Safety data sheet

This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878, without any country-specific
legislation

NEGRO SULFOTEX SN-155

SULFOTEX BLACK SN-155

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier: NEGRO SULFOTEX SN-155
SULFOTEX BLACK SN-155
Other means of identification:
Non-applicable
1.2 Relevant identified uses of the substance or mixture and uses advised against:
Relevant uses: Textile dyes. For professional users/industrial user only.
Uses advised against: All uses not specified in this section or in section 7.3
1.3 Details of the supplier of the safety data sheet:
Aplicación y Suministros Textiles S.A.U
AV. CAMÍ REIAL 13-15
08184 PALAU-SOLITÀ I PLEGAMANS - BARCELONA - España
Phone: +34938647111 - Fax: +34938645104
[email protected]
www.asutex.com
1.4 Emergency telephone number: +34938647111 (8:00 - 17:00)

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture:
CLP Regulation (EC) No 1272/2008:
Classification of this product has been carried out in accordance with CLP Regulation (EC) No 1272/2008.
Eye Dam. 1: Serious eye damage, Category 1, H318
Skin Corr. 1B: Skin corrosion, Category 1B, H314
2.2 Label elements:
CLP Regulation (EC) No 1272/2008:
Danger

Hazard statements:
Skin Corr. 1B: H314 - Causes severe skin burns and eye damage.
Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P264: Wash thoroughly after handling.
P280: Wear protective gloves/face protection/protective clothing/protective footwear.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P310: Immediately call a poison center/doctor.
Substances that contribute to the classification
disodium sulfide; sodium hydroxide
2.3 Other hazards:
Product fails to meet PBT/vPvB criteria
Endocrine-disrupting properties: The product fails to meet the criteria.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substance:
Non-applicable
3.2 Mixture:

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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878, without any country-specific
legislation

NEGRO SULFOTEX SN-155

SULFOTEX BLACK SN-155

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS (continued)

Chemical description: Colourant/s
Components:
In accordance with Annex II of Regulation (EC) No 1907/2006 (point 3), the product contains:
Identification Chemical name/Classification Concentration
CAS: 1313-82-2 disodium sulfide⁽¹⁾ ATP ATP01
EC: 215-211-5
5 - <10 %
Index: 016-009-00-8 Acute Tox. 3: H311; Acute Tox. 4: H302; Aquatic Acute 1: H400; Skin Corr. 1B:
REACH: 01-2119513694-38- Regulation 1272/2008 H314 - Danger
XXXX
CAS: 1310-73-2 sodium hydroxide⁽¹⁾ ATP CLP00
EC: 215-185-5
3 - <5 %
Index: 011-002-00-6
Regulation 1272/2008 Skin Corr. 1A: H314 - Danger
REACH: 01-2119457892-27-
XXXX

⁽¹⁾ Substances presenting a health or environmental hazard which meet criteria laid down in Regulation (EU) No. 2020/878

To obtain more information on the hazards of the substances consult sections 11, 12 and 16.
Other information:

Identification Specific concentration limit

sodium hydroxide % (w/w) >=5: Skin Corr. 1A - H314
CAS: 1310-73-2 2<= % (w/w) <5: Skin Corr. 1B - H314
EC: 215-185-5 0,5<= % (w/w) <2: Skin Irrit. 2 - H315
% (w/w) >=2: Eye Dam. 1 - H318
0,5<= % (w/w) <2: Eye Irrit. 2 - H319

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures:
Request medical assistance immediately, showing the SDS of this product.
By inhalation:
This product does not contain substances classified as hazardous for inhalation, however, in case of symptoms of intoxication
remove the person affected from the exposure area and provide with fresh air. Seek medical attention if the symptoms get worse
or persist.
By skin contact:
Remove contaminated clothing and footwear, rinse skin or shower the person affected if appropriate with plenty of cold water
and neutral soap. In serious cases see a doctor. If the product causes burns or freezing, clothing should not be removed as this
could worsen the injury caused if it is stuck to the skin. If blisters form on the skin, these should never be burst as this will
increase the risk of infection.
By eye contact:
Rinse eyes thoroughly with lukewarm water for at least 15 minutes. Do not allow the person affected to rub or close their eyes.
If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, in which case this could
cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as possible with the SDS of the
product.
By ingestion/aspiration:
Request immediate medical assistance, showing the SDS of this product. Do not induce vomiting, because its expulsion from the
stomach can be hazardous to the mucus of the main digestive tract, and also risk damage to the respiratory system through
inhalation. Rinse out the mouth and throat, as they may have been affected during ingestion. In the case of loss of
consciousness do not administer anything orally unless supervised by a doctor. Keep the person affected at rest.
4.2 Most important symptoms and effects, both acute and delayed:
Acute and delayed effects are indicated in sections 2 and 11.
4.3 Indication of any immediate medical attention and special treatment needed:
Non-applicable

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media:

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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878, without any country-specific
legislation

NEGRO SULFOTEX SN-155

SULFOTEX BLACK SN-155

SECTION 5: FIREFIGHTING MEASURES (continued)

Suitable extinguishing media:
Product is non-flammable under normal conditions of storage, handling and use. In the case of combustion as a result of
improper handling, storage or use preferably use polyvalent powder extinguishers (ABC powder), in accordance with the
Regulation on fire protection systems.
Unsuitable extinguishing media:
Non-applicable
5.2 Special hazards arising from the substance or mixture:
As a result of combustion or thermal decomposition reactive sub-products are created that can become highly toxic and,
consequently, can present a serious health risk.
5.3 Advice for firefighters:
Depending on the magnitude of the fire it may be necessary to use full protective clothing and self-contained breathing apparatus
(SCBA). Minimum emergency facilities and equipment should be available (fire blankets, portable first aid kit,...) in accordance
with Directive 89/654/EC.
Additional provisions:
Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident or other
emergencies. Eliminate all sources of ignition. In case of fire, cool the storage containers and tanks for products susceptible to
combustion, explosion or BLEVE as a result of high temperatures. Avoid spillage of the products used to extinguish the fire into an
aqueous medium.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures:
For non-emergency personnel:
Isolate leaks provided that there is no additional risk for the people performing this task. Personal protection equipment must be
used against potential contact with the spilt product (See section 8). Evacuate the area and keep out those who do not have
protection.
For emergency responders:
Wear protective equipment. Keep unprotected persons away. See section 8.
6.2 Environmental precautions:
Avoid spillage into the aquatic environment as it contains substances potentially dangerous for this. Contain the product absorbed
in hermetically sealed containers. In the case of serious spillage into the aquatic environment notify the relevant authority.
6.3 Methods and material for containment and cleaning up:
It is recommended:
Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other combustible
absorbents. For any concern related to disposal consult section 13.
6.4 Reference to other sections:
See sections 8 and 13.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling:
A.- General precautions for safe use
Comply with the current legislation concerning the prevention of industrial risks with regards manually handling weights.
Maintain order, cleanliness and dispose of using safe methods (section 6).
B.- Technical recommendations for the prevention of fires and explosions
Product is non-flammable under normal conditions of storage, handling and use. It is recommended to transfer at slow speeds
to avoid the generation of electrostatic charges that can affect flammable products. Consult section 10 for information on
conditions and materials that should be avoided.
C.- Technical recommendations on general occupational hygiene
Do not eat or drink during the process, washing hands afterwards with suitable cleaning products.
D.- Technical recommendations to prevent environmental risks

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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878, without any country-specific
legislation

NEGRO SULFOTEX SN-155

SULFOTEX BLACK SN-155

SECTION 7: HANDLING AND STORAGE (continued)

It is recommended to have absorbent material available at close proximity to the product (See subsection 6.3)
7.2 Conditions for safe storage, including any incompatibilities:
A.- Technical measures for storage
Minimum Temp.: 5 ºC
Maximum Temp.: 35 ºC
Maximum time: 18 Months
B.- General conditions for storage
Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection 10.5
7.3 Specific end use(s):
Except for the instructions already specified it is not necessary to provide any special recommendation regarding the uses of this
product.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters:
Substances whose occupational exposure limits have to be monitored in the workplace (European OEL, not country-specific
legislation):
There are no applicable occupational exposure limits for the substances contained in the product
DNEL (Workers):
Short exposure Long exposure

Identification Systemic Local Systemic Local

disodium sulfide Oral Non-applicable Non-applicable Non-applicable Non-applicable
CAS: 1313-82-2 Dermal Non-applicable Non-applicable Non-applicable Non-applicable
EC: 215-211-5 Inhalation Non-applicable 3,2 mg/m³ 13,84 mg/m³ 1,6 mg/m³
sodium hydroxide Oral Non-applicable Non-applicable Non-applicable Non-applicable
CAS: 1310-73-2 Dermal Non-applicable Non-applicable Non-applicable Non-applicable
EC: 215-185-5 Inhalation Non-applicable Non-applicable Non-applicable 1 mg/m³

DNEL (General population):

Short exposure Long exposure

Identification Systemic Local Systemic Local

sodium hydroxide Oral Non-applicable Non-applicable Non-applicable Non-applicable
CAS: 1310-73-2 Dermal Non-applicable Non-applicable Non-applicable Non-applicable
EC: 215-185-5 Inhalation Non-applicable Non-applicable Non-applicable 1 mg/m³

PNEC:
Identification
disodium sulfide STP 0,016 mg/L Fresh water 0,00027 mg/L
CAS: 1313-82-2 Soil Non-applicable Marine water 0,00027 mg/L
EC: 215-211-5 Intermittent 0,00027 mg/L Sediment (Fresh water) 0,0176 mg/kg
Oral Non-applicable Sediment (Marine water) 0,0176 mg/kg
8.2 Exposure controls:
A.- Individual protection measures, such as personal protective equipment
As a preventative measure it is recommended to use basic Personal Protective Equipment, with the corresponding <<CE
marking>> in accordance with Regulation (EU) 2016/425. For more information on Personal Protective Equipment (storage,
use, cleaning, maintenance, class of protection,…) consult the information leaflet provided by the manufacturer. For more
information see subsection 7.1. All information contained herein is a recommendation which needs some specification from
the labour risk prevention services as it is not known whether the company has additional measures at its disposal.
B.- Respiratory protection
The use of protection equipment will be necessary if a mist forms or if the occupational exposure limits are exceeded.
C.- Specific protection for the hands

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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878, without any country-specific
legislation

NEGRO SULFOTEX SN-155

SULFOTEX BLACK SN-155

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continued)

Pictogram PPE Labelling CEN Standard Remarks

Chemical protective gloves

(Material: Linear low-density
polyethylene (LLDPE), EN ISO 21420:2020 Replace the gloves at any sign of deterioration.
Breakthrough time: > 480
Mandatory hand min, Thickness: 0.062 mm)
protection
As the product is a mixture of several substances, the resistance of the glove material can not be calculated in advance with
total reliability and has therefore to be checked prior to the application.
D.- Eye and face protection
Pictogram PPE Labelling CEN Standard Remarks

EN 166:2002
Clean daily and disinfect periodically according to
EN 167:2002
Face shield the manufacturer´s instructions. Use if there is a
EN 168:2002
risk of splashing.
Mandatory face EN ISO 4007:2018
protection
E.- Body protection
Pictogram PPE Labelling CEN Standard Remarks
EN 13034:2005+A1:2009
EN 168:2002
Disposable clothing for EN ISO 13982-
For professional use only. Clean periodically
protection against chemical 1:2004/A1:2010
according to the manufacturer´s instructions.
Mandatory complete risks EN ISO 6529:2013
body protection EN ISO 6530:2005
EN 464:1994

Safety footwear for

EN ISO 20345:2011
protection against chemical Replace boots at any sign of deterioration.
EN 13832-1:2019
risk
Mandatory foot
protection
F.- Additional emergency measures
Emergency measure Standards Emergency measure Standards

ANSI Z358-1 DIN 12 899

ISO 3864-1:2011, ISO 3864-4:2011 ISO 3864-1:2011, ISO 3864-4:2011
Emergency shower Eyewash stations

Environmental exposure controls:

In accordance with the community legislation for the protection of the environment it is recommended to avoid environmental
spillage of both the product and its container. For additional information see subsection 7.1.D
Volatile organic compounds:
With regard to Directive 2010/75/EU, this product has the following characteristics:
V.O.C. (Supply): 0 % weight
V.O.C. density at 20 ºC: 0 kg/m³ (0 g/L)
Average carbon number: Non-applicable
Average molecular weight: Non-applicable

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties:
For complete information see the product datasheet.
Appearance:
Physical state at 20 ºC: Liquid
Appearance: Not available
*Not relevant due to the nature of the product, not providing information property of its hazards.

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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878, without any country-specific
legislation

NEGRO SULFOTEX SN-155

SULFOTEX BLACK SN-155

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continued)

Colour: Black
Odour: Characteristic
Odour threshold: Non-applicable *
Volatility:
Boiling point at atmospheric pressure: 100 ºC
Vapour pressure at 20 ºC: 2350 Pa
Vapour pressure at 50 ºC: 12381,01 Pa (12,38 kPa)
Evaporation rate at 20 ºC: Non-applicable *
Product description:
Density at 20 ºC: 1350 - 1450 kg/m³
Relative density at 20 ºC: Non-applicable *
Dynamic viscosity at 20 ºC: Non-applicable *
Kinematic viscosity at 20 ºC: Non-applicable *
Kinematic viscosity at 40 ºC: Non-applicable *
Concentration: Non-applicable *
pH: 10 - 12
Vapour density at 20 ºC: Non-applicable *
Partition coefficient n-octanol/water 20 ºC: Non-applicable *
Solubility in water at 20 ºC: Non-applicable *
Solubility properties: Miscible
Decomposition temperature: Non-applicable *
Melting point/freezing point: Non-applicable *
Flammability:
Flash Point: Non Flammable (>60 ºC)
Flammability (solid, gas): Non-applicable *
Autoignition temperature: Non-applicable *
Lower flammability limit: Non-applicable *
Upper flammability limit: Non-applicable *
Particle characteristics:
Median equivalent diameter: Non-applicable
9.2 Other information:
Information with regard to physical hazard classes:
Explosive properties: Non-applicable *
Oxidising properties: Non-applicable *
Corrosive to metals: Non-applicable *
Heat of combustion: Non-applicable *
Aerosols-total percentage (by mass) of flammable Non-applicable *
components:
Other safety characteristics:
Surface tension at 20 ºC: Non-applicable *
Refraction index: Non-applicable *
*Not relevant due to the nature of the product, not providing information property of its hazards.

SECTION 10: STABILITY AND REACTIVITY

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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878, without any country-specific
legislation

NEGRO SULFOTEX SN-155

SULFOTEX BLACK SN-155

SECTION 10: STABILITY AND REACTIVITY (continued)

10.1 Reactivity:
No hazardous reactions are expected because the product is stable under recommended storage conditions. See section 7.
10.2 Chemical stability:
Chemically stable under the indicated conditions of storage, handling and use.
10.3 Possibility of hazardous reactions:
Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not expected.
10.4 Conditions to avoid:
Applicable for handling and storage at room temperature:
Shock and friction Contact with air Increase in temperature Sunlight Humidity
Not applicable Not applicable Not applicable Not applicable Not applicable

10.5 Incompatible materials:

Acids Water Oxidising materials Combustible materials Others
Avoid strong acids Not applicable Precaution Not applicable Avoid alkalis or strong bases

10.6 Hazardous decomposition products:

See subsection 10.3, 10.4 and 10.5 to find out the specific decomposition products. Depending on the decomposition conditions,
complex mixtures of chemical substances can be released: carbon dioxide (CO₂), carbon monoxide and other organic compounds.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008:

The experimental information related to the toxicological properties of the product itself is not available

Dangerous health implications:

In case of exposure that is repetitive, prolonged or at concentrations higher than the recommended occupational exposure limits,
adverse effects on health may result, depending on the means of exposure:
A- Ingestion (acute effect):

- Acute toxicity : Based on available data, the classification criteria are not met, however, it contains substances classified
as dangerous for consumption. For more information see section 3.
- Corrosivity/Irritability: Corrosive product, if it is swallowed causes burns destroying the tissues. For more information about
secondary effects from skin contact see section 2.
B- Inhalation (acute effect):

- Acute toxicity : Based on available data, the classification criteria are not met, as it does not contain substances classified
as hazardous for inhalation. For more information see section 3.
- Corrosivity/Irritability: Prolonged inhalation of the product is corrosive to mucous membranes and the upper respiratory
tract
C- Contact with the skin and the eyes (acute effect):

- Contact with the skin: Above all, skin contact may occur as fabrics of all thicknesses can be destroyed, resulting in burns.
For more information on the secondary effects see section 2.
- Contact with the eyes: Produces serious eye damage after contact.
D- CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction):

- Carcinogenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified
as hazardous for the effects mentioned. For more information see section 3.
IARC: Non-applicable
- Mutagenicity: Based on available data, the classification criteria are not met, as it does not contain substances classified as
hazardous for this effect. For more information see section 3.
- Reproductive toxicity: Based on available data, the classification criteria are not met, as it does not contain substances
classified as hazardous for this effect. For more information see section 3.
E- Sensitizing effects:

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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878, without any country-specific
legislation

NEGRO SULFOTEX SN-155

SULFOTEX BLACK SN-155

SECTION 11: TOXICOLOGICAL INFORMATION (continued)

- Respiratory: Based on available data, the classification criteria are not met, as it does not contain substances classified as
hazardous with sensitising effects. For more information see section 3.
- Skin: Based on available data, the classification criteria are not met, as it does not contain substances classified as
hazardous for this effect. For more information see section 3.
F- Specific target organ toxicity (STOT) - single exposure:

Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for
this effect. For more information see section 3.
G- Specific target organ toxicity (STOT)-repeated exposure:

- Specific target organ toxicity (STOT)-repeated exposure: Based on available data, the classification criteria are not met, as
it does not contain substances classified as hazardous for this effect. For more information see section 3.
- Skin: Based on available data, the classification criteria are not met, as it does not contain substances classified as
hazardous for this effect. For more information see section 3.
H- Aspiration hazard:

Based on available data, the classification criteria are not met, as it does not contain substances classified as hazardous for
this effect. For more information see section 3.
Other information:

Non-applicable

Specific toxicology information on the substances:

Identification Acute toxicity Genus

sodium hydroxide LD50 oral >2000 mg/kg
CAS: 1310-73-2 LD50 dermal >2000 mg/kg
EC: 215-185-5 LC50 inhalation >5 mg/L
disodium sulfide LD50 oral 500 mg/kg (ATEi)
CAS: 1313-82-2 LD50 dermal 300 mg/kg (ATEi)
EC: 215-211-5 LC50 inhalation >5 mg/L

Acute Toxicity Estimate (ATE mix):

ATE mix Ingredient(s) of unknown toxicity
Oral 5714,29 mg/kg (Calculation method) 0%
Dermal 3428,57 mg/kg (Calculation method) 0%
Inhalation >20 mg/L (4 h) (Calculation method) Non-applicable
11.2 Information on other hazards:
Endocrine disrupting properties
Endocrine-disrupting properties: The product fails to meet the criteria.
Other information
Non-applicable

SECTION 12: ECOLOGICAL INFORMATION

12.1 Toxicity:
Product-specific aquatic toxicity:
Acute toxicity Species Genus
LC50 >100 mg/L (96 h) (OCDE TG 203) Oncorhynchus mykiss Fish

Substance-specific aquatic toxicity:

Acute toxicity:
Identification Concentration Species Genus
disodium sulfide LC50 Non-applicable
CAS: 1313-82-2 EC50 1,6 mg/L (48 h) N/A Crustacean
EC: 215-211-5 EC50 Non-applicable

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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878, without any country-specific
legislation

NEGRO SULFOTEX SN-155

SULFOTEX BLACK SN-155

SECTION 12: ECOLOGICAL INFORMATION (continued)

Identification Concentration Species Genus

sodium hydroxide LC50 189 mg/L (48 h) Leuciscus idus Fish
CAS: 1310-73-2 EC50 33 mg/L Crangon crangon Crustacean
EC: 215-185-5 EC50 Non-applicable

Chronic toxicity:
Identification Concentration Species Genus
disodium sulfide NOEC 0,009 mg/L Lepomis macrochirus Fish
CAS: 1313-82-2 EC: 215-211-5 NOEC 0,002 mg/L Gammarus pseudolimnaeus Crustacean
12.2 Persistence and degradability:
Product-specific information:
Degradability Biodegradability
BOD5 0,01 g O2/g Concentration 100 mg/L
COD 0,49 g O2/g Period 28 days
BOD5/COD 0,02 % Biodegradable 60 % (OECD TG 301F)
Substance-specific information:
Not available
12.3 Bioaccumulative potential:
Not available
12.4 Mobility in soil:
Not available
12.5 Results of PBT and vPvB assessment:
Product fails to meet PBT/vPvB criteria
12.6 Endocrine disrupting properties:
Endocrine-disrupting properties: The product fails to meet the criteria.
12.7 Other adverse effects:
Not described

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods:
Waste class (Regulation (EU) No
Code Description
1357/2014)
04 02 16* dyestuffs and pigments containing hazardous substances Dangerous

Type of waste (Regulation (EU) No 1357/2014):

HP8 Corrosive
Waste management (disposal and evaluation):
Consult the authorized waste service manager on the assessment and disposal operations in accordance with Annex 1 and Annex
2 (Directive 2008/98/EC). As under 15 01 (2014/955/EC) of the code and in case the container has been in direct contact with
the product, it will be processed the same way as the actual product. Otherwise, it will be processed as non-dangerous residue.
Waste should not be disposed of to drains. See paragraph 6.2.
Regulations related to waste management:
In accordance with Annex II of Regulation (EC) No 1907/2006 (REACH) the community or state provisions related to waste
management are stated
Community legislation: Directive 2008/98/EC, 2014/955/EU, Regulation (EU) No 1357/2014

SECTION 14: TRANSPORT INFORMATION

Transport of dangerous goods by land:
With regard to ADR 2021 and RID 2021:

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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878, without any country-specific
legislation

NEGRO SULFOTEX SN-155

SULFOTEX BLACK SN-155

SECTION 14: TRANSPORT INFORMATION (continued)

14.1 UN number or ID number: UN2801

14.2 UN proper shipping name: DYE, LIQUID, CORROSIVE, N.O.S. (sodium hydroxide)
14.3 Transport hazard class(es): 8
Labels: 8
14.4 Packing group: III
14.5 Environmental hazards: No
14.6 Special precautions for user
Special regulations: 274
Tunnel restriction code: E
Physico-Chemical properties: see section 9
Limited quantities: 5L
14.7 Maritime transport in bulk Non-applicable
according to IMO
instruments:
Transport of dangerous goods by sea:
With regard to IMDG 40-20:
14.1 UN number or ID number: UN2801
14.2 UN proper shipping name: DYE, LIQUID, CORROSIVE, N.O.S. (sodium hydroxide)
14.3 Transport hazard class(es): 8
Labels: 8
14.4 Packing group: III
14.5 Marine pollutant: No
14.6 Special precautions for user
Special regulations: 274, 223
EmS Codes: F-A, S-B
Physico-Chemical properties: see section 9
Limited quantities: 5L
Segregation group: Non-applicable
14.7 Maritime transport in bulk Non-applicable
according to IMO
instruments:
Transport of dangerous goods by air:
With regard to IATA/ICAO 2023:
14.1 UN number or ID number: UN2801
14.2 UN proper shipping name: DYE, LIQUID, CORROSIVE, N.O.S. (sodium hydroxide)
14.3 Transport hazard class(es): 8
Labels: 8
14.4 Packing group: III
14.5 Environmental hazards: No
14.6 Special precautions for user
Physico-Chemical properties: see section 9
14.7 Maritime transport in bulk Non-applicable
according to IMO
instruments:

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
Candidate substances for authorisation under the Regulation (EC) No 1907/2006 (REACH): Non-applicable
Substances included in Annex XIV of REACH ("Authorisation List") and sunset date: Non-applicable
Regulation (EC) No 1005/2009, about substances that deplete the ozone layer: Non-applicable
Article 95, REGULATION (EU) No 528/2012: Non-applicable

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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878, without any country-specific
legislation

NEGRO SULFOTEX SN-155

SULFOTEX BLACK SN-155

SECTION 15: REGULATORY INFORMATION (continued)

REGULATION (EU) No 649/2012, in relation to the import and export of hazardous chemical products: Non-applicable
Seveso III:
Non-applicable
Limitations to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII REACH,
etc ….):
Shall not be used in:
—ornamental articles intended to produce light or colour effects by means of different phases, for example in ornamental lamps
and ashtrays,
—tricks and jokes,
—games for one or more participants, or any article intended to be used as such, even with ornamental aspects.
Specific provisions in terms of protecting people or the environment:
It is recommended to use the information included in this safety data sheet as a basis for conducting workplace-specific risk
assessments in order to establish the necessary risk prevention measures for the handling, use, storage and disposal of this
product.
Other legislation:
The product could be affected by sectorial legislation
15.2 Chemical safety assessment:
The supplier has not carried out evaluation of chemical safety.

SECTION 16: OTHER INFORMATION

Legislation related to safety data sheets:
The SDS shall be supplied in an official language of the country where the product is placed on the market. This safety data sheet
has been designed in accordance with ANNEX II-Guide to the compilation of safety data sheets of Regulation (EC) No 1907/2006
(COMMISSION REGULATION (EU) 2020/878).
Modifications related to the previous Safety Data Sheet which concerns the ways of managing risks.:
COMMISSION REGULATION (EU) 2020/878
Texts of the legislative phrases mentioned in section 2:
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
Texts of the legislative phrases mentioned in section 3:
The phrases indicated do not refer to the product itself; they are present merely for informative purposes and refer to the
individual components which appear in section 3
CLP Regulation (EC) No 1272/2008:
Acute Tox. 3: H311 - Toxic in contact with skin.
Acute Tox. 4: H302 - Harmful if swallowed.
Aquatic Acute 1: H400 - Very toxic to aquatic life.
Skin Corr. 1A: H314 - Causes severe skin burns and eye damage.
Skin Corr. 1B: H314 - Causes severe skin burns and eye damage.
Classification procedure:
Skin Corr. 1B: Calculation method
Eye Dam. 1: Calculation method
Advice related to training:
Training is recommended in order to prevent industrial risks for staff using this product and to facilitate their comprehension and
interpretation of this safety data sheet, as well as the label on the product.
Principal bibliographical sources:
http://echa.europa.eu
http://eur-lex.europa.eu
Abbreviations and acronyms:

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 Safety data sheet
This SDS is an English translation of COMMISSION REGULATION (EU) 2020/878, without any country-specific
legislation

NEGRO SULFOTEX SN-155

SULFOTEX BLACK SN-155

SECTION 16: OTHER INFORMATION (continued)

ADR: European agreement concerning the international carriage of dangerous goods by road
IMDG: International maritime dangerous goods code
IATA: International Air Transport Association
ICAO: International Civil Aviation Organisation
COD: Chemical Oxygen Demand
BOD5: 5day biochemical oxygen demand
BCF: Bioconcentration factor
LD50: Lethal Dose 50
LC50: Lethal Concentration 50
EC50: Effective concentration 50
LogPOW: Octanolwater partition coefficient
Koc: Partition coefficient of organic carbon
UFI: unique formula identifier
IARC: International Agency for Research on Cancer

The information contained in this safety data sheet is based on sources, technical knowledge and current legislation at European and state level, without being able to guarantee its accuracy. This
information cannot be considered a guarantee of the properties of the product, it is simply a description of the security requirements. The occupational methodology and conditions for users of
this product are not within our awareness or control, and it is ultimately the responsibility of the user to take the necessary measures to obtain the legal requirements concerning the
manipulation, storage, use and disposal of chemical products. The information on this safety data sheet only refers to this product, which should not be used for needs other than those specified.

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