ORGANIC CHEMISTRY
Daily Practice Problems
Target JEE 2018
Class : XII Marks : 35 Date : 12-13/05/2017 Time : 30 Min. DPP. NO.-15
Q.1 Column I Column II [4]
(A) BH3 (P) Electrophile
CH3
(B) (Q) Nucleophile
(C) AlCl3 (R) Lewis acid
(D) CH 3 (S) Lewis base
(T) Having hyperconjugation, Inductive effect and
Resonance in same molecule
[Ans. (A) P,R (B) Q,S,T (C) P,R (D) Q,S ]
Q.2 Column I Column II [4]
(A) CH 3 (P) Nucleophile
(B) BF3 (Q) Base
(C) CH 3 (R) Electrophile
(S) Acid
[Ans. (A) PQ (B) RS (C)R ]
Q.3 Statement-1 : LDA is a very strong nucleophile but it is not a very good base. [3]
Statement-2 : Nucleophilicity is a kinetic property but basicityis thermodynamic property.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D*) Statement-1 is false, statement-2 is true.
Q.4 Statement-1 : Nucleophilicity is thermodynamic control & basicityis kineticallycontrolled. [3]
Statement-2 : Basic strength of a base is tendency to donated lone pair to H+ ion while
nucleophilicity is tendency to donate lone pair to atoms other than H+ ion.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D*) Statement-1 is false, statement-2 is true.
Q.5 Which is the correct order of nucleophilicity : [3]
(A) HO > S H (B*) F < I
(C) CH 3 SO 3 CH 3 CO 2 (D) H 3 C < F
Q.6 In the following groups, [3]
–OCOCH3 –OMe –OSO2Me –OSO2CF3
I II III IV
the order of leaving group ability is –
(A) I > II > III > IV (B*) IV > III > I > II (C) III > II > I > IV (D) II > III > IV > I
Q.7 Correct order of nucleophilicity of following anions in polar protic solvent is: [3]
(A*) CH 3 > NH 2 > OH > F (B) CH 3 < NH 2 < OH < F
(C) CH 3 = NH2 = OH = F (D) CH 3 > F > OH > NH2
Q.8 Which of the following correct order for leaving group ability [3]
(A) Br NH CH 3 CH 3 C O O CH 3
||
O
(B) CH 3 C O Br O CH 3 NH CH 3
||
O
(C*) Br CH 3 C O O CH 3 NH CH 3
||
O
(D) Br CH 3 C O O CH 3 NH CH 3
||
O
Q.9 Decreasing order of nucleophilicityof the following nucleophile. [3]
O
||
(1) CH3 (2) C N (3) SO (4) CH3CO 2
||
O
(A) 4 > 3 > 2 > 1 (B*) 1 > 2 > 4 > 3 (C) 2 > 1 > 3 > 4 (D) 1 > 2 > 3 > 4
Q.10 Which of the following statement is correct? [3]
(A) The relative nucleophilicity in aprotic solvent is in order.
I > Br > Cl > F
(B) The relative order of – I groups is
NF3 > – NH 3 > N Me3 > NO2
(C) The relative order of basic strength in aqueous solution is
NH3 < MeNH2 < Me2NH < Me3N
(D*) None of these
Q.11 What will be correct order of rate of reaction(s). [3]
(I) F + R – OTs DMF
RF + Ts O
(II) Cl + R – OTs DMF
RCl + Ts O
(III) Br + R – OTs DMF
RBr + Ts O
(IV) I + R – OTs DMF
RI + Ts O
(A*) I > II > III > IV (B) IV > III > II > I
(C) II > I > III > IV (D) III > I > II > IV
