oA3

.~f:(;TJON
•Ill
A
. II,. I '"' ',,.,./! /',,. I, ,111011,,11 "
1 1
I
w fi~ ,,.;.,, q,,,.,,,,•...,, .,,,,,rrM, 1,,,1,, ,,,,.•11 ,,,,, " • " " '' '

1
Jl,rrt' ,. ,,,, /nlr'I '"'', 1,,,1, II,,, ,1,1., .,l'I (/111/ ,
,1"'"" ,11, ,11,i" ,1 ,·rIr) I , Ir I," rd,· ,.,11, ,w,·,11 ') ,r,11 """ , •I I Irr· ,, "II rr, · ", 1," "II·d IV• I Ir I I II 1,/, • r,/ rr 11·

,Ill 111111111• 11,,11

.,Rll'i"S"·" ~
r, wil h "'" ,l,,•1 ,.-,r~•'" r '" '"" rr ,, I'" 11 lrrd ,,.111/tlr i11 ,111 ,r /k,, h
h 1 111c,11 IIPII ll'ilh 11/lrtlll' ,111d. prndt11l'd 11111111:crr g,1,
' 1 r, wil Ir l11•111,·rr,·,11iplu•11rl , Ir hII 1,k '" I, rr II, ,, I'"" I111 I Ih,r I i, i11wl11 I•k 'II ,11k II Ii
,..,.,

ii. d11r., 11111 n'oll I wtlh 11111,lil'I~ ll',r 8cr1t.

\I'hi,.'. "'" "' Ih,· ,.,/luwo II~ ha., Ih,· hl~h,•,1 ,I' I'""' "" "' 11•11 I/
,I. ( II I I·
Ii. C'I l1< I
c. CII 11
d. CIIJJI,
,
lhl' pr<1pl'I1 I , HfVt'll
M,,ILh<.ol,nnn ,1, . , Ill
, 111 w/1111111 I with ti II , 11111,,1. . 'Hl1111111 11

(A)
(i) Al tinoid h•il'in gu111hg11r,1t1011
, /Rn/ 51 76i 7,.!
14 'J '
tlt·dronk io11tig111,1lio11 J/1
, ,J ox1d
. 1· (H)
a1i1111 ~l,tll' J ,011 Sl,tlt'
d (L)
 I f
ol hr , n• 11 n
,iud~ th, gr ph i;ho"1n"' the b0 lin' p(I nt llofllnfl polnh ol hn,n-M>aU.Anc•
4,

Ill 100
0
0 2
Bromoa1kanc

Bc<>n><>mcth,,ne, 2 2 Brnnmhutauc, ' I llrnmohutanc, 4 2 Bromo 2 methjlp,opane

1 llo,,nohut,,nc, 2 2 B,omo-2 mcthylpmpanc, 3 - 2 Bromobntanc, 4 !lromomethane
a
llrnmoone<h.one, 2 = I Brnmubutanc, 3 = 2- llromo 2-methylpropanc, 4 2 Bromobutanc
h.
d. 1 = llromoowthane, 2 = 2-Brnmo-2-mcthylpropane, 3 =2 Brnmobutanc, 4 J Bromobutane
➔ P ;, 4.62 x JO
L
2
1h•· ,o ,,;,I concent, at ;on of R ,n the react ;on R mol/L. What ;s the half hfc for the rcacuon
5. 1 1
2
if k 2J I x 10 mol L s ? b. 3s
a. 30 s d. 10 s
C. 1 !,
6 When C H~COOCOCI-l3 is treated with I 120, the product obtained is
11
a. benzoic acid and ethanol
b. benzoic acid and ethanoic acid
c. acetic add an d phenol
d. benzotL anhydride and methanol.
--------
Formulation of Cobalt(III) Choride-Ammonia Co~ ; - -
7.
Solution conductivity corresponds to
Colour FormuJa
y
Yellow
r - - - - - + - - - - ~ l~:2 electrolyte
1 : 1 electrolyte

able are
Cl , Y = 1 : 3 b. X = [Co(NH3)4Cl2t ci-, y = 1 : 3
+c1 , Y= 1:1 d. X = [Co(NH3),iCl2]3+3Cl , y = 1 . 1
sonly ~ D-glucose as its monosaccharide unit ? .
b. Cell ulose
d. Maltose
ctly represents bth e increase
T3+ 1.1 th e par.,amagnetic property of the ions?
in 2+
• I < iv n < Fe~ .. < Cr· +
d• T3t
J < Cr 3+ < Fe2 <: ~1n2+

te constant, k _ 5.5 x 10-14 .s-1 . The time

. • completion of
taken tor

13
b. 2.52 X ]0 S

d. it nt'ver goes to completion.

23
 11 \ 111(1, 11 p 11111 1 11111111 l11 iii I ,I, orr,r• ,ur I
I I\ 11 al I lftllhl hl lh (tfllJ Pllll•I
i1 N1lt I I,
II I) llllllrlh d
) l
\\ 1111 Ii 111 tit, 1ollt,w111g 11111,p,,111,d 1•1w Ill oxtrnt Wallt hydmiyl n 111 ,

11 1 11 ,1 I 11 11 , h ll LOUIi
{t Ii < ( j( I
(I 11 11 ()) 11 d
I 1, \s,,., 111111 (,\) I li\111(1 NJ,,I' "1 l Ill 1r11ct11 lllllllltfll ol l\'lfl UIJJJdlrcd ti•
11,1 1 1m 1g1wl11 111111111•11111J l11u1 111111,1111.: d I I, l.11 1,11
l(,•u,011 (H) : ll\111(1 NJ,,!' 1 1111111 11i1 11 1,d t11111pl x 111volv1ng ti /' hybrid, 1t rm ,
I~ In< lel' 1s, 11111°1 111 '111 .,I 111111pl1•x 111volv1ng ,,Jd'
hyl,r 1d1',alJ1Jn .
Sl'11·, I 1111' 11111, t 111•p1np11.,11° ,111 ~w, 1 f 1rn11 tlw opl11,r, • given below
., 1111th ,\ ,111d It oil( II Ill' ,\IHI I{ I\ Ili c llJ I 1et..11•xpl.1lJ.Jtll/ll r,I A
h 1111th A .111d I{ ,111• 11 Ill' lnal I{ I\ 111,t tlu co11 c1 I explan,111,,n c,f A
,. J\ ,, II II\' li111 I{ h l,d o;1•.
d ,\ 1, f.11,1 h11t ll is 11111·

I •I. A,sl'rlion (A) : I 01 ~, 1011g l'lt·ll Iolyll'~, tlinl' i\ ,1 ~lr,w inuca<;e rn m<Jlar conductivity w th d
lw 1q 111·~rnlt'd hy llw 1·q11,111011
\ I,
' A,,I I\,
lk,1,on (R): '(he v,1h1l' of IIH' wmt,1111 'A' fo1 NaCl, CaU , and MgSO m a given s.olveru,
kmpt·1,1tun• 1s ddll'l l'lll. 2 4

~l'll'l t tlw mm1 ,1pprnpn,1ll' ,lllSWl'r frnm the option~given bcl,,w .

.i Both A ,ind R ,lll' t1 ue ,md I{ is thl' rnrrect explanation of A.
b. Both A ,md R ,Ill' t1 uc bu1 R is not the corm.I explanation of A.
A 1s Intl' but R is f,11-.l'.
d A i-. f,1l11l' but R 1'> lrul'.

15. Assertion (A) : C,lurnsl' does not form the hyJrogcmulphitc addition produc t with NaHSO.
Rca,on (R) : Glucose exists 111 a six membered cyclic structure called pyranose structure.
~dell the most appropnak amwcr from the option~ given below:
a Both A and R are true and R is the correcl explanation of A.
b. Both A and Rare true but R 1s not the correct explanation of A.
c. A is true but R I'> false.
d. A 1s false but R JS true.

16. As,erlion (A) : The half-life for a zero order readion is independent of the initial concentr2t.
rcaLtant.
Reason (R) : I·or a 1cro order reaction, Rate - k.
Select the most appropriate amwer from the options g1H·n below:
a. Both A and Rare true and R Js the correct explanation of A.
h. Both A and Rare true but R Js not the correct explanation of A.
c. A is true but R 1s false.
d. A is false but R is true.

SECTION B
is sat ion contains 5 questions wW1 internal cl1oice in one question. The followi11g qmstiom art 1 ~
er typt• and carry 2 marks eac/1.
N'ttrogc-n ga!-t is solublt' in water. At temperature 293 K, the value ot K
solubility of nitrogen vaq (mcrea,e, decrease or remam the same at
e value of KH nse~ to 88 8 kbar?
 I h ,, h 1111 l ht" I
l I Ill !hi 1111 "" I ,,
pl II 1,111 1 I f 11111 I
,Jttl l tit Oil

rt Ih 1' 111 l I, II l ti h' • II h I I I I ti rt

I\ I I11
1•1

11 1i, 111 ii II I t I
"r " ,1 111 I ' 1t1 111, ll i "'I th1 h I ih " ' I' I
)111\\ ,1, 11 ~ llf I
1, ll l'Al tllllll ttl lhl h Ihm llll 4 ""'I I i I I• rtl I <, fC ,,
th { ,,thr , ,l,\ltlllll't•Ufltiol{llll 1111 I ,, ol
\\111
11 0 111
1\-'' 11 tltl 11Hh11I''' ru
1
rfi
11 \HI ilu ljll H11n 1l111 lllllo~
•hr t,, 11 ,m1111 l( 11 11111 111

t 9,
pt, l\ '

~< I l< I

1u,,,, sl'tll 1h1• 'l'll sl111\\ II Ill 1lw hg111l'

,t
r-,:,
11111
, 1hc1,111il'1 s 11I tl11•1 u1111 11t 111 lltC'~.,1t hndgt.:
I,, l
\\', 1 •
11
thl' H'.ll lllHI t,1k111g phH l' ,11 till' ,111od1·
1
c Jktc thl' tollow111g 11\11 t1n11 s by w, it111g till' 111,1J111 .111d 111111or prod11d 111 cac.h case (any 2)
io. 111111
,I
l lJ 1Clt..B1 ~
I KCN ►
b. l 11 1( 11,C 11 Cl I, I 111\1 >
l, (C:111),CIH llCltll1 I ,Ill KOii - )
.21. 'Jlw prc~l'llll' of C.nbonyl gHn1p 111 glu10Sl' ts rnnhrmt<l by it~ reaction with hydroxylamine. Identify the
typl' of 1,1rbonyl group pt"l'St'lll .111d ,ts pos1l1on. ( ,1vc <l chemical rcallton in support of your answer.

SECTION C
nco,itai11s 7 questio11s with i11ter11al choice in one question. 1he following questions are short answer

Write down the reaction <KC urring on two inert electrodes when electrolysis of copper chloride b done.
What will happen if a concentrated solution of copper sulphate is replaced with copper chloride?
Write an expression for the molar conductivity of aluminium sulphate at infinite dilution according to
Kohlrausch law.
unt for the following:
1he lowest oxide of transition metal is basic, and the highest is acidic.
Chromium is a hard metal while mercury is a liquid metal.
The ionisation energy of elements of the 3d series does not vary much with increasing atomic number.
Give the chemical reaction involved when p-nitrotolucne undergoes Etard reaction.
Ydoes benzoic acid exist as a dimer in an aprotic solvent?
ene on reaction with methyl chloride in the presence of anhydrous AICl 3 forms toluene. What i~
cted outcome 1f benzene is replaced by benzo1c acid? Give a reason for your answer.
25
 OR • ,., I
I0 I . ndt•ns.111011. HmH•,·c-r X. wit l compound 'i"
An mgan11. . compourllI ,
·x d(le~ ,wt undergo aI( to liph~nylpiop-2 en- I one. tn
presrn~c of 11 strong ba~c 1t~lll 10 g1~e the cornpounc; • t 11 3
:\. ldl'nlily 'X' ,md ')~
\\'11tr the d1c1111c ti II :ll IH•n 11n11h-ul . ,
h. < ,I\\' tlllt l hc1111t.. 1d tc~t to d1st111guish hct\\'i.'l 11 X.111d }• . .
~ . I when the folluwmg two ,1n11no acid
2S. n. t,1,e the st1 udt1ll o( nll tlw pm~ilM d1pepllt1cs ornH t s f\/rlll
pq1thk bond.
Alanine
0
Il;C+()JI
Nll 2
c;l>dne
0
Il2N ,)l_CH I
h. Keratin, msulin, and myosin are a few examples of proteins present in the human body. ldentifywh
type of protein 1s keratin and insulin and differentiate between them based on their physical properti
26. Neeta wai, experimenting 111 the lab to study the chemical reactivity of alcohols. She carried out a dehydrau
reaction of propanol at I 40°C to I 80°C. Different products were obtained at these two temperatures.
a. Identify the maJor product formed at I 40°C and the substitution mechanism followed in this case.
b. Identify the maJor product formed at 180°C and the substitution mechanism followed in this case.
27. Various isomenc haloalkanes with the general formula C4H 9Cl undergo hydrolysis reaction. Among the
compound "A" is the most reactive through S~ 1 mechanism. Identify "A" citing the reason for your choic
Write the mechanism for the reaction.
28. The equilibrium constant of cell reaction :
snt;,1) +Al(,)~ Al 3+ + Snz,;q) is 4.617 x 10 184 , at 25 °C
Calculate the standard emf of the cell.
(Given: log 4.617 x 10 184 = 184.6644)
What will be the E" of the half cell A1 3+I Al , if E0 of half cell Sn 4+/Sn 2+ is o. 1s V?

SECTION D
·ng questions are case-based questions. Each question l1as an internal choice and carries 4 (2+ J+ 1)
. Read the passage carefully and answer the questions t1wt follow.
dence of the rate of reaction on the concentration of reactants, temperature, and other factors is the
general method for weeding out unsuitable reaction mechanisms. The term mechanism means all the
dual collisional or elementary processes invol\ ing molecules (atoms, radicals, and ions mcluded) that
lace simultaneously or consecutively to produce the observed overall reaction. For example, when
en gas reacts with bromine, the rate of the react um was found to be proportional to the concentration
to the square root of the concentration of Br,.
the rate was inhibited by increasmg the C(~Kentration of HBr as the reaction proceeded.'fhe~e
·
not consistent · Of a single molecule 01
wit h a mechanism involving bimolecu ]ar co 11·1~10ns

mechanism b considerably more complicated, involving the dissoaation ofbronunt

followed by reactiom. between atoms and molecules.
· h'10metry
pie that the mechanism cannot be predicted from the overa11 SIOJC
& Pearson, R. G. 0981). Kinetics and mechanbm. John W1k•y & Sons.)
ctasS 11
 ~on for the rate of f(',_;u.tlon 11nd ordC'.r for ihc ( n
"A t ,t,e c,cpre u m,,;1ne,
~- r~•c
H• t J3r2, , -.,HBr
t ,ate ,onstont for the uhov.! r,c-;i._,lon"
I t 11c <,unc.cntutton of l\r 2 ls uip\cd?
.. arc the uni sof01rc:ic ion be effcct<..-<l ·f
\-\"h.it
1
t-ft1" ,,,II th" rate <)I{
• c ~nccnuntii--in of 11.z ,, ill triple the rate uf f'c.aulc.n?
t,
,,'1111t d ugc ,n ' 1, het,~ccn
._, A nnd n. w.is cxpcrimcntolly found to be fust order wnh
....13 ,,., ,.on
tt"
• " "°"'
.. ~urP S', the rote cquot10n ls.
1, ond /l •
Rate k(fAl](~I w,,i mechonislll'I 1s l'OJ\Ststent with this cxpertmental finding?
which ,1 • 11:Sc
\\1h)'?
i\lC• Ji,1n1!>1n l
A _. c + J) (,l,1,,·)
F + C ~ H (fa"t)
r,1e.:hM''~ni 2
A+ 8-t C+ n ('-low)
c~ H (la~t)
" ,re basi, in natme. ·rhe p Kb value is a measure of the basic strength of an amine. Lowe< the val uc of
.,o. A;':,~" b,sic is the amine. The effect of substituent on the basic strength of amines in aqueous solution
;,,~determined using Htrations. The substituent "X' replaced "-CH 2 " group in piperidine (compound 1)
and propylarnine CH3CH2CH2NH 2, (compound 2).
compound l: H Compound 2: HXCH 2CH 2NH 2
(N)
X
1be experimental data is tabulated below: Substituted propylam~e- ~ - pKa
Substituent "X" 1 Electro- r\ Substituted piperidine \ pKa
negativity of X compound
compound
t
CH, - _I . 2.55 6 --\ j ]13
CH3CH2 CH 2NH 2

I
10.67 \

I
__,

\--- 3.12 l)H ·I

9 81 NH,CH,CH,NH,-
I 10.os I
I I
N I I
H
3.44 8.36 HOCH 2 CH 2NH 2 9.45
I
7.94 CH3CONHCH2CH2NH2 9.28
3.6

3.7 7.78 C6HsCONHCH2CH 2NHi

- _L
21
 (,Llllf\t H11ll Jr, Ii I( (19'i(I) Held ,ind Inductive effects o11 the base 5lrcngth~ of amines. lour11a1 OJ
Amott'nn ( hrmia,/ So.iet), 78(11 ), 2~70 2572.) 1-..
1
Mud\ che nbmc .Iota ,111d i111swcr 1hr (ollow1ng 4ucstio1w
u ·Plot u g1,1ph b, t\,ccn the clcd1011cg.itivl\y of th1.: subshtucnt v, pKb \Jluc of the corrcsPuri
:.ubstttillt d p1opyl an1111c (g1wn th11t pl{,, + pKb 14) Is thcrt' a11y rdc1tlon between the clcctronrg.li.
ot the ~ul,~11111t't1I nnd its ha~it strength?
h lhcclc. troncg.,tl\ 1l)'ol the suh~t1t11cnt "( 611 5c'ON" 1s ~.7, whc1t is the expected pKQ value of ccinipo
Ct1H~f ONIICll2< ll2N l 12? 14n,
(1) 99 (11) 9 5 (iii) 9.3 (iv) 9.1
0
c. fill pK \,thtl' ol tlw ~uh~t1tute<l pipcn<linc formell with suhslitutnt "X" ts found lo he 8 28. What
tlw t'\Pl'< kd eh lrorwg,1tivi1r of " )C'? 'I
(1) 3S (ii) 3.4 (iii) 3.8 (iv) 3.1
OR
>uit,bl,• Pl\, val"'· oft he substitut,d prnpylamh,c lo,m,d w,t b subst itueot •>.• "itl
Wha, fa th,• m<>,t 3.0?
l'll'dro1wg,11t,·ttr

(i) I0.67 (ii) I0.08 (iii) I 0.15 {iv) I I. I0

SECTION E
11,c• following q11estio11s I •
3 are ong answer tyJ,es a11d carry 5 marks eacl,. All questions liave an internal choice
1. a. A PU<pl'. colou, compound A, wh,ch ,s , stmng oxidising agent and used fo, bleaching of w~
foJlowe<l by and
rntton, s.lk othe,
strong tcxt<ie hb,e, was added to each of the
heating th,,,
test tubes ,lung with H,so, It was

A R C

Oxalic acid PbS Kl

In which of the above test tubes; A, B or C:
(i) Violet vapours will be formed.
(ii) The bubbles of gas evolved will extinguish a burning matchstick.
Write an equation for each of the above observations.
b. A metal ion M" of the fi<st trnnsit,on se,ies having d' wnfigurahon combines with thee, dideotate
ligands. Assuming 6 0 < P:
(i) Draw the crystal field energy level diagram for the 3d orbital of this complex.
(ii) What is the hybridisation of M111 in this complex and why?
(iii) Name the type of isomerism exhibited by this complex.
OR
a. Using, Valence Bond Theory identify A, B, C, D, E and Fin the following table :
- T
S.No. Complex Central Configuration Hybridisation Geometry Number of Magnetic
metal of metal ion of metal ion of the unpaired Behaviour
ion
• t- complex .._ electron
!CoF4J2- A 3d7
t
spl
+
~ lt.'lrahcdral B Paramagnetic,
[Cr(HPh (C204h} Cr3+ 1
3d -~

+ C octahedral 3 D
}
N1 3ds4s2 E F
0 Diamagnetic
ite the i<.lnic equations for the reaction of acidified K Cr O with
2 2 7
2S and (H) FeSO4

Class 12
 I1ll the following: .
Give re,1~110 ~ f cth,lllol \\ ith ,lll'l)'I "hlnnJc ts 1.:arr1ed 0111 111 the prl' encc ol pyrt<lme.
;;2. a h•rflc1Wll0 I
(1) 1 l ' ,du. than plH•no •
• tii' arc 1l"•~ '1 l • I
(u) Crt S • ., u,cd lor the prcpar,\t1on of et 1cr, Imm alkyl halide. lde11tily the alkyl bromide
• l)1~ prOlt:SS I

b. \\'1lh,1111 ~1 "d. used for the p1cpar,1tion ol 2 l-thoxy ::\ mcthylpcntanc.

idium alkox1 c
,111•I "
(011\l'fl; . · 1
C
.) ToIm•ne lo ~, nitrobcnzo1L auu.
(I . , • tl) ,n-nitroa(elophenonc
(ii) Jkrmnc OR

.r · , J and acetic ,1Lid, which one will give the f lYZ reaction?
Out ol 1ornt1C ol. 1 . • , • . . •.
J. _ . bl e.i.son 111 support of your answer and wnte the chemical reaction involved.
C,1\'l' a slllta e • . .
. . odic but they .ire weaker acids than water. Arrange vanous isomers of butanol m the
Akoho ls are a .
h. .JnLftJSl
. , .·ng order of their acidic nal ure. Give a reason for the same
.
nor anK compound A, which is a Grignard reagent is used to obtam 2-methylbutan-2-ol on
c. :eacti!t with a carbonyl compound 'B'. Identify 'A' and 'B' Wnte the equation for the reaction between
A and B.
An experiment was carried out in the laboratory, to study depression in freezing point. I M aqueous
33, a.
solution of Al(NO 3h and 1 M aqueous solution of glucose were taken. From the given figure identify
solution l and solution 2. Give a plausible reason for your answer.
A

\ p ---------
~ P1 · --
~ P2 ---·
0.. '
,_
::l
'
' '''
0
0..
' ''
''
~ ''
'' ''
:T2 :T1
Temperature -
b. The osmotic pressure of a solution of cane sugar was found to be 2.46 atm at 300 K If the solution was
diluted five times, calculate the osmotJc pressure at the same temperature.
the osmotic pressure of the given cane sugar solution be decreased without changing its
a reason for your answer.
OR
travenous inJections to the pallents, the doctors take utmost care of the concentration
used. \i\'hy is it necessary to check the concentration of the solution?
enol was obtained by dis1,olvmg 2 x IO 2 kg of phenol in 1 kg of benzene. Experimentally
be 73 % associated. Calculate the depression in the freezing point recorded.

21