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GRP-2.0 JEE (MAIN + ADVANCED) 2020

Enthuse + Leader Course
Path to success KOTA (RAJASTHAN )
CLASS TEST # 02
INORGANIC CHEMISTRY FULL SYLLABUS TIME : 30 MIN

SECTION–I : (i) Only One option correct Type

This section contains 06 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONLY ONE is correct. 3(–1)
1. By Le-blanc process potassium carbonate can be prepared but by solvay process it is not possible, why
(A) Due to presence of massive H– bonding in KHCO3
(B) KHCO3 soluble in water
(C) KHCO3 insoluble in water
(D) Thermal stability of KHCO3 is greater than NaHCO3
2. Which of the following statement is INCORRECT for hydra acid of halogen :-
(A) Down the group, as value of 'n' increases, size of 'ns' and 'np' orbial increases
(B) Down the group, acidic strength increases
(C) Down the group, orbital length of 'np' increases which increases the bond length of H–X bond
(D) Down the group, bond energy of H–X bond increases
3. Statement-1 : When H2S gas is passed through Na-nitorprusside soluton it gives purple colourasation
Statement-2 : H2S is an weak acid
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
4. Which of the following statements are INCORRECT regarding Mn(CO)5?
(A) It can undergo reduction as well as dimerisation
(B) Synergic bonding is involved
(C) (C – O) bond length in Mn(CO)5 is shorter than (C – O) bond length in CO
(D) It is an organometallic compound
5. Which of the following ore is/are mixed oxides ?
(A) Pyrolusite (B) Chromite (C) Ruby copper (D) Limonite
6. Find the maximum number of electrons in Cr , if l + m Þ 2
(A) 2 (B) 4 (C) 5 (D) 7
(ii) One or more options correct Type
This section contains 04 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE are correct. 4(–1)
7. Select CORRECT statement (s) -
(A) White phosphorus produce PH3 with NaOH conc. as one of the products.
(B) CN– is a pseudohalide ion
(C) White phosphorous is poisnous in nature
(D) FeI3 does not exist
8. Which of the following products are formed when AgCl fused with Na2CO3
(A) Ag (B) Ag2O (C) CO2 (D) Ag2CO3

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 TM
GRP-2.0 JEE (MAIN + ADVANCED) 2020
Enthuse + Leader Course
Path to success KOTA (RAJASTHAN )
CLASS TEST # 02
9. Select the CORRECT statements -
(A) The hydrogen carbonates of the alkali metal are soluble in water and NaHCO3 have lowest solubility
(B) Solution of carbonate forms reddish brown pptn basic mercury(II) carbonate (3HgO.HgCO3) on
reaction with Mercury(II) chloride
(C) When AgNO3 reacts with sulphite ion no visible change occurs initially because of the formation of
soluble sulphitoargentate ion.
(D) On standing in air the precipitate BaSO3 is slowly oxidised to it’s sulphate.

10. KI (solid) + conc. H2SO4 (variable concentration)

on warming

'X' + K2SO4 / KHSO4 + H2O

Here 'X' may be

(A) I2 (B) O2 (C) O3 (D) SO2
(iii) Paragraph Type
This section contains 02 paragraphs each describing theory, experiment, data etc. Four questions
relate to two paragraphs with two questions on each paragraph. Each question of a paragraph has
only one correct answer among the four choices (A), (B), (C) and (D).
Paragraph for Q. No 11 to 12
Stereoisomerism of complex arises due to difference in spatial arrangement of ligand around central
metal ion. Tetrahedral complex can show optical isomerism. Square planar complex can show geometrical
isomerism under some condition. Octahedral complex can show geometrical & optical isomerism both
11. One octahedral complex having metal ion with two identical monodentate ligands & other nonidentical
monodentate ligand.
Now if the number of possible stereoisomers when two identical ligands are at trans position is x & if the
number of possible stereoisomerism when two identical ligands are at cis position if y then find the value
of y–x
(A) 6 (B) 7 (C) 8 (D) 9
2+

12. For the complex Pt (CH3 – CH – CH – CH3)2 the number of stereommers having COS is y
NH2 NH2
then the value of y is
(A) 1 (B) 2 (C) 3 (D) 4
Paragraph for Q. No 13 to 14
Inert gases are good reference points to locate the position of an element in periodic table. Consider an
element 'X' of p-block having total five valence electrons and placed in the same period in which
transition elements of 3d series are present.
Answer the following question :
13. Element 'X' belongs to following period and group respectively :
(A) 3, 15 (B) 4, 15 (C) 4, 17 (D) 5, 15
14. Element just below to this element 'X' is :
(A) I (Iodine) (B) Sb (Antimony) (C) Ge (Germenium) (D) As (Arsenic)

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 TM
GRP-2.0 JEE (MAIN + ADVANCED) 2020
Enthuse + Leader Course
Path to success KOTA (RAJASTHAN )
CLASS TEST # 02
SECTION–II : Matrix-Match Type
This Section contains 02 question. Question has four statements (A, B, C and D) given in Column
I and five statements (P, Q, R, S and T) in Column II. Any given statement in Column I can have correct
matching with ONE or MORE statement(s) given in Column II. For example, if for a given question,
statement B matches with the statements given in Q and R, then for the particular question, against
statement B, darken the bubbles corresponding to Q and R in the ORS. 8(0)
1. Match the column:
Column I Column II
(Radicals) (Incorrect characteristics)
(A) Cl– (P) Produces white ppt. with AgNO3 solution
–
(B) Br (Q) Produces coloured gas with hot conc. H2SO4
–
(C) CH3CO2 (R) Produces colourless gas or vapour with dil.H2SO4
–
(D) NO3 (S) Produces no ppt. with AgNO3 solution.
(T) Produces white ppt. with BaCl2 solution.
2. Column-I Column-II
(A) MgO (P) Dissolve both in acid and alkali
(B) BeO (Q) Ingrediant of sorrel's cement
(C) MgSO4.7H2O (R) Epsom salt
(D) MgCl2.6H2O (S) Salt of dibasic oxyacid
(T) Suspension in water is not amphoteric

SECTION-IV : Numerical Answer

1. How many molecules are pyramidal in shape but does not have pp-dp bonding ?
· · Q Q
P(SiH3)3 , N(CH3)3 ; N(SiH3)3 ; C F3 , C H3 , C Me3 , C(CN )3 ; sulphite ion ; chlorate ion, XeO3.
2. (CH3)nSiCl4–n are called methyl subtituted chlorosilanes. If n = one, find maximum number of Si–O
linkages on each Si in product obtained by hydrolysis & condensation.
3. Find number of species which not produces ppt/turbidity in lime water
- 2- - 2-
CO2(g ) ,HCO3(aq.) ,CO3(aq.) ,HSO3(aq.) ,SO3(aq.) ,HCl (g ) ,SO2(g ) , C2O24- ,NO3- ,H2S
4. Total number of electrons present in spherical shape orbitals in Cu (Z = 29)
5. Find sum of the oxidation number of specified atom in product of given reactions.
(i) NaI + conc. H2SO4 ¾® oxidation number of iodine
(ii) P4 + conc. H2SO4 ¾® oxidation number of phosphorus
(iii) S8 + conc. HNO3 ¾® oxidation number of sulphur
(iv) FeO.Cr2O3 + Na2CO3 + O2 ¾¾¾D
fused
® oxidation number of chromium

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