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2571 Assessment 2

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15 views5 pages

2571 Assessment 2

Uploaded by

Israr Khan
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Autumn Semester 2020

Course: 2571 Semester: BS 8th /M.Sc 4th

Date: 23. 12. 2020 Total marks: 50

Q1. Multiple choice questions (25)

1. Which of the following statements will always apply when a reversible chemical reaction
has attained equilibrium?
a. All reactants will convert to products
b. The reaction proceeds alternately in the forward and reverse directions
c. The Gibbs free energy of the system reaches a minimum
d. The forward reaction will dominate over the reverse reaction

2. If gas is heated against a pressure keeping the volume constant, the work done is best
described to be
a. + ve
b. –ve
c. Zero
d. PV

3. In an isothermal process, the internal energy of gas molecules


a. Increases
b. Decreases
c. Remains constant
d. Depends upon nature of gas

4. If gas vapors are allowed to expand through a minute aperture, the such process is known as
a. Free expansion
b. Adiabatic expansion
c. Throttling
d. Hyperbolic expansion

5. Which is an example of irreversible process


a. Isothermal
b. Adiabatic
c. Throttling
d. None of the above

6. During throttling process


a. Heat exchange does not take place
b. No work is done in expansion
c. There is no change in internal energy
d. All of the above
7. At equilibrium, the isolated system exists at the peak of the entropy-hill and
a. dS<0
b. dS>0
c. dS=1
d. dS=0

8. When a gas undergoes continuous throttling process by a valve and its pressure and
temperature are plotted, then we get a
a. isotherm
b. isenthalpe
c. adiabatic
d. isobar

9. The curve passing through the ____ of the isenthalpes is called the inversion curve.
a. maxima
b. minima
c. base
d. center

10. PV/nRT is known as


a. Pressure factor
b. Compressibility factor
c. Volume factor
d. Mass factor

11. For a gas being throttled, the change in temperature can be


a. positive
b. negative
c. zero
d. all of the above

12. Which of the following relation is correct?


a. dU=TdS-pdV
b. dH=TdS+Vdp
c. dG=Vdp-SdT
d. all of the above

13. For an irreversible process


a. dS=dQ/T
b. dS<dQ/T
c. dS>dQ/T
d. dS≥dQ/T

14. For any process which is undergone by a system


a. dQ/T≥dS
b. dQ/T<dS
c. dQ/T>dS
d. dQ/T≤dS
15. Which of the following is not a Maxwell equation?
a. (∂T/∂V) = -(∂p/∂S)
b. (∂T/∂p) = -(∂V/∂S)
c. (∂p/∂T) = (∂S/∂V)
d. (∂V/∂T) = -(∂S/∂p)

16. SI unit of heat capacity is


a. Joule
b. Joule kg-1
c. Joule (kg×K)-1
d. Joule K-1

17. Chemical potential depends upon


a. Pressure and Temperature
b. Pressure and Volume
c. Temperature and Volume
d. Temperature and entropy

18. The kinetic component of internal energy is due to


a. Vibration of particles
b. Vibration of matter
c. Intermolecular forces
d. The collision particles

19. Which one is the correct interpretation of Zeroth law of thermodynamics


a. (∂U/∂T)v= H
b. (∂U/∂S)v= T
c. (∂S/∂T)v= U
d. (∂U/∂H)v= T

20. At the state of perfect order (W=1) of pure crystalline substances, how is the zero
entropy defined
a. Entropy at 0°C
b. Entropy at 0 K
c. Entropy at freezing point of substance
d. None of the above

21. A sample of ideal gas is having internal energy U is compressed to half of its original
volume while keeping the temperature same. What is the new internal energy of the
ideal gas
a. U
b. ½ U
c. 2U
d. U2

22. In an isothermal process the change of entropy will be


a. Cp ln (v2/v1)
b. Cp ln (v1/v2)
c. R ln (v2/v1)
d. RT ln (v1/v2)

23. Study the graph carefully and choose the incorrect statement below

a. Change in molar Gibbs energy is greater for substances with larger Vm


b. The slope of Gm should be greater for Liquid than Solid phase
c. At high Pressure gas phase is most stable
d. Slope of Gm vs P is steep for gas phase compared to condense phase

24. With the rise in temperature of a system, the sum of entropies of system and its
surroundings
a. Increases
b. Decreases
c. Remains constant
d. Always equal

25. For the process H2O(s) → H2O(l) at 1 atm Pressure and 270K, the value of ∆G is
a. < 0
b. > 0
c. = 0
d. ≤ 0

Q2. Indicate whether true or false (10)

1. The standard Gibbs energy of formation of α-Sn is 0 at 25°C and that of β-Sn is +0.13
kJ/mol; this implies that β-Sn is a thermodynamically less stable phase of tin (True / False)

2. The Carnot Cycle consists of the following steps: Step 1: isobaric expansion, Step 2:
adiabatic expansion, Step 3: isothermal compression, Step 4: adiabatic compression (True /
False)

3. The first law of thermodynamics gives value of internal energy (U) for any process (True /
False)
4. Intensive property of a system does not depend on mass of the system (True / False)

5. Spontaneous reactions require the input of energy from outside the system (True / False)

6. In an isothermal process the internal energy of gas may increase or decrease (True / False)

7. When an ideal gas is made to undergo a Joule-Thomson expansion, i.e., throttling, there is no
change in temperature. (True / False)

8. Change in Gibbs free energy is the difference between the chemical potential of the reactants
and the chemical potential of the products (True / False)

9. Phase change is an isothermal process (True / False)

10. The equation dU= TdS-PdV applies to both reversible and irreversible change (True / False)

Q3. Differentiate between the following terms (provide short answers) (15)

1. Pressure and fugacity


2. Reversible and irreversible process
3. Thermodynamic state and thermodynamic equilibria
4. Exact and inexact functions
5. Micro and macroscopic properties

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