Kashusk

Term 1(2024-25)
Subject-Chemistry MM 70
Class I
SECTIONA consists of 16 multiple-choice questions carrying 1 mark eacn.
There are 33 questions in this question paper with internalchoice.
SECTIONBconsists of 5very short answer questions carrying 2marks eac
SECTION Cconsists of 7 short answer questions carrying 3 marks each.
SECTIONE consists of 2case- based guestions carrying 4 marks each.
SECTIOND consists of 3long answer questions carrying 5 marks each.
Allquestions are compulsory.
Use of logtables and calculators is not alowed
Q1. Number of atoms in 558.6 g Fe (Molar mass Fe = 55.86g mol-1) is
(a) twice that in 60 g carbon (b) 6.023 x 1022
(c) haif that of 8g He (d) 558.6 x6.023x 10

Q2which has maximum number of atoms?

(a) 24 g of C(12) (b)56 g of Fe (56)
(c) 27 g of Al (27) (d) 108 g of Ag (108)
atom used
Q3Rutherford's experiment which established the nuclear model of the
a beam of
(a) B-particles which impinged on a metal foil and got absorbed
(b) y-rays, which impinged on ametal foil and got absorbed
(c) helium atoms which impinged on a metatfoil and got reflected
(d) helium nuclei which impinged on ametal foil and got scattered.
Q4 The set representing the correct order of first ionization potential is
(a) K> Na > Li (b) Be > Mg> Ca
(c) B> C> N (d) Ge > Si > C.
a5 The number of nodal planes in p, orbital is
(a)one (b) two (c) three. (d) zero
Q6 Azimuthal quantum number determines the
(a)size (b) spin c) orientation (d) angular momentum of orbitals
2+
Q7 The electronic configuration of Cu ion is
(a) [Ar] 4s'3de (b) [Ar] 4s² 3di" 4p' (c) [Ar] 4s' 3d0 (d) [Ar] 3d'
Q8 Set containing isoelectronic species is
(a) C,,NO, CN, 02* (b) CO, NO, 0, CN
(c) CO, NO,, O,, N,O (d) none of the above.
a9 According to the periodic law of elements the variation in properties of elements
is related to their
(a) nuclear neutron-proton number ratio (b)atomic masses
(c) nuclear masses (d) atomicnumbers.
Q10 Match the species in Column I with the type of hybrid orbitals in Column Il.
Column l Colum II

() SE, (a) sp'd

(ii) IF, (b) d'sp'
() NO; () sp'd
(v) NH; (d) sp
(e) sp
Q11 What is the shape of d orbital
a) spherical b)dumbbellc) clove leaf d)none of the above
Q12Cis platin used in
a)cancer therapy b)AIDS treatment c)AZT d)one of the above
 SIon,
a) A and R both are correct, and Ris the correct explanation of A.
(b) Aand Rboth are correct, but R is not the correct explanation of A.
(c) Ais true but Ris false.
(d) A Is false and Rtrue

o13 ASSERTION :
atomic size of O is
REASON:0 has higher nuclear chargebigger
than N
than N

Q14ASSERTION: The first

ionisation
energyof Be is higher than that of B
REASON:2p orbital is lower in energy than 2s
Q15 ASSERTION : He and Be
have similar outer
Reason :Both are chemically inert configuration ns2
Q16ASSERTION: Li "has higher ionic
size than Al*
REASON: Among isoelectronic ion,ion with higher
radius nuclear charge lower theionic
SECTIONB
Q17 Use the molecular orbital energy level
diagram to showthat N; would be
expected to have triple bond
OR
Discuss the concept of hybridisation. What is its different
condition for that?
Q18. If two elemnents can combine to form more than one
one element that combine with a fixed mass of the other
compound, the masses of
element, are in whole
number ratio.
(a) ls this statement true?
(b) Ifyes, according to which law?
(c)Give one example related to this law

Q19 Yeliow light emitted from a sodium lamp has a wavelength of 580 nm. Calculate
the frequency and wave number of yellow light.

Q20 Forthe reactionNH,NO---’N, t+2H,0 AT 373k AH=-223.6KJ/mol

.Calculate AU

Q21 what is diagonal relationship. What is the reason of this?

SECTIONC (3MARKS )
Q 22 Give reasons for the following:
() Covalent bonds are directional bonds while ionic bonds are non directional.
(ii) Water molecule has bent structure
(ii) Ethyne molecule is linear.
 3

Qe31) Explain size of cation alwavs smaller than the corresponding atom
y write gernal electronic configuration of second and 14th group elemen
ie reactant which is entirelv consumed in reaction is known as limiting reagent.
e Tedction 2A + 4B -> 3C+ 4D. when5 moles of Areact with6 moles of B, then

i)which is the limiting reagent? (i) calculate the amount ofC formed

Q25. A. (0) Write the electronic configuration of Feand Al

i) what is Pauli exclusion principle

ii) Threshold frequency for metal is 7x104s.calculate the kinetic energy of an electron
emitted when radiation of frequency 1.0x 10s hits the metal.
OR
Q 25. B. i) Assign the position of the element having outer electronic configuration,
(a) ns np for n =3 (b) (n-1) d ns for n=4
ii)the wavelength of the first line in the Balmer series is 656nm.Calculate the
wavelength of limiting line in Balmer series

Q26 i)state Heisenberg uncertainty principlé

ii) Calculate the mass of photon with wavelength 3.6 A0
iii) Write the set of quantum number for 4f

Q27 Define electron gain enthaipy? Discuss the factors which influence the electron
gain enthalpy.
Q 28 Calculate the enthalpy of combustion of ethene at 298 k and latm if
C+0, ---’CO, AH° 393.5 kj/mol
H, +1/2 O, ---’H,0 AH' =-241.8 kj/mol
2 C+2H2>CztH4 AH°= 52.3 ki/mol
SECTIOND (5 MARKS)
Q 29 i)Calculate the empirical formula of salt with the following composition
K=15.1 Al=10.50 S=24.96 O =49.92

i)Define mole
i)Why molality better than molarity
OR
following composition
I)calculate the empirical formula of salt with the
A=14.32 B= 9.20 C=49.0 D=27.57 (Molar mass of A=56 ,B=18 ,C=96
,D=18)
2.00 and 0.0049
i) Calculate the number of significant figure in
ii) State the law of multiple proportions
atom., how it can be calculated take
DUWnat do you mean by formal charge of an
example of O3
i) Explain hydrogen bonding and its type with exampler
iii) Qut of NH3 and NF3 which have higher dipole moment and why
OR
I Draw the shape of NH3, St6, CIF3 and write there geometry?
 i) why s
4
i) What and 2p combination not possible?
is resonance .Draw the
resonance structure of carbonate ion?
31 What do you mean by
each intensive extensive properties? Give
and
) Calculate W and AU
example of
400k from 10 litre to 20When mol of a gas expand isothermally and
2
ii) Explain heat litre reversibly at
capacity, Write its formula also
SECTION (E) (2+2+1)
Q32 Molecular orbitals are CASE STUDY 1
orbitals combine to form two formed by the overlap of atomic orbitals. TwNO atomic
(BMO) and anti bonding molecular molecular orbitals called bonding molecular
orbital
raised above the parent atomic orbital (ABMO). Energy of anti bonding orbital is
bonding orbital is lowered than orbitals that have
the parent atomic combined
and the energy of the
Different atomic orbitals of one atom orbitals.
second atom which have comparable combine with those atomic orbitals of the
enetgies and proper
overlapping is headon, the molecular orbital is called orientation. Further, if the
lateral, the molecular orbital is called 'pi', (T). 'Sigma', (o) and if the overlap is
The
molecular orbitals are filled with electrors according to the
for filling of atomic orbitals. same rules as
However, the order for filling is not the same followed
for all
molecules or their ions. Bond order is one of the most
compare the strength of bonds. important parameters to
1 arrange the following in
(i) o*1s
increasing order of energy (before oxygen atom)
(ii) o*2pz (ii) 2px (iv) *2py
2 Which of the following pair is
expected have the same bond order? Also
to
calculate the valuel
ki) O;, N (iü) o* N?
(ii) O,-, N²* (iv) o² N
3 Write the four point of
difference between sigma and pi bond
Case study 2
Q 33. A system in thermodynamics refers to that part of universe in which
observations are made and remaining universe constitutes the surroundings. The
surroundings include everything other than the system. System and the surroundings
together constitute the universe. The universe = The system + The surroundings
However, the entire universe other than the system is not affected by the changes
taking place in the system. Therefore, for all practical purposes, the surroundings are
that portion of the remaining universe which can interact with the system. Usually,
the region of space in the neighbourhood of the system constitutes its surroundings.
The wallthat separates the system from the surroundings is called boundary.
Types of the System We, further classify the systems according to the movements of
matter and energy in or out of the system.
1) State First law of thermodynamics
2) Explain the different type of system with example
3) What do you mean by state function and path function?