1

XII M-1, M-2 BATCH

PART TEST (CHEMISTRY)
Solutions, G.O.C., Kinetics, Haloalkanes, Haloarenes Electro, Alc. Phenol, Ethers
Time : 1.40: Min. (Marking Scheme +4, –1, 0) Date: 21/12/2024 M.M. : 200
SECTION-A: SINGLE CORRECT CHOICE
This section contains 40 QUESTIONS. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE Option is correct.
1. The vapour pressure of an aqueous solution of glucose is 750 mm of Hg at 373 K. the molality is
(a) 0.64 (b) 0.741 (c) 0.68 (d) 0.94
2. The wt. of solute (M= 60) required to be added in (180g of water to reduce the vapour pressure 4/5 th of pure
water is :-
(a) 140 g (b) 134 g (c) 150 g (d) 240 g
3. Which of the following compound is incapable of exhibiting tautomerism

O O
(a) (b)
O O

(c) O O (d) CH CH OH

4. At 363 K, the vapour pressure of A is 21 kPa and that of B is 18 kPa. One mole of A and 2 mole of B are
mixed. Assuming that this solution is ideal, the vapour pressure of the mixture is ...........kPa. (Round off to
the nearest integer).
(a) 19 (b) 20 (c) 33 (d) 44
5. A 1 molal K 4 [Fe(CN)6 ] solution has a degree of dissociation of 0.4. Its boiling point is equal to that of
another solution which contains 18.1 weight per cent of a non-electrolytic solute A. The molar mass of A is
................. u. (Round off to the nearest integer). [Density of water = 1.0 g cm3 ]
(a) 90 (b) 85 (c) 75 (d) 95
6. 2 molal solution of a weak acid HA has a freezing point of 3.885C. The degree of dissociation of this acid
is.............. 103 (Round off to the nearest integer). [Given: molal depression constant of water =1.85 K kg
mol1 , freezing point of pure water =0C]
(a) 30 (b) 40 (c) 50 (d) 75
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7. A solute a dimerises in water. The boiling point of a 2 molar solution of A is 100.52C. The percentage
association of A is..............(Round off to the nearest integer). [Use: K b for water  0.52K kg mol1, boiling
point of water =100C]
(a) 200 (b) 300 (c) 400 (d) 100
8. The vapour pressures of A and B at 25C are 90 mm Hg and 15 mm Hg respectively. If A and B are mixed
such that the mole-fraction of A in the mixture is 0.6, then the mole fraction of B in the vapour phase is
x  101 . The value of x is....................... (Nearest integer).
(a) 1 (b) 3 (c) 4 (d) 5
9. CO2 gas is bubbled through water during a soft drink manufacturing process at 298K. If CO2 exerts a
partial pressure of 0.835 bar then x m mole of CO2 would dissolve in 0.9 L of water. The value of x
is............ (Nearest integer) [ K H  1.67 103 bar ]
(a) 30 (b) 25 (c) 15 (d) 10
10. When 3.00 g of substance 'X' is dissolved in 100g of CCl4 , it raises the boiling point by 0.60 K. The molar
mass of the substance 'X' is.............. g mol1 . (Nearest integer) [Given, K b for CCl4 is 5.0K kg mol1 ]
(a) 125 (b) 175 (c) 250 (d) 300
11. The boiling point of an aqueous solution of a nonvolatile solute is 100.15°C. What is the freezing point of
an aqueous solution obtained by diluting the above solution with an equal volume of water? The value of K b
and K f for water are 0.512°C and 1.86°C molality-1 respectively.
(a) 0.544C (b) 0.52C (c) 0.272C (d) 1.86C
12. Acetic acid exists in benzene solution in the dimeric form, in an actual experiment the Van’t Hoff factor was
found to be 0.52. Then the degree of association of acetic acid is
(a) 0.48 (b) 0.88 (c) 0.96 (d) 0.52
13. In the reactions given below. The compounds A and B are
R–Cl 
KCN
 product A
R–Cl 
AgCN
 product B
(a) chain isomers (b) position isomers
(c) functional isomers (d) metamers
14. Which is the correct reaction coordinate diagram for the following solvolysis reaction?
CH3 CH3 OH
H2O
Br OH + CH3
Potential energy
Potential energy

(a) (b)

Reaction Coordinate Reaction Coordinate

Potential energy
Potential energy

(c) (d)

Reaction Coordinate Reaction Coordinate

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15. Identify the incorrect statements about the following reactions:
 
CH3–CH2–CH2–CH2–CH2–CH(Br)─CH3 CH
3CH
2O
K
P
CH CH2OH

CH3
CH3–C–O–K+

CH3–CH2-CH2-CH2-CH2-CH(Br)─CH3 CH3
Q
CH3CH2OH
(a) P and Q are geometrical isomer.
(b) P is more stable than Q.
(c) There is change in optical property of the reaction mixture as reaction proceeds.
(d) Equimolar mixture of P and Q will give zero optical rotation.
16. Which of the following is incorrectly matched? (G = Free energy)

G G G G
c d
a b

Progress Progress Progress Progress

(a) E2 reaction with Keq< 1 (b) E1 reaction with Keq> 1
(c) SN1 reaction with Keq> 1 (d) rapid E2 reaction with Keq> 1
17. (I) 1, 2-dihydroxy benzene (II) 1, 3-dihydroxy benzene
(III) 1, 4-dihydroxy benzene (IV) hydroxy benzene
The increasing order of boiling points of above-mentioned alcohols is
(a) I < II < III < IV (b) I < II < IV < III
(c) IV < I < II < III (d) IV < II < I < III
18. What is the role of H+ in this reaction?
+
H3O
+ H2O
OH
(a) Nucleophile (b) Catalyst (c) Leaving group (d) Base
19. Which of the following are the starting materials for the Grignard synthesis of tert butyl alcohol?
(a) CH3MgBr + CH3COCH3 (b) CH3CH2MgBr+ CH3COCH3
(c) CH3MgBr + CHCH(OH)CH3 (d) CH3MgBr + (CH3)3CH
20. Which is the best synthesis of 2-pentanol?

(a) 
(i) Hg(OAc)2 /H2 O
(2) NaBH
 (b) 
(i) Hg(OAc)2 /H2 O
(2) NaBH

4 4

(c)  (i) BH3

(ii) H O /HO
 (d)  (i) BH3
(ii) H O /HO

2 2 2 2

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21. Consider the following reaction,
H H
H H H2O2/NaOH
(i) BH3 B B OH
H Step -1 Step -2
Step -1 H
Which one of the following statements is incorrect?
(a) In step 1, the boron atom acts as a Lewis base
(b) In step 2, the boron atom is oxidized by hydrogen peroxide
(c) The borane addition occurs with syn-stereospecificity
(d) In step 1, a hydride is added at carbon 2.
22. Predict the major product of the following reaction.
H2SO4

OH

(a) (b) (c) (d)

23. Which of the following compound is most reactive with HCl in presence of anhydrous ZnCl2 (Lucas
reagent)?
Cl

(a) CH2OH (b) OH (c) CH2OH (d) CH2CH3

24. The conversion of ethanol to propanenitrite is best done by

 
(a) CH3  CH2  OH  KCN   (b) CH3  CH2  OH  HCN  

(c) CH3  CH2  OH 

(i) TsCl / Pyridine
(ii) KCN
 (d) CH3  CH2  OH  CH3CN 


25. Which chloroderivative of benzene among the following would undergo hydrolysis most readily with
aqueous NaOH to furnish the corresponding hydroxy derivative?
NO2
(a) O2N Cl (b) O2N Cl
NO2

(c) (CH3)2N Cl (d) C6H5Cl

26. Which of the following alcohols have highest solubility in water at 25°C?

(a) CH3OH (b) OH (c) t-butyl alcohol (d) Isobutyl alcohol

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27. Reagent - I and II are respectively
COOH CH 2OH
Reagent  I

 
Reagent  II

(a) [LiAlH4] and [ H / KMnO4 /  ] (b) [NaBH4] and [ H / KMnO4 /  ]

(c) [NaBH4] and [PCC] (d) [LiAlH4] and [PDC]
28. When phenol is treated with excess of bromine water, it gives
(a) m-bromo phenol (b) o- & p-bromophenol
(c) 2, 4-dibromophenol (d) 2, 4, 6-tribromophenol
29. Which one of the following compounds gives aspirin on reaction with acetic anhydride in presence of
H2SO4?
OH CHO CHO OH
COOH COOH OH
(a) (b) (c) (d)

NH2
OH

OC H
30. + C2H5I 2
5 
anhy. C2H5OH

(a) C6H5I (b) C2H5OC2H5 (c) C6H5OC6H5 (d) C6H5OC2H5

31. By passing 0.1 Faraday of electricity through fused sodium chloride, the amount of chlorine liberated is
(a) 35.45 g (b) 70.9 g (c) 3.545 g (d) 17.77 g
32. What is the potential of half - cell consisting of zinc electrode in 0.01 m ZnSO4 solution at 25C ( EOP0 =
0.763 V for Zinc Electrode)
(a) 0.8221 V (b) 8.221 V (c) 0. 5282 V (d) 9.282 V
33. The hydrogen electrode is dipped in a solution of pH =3 at 25C. The potential of the cell would be (the
value of 2.303 RT/F is 0.059 V)
(a) 0.177 V (b) 0.087 V (c) –0.177 V (d) 0.059 V
34. When the sample of copper with impurity is to be purified by electrolysis, the appropriate electrodes are
Cathode Anode Cathode Anode
(a) Pure zinc Pure copper (b) Impure sample Pure copper
(c) Impure zinc Impure sample (d) Pure copper Impure sample
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35. In a solution of CuSO4 how much time will be required to precipitate 2 g copper by 0.5 ampere current?
(a) 12157. 48 sec (b) 102 sec (c) 510 sec (d) 642 sec
+
36. What will be the emf of the given cell, Pt | H2 (P1) | + H (aq) | H2(P2) | Pt
RT P1 RT P1 RT P2
(a) ln (b) ln (c) ln (d) None of these
F P2 2F P2 F P1
37. Which of the following reaction is possible at anode?
(a) 2Cr3+ + H2O  Cr2O72- + 14 H+ (b) F2 2F-
1
(c) O 2 + 2H+ +  H2O (d) All of these
2
38. On the electrolysis of acidified water, if volume of hydrogen liberated is 5.6 cm 3,then the volume of oxygen
liberated is equal to
(a) 2.8 cm3 (b) 5.6 cm3 (c) 8.4 cm3 (d) 11.2 cm3
39. The solubility product of a saturated solution of Ag2CrO4 in water at 298 K if the emf of the cell
Ag|Ag+(satd. Ag2CrO4 soln.) || Ag+ (0.1 M) | Ag is 0.164 V at 298 K will be
(a) 2.287  1010 mol3 L3 (b) 2.287  1011 mol3 L3
(c) 2.287  1012 mol3 L3 (d) 2.287  109 mol3 L3
40. During the electrolysis of acidulated water, using inert electrodes, the total volume of the gases collected at
STP is 1.68 L. The amount of electricity passed through water is
(a) 1 F (b) 0.5 F (c) 0.2 F (d) 0.1 F.

SECTION – B : INTEGER TYPE

This section contains TEN QUESTIONS. The answer to each question is a Single or More digit
Integer ranging from 0 to 999. The correct digit below the question number in the ORS is to be bubbled.
1. Number of open chain isomers possible for C4H8 are ______
2. How many structural isomers are there of C4H10O that are ethers?
3. How may structural (including stero isomers) isomer could be obtained by replacing one hydrogen of
propane with chlorine.
4. When 9.45 g of ClCH2COOH is added to 500 mL of water, its freezing point drops by 0.5C. The
dissociation constant of ClCH2COOH is x 103 . The value of 10x is.................. . (Rounded off to the
nearest integer) [ Kf (H2O)  1.86K kg mol1 , Atomic Mass of Cl=35.5, density of water = 1g/mL]

5. The reaction 2A  B2 
 2AB is an elementary reaction. For a certain quantity of reactants, if the volume
of the reaction vessel is reduced by a factor of 3, the rate of the reaction increases by a factor of ..............
(Round off to the nearest integer).
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6.  2NOCl(s) . This reaction was studies at –10C and the following data was obtained
2NO(g)  Cl2 (g) 
run.
[NO]0 [Cl2 ]0 r0
1. 0.10 0.10 0.18
2. 0.10 0.20 0.35
3. 0.20 0.20 1.40
[NO]0 and [Cl]0 are the initial concentrations and r0 is the initial reaction rate. The overall order of the
reaction is.................... .(Round off to the nearest integer).
7. A reaction has a half-life of 1 min. the time required for 99.9% completion of the reaction is.......... min
(Round off to the nearest integer). [Use: ln 2= 0.69, ln 10 = 2.3]
8. The inactivation rate of an viral preparation is proportional to the amount of virus. In the first minute after
preparation, 10% of the virus is inactivated. The rate constant for viral inactivation is ..... 103 min 1 .
(Nearest integer) [Use: ln 10 = 2.303; log10 3  0.477 ; property of logarithm; log x y  ylog x ].

9. PCl5 (g) 
 PCl3 (g)  Cl2 (g) .

In the above reaction, the concentration of PCl5 requires from initial concentration 50 mol L1 to 10 mol L1
in 120 minutes at 300 K. The rate constant for the reaction at 300K is x 102 min . The value of 'x'
is..................... . [Given, log 5 = 0.6989]
10. For a chemical reaction A  B , it was found that concentration of B is increased by 0.2 mol L1 in 30 min.
The average rate of the reaction is ........... 101 mol L1h 1. (Nearest integer).
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Hints and Solution XII M-1, M-2 Batch

Section-A : Single correct type
P0  Ps w1  m2
1.[b]  (Assuming the solution to be dilute and remembering that at 373 K the equilibrium vapour
Ps m1  w 2
pressure of water is 760 mm of Hg).
P0  Ps (w1 1000) m2 m  m  molality 
   = M 2  
Ps (m1  w 2 ) 1000 1000  2
m  mol wt of solvent 
760  750 18 10×1000
  M  m= = 0.741mol /Kg of solvent
750 1000 750×18

P0  Ps w1  m2 P0  4  P0 w 18
2.[c]   5  1
Ps m1  w 2 4P0 60 180
5
60 180
  w1   150g
4 18
3. [c] Benzoquinone cannot show tautomerism otherwise indicated carbon will get sp hybridized . Due to which
bond angle should be 180°, which is not possible because the bond angle in the ring can’t be 180˚.
*
HO OH
*
4.[a] From Roult's law, pT  pA A  pBB ......................(i)

Where, pT  total pressure of solution, pB , pA  vapour pressure of pure liquid B and A respectively.
A , B  mole fraction of A and B in solution phase.

Given, pA  21kPa, pB  18kPa

n A  1, n B  2
nA 1
A  
nA  nB 3
2
B  1  A 
3
Putting the values in equation (i),
 1  2
pT   21   18    7  12  19kPa
 3  3

5.[b]  4K   [Fe(CN)6 ]4  i  1  (5  1)  0.4  2.6

K 4 Fe(CN)6 
For same boiling point
 Tb, K4 [Fe(CN)6 ]  Tb,A  (ik b m)K4 [Fe(CN)6 ]  (1 k b m)Solute A  (i  m)K4 [Fe(CN)6 ]  (m)Solute A
Now,18.1 weight per cent solution means 18.1 g solute is present in 100 g solution and hence,
(100  18.10)  81.9g water
Mass of solute
Molar mass of solute(M) 18.1 / M
Molality =  2.6 1 
Mass of solvent (kg) 81.9 / 1000
Molar mass of solute, M = 85.
6.[c] Given,

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 9
Depression in freezing point,
Kf  1.85K kg mol1
Tf  0 C
Tf  3.885 C

Tf  Tf  Tf  3.885  0  3.885 C

Tf  3.885 C
Tf  i  Kf  m
But, i  1  (2  1)  (1  )
3.885  (1  ) 1.85  2
0.185
     0.05
3.7
  50 103
7.[d] Given: Tb  100.52 C

Tb  100 C
 K b  0.52K kg mol1
Elevation in boiling point,
Tb  Tb  Tb
Tb  100.52  100
Tb  0.52 C

1   
For dimerisation (van't Hoff factor) i  1    1   1  
n   2
 Tb  i  K b  m

 
0.52  1    0.52  2
 2
 1
So, percentage association = 100%
8.[a] Partial pressure of A, pA  90 mm of Hg

Partial pressure of B, pB  15 mm of Hg

Mole fraction of A, A  0.6
Mole fraction of B, B  0.4
pT  A pA  B pB  (0.6  90)  (0.4 15)  54  6  60mm
Now, mole fraction of B in vapour phase, i.e.
p B B pB
YB    0.1  1 101
pT 60
x 1
9.[b] According to Henry's law, pCO2  K H XCO2

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 10

pCO2  K H and XCO2 are pressure of CO gas. Henry's constant and mole fraction of CO respectively.

pCO2
 XCO2  ..................(i)
KH

Given, K H  1.67 103 bar

pCO2  0.835 bar

Put all values in equation (i), we get

0.835
XCO2 
0.835  103  2
XCO2  0.5 103
Volume of water = 0.9 L = 900 mL
Density of water = 1g/mL
Mass of water = density × volume = 900 g
900
So, number of mole of water   50moles
18
n CO2
So,  0.5  103
n CO2  n H2O

n CO2  H2O  50moles

So, n CO2  n H2O  H2O

n CO2  0.5 103  50  25 103 mol

Millimoles of CO2  0.025 1000  25

10.[c] Weight of substance 'x' = 3.00g
Elevation in boiling point, Tb  0.60

K b ( boiling constant) of CCl4  5K kg mol1

3
Molar mass of compound
Molality (m)   M ...............(i)
Volume of solution (in L) 100
1000
Formula, Tb  Kb  molality
3
3  1000
Put value of (i) we get, 0.60  5  M  0.60  5 
100 M  100
1000
150
0.60M  5  30  M   250
0.60
Molar mass of substance 'x' is 250 g mol1 .
11.[c] For the same solution
Tf K f K 0.15 1.86
  Tf  f  Tb  Tf   0.545
Tb K b Kb 0.512
On diluting the solution to double

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 11

1 0.545
Tf   Tf   0.272   Freezing point = - 0.272
Wt. of solvent 2
12.[c] 2CH3COOH  (CH3COOH)2
1 0
(1-) /2
i = 1-/2  = 2×(1-i)  2(1-0.52) = 0.96
13.[c] R – Cl 
KCN
 R  CN
R – Cl 
AgCN
 R  NC
14.[b] In Solvolysis (Neutral nucleophile), three transition states are formed. If Nucleophile is negatively charged
than only two transition states are formed.
Potential energy

 
R   Br
 
R   OH 2

R+ 
R  OH   H



R  OH 2

Reaction Coordinate
15.[a] CH3 – (CH2 )4 – CH  Br  ─CH3 

 CH3 – (CH2 )3 – CH  CH─CH3
CH3CH2 O , Strong base
Settzeff product

CH3 – (CH2 )4 – CH  Br  ─CH3 


  CH3 – (CH2 )4 – CH  CH 2
(CH3 )3 CO , Strong hindered base
Hoffmann product

16.[b] For ‘b’ G is positive hence Keq<1.

17.[c] Boiling point increases with increase in intermolecular hydrogen bonding.
In 1, 4–Dihydroxy benzene intermolecular hydrogen bonding occurs. Therefore it has highest boiling point
whereas hydroxy benzene consist of only one –OH group therefore the intermolecular hydrogen bond are
weak.
18.[b] H3O+ used in small amount to increase rate of reaction. H3O+reagenerates at end of reaction
19.[a] Tertiary alcohols are prepared by the reaction of a Grignard reagent with a ketone followed by acid
hydrolysis.
H O
CH3MgBr + CH3COCH3 (CH3)3COMgBr 
2
 (CH3)3OH
20.[a] In (b) and (d) ‒ The mixture of product will be obtained

21.[a] In step 1, BH3 act as Lewis acid.

22.[c]
CH3 H3C H3C
H CH3
CH3 CH3
1,2  methyl shift
  H3C   H3C
Hydrogen
H3C
H3C  Abstraction
CH3
CH3

ZnCl2/HCl
23.[c] CH2OH CH2 – Cl + Zn(OH)Cl
benzyl alcohol
Though benzyl alcohol is a 1º alcohol, it reacts vigorously with Lucas reagent, since
benzylic carbocation is very stable.
24.[c] –OH is bad leaving group (in absence of H+); while –OTs is good leaving group.
Weak acid HCN is unable to protonate ROH

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 12

25.[a] Greater the number of electron withdrawing group present at o& p positions, easier the nucleophilic
substitution.
26.[a] As the number of carbon atom increases solubility decreases
27.[a] LAH reduces carboxylic to alcohol whereas KMnO4 oxidizes primary alcohol to carboxylic.
OH OH
Br Br
28.[d]
+ Br2(excess) 

Phenol
Br
2,4,6-Tribromophenol
29.[a] Salicylic acid gives aspirin on reaction with acetic anhydride in the presence of H2SO4.
OH OCOCH3
COOH COOH
+ (CH3CO)2O 
H2SO4

Salicylic acid Aspirin

OH O– OC2H5
–
OC2H5 C2H5–I
30.[d]

1
31.[c] Cl- Cl2 + e-
2
i.e. 1 Faraday liberates Cl2 = 1/2 mol = 35.45 g
 0.1 Faraday will liberated Cl2 = 3.545 g
0.0591 1
32.[a] Zn2+ + 2e- Zn, E = E– log
n  Zn 2  
 
0.0591
= – 0.763 + log102  0.822V or Eox = 0.822 V
2
33.[c] H+ + e- 1/2 H2
0.059 1 0.059
E = E - log   0  pH
n H  1
 
= – 0.059  3 = – 0.177 V
34.[d] Impure sample is made the anode and pure copper as the cathode
35.[a] Cu+ + 2e- Cu,
63.5 g of Cu require 2 96500 C, Hence 2 g will require
2  96500
Q= 2 = 6078.7 C
63.5
Q 6078.7
t =   12157.4 sec
I 0.5
 H2(P2)
36.[b] R.H.S 2H+ = 2e- 

 2H+ + 2e-

L.H.S. H2(P1) 

 H2(P2)
Overall reaction: H2(P1) 
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 13

RT P2 RT P2 RT P1
E =E- ln  0  ln  In
nF P1 2F P1 2F P2
37.[a] Oxidation takes place at anode viz (a)
38.[a] H2O  H2 + 1/2 O2 i.e. vol of O2 liberated is half that of H2.
0.059 [Ag  ]R.H.S
39.[c] Ecell = log10
1 [Ag ]L.H.S
0.059 0.1
0.164 = log or [Ag+]L.H.S. = 1.66  104 M
1 [Ag  ]L.H.S

1.66  104
So [CrO 24  ] 
2
 1.66  104 
Ksp(Ag2CrO4 )  [Ag  ]2 [CrO42 ] = (1.66  104)2  12 3 3
 = 2.287  10 mol L
 2 
40.[d] The volumes of O2 and H2 obtained on the electrolysis of water of water are in the ratio
1 2
1: 2. Hence volume of O2 = × 1.68 = 0.56 L and volume of H2 = × 1.68 = 1.12 L.
3 3
2H+ + 2e  H2
22.4 L of hydrogen liberated required = 2 F
2
1.12 L of hydrogen liberated required =  1.12  0.1 F
22.4
1
20H O 2  H2 O  2e 
2
11.2 L of O2 required = 2F
2
0.56 L of O2 required =  0.56  0.1F
11.2
Section-B: Numerical Value type
1.[4]
H3C CH3 H3C H H CH2 CH3
H3C H
C C C C C C
C C
H H H CH3 H H
H3C H
cis trans
2.[3] Three These are:
CH3OCH2CH2CH3, CH3-O-CH(CH3)2 and CH3CH2OCH2CH3
3.[4]
H3C H
Cl CH3 ,
Cl H
H3C H H3C Cl
and
H Cl H H

4.[344]
 ClCH2COO  H
ClCH2COOH 

t 0 1 0 0
at t  t 1   

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 14

Final moles
Here, i 
Initial moles
i  1       i  1 
Formula used for freezing point; Tf  iKf m
Here, K f  freezing constant of H2 O

Kf (H2O)  1.86K kg mol1

m = molarity
Tf  iKf m
(9.45 / 94.5)
0.5  (1  )(1.86)
(500 / 1000)
5 5 1.28 32
1   1        0.344
3.72 3.72 3.72 93
5.[27] Given, the reaction 2A  B2  2AB is an elementary reaction.
So, rate of reaction  k[A]2 [B2 ]
Initial rate k(a / V)2 (3b / V)1
Where, a and b are the number of moles of A and B and V is the volume.
On reducing the volume by a factor of 3, the concentrations of A and B2 will become 3 times
Final rate k(3a / V)2 (3b / V)1
2 1
a b
32  3k      27  initial rate
V V
Hence, the rate becomes 32  3  27 times of initial rate.
6.[3] According to given reaction,
 2NOCl(s)
2NO(g)  Cl2 (g) 
Given data are as follows,
By rate law expression, r  k[NO]x [Cl2 ]y
Exp (1) 0.18  k(0.1) x (01.) y ..............(i)
Exp (2) 0.35  k(0.1)x (0.2) y ..............(ii)
Exp (3) 1.40  k(0.2)x (0.2) y ..............(iii)
Dividing equation (ii) and (iii), we get
0.35 k(0.1) x (0.2) y

1.40 (0.2) x (0.2) y
x
1 1
  x 2
4 2
Similarly dividing equation (i) and (ii), we get
y
1 1
    y 1
2 2
Now, x  y  order of reactions
x  y  2 1 3
Overall order of the reaction is 3.
1 C 
7.[10] Using formula, k  ln  0 
t  Ct 
ln 2
As k 
t1/ 2

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 15

t1/2  1min [Given]

ln 2 1  100  ln1000
  ln   t 
1 t  0.1  ln 2
3  2.3
t  10
0.69
8.[106] Unit of rate constant is min 1 , so it must be a first order reaction.
A
For first order reaction, k  t  2.303log 0
At
k is the rate constant t is the time
A 0 is the initial concentration
A t is the concentration at time t.
Using formula, A0  100, At  90in1min
100
So, K  1  2.303  log
90
 2.303  (log10  2log3)  2.303  (1  2  0.477)
 0.10593  105.93 103  106
Hence, the rate constant for viral inactivation is 106.
9.[1] PCl5 (g) 300K
 PCl3 (g)  Cl2 (g)
It is of first order reaction
t 0 50 M
t  120min 10M
2.303 [A ]
For first order reaction, k  log 0
t [A t ]
[A0 ]  initial concentration of PCl5
[A t ]  concentration of PCl5 at t = 120 min
2.303 50
k log
120 10
2.303
  0.6989  0.013413min 1  1.3413102 min 1
120
1.34  1
10[4] Reaction, A   B
At t=0 0
At t=30 min 0.2M
Here, initially at time zero, reaction is constant but after 30 minutes concentration of B is increased by
0.2 mol L1 .
Average rate of reaction
[A] [B] (0.2  0)
    0.4mol L1h 1  4 101 mol L1 h 1
t t 1
2
*****

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