SAFETY DATA SHEET

Section 1. Identification
Product name : CRW9152A CORROSION INHIBITOR
Product code : CRW9152A

Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Corrosion Inhibitor

Print date : 1/16/2020

Validation date : 1/16/2020
Version : 3.01

Supplier's details : Baker Petrolite LLC

12645 W. Airport Blvd.
Sugar Land, TX 77478
For Product Information/SDSs Call: 800-231-3606
(8:00 a.m. - 5:00 p.m. CST, Monday - Friday) 281-276-5400

Emergency telephone : CHEMTREC: 800-424-9300 (U.S. 24 hour)

number (with hours of Baker Petrolite: 800-231-3606
operation) (001)281-276-5400
CHEMTREC Int'l 01-703-527-3887 (International 24 hour)

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE LIQUIDS - Category 2
substance or mixture ACUTE TOXICITY (oral) - Category 4
ACUTE TOXICITY (dermal) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN IRRITATION - Category 2
SERIOUS EYE DAMAGE - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (optic nerve) -
Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (liver) - Category 2
AQUATIC HAZARD (ACUTE) - Category 2

GHS label elements

Hazard pictograms :

Signal word : Danger

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Section 2. Hazards identification

Hazard statements : Highly flammable liquid and vapor.
Harmful if swallowed, in contact with skin or if inhaled.
Causes serious eye damage.
Causes skin irritation.
Causes damage to organs. (optic nerve)
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure. (liver)
Toxic to aquatic life.
Precautionary statements
Prevention : Wear protective gloves: > 8 hours (breakthrough time): Nitrile or Neoprene gloves..
Wear eye or face protection. Wear protective clothing. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-
proof electrical, ventilating, lighting and all material-handling equipment. Use only non-
sparking tools. Take precautionary measures against static discharge. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Avoid release to the
environment. Do not breathe vapor. Do not eat, drink or smoke when using this
product. Wash hands thoroughly after handling.
Response : Get medical attention if you feel unwell. IF exposed: Call a POISON CENTER or
physician. IF INHALED: Remove person to fresh air and keep comfortable for
breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED:
Call a POISON CENTER or physician if you feel unwell. Rinse mouth. IF ON SKIN (or
hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
IF ON SKIN: Wash with plenty of soap and water. Call a POISON CENTER or
physician if you feel unwell. Take off contaminated clothing and wash it before reuse. If
skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or physician.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label : Avoid contact with skin and clothing. Wash thoroughly after handling.
elements
Hazards not otherwise : Prolonged or repeated contact may dry skin and cause irritation.
classified
Additional information
The NIOSH IDLH (Immediately Dangerous to Life and Health) value for hydrogen sulfide is 100 ppm. Hydrogen sulfide
odor is not a good warning property. The human sense of smell may become "fatigued" after a few minutes of exposure to
hydrogen sulfide and no longer be able to detect the odor. See Section 11 for more detailed information on health effects
and symptoms.

Section 3. Composition/information on ingredients

Substance/mixture : Mixture

Ingredient name % CAS number

Isopropanol 30 - 40 67-63-0
Methanol 20 - 30 67-56-1
Butanol 5 - 10 71-36-3
Phosphates 5 - 10 Trade secret.
Quaternary ammonium chloride 5 - 10 Trade secret.
Polyoxyalkylene phosphate 5 - 10 Trade secret.
Diethanolamine 1-5 111-42-2
Morpholine 1-5 110-91-8
Fatty amine 0 - 0.1 Trade secret.
Hydrogen sulfide <0.1 7783-06-4

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Section 3. Composition/information on ingredients

Additional information
The 0.1% (1000 ppm) maximum hydrogen sulfide (H2S) content shown above is for the liquid phase. The headspace of
containers of this product may contain levels of H2S higher than this.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush
the eye(s) continuously with lukewarm, gently flowing water for at least 20-60 minutes
while holding the eyelid(s) open. Check for and remove any contact lenses. Chemical
burns must be treated promptly by a physician.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. In case of inhalation
of decomposition products in a fire, symptoms may be delayed. The exposed person
may need to be kept under medical surveillance for 48 hours.
Skin contact : Get medical attention immediately. Call a poison center or physician. Wash affected
area with soap and mild detergent for at least 20 - 60 minutes. Wash skin thoroughly
with soap and water or use recognized skin cleanser. Remove contaminated clothing
and shoes. Wash contaminated clothing thoroughly with water before removing it, or
wear gloves. Chemical burns must be treated promptly by a physician. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Do not induce vomiting unless
directed to do so by medical personnel. If vomiting occurs, the head should be kept low
so that vomit does not enter the lungs. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause
drowsiness or dizziness.
Skin contact : Harmful in contact with skin. Causes skin irritation. Defatting to the skin.
Ingestion : Harmful if swallowed. Can cause central nervous system (CNS) depression.
Over-exposure signs/symptoms
Eye contact : pain,watering,redness
Inhalation : nausea or vomiting,headache,drowsiness/fatigue,dizziness/vertigo,unconsciousness
Skin contact : pain or irritation,redness,dryness,cracking,blistering may occur
Ingestion : stomach pains

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

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Section 4. First aid measures

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, alcohol-resistant foam or water spray (fog).
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
from the chemical In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back. This material is toxic to aquatic life. Fire
water contaminated with this material must be contained and prevented from being
discharged to any waterway, sewer or drain.
Hazardous thermal : carbon dioxide,carbon monoxide,nitrogen oxides,sulfur oxides,phosphorus oxides
decomposition products

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities.

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.

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Section 6. Accidental release measures

Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
If RQ (Reportable Quantity) is exceeded, report to National Spill Response Office at 1-800-424-8802.
Additional information
Released material may contain residual sulfides. Spray residual material left after initial clean up with weak (approximately
5 percent) hydrogen peroxide to oxidize sufides. Recover as much solution as possible. A respirator suitable for H2S may
be necessary in the event of a spill.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or
on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid release to the
environment. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in original container protected from direct sunlight in a dry, cool and well-ventilated
incompatibilities area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.
Additional information
Avoid inhalation of vapors near openings on storage containers and manufacturing equipment. This product should be
transferred under negative pressure.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits

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Section 8. Exposure controls/personal protection

Ingredient name Exposure limits
Isopropanol ACGIH TLV (United States, 4/2014).
STEL: 400 ppm, 0 times per shift, 15 minutes.
TWA: 200 ppm, 0 times per shift, 8 hours.
NIOSH REL (United States, 10/2013).
STEL: 1225 mg/m³, 0 times per shift, 15 minutes.
STEL: 500 ppm, 0 times per shift, 15 minutes.
TWA: 980 mg/m³, 0 times per shift, 10 hours.
TWA: 400 ppm, 0 times per shift, 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 980 mg/m³, 0 times per shift, 8 hours.
TWA: 400 ppm, 0 times per shift, 8 hours.
OSHA PEL 1989 (United States, 3/1989).
STEL: 1225 mg/m³, 0 times per shift, 15 minutes.
STEL: 500 ppm, 0 times per shift, 15 minutes.
TWA: 980 mg/m³, 0 times per shift, 8 hours.
TWA: 400 ppm, 0 times per shift, 8 hours.
Methanol ACGIH TLV (United States, 3/2018). Absorbed through
skin.
STEL: 328 mg/m³, 0 times per shift, 15 minutes.
STEL: 250 ppm, 0 times per shift, 15 minutes.
TWA: 262 mg/m³, 0 times per shift, 8 hours.
TWA: 200 ppm, 0 times per shift, 8 hours.
NIOSH REL (United States, 10/2016). Absorbed
through skin.
STEL: 325 mg/m³, 0 times per shift, 15 minutes.
STEL: 250 ppm, 0 times per shift, 15 minutes.
TWA: 260 mg/m³, 0 times per shift, 10 hours.
TWA: 200 ppm, 0 times per shift, 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 260 mg/m³, 0 times per shift, 8 hours.
TWA: 200 ppm, 0 times per shift, 8 hours.
OSHA PEL 1989 (United States, 3/1989). Absorbed
through skin.
STEL: 325 mg/m³, 0 times per shift, 15 minutes.
STEL: 250 ppm, 0 times per shift, 15 minutes.
TWA: 260 mg/m³, 0 times per shift, 8 hours.
TWA: 200 ppm, 0 times per shift, 8 hours.
Butanol ACGIH TLV (United States, 3/2018).
TWA: 20 ppm, 0 times per shift, 8 hours.
NIOSH REL (United States, 10/2016). Absorbed
through skin.
CEIL: 150 mg/m³, 0 times per shift, 0 hours.
CEIL: 50 ppm, 0 times per shift, 0 hours.
OSHA PEL (United States, 5/2018).
TWA: 300 mg/m³, 0 times per shift, 8 hours.
TWA: 100 ppm, 0 times per shift, 8 hours.
OSHA PEL 1989 (United States, 3/1989). Absorbed
through skin.
CEIL: 150 mg/m³, 0 times per shift, 0 hours.
CEIL: 50 ppm, 0 times per shift, 0 hours.
Phosphates None.
Quaternary ammonium chloride None.
Polyoxyalkylene phosphate None.
Diethanolamine ACGIH TLV (United States, 2/2010). Absorbed through
skin.
TWA: 1 mg/m³, 0 times per shift, 8 hours. Form:
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Section 8. Exposure controls/personal protection

Inhalable fraction and vapor
NIOSH REL (United States, 6/2009).
TWA: 15 mg/m³, 0 times per shift, 10 hours.
TWA: 3 ppm, 0 times per shift, 10 hours.
OSHA PEL 1989 (United States, 3/1989).
TWA: 15 mg/m³, 0 times per shift, 8 hours.
TWA: 3 ppm, 0 times per shift, 8 hours.
Morpholine ACGIH TLV (United States, 3/2018). Absorbed through
skin.
TWA: 71 mg/m³, 0 times per shift, 8 hours.
TWA: 20 ppm, 0 times per shift, 8 hours.
NIOSH REL (United States, 10/2016). Absorbed
through skin.
STEL: 105 mg/m³, 0 times per shift, 15 minutes.
STEL: 30 ppm, 0 times per shift, 15 minutes.
TWA: 70 mg/m³, 0 times per shift, 10 hours.
TWA: 20 ppm, 0 times per shift, 10 hours.
OSHA PEL (United States, 5/2018). Absorbed through
skin.
TWA: 70 mg/m³, 0 times per shift, 8 hours.
TWA: 20 ppm, 0 times per shift, 8 hours.
OSHA PEL 1989 (United States, 3/1989). Absorbed
through skin.
STEL: 105 mg/m³, 0 times per shift, 15 minutes.
STEL: 30 ppm, 0 times per shift, 15 minutes.
TWA: 70 mg/m³, 0 times per shift, 8 hours.
TWA: 20 ppm, 0 times per shift, 8 hours.
Fatty amine None.
Hydrogen sulfide ACGIH TLV (United States, 3/2018).
STEL: 5 ppm, 0 times per shift, 15 minutes.
TWA: 1 ppm, 0 times per shift, 8 hours.
NIOSH REL (United States, 10/2016).
CEIL: 15 mg/m³, 0 times per shift, 10 minutes.
CEIL: 10 ppm, 0 times per shift, 10 minutes.
OSHA PEL 1989 (United States, 3/1989).
STEL: 21 mg/m³, 0 times per shift, 15 minutes.
STEL: 15 ppm, 0 times per shift, 15 minutes.
TWA: 14 mg/m³, 0 times per shift, 8 hours.
TWA: 10 ppm, 0 times per shift, 8 hours.
OSHA PEL Z2 (United States, 2/2013).
AMP: 50 ppm, 0 times per shift, 10 minutes.
CEIL: 20 ppm, 0 times per shift, 0 hours.

Consult local authorities for acceptable exposure limits.

If OSHA permissible exposure levels are shown above they are the OSHA 1989 levels or are from subsequent
OSHA regulatory actions. Although the 1989 levels have been vacated the 11th Circuit Court of Appeals, Baker
Hughes recommends that these lower exposure levels be observed as reasonable worker protection.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.

Individual protection measures

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Section 8. Exposure controls/personal protection

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Wear chemical safety goggles. When transferring material wear face-shield in addition
to chemical safety goggles. If inhalation hazards exist, a full-face respirator may be
required instead.
Hand protection : Chemical-resistant gloves: Nitrile or Neoprene gloves.
Skin protection : Wear long sleeves and chemical resistant apron to prevent repeated or prolonged skin
contact.
Respiratory protection : Hydrogen sulfide accumulates in the headspace of containers of this product. During
sealed transfer of this product under well-ventilated conditions, where inhalation
exposure potential is minimal, respiratory protection is not expected to be necessary.
However, if after a thorough hazard assessment respiratory protection is deemed
necessary an appropriate supplied air respirator must be utilized.
Additional information
Prior to handling containers of this product, make sure to be wearing a hydrogen sulfide (H2S) monitor that is in sound
working condition.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid. [Clear.]
Color : Green to Amber. [Light]
Odor : Mercaptan Pungent. [Strong]
Odor threshold : Not available.
pH : 7.9 [Conc. (% w/w): 5%]
: 5% in IPA/water
Melting/freezing point : Not available.
Boiling point : Not available.
Initial Boiling Point : Not available.
Flash point : Closed cup: 12.8°C (55°F) [SFCC]
Burning time : Not applicable.
Burning rate : Not applicable.
Evaporation rate : Not available.
Flammability (solid, gas) : Highly flammable in the presence of the following materials or conditions: open flames,
sparks and static discharge and heat.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : 47.9 kPa (359.4 mm Hg) @ 54.4°C
Vapor density : >1 [Air = 1]
Relative density : 0.864 (15.6°C)
Density : 7.2 (lbs/gal)
Solubility in water : Dispersible
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.

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Section 9. Physical and chemical properties

Viscosity : Dynamic (15.6°C): 3.7 cP

VOC : Not available.

Pour Point : <-42.8°C (<-45°F)

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.

Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials, reducing
materials and acids.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Isopropanol LC50 Inhalation Vapor Rat >10000 ppm 6 hours
LD50 Dermal Rabbit 6.29 g/kg -
LD50 Oral Rat 4700 mg/kg -
Methanol LC50 Inhalation Gas. Rat 145000 ppm 1 hours
LC50 Inhalation Gas. Rat 64000 ppm 4 hours
LD50 Dermal Rabbit 15800 mg/kg -
LD50 Oral Human 500 mg/kg -
LD50 Oral Rat 5600 mg/kg -
Butanol LC50 Inhalation Vapor Rat 24000 mg/m³ 4 hours
LD50 Dermal Rabbit 3400 mg/kg -
LD50 Oral Rat 790 mg/kg -
Phosphates LD50 Dermal Rabbit >8000 mg/kg -
LD50 Oral Rat 9200 mg/kg -
Quaternary ammonium LD50 Dermal Rat 1664 mg/kg -
chloride
LD50 Oral Rat 295 mg/kg -
Diethanolamine LD50 Dermal Rabbit 3000 mg/kg -
LD50 Oral Rat 680 mg/kg -
Morpholine LD50 Dermal Rabbit 0.5 g/kg -
LD50 Oral Rat 1.05 g/kg -
LD50 Oral Rat 1450 mg/kg -
Fatty amine LD50 Dermal Rat 5600 mg/kg -
LD50 Oral Rat 1330 mg/kg -
Hydrogen sulfide LC50 Inhalation Gas. Rat 444 ppm 4 hours
LC50 Inhalation Vapor Rat 700 mg/m³ 4 hours
LCLo Inhalation Gas. Man 634 ppm 1 hours

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Section 11. Toxicological information

Irritation/Corrosion
No applicable toxicity data
Sensitization
No applicable toxicity data
Mutagenicity
No applicable toxicity data
Carcinogenicity
Product/ingredient name OSHA IARC NTP
Isopropanol - 3 -
Diethanolamine - 3 -
Morpholine - 3 -
Reproductive toxicity
No applicable toxicity data
Teratogenicity
No applicable toxicity data
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Isopropanol Category 3 Not applicable. Narcotic effects
Methanol Category 1 Oral optic nerve
Butanol Category 3 Not applicable. Respiratory tract
irritation and
Narcotic effects
Hydrogen sulfide Category 3 Not applicable. Respiratory tract
irritation
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
Diethanolamine Category 2 Oral liver

Aspiration hazard
Not available.

Information on the likely : Routes of entry anticipated: Dermal, Inhalation.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause
drowsiness or dizziness.
Skin contact : Harmful in contact with skin. Causes skin irritation. Defatting to the skin.
Ingestion : Harmful if swallowed. Can cause central nervous system (CNS) depression.

Potential chronic health effects

General : May cause damage to organs through prolonged or repeated exposure. Prolonged or
repeated contact can defat the skin and lead to irritation, cracking and/or dermatitis.
Carcinogenicity : No known significant effects or critical hazards.

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Section 11. Toxicological information

Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Route ATE value
Oral 364.8 mg/kg
Dermal 1077.5 mg/kg
Inhalation (gases) 30515463.9 ppm
Inhalation (vapors) 11.89 mg/l

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
Isopropanol Acute LC50 1400000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 1400000 µg/l Fish - Gambusia affinis 96 hours
Methanol Acute EC50 16.912 mg/l Marine water Algae - Ulva pertusa 96 hours
Acute EC50 10000000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 2500000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 100 mg/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 9.96 mg/l Marine water Algae - Ulva pertusa 96 hours
Butanol Acute EC50 1983000 to 2072000 µg/l Daphnia - Daphnia magna 48 hours
Fresh water
Acute LC50 1910000 µg/l Fresh water Fish - Pimephales promelas - 96 hours
Juvenile (Fledgling, Hatchling,
Weanling)
Phosphates Acute EC50 0.48 mg/l Algae - Skeletonema 72 hours
Acute LC50 3.2 mg/l Fish 96 hours
Quaternary ammonium Acute LC50 0.145 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours
chloride
Diethanolamine Acute LC50 2150 µg/l Fresh water Daphnia - Daphnia pulex 48 hours
Acute LC50 100000 µg/l Fresh water Fish - Pimephales promelas - 96 hours
Juvenile (Fledgling, Hatchling,
Weanling)
Chronic NOEC <24000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Chronic NOEC 540 ppm Marine water Fish - Cyprinodon variegatus - 96 hours
Juvenile (Fledgling, Hatchling,
Weanling)
Morpholine Acute EC50 28 mg/l Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata
Acute LC50 1000 µg/l Fish - Danio rerio 96 hours
Hydrogen sulfide Acute EC50 62 µg/l Fresh water Crustaceans - Gammarus 2 days
pseudolimnaeus
Acute LC50 2 µg/l Fresh water Fish - Coregonus clupeaformis - 96 hours
Yolk-sac fry

Persistence and degradability

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Section 12. Ecological information

Product/ingredient name Test Result Dose Inoculum
Phosphates - 28 % - 28 days - -

Product/ingredient name Aquatic half-life Photolysis Biodegradability

Phosphates - - Inherent

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Vapor from product residues may create a highly flammable or
explosive atmosphere inside the container. Do not cut, weld or grind used containers
unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.

Section 14. Transport information

DOT Classification TDG Classification IMDG IATA
UN number UN1992 UN1992 UN1992 UN1992

UN proper FLAMMABLE LIQUID, FLAMMABLE LIQUID, FLAMMABLE LIQUID, FLAMMABLE LIQUID,

shipping name TOXIC, N.O.S. TOXIC, N.O.S. TOXIC, N.O.S. TOXIC, N.O.S.
(Contains: Isopropanol, (Contains: Isopropanol, (Contains: Isopropanol, (Contains: Isopropanol,
Methanol) Methanol) Methanol) Methanol)
Transport 3 (6.1) 3 (6.1) 3 (6.1) 3 (6.1)
hazard class(es)

Packing group II II II II
Environmental No. No. No. No.
hazards

Additional information
DOT Classification : Reportable quantity 4761.9 lbs / 2161.9 kg [661.01 gal / 2502.2 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
TDG Classification : Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3), 2.26-2.36 (Class 6).
IMDG : Emergency schedules F-E S-E

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

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Section 14. Transport information

Transport in bulk according : Not available.
to Annex II of MARPOL and
the IBC Code
DOT Reportable Methanol, 2991 gal of this product.
Quantity Butanol, 6944 gal of this product.
Diethanolamine, 661 gal of this product.

Marine pollutant Not available.

North-America NAERG : 131

Section 15. Regulatory information

U.S. Federal regulations : TSCA 5(a)2 final significant new use rules: Polycarboxylate salt
TSCA 12(b) one-time export: No products were found.
TSCA 12(b) annual export notification: No products were found.
United States inventory (TSCA 8b): All components are listed or exempted.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: hydrogen sulphide
United States - Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) :
List name Status Ingredient name Name on list Conc.
United States - Clean Air Act Section Listed Diethanolamine Diethanolamine 1-5
112(b) Hazardous Air Pollutants
(HAPs)
United States - Clean Air Act Section Listed Methanol Methanol 20 - 30
112(b) Hazardous Air Pollutants
(HAPs)
United States - Clean Air Act Section Listed Hydrogen sulfide Hydrogen sulfide 0 - 0.1
112(b) Hazardous Air Pollutants
(HAPs)
United States - Clean Air Act Section Listed 1,4-Dioxane 1,4-Dioxane 0 - 0.1
112(b) Hazardous Air Pollutants
(HAPs)

SARA 302/304
SARA 302 TPQ SARA 304 RQ
Name % EHS (lbs) (gallons) (lbs) (gallons)
Hydrogen sulfide <0.1 Yes. 500 - 100 -
SARA 311/312
Classification : Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
SARA 313
Product name CAS number %

Supplier notification Isopropanol 67-63-0 30 - 40

Methanol 67-56-1 20 - 30
Butanol 71-36-3 5 - 10
Diethanolamine 111-42-2 1-5
California Prop. 65

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Section 15. Regulatory information

WARNING: This product can expose you to chemicals including 1,4-Dioxane, which is known to the State of
California to cause cancer, and methanol, which is known to the State of California to cause birth defects or other
reproductive harm. For more information go to www.P65Warnings.ca.gov.
Canada
Canada (CEPA DSL): : All components are listed or exempted.

Section 16. Other information

National Fire Protection Association (U.S.A.)

3 Flammability BPC
Health 2 0 Instability
Special

History
Date of printing : 1/16/2020
Indicates information that has changed from previously issued version.
Notice to reader
NOTE: The information on this SDS is based on data which is considered to be accurate. Baker Hughes, however,
makes no guarantees or warranty, either expressed or implied of the accuracy or completeness of this
information.

The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may
be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim
liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or
disposal of this product.

This SDS was prepared and is to be used for this product. If the product is used as a component in another
product, this SDS information may not be applicable.

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