TM

GRP-2.0 JEE (MAIN + ADVANCED) 2020

Enthuse + Leader Course
Path to success KOTA (RAJASTHAN )
CLASS TEST # 05
INORGANIC CHEMISTRY FULL SYLLABUS TIME :30 Min
SECTION–I : (i) Only One option correct Type
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONLY ONE is correct. 3(–1)
1. If s and p mixing is absent and Hund's rule is violated then the magnetic behaviour and bond order of C2 molecule
is :-
(A) Diamagnetic, bond order = 2 (B) Paramagnetic, bond order = 2
(C) Diamagnetic, bond order = 1 (D) Paramagnetic, bond order = 1
2. Which of the following sodium salt react with dil. H2SO4 & gives triatomic gas
(A) Na2CO3 (B) Na2SO3
(C) Na2S (D) All of the above
3. Give the correct order of initials true (T) or False (F) for following statements.
(I) For transition elements the d-subshells are filled with electrons monotonically with increase in atomic
number
(II) For hydrogen atom 3s, 3p & 3d orbitals all have the same energy
(III) For ground state configuration Hund's rule is valid for atomic oxygen but as per MOT it is not valid
for molecular oxygen
(A) F, T, F (B) F, T, T (C) T, F, T (D) F, F, T
4. Which of the following complex does NOT have D > PE ? (D = CFSE, PE = Pairing Energy)
(A) (A) [Ni(CN)4]2– (B) [NiF6]–2 (C) [PdCl2(SCN)2]2– (D) [Mn(NH3)6]+2
5. In which of the following reaction given change is correctly represented :-
(A) NO ® NO+ (Internuclear distance increases)
(B) Na+ ® Na (Size increases)

10 +10 n 11
(C) 5 B ¾¾¾ ®5 B (Size increases)

(D) Pb4+ ® Pb+2 (Oxidising power of cation increases)

SECTION–I : (ii) One or more options correct Type
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE are correct. 4(–1)
6. Which of the following products are formed when AgCl fused with Na2CO3
(A) Ag (B) Ag2O (C) CO2 (D) Ag2CO3
7. In which of the molecule on hydrolysis proton donor oxyacid is formed from their central atom-
(A) NCl3 (B) PCl3 (C) SF4 (D) P4O10
8. Which of the following statement is incorrect -
(A) Ca2+ and Mg2+ ions do not form complex with EDTA
(B) Be(OH)2 is only acidic in nature
(C) Na2O2 is an oxidising agent and it oxidises charcoal , CO, NH3, SO2 etc.
(D) On heating white colour of K2O become changed into black.
9. Which of the following oxide does not give hydrogen peroxide on reaction with a dilute acid is -
(A) PbO2 (B) Na2O2 (C) MnO2 (D) TiO2

1/3
 TM
GRP-2.0 JEE (MAIN + ADVANCED) 2020
Enthuse + Leader Course
Path to success KOTA (RAJASTHAN )
CLASS TEST # 05
(iii) Paragraph Type
This section contains 2 paragraphs each describing theory, experiment, data etc. Each question of
a paragraph has only one correct answer among the four choices (A), (B), (C) and (D). 3(0)
Paragraph for Q. No. 10 and 11
Read the following paragraph which involve extraction procedure of Mercury and answer the following
questions :
Mercury is mainly exist as bright red coloured ore cinnabar. The ore is crushed and concentrated by
gravity separation or froth floatation. Concentrated ore is heated in air to produce Hg vapours
(B.P. = 357ºC) and condensed to Hg(l). Hg obtained in this way contain traces of other metals dissolved
in it, particularly Pb(B.P.=1751ºC) Zn(B.P. = 908ºC) Cd(B.P. = 765ºC)
10. Process which are involved in the extraction of Hg from cinnabar :
(A) Roasting, Self reduction, Carbon reduction
(B) Calcination, Carbon reduction, Liquiation
(C) Roasting, Self reduction, Distillation
(D) Roasting, Electrolytic reduction, Vapour phase refinning
11. When zinc amalgam (Zn – Hg Alloy) react with dil. H2SO4 it produce :
(A) ZnSO4 + HgSO4 + H2­ (B) ZnSO4 + Hg + SO2
(C) Zn + HgSO4 + SO2 ­ (D) ZnSO4 + Hg + H2 ­

Paragraph for Q. No. 12 and 14

D
(i) Compound ‘A’ ¾¾ ® B+C
+
H
(ii) Aq. solution of ‘B’ + N,N-dimethyl-p-phenylenediamine + FeCl3 solution ¾¾ ¾
® deep blue
solution (M)
boil
(iii) Aq.solution of (A) + S-powder ¾¾¾ ® compound (D).
(iv) Compound (D) (aq.solution) + [Ni(en)3](NO3)2 ¾¾
® Violet ppt (E).
(v) Aq. solution of (C) + HgCl2 ¾¾ ® yellow ppt. (F).
12. Compound ‘F’ has the formula of -
(A) Hg2SO4 (B) HgO.H2SO4 (C) Hg2O.HgSO4 (D) HgSO4.2HgO
13. Which of the following compound produces colourless gas with dil.H2SO4
(A) A (B) B (C) D (D) All of these
14. The number of homocyclic ring present in the compound (M) in -
(A) 1 (B) 2 (C) 3 (D) 4
SECTION–II : Matrix-Match Type
This Section contains TWO questions. Each question has four statements (A, B, C and D) given in
Column I and five statements (P, Q, R, S & T) in Column II. Any given statement in Column I can have
correct matching with ONE or MORE statement(s) given in Column II. For example, if for a given
question, statement B matches with the statements given in Q and R, then for the particular question, against
statement B, darken the bubbles corresponding to Q and R in the ORS. 8(0)
1. Match the column
Column-I Column-II
(Type of complex) (Correct characteristics of the complex given)
3+
(A) [Ti(H2O)6] (P) Diamagnetic
(B) [Cu(NH3)4]2+ (Q) Coloured
(C) [Fe(H2O)5NO] SO4 (R) d2sp3
(D) [CrO4]2– (S) central metal atom or ion in their highest
oxidation state
(T) Does not show geometrical isomerism
2/3
 TM
GRP-2.0 JEE (MAIN + ADVANCED) 2020
Enthuse + Leader Course
Path to success KOTA (RAJASTHAN )
CLASS TEST # 05
2. Column-I Column-II
(A) S + conc. HNO3 ® (P) NO is formed
(B) Cu + dil. HNO3 ® (Q) NO2 is formed
(C) Cu + conc. HNO3 ® (R) N2O is formed
(D) Zn + dil. HNO3 ® (S) Cu(NO3)2 is formed
(T) Redox reaction

SECTION-IV : Numerical Answer

This section contains 4 questions. The answer to each question is a single digit Integer, ranging from
0 to 9 (both inclusive) 3(0)
1. Find the number of the following molecules having 3c–2e bond(s) is present
(a) Al2(CH3)6 (b) BeCl2 (c) BeH2(solid) (d) B2H6 (e) Fe2Cl6 (f) PCl5(solid)
2. Find the number of O-atoms present in [Ni(gly)2]
3. Total number of process which are not common during the extraction of metal from two different ores
calamine & zinc blende out of following is –
Froth Floatation, Gravity Separation, Calcination, Sintering, Distillation, Electro-refining
4. The ionization energy of a representative element is given below (in KJ/mol) :-
IE1 IE2 IE3 IE4 IE5
756 2300 3500 25060 32900
Find out the IUPAC group number of the element.
If your answer have more than one digits fill your answer as sum of digits till you get the single digit
answer.

3/3