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14 views4 pages

NewSyllabus_1133201642672914

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itsmalem
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© © All Rights Reserved
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Annexure ‘CD-01’

Course Title: SPECTROSCOPIC METHODS OF ANALYSIS L T P/ SW/ TOTAL


Course Code: CHEM601 S FW CREDIT
Credit Units: 4 UNITS
Level: Post graduate
3 1 0 0 4

# Course Title Weightage (%)

1 Course Objectives:
The rapid development of spectroscopic techniques during the recent times, both in instrumentation and
interpretation has revolutionized the approach to structure determination problems. The major objective of
this course is to integrate theory and practice and to bring together different branches of both Academic
studies and Industrial Research through the presentation of critical aspects of modern Spectroscopy.

2 Prerequisites:
students must have studied basics of analytical chemistry
3 Student Learning Outcomes:
 an understanding of major concepts, theoretical principles and experimental findings in chemistry.
 an ability to employ critical thinking and efficient problem-solving skills in the spectroscopic
analysis of chemistry
 an ability to, analyze data, and interpret results...
 an ability to use modern instrumentation for chemical analysis.

Course Contents / Syllabus:


4 Module I General Features of Spectroscopy 5
Type of Electromagnetic Radiations, Energies corresponding to various electromagnetic radiations,
Intensities of spectral peaks, peak widths, Broadening.
5 Module II Rotational and Vibrational Spectroscopy 20
Rotational spectra for diatomic molecule, intensities of spectral lines, Effect of isotopic substitution,
spectrum of non-rigid rotator, vibrating diatomic molecule, Anharmonic oscillator, diatomic vibrating –
rotator, Vibrations of polyatomic molecules, fundamental vibrational frequencies, Fermi Resonance,
combination bands and overtones, complications due to interactions of vibrations of similar frequency,
Instrumentation and sampling techniques, Application of IR in structure elucidation of organic compounds
and carbonyl compound and effect of substituents on it C-H, N-H, O-H vibrations and H-bonding

6 Module III UV and Visible Spectroscopy 20


Measurement technique, Absorption Laws, Molar extinction coefficient, Frank-Condon Principle, Ground
and first excited electronic states of diatomic molecules, chromophores, auxochromes, electronic spectra of
polyatomic molecules, Instrumentation, Woodward rules for conjugated dienes and - unsaturated
carbonyl groups, extended conjugated and automatic sterically hindered systems, Red and Blue shifts, hypo
and hyperchromic effect, spin-orbit coupling, intensities of d-d transitions, relaxation in Laporte forbidden
rule, d-p mixing. Applications.

7 Module IV NMR 20
The nuclear spin, precessional motion, larmor frequency, the NMR isotopes, populations of nuclear
spin levels, spin-spin and spin-lattice relaxation, CW and FT methods, solvent used, chemical shift,
shielding and deshielding effects, Anisotropic effect, factors affecting chemical shift 1H spectra,
double resonance, Nulcear Overhauser effect (NOE), coupling constant, factors affecting coupling
costant, karplus relationship, Non-first order spectra, ABC, ABX and AMX type system,
Heteronuclear coupling, Shift reagent in NMR spectroscopy.
8 Module V Mass spectroscopy 20
Introduction, Various techniques of ionization such as EI, CI, LD, FAB, SIMS, ESI. Isotope effects, general
rules for predicting fragmentation patterns, combinatorial spectroscopy techniques such as GC-MS and its
application
9 Module VI Raman spectroscopy 15
Introduction, Polarization of light and Raman Effect, pure rotational Raman spectra, Vibrational Raman
spectra, Structure determination from Raman and Infra-Red spectroscipy
10 Pedagogy for Course Delivery:
The class will be taught using theory, numericals and instrumentation of different spectroscopy. Different
spectra will be provided and explained to understand the use of spectroscopy.

Assessment/ Examination Scheme:


Theory L/T (%) Lab/Practical/Studio (%) End Term Examination

100 NA 70

Theory Assessment (L&T):


Continuous Assessment/Internal Assessment End Term
Examination

Components (Drop CT HA S/V/Q AT EE


down)

Weightage (%) 10 7 8 5 70
100

Abbreviations:
CT – Class Test, S- Seminar, V- Viva, Q- Quiz, HA- Home Assignment, AT: Attendance; EE: End Term Examination

Text & References:


 Application of absorption Spectroscopy of Organic Compounds, J. R. Dyer.
 Modern Methods of Chemical Analysis, Robert L. Pecsok & Donald Shields.
 Instrumental Methods of Analysis, Williard, Merit and Dean, CBS.
 Instrumental Methods of Chemical Analysis by Gurdeep Chatwal & Anand S. K.
 Environmental Chemistry by V. P. Kudesia (Pragati Prakashan, Meerut).
 R.M. Silverstein, G.C. Bassler, T.C. Morrill, “Spectrometric Identification of Organic Compounds.
 W. Kemp, “Organic Spectroscopy”.
 D.H. Williams, I. Pleming, “Spectroscopic Methods in Organic Chemistry”.
 R.V. Parish “NMR, NQR, EPR and Mossbauer Spectroscopy in Inorganic Chemistry”.
 E.V.A. Ebsworth, D.W.H. Parkin, S. Cardock, “Structural Methods in Inorganic Chemistry”.
 D.H. Williams, I. Fleming, “Spectroscopic Problems in Organic Chemistry”, 1967.
 R.C. Banks, E.R.Matjeka, G. Mercer, “Introductory Problems in Spectroscopy”,1980.
 G.M. Barrow “Introduction to Molecular Spectroscopy”.
 C.N. Banwell “Fundamentals of Molecular Spectroscopy”.

Remarks and Suggestions:

_______________________________
Date: Name, Designation, Organisation

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