(ested saa Renken > Leste rec [co(rsrs), 7 e2, — (co¥),05)7 euoss of a4. MANO s1each ually Ine Compe Nl Mabe, My j Jnecibitastes ual Cf dons, preg Jn He (colts), Cty] Agog (@ Wu} Lanes (Cow, cy” + NOS + MAL) Ms ee Wau, Sn {cotwny cf + DN + 2AG0) dy, [OOD] u Aane, Kolo. $3NKY 43 AYU) ore Ist eddance => wight oh AW chabained- Bond evdence = wales Cyndudome. WAL cogmnga, > (coors) a, > (Copy Uz\u >| obiMS aD 0 Ovrahedsel ,,) 2 died , age hay as 93 ww) om OY e J apa —Fremtontent Puy =) iviney d-orbital Js \nvalveol ABd* 3 outer d-oroitet Smtdved - ® Wouheds) (G) = af, ad ; 4 4 " + 2 @® 4: a Aghane _planen Aa\s 54 Aa ¥ csp = Wines, l-eabiilalt Gs waved sf ds onter d- gxbttal J» Jhoslsed . 4) by, any @ Mgnelic m moment {fagamagnetic Uunbasied obi ctieo (oh eost one Mr a dia ne unaired als Secs @ Ugands— Avy hyper (Ss * Guser padiing a Secbious |» do ved ingen &ph ? 2\ , iV CrMn Fe CoNi Cy Zn L < - NbMo Te Rukh Rag ch LAV Te We Og Tr tht*h as of mae Han 1 uriboived 7 Pua: Js weak. Coley @ Co ™ WS aay ayaa ud Co) = bak apt 3eap6 au% us? acer, Cat)5 TT OS § file ae oh Ligands. Colao mm fr Ae tal ape a foto? Ea Fe ag {ied oy 6 CN Nigand 9 (minor), Mn > Se 22 pt Reg ay ad yt Mui > Ac 2H VE ays Mn G3) i m4 to co momout wad copes Ap v0 ‘bes, Wider Cat Braud dune icate “cae aa) atachiunt!we Bd 4b J hybidisde, SRSESEEY) dee wiley Tita bag? nc* Is 28" apt Bip! odtus Ni) = [gh atopt at y6 aahus yt a 2 ap Aine, Cempoured Ssloramagact usith 2 Un}pars4 ec} St ce a | (oey)" GS We atays ahapadt yt 75 Wrox at saat co Om “oo Combourrd me uit one urpadad ebrdbysy so we couclude Shot cnr Gs a ashing Nigard .oyd eauie poiriig nith eye olution -(Gang, tit) og CO Pecunl—=* aq us ub wd oiler aud. sydd st ) © exGterUd yhox Seon “ aa us Up dy weur ddbeon sn [Cony]? comiplux tor be Hoason vOKg aatly 46 Shu cypbox os a ond wednong agent a ach oridlaed even in ant [aw] — [ato)™+ 16 +3 ase dole Jn 43 0S +e * copalt on Od conplexes o # (aor) { Wa) an ad? ust Gi. sdlus Ay ood oa \ aq Us up ud Garhound a9 ie wath ome wpa dedi aja AFP Cen uhiy of, compton ss Aquant NOL - Jnubsddizabons AP webs, Gby Gd oo a,pew ob, 3 not inl Jn bupbsdl eae, i 4] by ws ahs Ou Bs eo tla | ik dy (Slane th Siaands. (ae na mMnoy Mn= 43 Mn = Uiage be Mut] Coop 3d Us ub = Too 4 24 tehohedoal 37 bowls My bn—bt bods => 07 \, nat bonds => Poy 4 Mn M@) WET 99 )2?2¥ 0: 6 ‘0,0: eo 1Y hv. nh us| ‘ay fh a anew ‘fe “0: \ +0. ~~0: “ a bai yT-bowds 4 Pn-pn, n-bondRy: Count Prd? boots. ( Cc) xy W Po oy BA ab ad M Win \e \. ‘S hy \ . x ~~ x “ % M6. eg FOr bn ~ piinbwols =8 bh -Att -n-bowl2 F _ Se eee CHEMISTRY) ChemContent{Nm fel are tessa (O40 aa 2 s . vhs eo ts Se aN SS Sou Nuhy Ais Ny i ) B. How many Co-0 ie Co-n bonds ase Hate CoD bow=) 6xXR=12 vw ee (y-N bowl =) YAS = 1% a“— oo” ’ Goidions of whore Lond Aepy -® How Ligands, Weave a9 0 woo, udachobe, wd, | difowsl coudition, oi a why along Ngonds oust sup She dado viwuos Locak Digands cannot © tn odchendsal compares, se Ndsogeu) baud are, Sov hiimes urged «91 shunned: Snazecdipasiinannonenaes = cain J © CFT 00s fixst abplied dn Lowe comounds Shab hy ok As codled Cayo ell theory. ® M-L bond is simpy te tedicidelied Thou 33 nod on idigalien) ovedahying| cov erative hyoruiga ‘\ owt esi- F OW, BY, SCNT, CNT pout NM HD,CO St Ponape : e M mo. Sat 'oh- ion interaction F ; “tH $y > cn dia \nteraction ~ :dae (i) rid Seog att by dy Sas ; Ss 1s oaited re fre because of Ngard — Heray of dudsidns siebibion aeyrond APO malsed mae bee Hey Oro breannt om re axis (direchen © dn which Qigords dps Sty Hon othen 3.d5- ApiA ' 40.6 lo ee 7 (Pf -0.4 by y= Coplal Field Spitivg Gwoay facsss sfocting BEA. O Naline cf ligands:- , Strong liganda= high abliting pauses. mine CFSE wag Ligands= tov sbliitig frnoo. =ss CFSE Legand's aspecdsun-chomizaf series T Ud>3d- 6 Now of lectiows cin valance. shell Eledieoy clouds Sh mekab ions bends fo bol dhe Jigands so ated He balarization badly. wo cleceous an Last Aulshroll A. (ee)Wak Red Complies | |___ Strong Fide, Chey > i bdo arin. | > |=) unpael hts Ninny, a) ng. > pangs " j oo ey ! fan be | 4 HOY gob snsmall so lectsow Hef te fim 4944 esind lewd | che do ppt ee Sey, cup Dnaleadl of an Seon a, 2 CEL) Ja not voy nigh & cur ‘poist-ub tne "i iy gid - ‘ | lt 6 EEhes geleand while 3 bag of orbital. (ve) e Paibing os dele aiven “ty eluctrrour dp Apia * antft] ; “Deas EL) Tugs of : tik.) fag »os F Imp fois | © se dealin sab chan(ra) *Sigands bihoce Wh, (weak Fickd Jisards) nae odjganda of Nig, ( shong Ril Aigonda) OM) Sat a Poet pet ce ni a o Sigonds ne WHs (week Held igor) + Signals ope nity Cheng eld Loans) ji so the weok th Jugorda caniivup ahecbiny BCP, 3, Cat Etch [17,0605 F 1 se ON’ co, No Ligands a vay Aber, adios itchy ee Jauioy shin cpl WY If oridalion stake ds oor more, pairing Will babar dale ob the ype of Digan. M(n>4) ° all Jigards axe send enotgh do boit.ub dno alutivons. O Pasing watt Jnappor in all cases toy, 4d ards ui ilies tcp tsb de igh yc Sham © [Feteo.]”- g. Moilion hydson rial @ b ea ie il ew a el atl a 0 (Co Gotten 1” tt i 4 ah 70 bing We (Co nor)” Ge 46 & yonivg ise 0 (co (ty 9” be @ RAE bor 0 [Fenny] ve O [mney] se tee tg tse te ppaing Use ae no bainivg HSC ey] pang SC @ [er wei Le +e tong se elo se Sy pasune Lee ~ Bo fs Be Ge BEG Eg Bs GTS ‘ChemContentGusht Geld Stbleation eniryy SESE): eee |, faut 4h eh wong nde ode af ‘poocuss- i Seleased spl a ae rath mae ee O.+P [orhshn conviction] he -(a.-#) (itnout Caonvestion) duit use this Mi ae he hy he ty CFSE = (-0.4b 40. 64a, tn? 4 b=no same a m= mat tats" dn dhe d-cnljavoating Joocuse Sige2B ds | dh t°ys-o—[ae+vc'i-be"s1- fet Uh: Z- bee VOZ— lavo-l- Ve l- |°ps'o— | *vh‘o- Auunstod 8, & e | BS] oA] 28 [ep] > 8] 8] bf 55/ b'n] & S| soar ws on o | *yxe- aes *yho= © | *y9-0- | "7z1-|eyaco- | °v ho Grnero4 SN } 8,4 R, 8, g l P Leet] 23] eh] Bis) 6%) SS P| S5| bo | bh Saxe) wid Ubi : ? | Select tee eee ste |e ea ore Psr a Find crse [Col.2),] Co = adhs™ cold > 34° 44! (34) AG, 4 fr Mtv) ty . ces = $-0.4(6) os 0.6(9) 3A. +3P CSE = ~t4A, + 3P x / ANS. witha ay i Longa ti im) AMS: without any gor conunaiog > an prosenee @ shovg Yond = CO $ § ahorg lgand => 7 te obtng © was abvedy -baiyed. PE Js cousuned be padding 2 unbaited olertoaouy. Wa. C&S = -9.4A 420 — A fos Co? adele cnper [Col] L= et moneda”! Ay = 12.000 om? P= (5000 Om bee flight (m9 t E-hy-ht chev Dp aolN wave nd (on) = Fentoient plank's t : Custos (Ts) Ab Lave const se gutrny Mgomelhnes vlerdelet on) Flrrs CSE = Eo4Xp4 0.6 XY) do pome 25 = OKAY Y O6XA) bo Flop? = 0.418006 one) CFSE = -Y800 an) ~ Sine Sigoxd iy L” Sybe 40 awing gownal haben in (#3 Bee? eal wn Ci fox CE FeSO wz)ell An A.- + 4, ty tf $oL4My ~O.GAL 4 CRSE = 0.6 bog) ny dz @ 4, a: op 4 a 2 ep! At -e42 at & a? 43 d's ef e a? etets at - eg tty a = eg ue to as G46a LMP, [Co dueisoo ern, Gin Ae mo th AD -fde [Ponts formals, Siegrd ond oxidalisnne so “yt roost ] ilies 0 spins Paedieling shouc lune, 08, MIM), Oy (Abs) tye comin, Test 01@ mixed older oh combpsition 18,0, We an a 4 i 8=43 OF = couthhde Jobe pauls = + Ora APL BF Osvids on Ta? Tywids=8 On=4 Napinal. 4Finel Inverse fine M =D woids = Yoth of T vets a vod = 4h of Ox veids = OQ), voids = Jy ot, Quvoids Br Tavoid 24M Ta void = ovoid = id rth A Oh Was Ke a? B ar gt as Y/ ¢oe f ob Mo % Te Oyeee eee Hvt [RBG] mln of mut? 4° mie di We Eo. xrro-ux2)ae Seah = 0-18 A, — On 208 Hi. ie neat eect i Sine wy Jelena by Mil? anon ds mare (0.67 2-8) av Mui frehar toeley in On vols. Rene MijO4 Js 0. normal ie G. R04 Fer gf RP de | Oe 0-6 One ata arin ts On= (0.4 XY +0.6K9)Bo .. e Cle +lyn. > = —0.4Ds Ye WWW] +04 Tue 7] [a] |\-0.6 si 2(—0.6x3 +0-Uy3)hy C18 +12) Ag "” 1 = 7 0-61M A, = Qed tle aSinle Fa! please mae WVGy iD, 30 at pra” At) th Oy» Horie R™ gh pe loo \ Oh Qn Th S> ih x Iwese a #(o0y IR gt ac — qe e a | cf3 : 6 Gow ginopaniy ) Oz tot\o,- (e2 $0.6 a | (lati | ..4 2 (-D.YXS +0-6K Xho = —0-4XG 40. 6X 2 (0 +1A)be = (eo, — 2.4 A. ee ere 2 = 6.8 dy 5 12% EEE (uy [-o6 #03 =r 2 —0.6XY 40.UX3 2 C0-6x340.4 X3) Dy = -44 12 Be =(-18 +2)" oni) = —0-6X4 A, 2 a Bo 4 = U2 = 0,531, = PH. —O.0F Oe 4 4 a)| C= = Oy>Ta | Cot? & On s Tk Gg lity rene aplitting dnouy 310) da.j0ol shaus Cot | June we brdoo ws odleonys po ANCE Yon ee » Oh>Ta co te ott De lie oH on Wd Ws noel slinod bore sfindsfavi B® jon age mottdikdly $0 be _ VOD, abbas. but nat (24%04) onif, Az te ) ChemContent Fricks ABO Bip ACE bobrars nom bastion, Dike Mg Addy itwill be noyral spinel - 3 @ wi Ahoy —— ceSE NE >ALT ca yn pasion ahd ANI uy, Mave (SE=0 , © terse goinal ®Oa Fea0y ay , th A =Zn** __s noimall shine! Ib A= Mnl® sy Miyed bin) since od sie \ HAE WAG he ec, Kincade be i Wabval eticys busyy- 44 hor or role of, toe combowsd {ontaad fou DA eoushituort Ganinus Liows surgyy vadaarsd > alind SQbt Chong, e + = Noo) + Gy > ‘NAW () Lattivce = NABB (\_ | wou NAb (\ As N= Avoqadnto Numbase A= Madeding Conbouet dekard on Shepway ob cow as- Yo= Intex Lomin distance nz bond exlanut|bond castor. stage Zz posikive = negative chasge LEX 42. KE rx Same in at Ns Nak F ssolsosame a BoE Oe Veo US OEE A A Settiieg envoyy= Lip >nae? KF> GF Sivileodyr Naf > Nadl> NaBr> Nat 4 NaF natt hacer AAP alio gudus Mj < Nal hnceLe Mgfa7Na$ ilabides of 3a- Mua. yf “noni i nl havesame goomelery Vout Jone coordination wombs fs | sion Stale + Git see ye vw oc mit pee pe dz o ie 3 y oi ’ “ a co si V5 OB Mh Fe CoB ig Gh. 2nf. Th mat A” CFSE 0 ath | ps fm) “SE a ¢ cese=o sé* 2 3d! ? D ELTnow gadis Nie vir heme, LE wif> VF, 33 Hy ccest) 7 “iF uitincs |) +* Coun tng ¢ , ie —ve dames dian coveyshioe fer release of cre . - = 3 -O.Ye ne ae = -0.8A 12 3 a =a _ Fahd. oo thee L 1240.62 -O-6A- Mul = de ae pe a loyae a = at = 0.8K. Mi 2a 2 -12ne GP sdt= -0.6ds Zr 2d= oo a CFSE of VEy ond WiFa, Qc gid City voi a nite 1, CESE US Same ‘CES IS Same. wodluse Cate ty Ee o> Otyey pe Nad Se or odalion Stale = 13 L trihatide,} ™ 3] | s| te jis ut 1 tae oo , a a Yo Mee sd a" y" va cr Mtg “3 Ff — fo Cor NI fags d= dq a oe ae a 7 yoy CASES 0 0.4K, -0.84,-1.20, -0.60, © OM, 0.84, ~1.21, 0-8, -1.20, 0.60, Zopsieel biel aBh 34 wbb cquden a CN =? “No vb) Sigrid ¢ ) ) *) Cosa onan 2 {om Yow Di tas CLES? i | ChemContent F Dicyanider + oxidation stole » (19) fo a ee . ELE cht 16? 4 . ees A pe aa CP se ae dy o @¢ 2 lo? GY GF un as 3 4 sy i 6h het bed hed hed FE) O -O.M, 0.80, -1.74, a ze, o 4 $s 3 Se) Pa heh. Oph ge “‘ 3 a ones CON OP ate are 7 * 4 Ie NBA. Othe 0=) @ tydyalion E199 - = sem Vogt Jos HO fiat =| whos Ole, vale ask £ pe jug = , paler, wtlernnol cies poroourdy Se MM ayy F i aleosed yn sve ous wo Jodbsd Saydrealinn | 4 : Iybsadion mn « chars ‘ 1 ! ae world vey slowed Hiydsuhin 4 CFSE walle sdvalion “ aidan Ooniatcon ah HE fot divulad mulal low, mM J 208d, Avs, ws dollar Uy. @ for Arivabead merle albuee apfense!? jue, C8? MEE, ot HO ad 020 shong (u Sigond hore sill case passing woh dodvaus. Hone, CFs sien, , +3_ ab di # GPed - creg = 0.46 = —2-“be 1 , j HE=-HE - 2.4A. de OD. 90 vies (crs) now a NIP. dl ft | RCH] ~ ox ot | ae 2 OM! se Lae coe) «-* Oak Gi “ , i d 2 1K i tala OH) is a GDHe weak field Sigal (highs combats wr] a Terse Sth d —b.4O. edb -o¥a. yw dd -128. tr dF -oA, mye o A fe” P04. Ged -o8A, Nat 1-2 fe GP dt Lota. i re | eet Na ak 8 Te VS ce mld Be op nit G3 2yt? se vo md a ae ale Aire = Sd + CESE (ad ithod) a se & ) Meg. hun size will decrease usith tnowose un CFSE sdaseh: Bsali Gulu stability x CFSE moe Sve CFSE sebevted, musia stable Compl Wl cl Iv 4. [Ni eon =~ [way a ED GS ey fata) I-04 hee) a |< CRSE > -12d0 = -ORA, = aarti CFSE of [ii ayy 7s Vey Jail 20 Jd alert comply shan [Nid]? Hone the seaction usill be ethene moves.sible . 2 Kooy (cad + wh) yb a) dl d = ze ta) Cam) IS cpses —06be CFSE = —12dy Fe) Cosy Koff tu’c [ata] ace! = (ama febo # Smee das Sess sibling bo "i aoa gt? 5 crone dda Hortt® So [RE]? Us mote acide Peon (MEY? se Acidity [Falrydh] > Ft 09)" > Rew8 Copan, oly UMAT, nth, Meat @ fate J” Sie WB nis ah hg™ Guy. p> . Aaddby 6 £ has Very potdt Shielding so proto on ie alee 2. Radlty => Javad [abyoet >lve tnd” Gy # Somchiomas , ABD, Complexes stows exchtienl behaviout because ohusbics swecart ordi seine stouchiore accusgh ~ A Vartstn) dis a1 exkounwdal padowncy te pred | Bre Beudiusre of kinel outusoledy. | ~ Ada de hocbadion 6" iow could U void: & Pi A220 Mot meas dhwd Lao 6 Jour nT ~ veld ower comix eas mena, pind buds 2 Ipdzes A mas Ac, $peopention Bigs Qa WA Tyvolds, Jhon os : ee WAR boar © comblrx is Juve apn! Wr shows e a ious one Jpreduntt nT vod Jute J dd 0H Jingue Abd. X- NEMO, A= 0.38 Las wniyed| Aye due Se sivilan sige ois | —~y{.at Zale, Oy > Invoue Mufesoy = rama Ni fepOy = mixed Bg Fey 0y = Inverse5 | f I a J Reaulr “Teh gonop Ockdredref ESangation bowls b cst te ek, cena a hon other ones 2 Y ny) : < aabadion = Mok —> RABI 0 : ae fos aap ri or @pantion 0 & ft] oll boud apa >ve ised sefullion=> 2 toy IL[L] sau ocl conn ® FL. lu lion dourrds 2-diredion> F > He oi taal @ (om of -degureragy- (1 4 Co fat diy dye dee day dye dex day dp de (Cam=F] toy has one chution, st sass be an any ata teOtbHade ie. dayrdye erdyy Nene d gutyy sites sald catty apes i Wihsby fou (ign sbieay Clooshin) a 4 aur ey 2 donb, Auqoioe My > iy dnl Que daduoy 5b ty coun b-dn Or of zg AE wibiad so % calud doubly dequurole. —phaual Couse distyrhen e<— Hose: bor 43 02 | ouly ove anangerrd 80s 5 Wnighsin) boos a -degantol TA) Sune. d (highnsin) Woes a rm Loe Nen deenoate Doubly ov Ribly deqouvele 2 oF (lags) sid’ > Seeq Sas octheahal > dlghabin)ord aiuvon’? _ diction devdithod erties gata Fw won Seay molecule om dow Ga Ale i deguaok tole Js unstable ond andsige some sod al, distortion to Sousa davon sts WoLGy Sn Same Ms deanna and ctr Lowen she yin ! : ——1 (iy shen, sist sr 0) ye eg hls) Judd ayo ue aun) doubly deqonle ty 4 = doubly deyenorote 6 No distortion tog e a ‘ Now- ve tl by e oa se y gy - (4 g bn = 4 - Os plow a “ 7 “ ; ” ical Aare ; Sy eit 4 fi 4 ye ge yo co fo? aan Bp kg on ae if 4,2 yf 499° oo Wh tH lea i _“ay Abisstion vou be sch in me: 4 ignered, Sheng dists\ion mgd Sood) 49 pega) ebergolin & cydbaction, “hs [Elargcko ¢ day spe c nie Is me ‘nda dd. Ore otal > dosme seid out, L oeplsiou> 2 -dipedtion -) MeL bord rae of M— Lhd ¢ arisahwrertrah othr ae gal agrees ig counted, ee \ ov [aie]z i frvapahdo" dive N 4 Liber Ee rpl-eu Hat face y ey (Koy G26vy | 47. adda? Ate yte Cate CI de *y r | Tjader OY day dye det \n oibrtlus, \ nvdvenaut of oxtitalls Jowurdous Ya WHY AAs andi wu Agey- aq ay{oom possi ot | 2 roy EEG sy dyy dy er (114) Av av 1 dg% dye hy dp dex (a) asy<< Snr Ged oh, Even CULS o a. 0 RAalive eC ditas' ty ne, ard kup decides MOU™ dose a gona Cam ab\rruach @ Distance behieun M akiet and Lgond cucdes as ie 6 mibalion ved a. % @ Diclomee (ty => ooh hsion() => wogy VY oDiskure W = oehubilon(t) = away Cuf, B-arls Gf AGA. [7eboqpnal t g aot h, L&@mbresion xyors Ga-F Lu (hey) -» Tebagn : ~— _ Tek Tele debettior Jt of Luse Sqper- (cca dish“) Stohie TT Grit ier) Dynawrie TID (sits ) > \Kcounbe ane Jurder all nip distortion caunbe dabeded FAN Addids od wi Seon demouluag coudibions, ds ot welllax in Rely - 2) ad all Spe of anodes equines 2" CR ane =) Weds abioug aud pormondudt | av iva yo ‘ 2) courbe eer wndor all Sype changes 4 Frey ten : of ly, ay ef Cond J sacha ot fering Sorc der (Cdr J rVabpon 2 Roth fous eptitn Aut do Sarge gab bho RXlain eos Nitorwmn eGo) 77 ey orbitals a a Ee etartt Cony. (Cra LKIe,A 1 Guseqneues eof ahn-Teblor Distarion 4 j © staility ot, an comer ex— 4 (Ge @hs},] dow IM undustested Ct gHorohion aH (14 naroyy Vins ae. AR city, (1 Uway of ug © Ly AN 2osed and aye SHO of awo o deca. 54 — Adloves MOY 92,d-ecreased. Hane distortion Jy raleing ire comisiy sae 4, TahhFelloy ci afd, @ (cu. e da unable because ae * . ay CB, tte v ! “othe molecule Jy B (cen tty,] oS more stable in dans hore 430 . Uy joa Tk Vs N ( ™® 2 bo A ie | [7 Ho | no Abatin, mone. Ch Rastk sag cil to stably comple Shen is sugdedBD BAM —s pal + Ault dinjanhnohiowadion —”/ reaeon, Cut) 249 te] yd Att | sa As Ni > Al > oF > bg > 8 G a al 2 mt | on oo ar put We day © ott dnod very high tes Te debts dl ne Avlsssre Ais exe o- th Pa —— Pe geneS et Swe Cle Guts Nit? 9) Tt " Octuredn oh Telhedsia Square Ronee "i at - [NiGuts)e} [Nixa] *y. wiper [Nilay] Weak field Ligands a Ugerds No bai vin. Hy pi tow Cadgintse ¢ cH] = ay dz i op fll af Thesebasation behoeen dit-y ed K ce Uboh abet ut ae tei oe EL al Tu A “Mn Kang ds aa ake cr, Abosation aa Che __ oe >» — Inkose of shoug di : ltt chet = ee) i, suased So Prot ma "spay: peving wp wath did Jn do esibital. Sn dy. 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