QB solutions CBSE
QB solutions CBSE
1.
2. a. A 0.2 percent aqueous solution of a non-volatile solute exerts a vapour pressure of 1.004
bar at 100 oC . What is the molar mass of the solute? (Given: Vapour pressure of pure
water at is 1.013 bar and molar mass of water is 18 g)
b. Calculate the freezing point of a solution containing 18 g glucose, and 68.4 g sucrose,
in 200 g of water. The freezing point of pure water is 273 K and Kf for water is 1.86 Km-
1.
3. The air is a mixture of a number of gases. The major components are oxygen and nitrogen
with the approximate proportion of 20% is to 79% by volume at 298 K. The water is in
equilibrium with air at a pressure of 10 atm. At 298 K if Henry's law constants for oxygen
and nitrogen are 3.30 107 mm and 6.51 107 mm respectively, calculate the composition
of these gases in water
4.
5.
6. At the same temperature, CO2 gas is more soluble in water than O2 gas. Which one of them
will have higher value of KH and why ?
7. How does the size of blood cells change when placed in an aqueous solution containing
more than 0·9% (mass/volume) sodium chloride ?
8. 1 molal aqueous solution of an electrolyte A2B3 is 60% ionized. Calculate the boiling
point of the solution. (Given : Kb for H2O = 0·52 K kg mol 1 )
9. The vapour pressures of A and B at 25ºC are 75 mm Hg and 25 mm Hg, respectively. If
A and B are mixed such that the mole fraction of A in the mixture is 0·4, then calculate
the mole fraction of B in vapour phase.
16. The relative lowering of vapour pressure of an aqueous solution containing non-volatile
solute is 0·0225. The mole fraction of the non-volatile solute is :
(A) 0·80 (B) 0·725 (C) 0·15 (D) 0·0225
17. A 6% solution of glucose (molar mass = 180 g mol 1 ) is isotonic with 2.5% solution of
an unknown organic substance. Calculate the molecular weight of the unknown organic
substance.
18. The vapour pressure of a solvent at 283 K is 100 mm Hg. Calculate the vapour pressure
of a dilute solution containing 1 mole of a strong electrolyte AB in 50 moles of the solvent
at 283 K (assuming complete dissociation of solute AB).
19. A 4% solution of urea (molar mass = 60 g mol 1 ) is isotonic with 5. 2% solution of an
unknown organic substance. Calculate the molecular weight of the unknown organic
substance.
20. On mixing 10 mL of acetone with 50 mL of chloroform, the total volume of the solution
will be : (A) < 60 mL (B) > 60 mL (C) = 60 mL (D) = 100 mL