CHM First Term Exam
CHM First Term Exam
6. The name of the gas driven off at the 13. Detergent is more efficient than soap in
negative electrode during the cleansing clothes and dishes because of
electrolysis of brine is the following reasons except that
A] hydrogen A] the corresponding Ca and Mg
B] chlorine compound formed is soluble in H2O
C] oxygen B] detergents are not affected by
D] chloride hardness of water
C] it cleans better than soap
7. The furring of kettles is caused by the D] it is less expensive
presence of
A] calcium hydroxide 14. In the manufacture of soap industrially,
B] calcium hydrogen trioxocarbonate IV brine is used to ____ the acid salt
C] calcium trioxo carbonate IV A] oxidize
D] calcium tetraoxosulphate VI B] reduce
C] bleach A] CO2
D] precipitate B] SO3
C] CH4
15. Methane gas can be made from carbon II D] H2
oxide gas according to the equation:
2CO(g) + 2H2(g) CH4(g) + CO2(g). Calculate 22. Synthesis gas is a mixture of
the mass of CO required to produce 8.75 A] CH4 and H2O
x 1025 molecules of CH4? (C = 12, H = 1, B] CH4 and H2
O = 16, Avogadro’s no: 6.02 x 1023 C] CO2 and H2
molecule) D] CO and H2
A] 81.40g
B] 40.70g 23. The chlorinated alkane often used
C] 160.0g industrially to remove grease is
D] 32.00g A] tetrachloromethane
B] chloromethane
16. The relatively high boiling point of C] trichloromethane
alkanols is due to D] chloromethane
A] aliphatic character
B] ionic bonding 24. The reaction of carbide with water gives
C] hydrogen bonding A] ethyne
D] covalent bonding B] ethane
C] ethane
17. When palm wine is left exposed to air for D] ethanol
a few days, it goes sour. The bacteria in
the air oxidizes ____ in the palm wine to 25. Sucrose is made up of
_____ A] glucose and glucose
A] ethanol, ethanoic B] glucose and fructose
B] ethanoic acid, ethanol C] fructose and fructose
C] ester, ethanoic acid D] galactose and glucose
D] ether, ethane
26. Unsaturated organic compounds are
18. 50cm3 of carbon II oxide exploded with identified by decolourization of
150cm3 of air containing 20% oxygen by A] silver bromide and potassium
volume. Which of the reactants was in tetraoxomanganate (VII)
excess? B] bromine solution
A] Carbon II oxide C] silver bromine solution and bromine
B] Carbon VI oxide water
C] Oxygen D] bromine water and alkaline
D] Nitrogen potassium tetraoxomanganate (VII)
solution
19. The ratio of the initial to the final
pressure of a given mass of gas is 1: 1.5. 27. Proteins in acid solution undergo
Calculate the final vol of the gas if the A] substitution
initial volume was 300cm3 at the same B] fermentation
temperature C] hydrolysis
A] 120cm3 D] polymerization
B] 200cm3
C] 450cm3 28. The pair of organic compounds that are
D] 750cm3 isomers is
A] ethanol and propanone
20. The partial pressure of oxygen in a B] benzene and methyl benzene
sample of air is 452mmHg and the total C] but-l-ene and but-2-ene
pressure is 780mmHg. What is the mole D] trichloromethane and
fraction of oxygen? tetrachloromethane
A] 0.203
B] 0.579 29. A characteristic reaction of the
C] 2.030 compounds with the general formula
D] 5.790 CnH2n is
A] polymerization
21. A gas that is not associated with global B] substitution
warming is C] esterification
D] decarboxylation D] chlorine gas and hydrogen
Section A
1a. State the condition necessary for the cracking of long-chain hydrocarbons to produce more
gasoline 2mks
b. A hydrocarbon having the formula C 10H22 was cracked to produce C 6H14 and another
hydrocarbon P.
i. give the formula of P
ii. draw the structures of two isomers of P 2mks
ci. Write an equation for the fermentation of glucose 2mks
ii. Explain briefly why a tight-corked glass bottle filled to the brim with fresh palm wine shatters on
standing for some time 3mks
d. Name three products obtained directly from the destructive distillation of coal 3mks
e. Write an appropriate equation showing how the following can be obtained from propan-1-01 in
the laboratory: i. propene 2mks ii. propylmathanoate 2mks
iii. state the type of reaction involved in each case 2mks
f. Consider the following reaction equation
2H2(g) + O2(g) 2H2O(g)
Calculate the volume of un-used oxygen gas when 40cm 3 of hydrogen gas is sparked with
30cm3 of oxygen gas 2mks
g. Define the following terms: i. esterification 2mks ii. saponification 2mks
Section B
Answer any three (3) questions from this section
2ai. Define each of the following terms: i. Biotechnology ii. Biogas
ii. State two applications of biotechnology 6mks
bi. Describe briefly the production of ethanol from sugar cane juice
ii. State the by-product of the process in 2b(i)
iii. Ethanol can be produced from both cane sugar and petroleum. Explain briefly why the ethanol
from cane sugar is renewable but that from petroleum is non-renewable 9mks
ci. What is structural isomer?
ii. Write all the structural isomeric alkanols with the molecular formula C 4H10O
iii. Which of the isomers from 2b(ii) above does not react easily on heating with acidified K 2Cr2O7?
7mks
di. List the raw materials needed for the manufacture of soap
ii. Name the main by-product obtained from the manufacture of soap 1mk
3a. Chlorine reacted with excess pentane in the presence of light. Chloropentane and a gas which
fumes on contact with air were produced
i. write an equation for the reaction
ii.draw the structure of the major produce
iii.
what is the role of sunlight in the reaction?
iv.If a mixture of pentane and the major product is heated, which compound would
distil off first? Give a reason for your answer
v. Write the formula of the main product that would have been formed if but-1-ene
(C4H8) has been used instead of pentane 7mks
bi. Write the structure of the amino acid CH3CH(NH2)COOH in
I. acidic medium II. alkaline medium
ii. On analysis, an ammonium salt of an alkanoic acid gave 60.5% carbon and 6.5% hydrogen. If
0.309g of the salt yielded 0.0313g of nitrogen, determine the empirical formula of the salt.
H = 1, C = 12, N = 14, O = 10 7mks
ci. What is polymerization? 2mks
ii. Mention two types of polymerization 2mks
iii. State one difference between the two types 2mks
d. In the manufacture of margarine, a vegetable oil X was treated with activated charcoal and then
with a gas Y in the presence of a catalyst
i. name the gas Y
ii. state the function of the activated charcoal
iii. name the products that would have been formed if a sample of X was heated with
concentrated sodium hydroxide solution
iv. what is the catalyst used
H H C H O–H
IV. Name the major product(s) of each of the reaction in 5 d(ii) 8mks
CHRIST THE REDEEMER SECONDARY SCHOOL
3, Morenikeji Street, Behind Jolad Hospital New Garage, Gbagada, Lagos
2024/2025 FIRST TERM EXAMINATION
SUBJECT: CHEMISTRY CLASS: SS
TWO
SECTION A–Objectives
Answer all the questions. All question carry equal marks.
4. The element that is likely to participate in 10. What current will deposit 2.7g of
covalent rather than ionic bonding is aluminium in 2 hours? (Al=27, IF=96500C)
A] Z A] 4
B] Y B] 8
C] X C] 16
D] W D] 32
5. The least reactive element is 11. What is the percentage by mass of oxygen in
A] W Al2(SO4)3.2H2O? (Al=27, S=32, H=1, O=16)
B] X A] 59.25%
C] Y B] 50.79%
D] Z C] 25.39%
D] 14.29%
6. Sieving is a technique used to separate
mixtures containing solid particles of 12. Which of the following is a physical
A] small sizes change?
B] large sizes A] freezing ice-cream
C] different sizes B] dissolving calcium in water
C] burning kerosene A] X2Y
D] exposing white phosphorus to air B] XY2
C] XY
D] X2Y3
13. 3Cu + PHNO3 3Cu(NO3)2 + 4H2O + X
NO. In the equation above, the value of P 21. Calculate the mass of copper deposited
and X respectively are when a current of 0.5ampere was passed
A] 8 and 2 through a solution of Copper II chloride for
B] 6 and 2 45minutes in an electrolytic cell (Cu=64,
C] 2 and 3 IF=96500C)
D] 1 and 3 A] 0.3g
B] 0.25g
14. In the electrolysis of brine, the anode is C] 0.224g
A] Zinc D] 0.448g
B] Platinum
C] Carbon 22. Mn O4-(aq) + Y + 5Fe2+(aq) Mn2+(aq) +
D] Copper 3+
5Fe (aq) + 4H2O. In the equation above, Y
is
15. The mass of Silver deposited when a A] 10H+
current of 10A is passed through a B] 5H+
solution of silver salt for 4830s is C] 8H+
(Ag=108, IF=96500C) D] 4H+
A] 54g
B] 27g 23. In an electrochemical cell, polarization is
C] 13.5g caused by
D] 108g A] oxygen
B] hydrogen
16. A concentrated solution containing H+, C] tetraoxosulphate IV acid
Cu2+, OH- and Cl- was electrolyzed using D] chlorine
platinum electrodes, the ion that will be
discharged at the cathode is 24. In the periodic table, alkali earth metals
A] Cu2+ belong to the
B] Cl- A] p-block
C] H+ B] f-block
D] H- C] d-block
D] s-block
17. The element with electron configuration
IS2 2S2 2P3 is 25. An element X has electron configuration
A] Oxygen IS2 2S2 2P6 3S2 3P5. Which of the following
B] Chlorine statement is correct about the element?
C] Nitrogen A] it is a halogen
D] Calcium B] it has a completely filled p-orbital
C] it has 5 electrons in its outermost shell
18. A difference between chemical and D] it belongs to group II on the periodic
physical change is that in a chemical table
change
A] heat is supplied 26. Beryllium and aluminium have similar
B] a new substance is formed properties because they
C] oxygen is consumed A] are both metals
D] a reversible reaction occur B] are positioned diagonally to each other
C] belongs to the same group
19. Elements in the same period in the D] belong to the same period
periodic table have the same
A] chemical properties 27. If the difference in electronegatively of
B] physical properties element P and Q is 3.0. The bond that will
C] number of shells be formed between them is
D] atomic number A] ionic
B] metallic
20. If Y = IS2 2S2 2P4 and X = 1S2 2S2 2P6 3S2, C] covalent
the chemical formula of the likely D] co-ordinate
compound formed between X and Y is
28. An example of a hydroscopic substance is A] B, C, N and O
A] CaCl2 B] Na, Mg, S and Ar
B] NaOH C] Li, Be, Al and P
C] CuO D] Na, P, O and Cl
D] MgCl2
37. Zinc and Carbon rods are used as anode
29. An insoluble salt can be prepared by and cathode respectively in a
A] the action of dilute acid on an insoluble A] voltaic cell
base B] lead accumulator
B] the reaction of metals with an acid C] Leclanche cell
C] the reaction of trioxocarbonate IV with D] Daniel cell
an acid
D] double decomposition 38. The property of elements which increases
down a group in the periodic table is
30. A hydrogen atom which has lost an A] electronegativity
electron contains B] electron affinity
A] one proton only C] ionic radius
B] one neutron only D] ionization energy
C] one proton and one neutron
D] one proton, one electron and one 39. The reason for the decrease in the atomic
neutron size of elements across a period is that
A] nuclear charge increases while the
31. The electronic configuration of Mg2+ is outermost electrons are drawn closer to
A] 1S2 2S2 2P6 the nucleus
B] 1S2 2S2 2P6 3S2 3P5 B] nuclear charge decreases while the
C] 1S2 2S2 2P6 3S2 outermost electrons are drawn closer to
D] 1S2 2S2 2P4 the nucleus
C] valence electron increase across the
32. Which of the following metals is the least period while the valence shell remains
reactive? constant
A] Pb D] nuclear charge decreases while the
B] Sn distance of the valence shell from the
C] Ag nucleus is increasing
D] Au
40. Which of the following arrangements
33. Moving from left to right across a period, indicate the correct decreasing order of
the general rise in the first ionization ionization energy of period 3 elements?
energy can be attributed to the A] Na, Al, P, Cl
A] decrease in screening effect B] Cl, P, Al, Na
B] increase in screening effect C] Na, P, Cl, Al
C] decrease in nuclear charge D] Al, Na, P, Cl
D] increase in nuclear charge
41. The ionization energy is affected by the
34. The acid used in electrolysis of water is following factors except
dilute A] distance of the outermost electron(s)
A] HNO3 from the nucleus
B] CH3COOH B] size of the positive nuclear charge
C] H2SO4 C] ability to attract shared electron(s)
D] HCl D] screening effect of the inner electron(s)
35. When sodium trioxocarbonate IV 42. The flow of current in electrolysis is due to
decahydrate (Na2CO3.10H2O) loses its the movement of
water of crystallization to the atmosphere, A] charges
the process is B] electrons
A] deliquescence C] ions
B] efflorescence D] poles and electrons
C] hygroscopic
D] effervescence 43. When concentrated sodium chloride
solution is electrolyzed using inert
36. The elements that belong to the third electrode, the products are
period of the periodic table are A] hydrogen and chlorine
B] oxygen and chlorine A] mechanism of electrolysis
C] oxygen and hydrogen B] electrolytic reactions
D] sodium and chlorine C] nature of electrode
D] type of electrolytic cell
45. The periodic classification of the elements 49. The change in the oxidation state of iron
is an arrangement of the elements in in the reaction represented by the
order of their equation below is FeCl3 + H2S 2FeCl2 +
A] atomic size 2HCl + S
B] atomic number A] +2 to +3
C] ionic masses B] +3 to +2
D] molecular masses C] 0 to +2
D] +3 to 0
46. Which of the following equations represent
a redox reaction? 50. Which of the species in the reaction below
A] AgNO3(aq) + KCl(aq) AgCl(s) + K NO3(aq) is the reducing agent?
B] HNO3(aq) + NaOH(aq) NaNO3(aq) + 2I-aq + 2Fe3+aq I2(s) + 2Fe2+aq
H2O(l) 2+
A] Fe aq
C] CaCO3(s) CaO(s) + CO2(g) B] 2Fe2+aq
D] 2H2S(g) + SO2(g) 2H2O(l) + 3S(s) C] 2Fe3+aq
D] I-aq
47. The preferential discharge of ions during
electrolysis is influenced by the
OBJECTIVE TEST
THEORY
Answer all the questions
THEORY
Answer all the questions