Draw ring structure of a- D - (+) - glucopyranose?
(Oct. 2015) (2)
(9) What is peptide linkage? How is tripeptide formed?
(Oct. 2015) (3)
(10) What are carbohydrates? (March 2016) (1)
(11) What is the action of following reagents on glucose?
(a) Bromine water (b) Dilute HN03 (c) Hydroxyl amine. (July 2016, 2018) (3)
(12) How is the glucose prepared from sucrose? (March 2009, 2017; July 2022) (2)
(13) Define enzymes. How is peptide linkage formed? (July 2017) (3)
(14) What happens when glucose is treated with:
(a) Hydroxylamine (b) Hydrogen cyanide. (July 2017) (2)
(15) How glucose is prepared from cane suger? (March 2018) (2)
(16) What are amino acids? Write the correct reaction for formation of peptide bond between
amino acids. (March 2018) (2)
( 17) How is glucose prepared from starch? (July 2018) (2)
(18) Draw the structure of Thymine. (July 2018) (1)
(19) Write the number of hydroxyl groups present in a - D - (+) - Glucopyranose (trans). (March 2019) (1)
(20) How is glucose prepared by commercial method? How is peptide linkage formed? (March 2019) (3)
(21) Define enzyme. (July 2019) (3)
(22) How are the following conversion carried out?
(i) Glucose into n - hexane (ii) Glucose into glucoxime? (July 2019) (2)
(23) Write Haworth projection formula of a-D- (+)-glucopyranose. Define hormones. (March 2020) (2)
(24) What are monosaccharides? Explain denaturation of proteins. (March 2020) (3)
(25) Write the name of sugar present in RNA. (Sept. 2021) (1)
(26) Write classification of proteins on the basis of molecular shapes with examples. (Sept. 2021) (2)
(27) Explain formation of peptide linkage in protein with an example. (March 2022) (2)
(28) Write commercial method of preparation of glucose. Write structure of adipic acid. (March 2022) (3)
(29) What is denaturation of protein? (July 2022) (1)
(30) Write chemical reaction for the preparation of glucose from sucrose.
(March 2023) (2)
Write structure of D -ribose.
(March 2023) (1)
(31) What is peptide bond.
 2 96 UTTAM's Xll Chemistry Papers Solutio
~~----- -------- -------- =-:...:. :.::.__= ==--__ __,---- .;:..:::: ~

(1}
I iiliMHMiMIIHIMtiMM9iiMM141
1s
Explain the following terms: 2
(fJ Homopolymers (UJ EJastomers. (March 0l 3J f2)
2 f2)
(2 J Write the chemical reaction to prepare novoJac polymer. (March 0l3J
2013}
(3J How are polymers classified on the basis of polymerisatio n process? (Oct. f2)
2
(4J Write the structure of melamine. (Oct. 0l 3J fl)
2 0l4J (2)
ISJ Write names and chemical formulae of monomers used in preparing Buna-S. (March
(6) What are thermoplastic polymers? (March 2 014} fl)

17J How is Nylon 6, 6 prepared? Write any 'two' uses of terylene. (Oct. 2 0l4J (3)
(81 Explain with examples, branched and linear polymers. (March 2015) (2)
(9J What are biodegradable polymers and non-biodegradable polymers? Write 'one example' of each.
(March 2015) (2)
(Oct. 20l SJ (3)
(10} Write the reactions involved in the preparation of - (a) Teflon (b) Orlon (c} PVC.
(March 2016) (1)
(11) Write the reaction for the preparation of Nylon-6.
(March 2016) (2)
(12} How are polythene and neoprene prepared?
(July 2016) (1)
(13J Write the formulae of the raw materials used for preparation of Buna-S.
(14J How are the following polymers prepared?
(July 2016) (2)
(aJ Orlon (bJ Teflon
(March 2017} (2)
(15J Explain the term: Homopolymers
(March 2017} (1)
(16J How is nylon 6,6 prepared?
(July 2017} (2)
(17) How is Te.rylene prepared?
(July2017} (2)
(18J Write the names and chemical formulae of monomers used in preparing Buna-N.
(March 2018} (3)
(19J Explain the preparation and uses of nylon-2-nylon-6.
(20J What are elastomers?
(July 2018) (3)
Distinguish between thermoplasti c polymers and thermosetting polymers.
(21J Write chemical reactions to prepare the following polymers:
(March 2019) (3)
(iJ Teflon (HJ Nylon-6
(22J Write the reactions for the preparation of polymers by using the following monomers:
(July 2019) (2)
(iJ Vmy1 chloride (HJ Tetrafiuoroethane.
(July 2019) (2)
(23J De.fine: (iJ Condensatio n polymer (UJ Homopolymer.
non - biodegradable polymer. Write the preparation of terelyne. (March 2020) (2)
(24J De.fine
names and structure of monomers used in the preparation of Nylon 6, 6 polymer. (Sept. 2021) (2)
(25J Write
(March 2022) (3)
(26J Write classification of polymers on the basis of structure.
(March 2022) (1)
(27J Write the name of biodegradabl e polyamide copolymer.
(July 2022)
(28J Write the name of monomer used for preparation of Nylon 6.
(1)
(July 2022) (1)
(29J Write chemical composition of Zieglar-Natt a catalyst.
(July 2022) (1)
(30J De.fine: Elastomer.
(March 2023) (3)
(31J Write the reactions for the formation of nylon 6, 6 polymer.
(March 2023) (1)
(32J De.fine: Vulcanization.

m GREEN CHEMIST RY AND NANOCHEMISTRY

(Sept. 2021) (1)
(1J Write the name of nanostructu ral material used in tyres to increase their life.
(Sept. 2021) (2)
(2J Explain three principles of green chemistJy.
(March 2022) (1)
(3J Write the name of the alloy used in Fischer Tropsch process in the synthesis of gasoline.
Define green chemistJy. Write two disadvantag es of nanotechnolo gy. (March 2022) (2)
(4J
(July 2022) (1)
(SJ Define: Nanochemis tJy.
(July 2022) (1)
(6J Define: Nanotechnol ogy.
(July 2022) (1)
f7J Define: Green chemistJy.
{SJ Write the name of the technique used to know geometJy of nanoparticle s. (March 2023) (1)
(9J De.tine: Green chemistJy. Write two advantages of nanoparticle and nanotechnol ogy. (March 2023} (2)
(lOJ Write the name of nano structured material used in car tyres to increase the life of tyres. (March 2023) (1)

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