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SEC:OSR_*CO-SC Date: 21-05-24

Time: 3 Hrs Max. Marks: 198

21-05-24_OSR.STAR CO-SUPER CHAINA_JEE-ADV_PGTA-7_SYLLABUS

PHYSICS: TOTAL SYLLABUS

CHEMISTRY: TOTAL SYLLABUS

MATHEMATICS: TOTAL SYLLABUS

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Narayana IIT Academy 21-05-24_OSR.IIT_*CO-SC_JEE-Adv_PGTA-7_Q’P
TIME: 3HRS IMPORTANT INSTRUCTIONS Max Marks: 198

PHYSICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 1 – 6) Questions with Single digit integer(0-9) +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 7 – 12) +4 -2 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 13 – 18) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66

CHEMISTRY
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 19 – 24) Questions with Single digit integer(0-9) +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 25 – 30) +4 -2 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 31 – 36) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66

MATHEMATICS
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec – I (Q.N : 37 – 42) Questions with Single digit integer(0-9) +3 -1 6 18
One of More Correct Options Type
Sec – II (Q.N : 43 – 48) +4 -2 6 24
(partial marking scheme) (+1)
Questions with Numerical Value Type
Sec – III (Q.N : 49 – 54) (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐1 +4 0 6 24
27.30)
Total 18 66

OSR.IIT_*CO SC Page No:2

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Narayana IIT Academy 21-05-24_OSR.IIT_*CO-SC_JEE-Adv_PGTA-7_Q’P
MATHEMATICS MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
The answer to each question is A SINGLE DIGIT INTEGER rangeing from 0 TO 9 , BOTH INCLUSIVE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric
keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
1. Let the function f ( x)  sin 1  e x    sin 1  e  x   , the domain of f ( x) is ( ,  ) and range of

f ( x ) contain two elements  and  then the value of [       ] is, where

 ,  ,  ,   R and [.] denotes greatest integer function

4
2. If | y | 2  , then number of real solutions if | y | 1 are m and if | y | 3 are n, then the
| x  1|

value of m – n is equal to

3. If z1  z2  z3  2, z1  z2  z3  2  
2  1 and z1 z2 z3  8 , then the value of
1

   2 z  3 2 z  3 2 z  3  50  is_____

1 2 3
3

Where [.] represents G.I.F

xn  xn2 1
4. If  xn  is a sequence of numbers n  N such that xn 1  and x1  and
1  xn  xn2 2

1 1 1 1 N
N    then sum of digit of is equal to :
x1  1 x2  1 x2022  1 x2023 2

5. If the equation of the plane passing through (1,2,0)and which contains the line
x  3 y 1 z  2
  is 6x   y   z  k , then the value of (2   5  k ) is equal to :
3 4 2

6. India and Pakistan plays best of seven matches series. Probability that India wins a
1 2
match is and that Pakistan wins is , if it is known that India wins, then probability that
3 3
p
India wins in the decider match is , where p and q are coprime then unit digit of |p-q|is
q

equal to :

OSR.IIT_*CO SC Page No:3

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Narayana IIT Academy 21-05-24_OSR.IIT_*CO-SC_JEE-Adv_PGTA-7_Q’P
SECTION - 2 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
n
n n 1
n
7. Let Tn   2 2
and S n   2 2
, for n  1, 2,3, Then which of the following is
k 1 n  k k 0 n  k

correct
   
A) Sn  B) Sn  C) Tn  D) Tn 
4 4 4 4

8. Consider a family of curve such that the tangent and normal at any point meet the
x-axis at a points 'P' and 'Q' and mid-point of PQ is origin O. Then such a family of
curves are
A) parabola
B) parabola with origin as focus
C) y 2  c 2  2cx (where c is a constant)
D) y 2  2cx  c 2 (where c is a constant)
9. Let f be a non-negative function defined on the interval [0,1]. If
x x

 1  ( f (t )) 2 dt   f (t )dt ,0  x  1 and f(0)=0, then which of the following is NOT correct.
0 0

1 1 1 1 1 1 1 1

A) f    and f    B) f    and f   
2 2  3 3 2 2  3 3

1 1 1 1 1 1 1 1

C) f    and f    D) f    and f   
2 2  3 3 2 2  3 3

10. A,B,C are three events for which P  A   0.4, P  B   0.6, P  C   0.5, P  A  B   0.75

P  A  C   0.35 and P  A  B  C   0.2 . If P  A  B  C   0.75 , then P  B  C  can

take values
A) 0.15 B) 0.2 C) 0.3 D) 0.4

OSR.IIT_*CO SC Page No:4

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Narayana IIT Academy 21-05-24_OSR.IIT_*CO-SC_JEE-Adv_PGTA-7_Q’P
7

 3 5  3
11. Let f :  ,   R and f is a continuous, f  2   2 . If  f  t  dt  0 , then Which
 2 2  2

of the following is/are CORRECT?

 3 x  x 3  7 
f  t  dt  Sin    e
x
A) The equation  has atleast one solution in  2 , .
2
 2   3 
 5 
B) The equation f  x   0 has atleast one solution in  2 , 
 2 

 7 
C) The equation f  x   e 2024 x has atleast one solution in  2 , 
 3 
D) The equation f  x   3cos3x   2 x  3  e3 x 9 x 14 has attest one solution in
2 2

 7 
 2 , .
 3 
        
12. a , b , c are
three non-zero vectors. If  be defined as x  y  x  y  x  y if
     
a  (b  c )  ( a  b )  c ; then which of following can be true?
 
A) a and c are collinear
  
B) a , b and c are mutually perpendicular
  
C) b is perpendicular to a and c
 
D) b and c are collinear

SECTION - 3 (Maximum Marks : 24)

This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
13. Let ' L ' be the set of all lines in XY plane and let R be the relation in '  ' defined as
R   L1 , L2  : L1 is parallel to L2  . Assume 'A' as the set of equivalence class of

y  2 x  4 . 'B' is the set of elements in A which has X-intercept and Y-intercept as non

zero integers. C   x, y  : x 2  y 2  16 and  x, y  lies on any element of B}. Then

cardinality of 'C' is

OSR.IIT_*CO SC Page No:5

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Narayana IIT Academy 21-05-24_OSR.IIT_*CO-SC_JEE-Adv_PGTA-7_Q’P
a
If the value of lim  n3  n2   
1/3
14. ( n 1)
P2   where n  N then the value of 1998a  8b
n   b
is____(where [x]denotes greatest integer function less than or equal to xand
HCF( a , b )  1 )

15. If a circle of constant radius 3 2 passes through origin O and meets the coordinates axes
at A and B and the locus of centroid of OAB lies on a curve, then the radius of the
director circle of that curve is

16. Let set A contains all the (3  3) matrices whose two element are 1 each, two elements are
-1 each and five elements are 0 each. Let B be a matrix belonging to set A. If the number
 x  0 
of matrices B for which equation B  y   0  has non trivial solution is  , then  equal to
 z  0 

x2 y2
17. A variable chord of hyperbola  1 subtends a right angle at center of hyperbola. If
4 8

this chord touches a fixed circle concentric with hyperbola, then square of radius of this
circle is
2
18. Let f ( x)  x (2ln x  1)  ex  k , k  R . If least value of k for which f ( x) is defined for all
4
a 2
x  (0,  ) is e , where a, b, N . then then least value of (a+b) is
b

OSR.IIT_*CO SC Page No:6

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Narayana IIT Academy 21-05-24_OSR.IIT_*CO-SC_JEE-Adv_PGTA-7_Q’P
PHYSICS MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
The answer to each question is A SINGLE DIGIT INTEGER rangeing from 0 TO 9 , BOTH INCLUSIVE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric
keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
19. In the figure shown, the mass of the hanging block is m , while that of the block resting
on the floor is 3 m . The floor is horizontal and frictionless and all pulleys ideal. The
system is initially held stationary, with the inclined thread making an angle   30 , with
the horizontal. The blocks are now released from rest and allowed to move. The hanging
block falls through a height (49/5) m before hitting the floor. It is found that the value of
 becomes 60 , when the hanging block hits the floor Find the speed (in m/s) with which
the hanging block hits the floor.  g  10 m / s 2 

20. The value of current through indicated 5 resistor is x ampere. Then the value of x is:

21. A circuit consists of two capacitors and an emf source of emf   10 V . The capacitance of
capacitors are equal to C1  1 F and C2  2 F . The potential difference VA  VB  5 V . The
voltage across the capacitor C1 is equal to 5n (Volt). Then the value of nis :

OSR.IIT_*CO SC Page No:7

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22. A wire lies along the body diagonal of an imaginary cube of side a  20 cm , the current
flowing through the wire is 5 A as shown in the figure. Then the force due to uniform

magnetic field B  0.6 ˆjT on the wire is 0.17 x( N ) . Then the value of x is:

23. A uniform rod is placed on the edge of a horizontal table. The length of rod is 2a and
initially the center of mass of the rod is at a distance a / 3 from the edge. The rod is
released from rest. If the rod slips after it turned through an angle 60 , then the
coefficient of friction between the rod and the table is x y . The value of ( x  y ) is ( x and
y are co-prime):
24. When 12 V DC source is connected to a coil 4 A currents flows in it. If the same coil is
connected to the 12 V,50rad / sAC source a current of 2.4 A flows in the circuit. Then the
value of inductance of the coil is xH. Then the value of 100x is:
SECTION - 2 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
25. A thin, symmetric double convex lens of power P is cut into three parts A, B and C as
shown. The power of

P P
A) A is P B) A is 2P C) B is D) C is
2 4
OSR.IIT_*CO SC Page No:8
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26. A partition divides a container having insulated walls into two compartments I and II.
The same gas fills the two compartments whose initial parameters are given. The
partition is a conducting wall which can move freely without friction. Which of the
following statements is/are correct, with reference to the final equilibrium position?

P, V, T 2P, 2V, T
I II

A) The Pressure in the two compartments are equal.

3V
B) Volume of compartment I is
5

12 V
C) Volume of compartment II is
5

5P
D) Final pressure in compartment I is
3

27. Charge 'Q' is uniformly spread on a circular disc, of mass ' m ' and radius ' R '. It is free to
rotate in horizontal plane about vertical axis. Initially the disc is at rest in a uniform
vertical magnetic induction field ' B ' which covers its entire area. Now the field is
switched off. The angular velocity gained by the disc depends on

A) Q B) R C) m D) B

28. A hollow cube open at the top of side L has two parallel sides conducting (shaded sides)
and remaining three sides are non-conducting. It is completely filled with a liquid of
dielectric constant K . A small hole of area A at bottom of cube is opened at t  0 and
liquid starts leaking through it. The two conducting sides are connected by a battery of
 18 2 
emf E  L  9 m, A  m , K  10, E  81 V, g  10 m / sec2  (Assume electric field has negligible
 20 

effect on speed of efflux.)

OSR.IIT_*CO SC Page No:9

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Narayana IIT Academy 21-05-24_OSR.IIT_*CO-SC_JEE-Adv_PGTA-7_Q’P
2
 t
A) Height of liquid as a function of time t is 3  9 
 

0 2
B) Capacitance of capacitor as a function of time is
9
 t  54t  810  in the given time

range until the dielectric leaks out completely

C) Current through the connecting wire of a function of time is given by 9 0 (54  2t ) in

the given time range until the dielectric leaks out completely

D) Height of liquid as a function of time t is a constant

29. Two capacitors C1  1 F and C2  1 F are connected in a circuit with a battery of emf 10 V .
There is an initial charge 5 C on C1 and its polarity is shown in fig.

Now switch ' S ' is closed for long time. Select the correct statement(s)

A) Potential difference across C2 is greater than that across C1 .

B) Charge on both the capacitors is same.

C) Charge on C1 is 2.5 C

D) Charge on C2 is 7.5 C

30. Two circular coils X and Y having equal number of turns and carrying equal currents in
same sense are placed co-axially, such that they subtend the same solid angle at O . Let
B be the magnetic field at O due to smaller coil X , then

OSR.IIT_*CO SC Page No:10

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Narayana IIT Academy 21-05-24_OSR.IIT_*CO-SC_JEE-Adv_PGTA-7_Q’P
A) Magnetic field at O due to larger coil  2 B

B) Magnetic field at O due to larger coil  B / 2

C) Total magnetic field at O is 3 B / 2

5B
D) Total magnetic field at O is
2

SECTION - 3 (Maximum Marks : 24)

This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
31. One end of a spring of negligible unstretched length and spring constant ' k ' is fixed at
origin. A point particle of mass 'm' and charge 'q'is attached at its other end. When
another point charge 'Q' is fixed at origin, the spring gets stretched to a length '  ' thereby
attains equilibrium. If the point mass is now displaced slightly from its equilibrium
m
position and released, it is found to oscillate with time period a . Find the value of a
12k
. (use   3.14 )
y

q
x
Q


32. A coherent parallel beam of microwaves of wavelength   0.25 mm falls on a YDSE

apparatus. The separation between the slits is 1.0 mm . Screen is placed at a distance
7
D  1.0 m as shown. If y coordinate of 2 nd minima above central maxima is m, then
N
find the value of N .
y
S1
x
d
30º
S2
D

OSR.IIT_*CO SC Page No:11

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33. Starting from origin a particle follows two dimensional trajectory in x  y plane with
speed increasing at a rate of 5 m / s2 . The equation of the path is given by x2  5 y . Find the
ux
value of , when particle is at x  2 .
uy

r  2

34. A circular disc of radius R carries surface charge density  (r )   0 1  2  , where  0 is a
 R 

constant and r is distance from center of the disc. Consider two spherical surfaces of
radius R / 3 and 2R / 3 concentric with the disc. If 1 and  2 be the electric flux through
1
larger and smaller spherical surface, then find the ratio .
2

35. A particle of mass 12kg moving with velocity 10m/s collides head on with an another
particle of mass 4kg moving with velocity 2m/s in the same direction. What can be the
maximum possible loss of energy (in J).

36. A particle of mass 2.0 kg can move in vertical plane along cylindrical groove of radius
1.0 m made in a large block of mass 8.0 kg , which is kept on a smooth horizontal surface.
The particle is released from a position in level with the axis of the cylindrical groove.
Find work done (in J) by normal reaction (between particle and block) on block till the
particle reaches lowest position for the first time.  g  10 m / s 
2

m
R

OSR.IIT_*CO SC Page No:12

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CHEMISTRY MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
The answer to each question is A SINGLE DIGIT INTEGER rangeing from 0 TO 9 , BOTH INCLUSIVE.
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric
keypad in the place designated to enter answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.
37. In carbylamines reaction of 3 moles of ethanamine, stoichiometric moles of KOH
required is ________

38. Aqueous solutions of how many of the following ions are colourless?

Sc+3, Ti+3, Ti+4, Cr+3, Co3+, Fe+3, Cu+2, Zn+2

39. Observe the following reaction and find out that how many number of reactant
stereoisomers can be reduced to optically inactive meso products.
CHO CH 2OH
CHOH CHOH
CHOH CHOH
Na BH 4
CHOH   CHOH
CHOH CHOH
CH2 OH CH 2OH

40. Fe 2  (aq)  NO3– (aq)  H 2SO 4 (conc.) 

 Brown ring

The brown ring is due to the formation of complex, [Fe(H2O)5 NO]SO4 .The spin only
magnetic moment of the complex is ___BM

(Round off to nearest integer)

41. How many aldol addition products are possible (structural only) when mixture of
O
||
HCHO, CH3CHO and CH3 – C – CH 3 are reacted in dilute NaOH ?

42. The number of lone pairs on chlorine containing product obtained by reaction of HClO 4
x
with P4 O10 is x. Then is _____.
2

OSR.IIT_*CO SC Page No:13

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Narayana IIT Academy 21-05-24_OSR.IIT_*CO-SC_JEE-Adv_PGTA-7_Q’P
SECTION - 2 (Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
43. Select the correct statement(s)-
A) Molecularity of a reaction can be zero.
B) Molecularity is defined only for elementary reactions
C) For complex reactions order is determined by the slowest step
D) Order of a reaction is an experimental quantity
44. Select the correct statement(s) regarding carboxylic acids-
A)The acidic strength of CN  CH2  COOH  NO2  CH2  COOH
B)On heating pentadioic acid we will get pentadioic anhydride
C)Reactivity order towards nucleophilic acyl substitution is
acyl halides > anhydrides > esters > amides
D)Amides can be obtained on partial hydrolysis of cyanides
45. t-butyl methyl ether can be prepared in good yield by which of the following reaction(s)-
A) Me3C  Cl  MeONa 
 B) (i) Hg(OAc)2 +MeOH
Me2 C= CH 2 (ii) NaBH 4

C) Me3C  ONa  MeCl  D)


H
 Me 2 C  CH 2 
MeOH


46. The total vapour pressure in a closed beaker containing a binary solution of compounds
A and B is found out to be a function of mole fraction of A and B as-
P = 100 XA + 200 XB mm Hg
Then select the correct statement(s)-
A) A is more volatile than B
B)Vapour pressure of pure B is more than that of the solution of A and B
C)Vapour pressure of pure A and pure B are 100 mm Hg and 200 mm Hg respectively
D)Vapour pressure of pure A is more than that of the solution of A and B

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47. Select the correct statement(s) regarding [Cu(NH3)4]SO4

A)The orbital used in hybridisation of Cu is d x 2 – y2

B)It produces white precipitate with BaCl2

C)It is paramagnetic with unpaired electron in d subshell

D)Its IUPAC name is tetraamminecopper(II) sulphate

48. Select the correct statement(s)-

A) AgBr shows Schottky defect only.

B) Coordination number of each ion in CsCl is 8

C) CsCl type crystal changes to NaCl type crystal structure on heating

a 3
D) Closest distance between C atoms in diamond unit cell is where a is the edge
4

length of the unit cell.

SECTION - 3 (Maximum Marks : 24)

This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
49. Total number of ore of Cu from the following ore is______.

Atacamite, Sphalerite, Cuprite, Chalcanthite, Fool's gold, Chalcopyrite, Anglesite,

Baryte, Chalcocite, Zincite

50. Total stereoisomers in the following compound(s) are

Cl

(a) (b) (c) (d)

Cl Cl

If your answer (a) is 5 , (b) is 2 , (c) is 1 and (d) is 4 then write 5214 in the OMR Sheet.

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Narayana IIT Academy 21-05-24_OSR.IIT_*CO-SC_JEE-Adv_PGTA-7_Q’P
51. Number of reactions which can produce 1° amine are:
O

(i) OH–
N – H (ii) R–I
(I) R – C – NH 2  (II)
–
OH /Br
(iii) OH /H2O
–
 2

|| O
O

NH (i) LAH
(III) CH3 (ii) H2 O (IV) C N
(i) LAH
O (ii) H2O

NH–Et H+/H2O
N C
+
+
H / H2O
(V) (VI) O

(i) LAH C N
(VII) (VIII)
+
H / H2O
(ii) H2O  
NO2

H3C Et
C PCl5
(IX) N
OH

52. 0.5 mole of an ideal monoatomic gas at STP conditions undergoes a process, if the final
volume of gas is (22.7 × e) lit., then the entropy change in this process in J / K mol is
[Given: Process isobaric]

100
(Fill your answer by multiplying it with )
R

53. The specific conductivity of a 0.5 M aq. solution of monobasic acid HA at 27°C is 0.006
Scm–1. It's molar conductivity at infinite dilution is 200 S cm2mol–1. Calculate osmotic
atm L
pressure (in atm) of 0.5 M HA (aq) solution at 27°C. Given R = 0.08 .
mol K

54. A sample of Mg is burnt in excess of air to produce Mg3N2 and MgO. The products are
dissolved in excess of HCl solution. Then the solution is boiled with excess of
concentrated NaOH solution. If 12 moles of HCl is consumed in the reaction with
Mg3N2 and MgO, and 2 moles of NH3 gas is evolved on boiling the solution with
NaOH, then the mass (in gm) of Mg burnt is (Mg = 24)

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