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Sakshi Vora Atomic Structure

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0% found this document useful (0 votes)
85 views105 pages

Sakshi Vora Atomic Structure

Uploaded by

rangavignesh855
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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SYLLABUS
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Waves
A wave motion is a means of transferring energy from one point to another point without
any actual transportation of matter between these points.
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Characteristics of waves
(i) Wave length: Length of 1 complete wave.

(ii) Amplitude:

(iii) Frequency (v): Number of waves passing through a fixed pt in 1 sec

Number of oscillations per unit time


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Characteristics of waves
Time period (T): Time for one complete oscillation of wave.

Time taken by the wave to travel a distance equal to one wavelength.


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EM Waves
Waves consisting of oscillating electric and magnetic field.

Characteristics of electromagnetic radiations:

(A) All em waves moves with the same speed equal to that of light.

(B) They do not require any medium to propagate.

(C) These consist of electric and magnetic field that oscillate in the direction
perpendicular to each other and to the direction in which the wave propagates.
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EM Waves
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Electromagnetic Spectrum
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JEE MAIN 2024 PYQ

Ans: 1724
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Planck’s Quantum Theory


Atoms or molecules could emit or absorb energy only in discrete quantities (small packets)
and not in any arbitrary amount.
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Planck’s Quantum Theory


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Planck’s Quantum Theory


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#chamka
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JEE MAIN 2024 PYQ

Ans: 494
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JEE MAIN 2022 PYQ

Ans: C
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Photoelectric Effect
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Facts and explanation: Photoelectric Effect


● There is no time lag between incidence of light and emission of photoelectrons.
● Rate of emission of photoelectrons from a metal surface is directly proportional to the
intensity of incident light.
● The maximum kinetic energy of photoelectrons depends on the frequency of incident
radiation; but, it is independent of the intensity of light used.
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Intensity
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JEE MAIN 2021 PYQ

Ans: 2
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Graphs of Photoelectric effect


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Stopping Potential
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JEE MAIN 2021 PYQ

Ans: 222
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JEE MAIN PYQ

Ans: 3
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Bohr’s Atomic Model


● Mono electronic system
● Atom has a central massive core nucleus where all the protons and neutrons are present.
● The size of the nucleus is very small.
● Electron in an atom revolve around the nucleus in certain discrete orbits.
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Bohr’s Atomic Model


● An electron can move only in those permissive orbits in which the angular
momentum (mvr) or the electron is an integral multiple of h/2π

● The radiation is emitted or absorbed as a single quantum (photon) whose


energy is equal to the difference in energy of the electron in the two orbits
involved.
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Bohr’s Atomic Model : Derivation


● Columbic FOA = centripetal force
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#chamka
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#chamka
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Time period
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Absorption and Emission of energy


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Levels : Ground, first, second excited states


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JEE MAIN 2021 PYQ

Ans: A
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JEE MAIN 2021 PYQ


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JEE MAIN PYQ

Ans: 270
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JEE ADVANCED 2024 PYQ

Ans: B
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Line Spectrum of HYDROGEN


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Electronic transitions
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Wavelength of photon
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#chamka
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Ionization of mono electronic species


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Total number of unique spectral


lines
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JEE Main 2019 PYQ

Ans: a
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JEE Main 2019 PYQ


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JEE Main 2019 PYQ

Ans: b
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JEE Main 2019 PYQ


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De Broglie’s Hypothesis
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#chamka
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De Broglie’s Hypothesis
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De Broglie’s Hypothesis
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JEE Main 2020 PYQ

Ans: d
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Heisenberg’s Uncertainty Principle


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Error in speed
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JEE Main 2024 PYQ

Ans: 58
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JEE Main 2022 PYQ

Ans: 22
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Wave Mechanical Model


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Wave Mechanical Model


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Wave Mechanical Model


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Wave Mechanical Model


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Wave Mechanical Model


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Significance of wave function


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Significance of psi 2
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Nodes
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Radial Nodes and Angular Nodes


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Radial Nodes and Angular Nodes


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Principle Quantum Number (n)


● Energy of electron in an orbit
● Average distance b/w electron and nucleus
● K,L,M,N
● As n inc, energy inc
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Azimuthal Quantum Number (l)


● Number of subshells/ sublevels to which the electron belongs
● Shape of subshell
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Azimuthal Quantum Number


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d orbitals
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Magnetic Quantum Number (m)


● Number of permitted orientation of subshells
● -l to +l
● Total value of m is 2l +1
● For n, the total value of m is n2
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#chamka
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Degenerate Orbitals
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Spin Quantum Number


● Rotation of electron on its axis
Spin angular momentum
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#chamka
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#chamka
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Nodal Planes
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Nodal Planes and Cones


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JEE Main 2023 PYQ

Ans: 3
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JEE Main PYQ 2022

Ans: A
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JEE Main PYQ 2022

Ans: d
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JEE Main PYQ 2021

Ans: B
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JEE Main 2024 PYQ

Ans: A
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JEE Main PYQ 2021

Ans: B
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JEE Main 2020 PYQ

Ans: D
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JEE Main 2022 PYQ

Ans: C
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Graphs of R(r) v/s r


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Rules for R2(r) v/s r graph


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Radial Probability Distribution Function


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Rules for P(r) v/v r graph


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R(r) v/s r for 1s 3s


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P(r) v/s r graph for 4p


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JEE Main 2019 PYQ

Ans: d
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JEE Main PYQ 2022

Ans: B
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JEE ADVANCED 2016 PYQ

Ans: D
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Electronic Configuration
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Electronic Configuration
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Electronic Configuration : Short cut


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Electronic Configuration
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Maximum Multiplicity
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Exchange Energy
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Electronic Configuration
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Elements 1 to 30 electronic configuratiom


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Elements 1 to 30 electronic configuratiom


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Elements 1 to 30 electronic configuratiom


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D block exceptions
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Exception

Ni

Pd

Pt

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