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18.12.24 - SR - STAR CO-SC (MODEL-A& APEX) - Jee - Main - GTM-1 - QP - Unlocked

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18.12.24 - SR - STAR CO-SC (MODEL-A& APEX) - Jee - Main - GTM-1 - QP - Unlocked

18.12.24_SR.STAR CO-SC(MODEL-A& APEX)_Jee_Main_GTM-1_QP_unlocked
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NARAYANA Sec: SR.IIT_*CO-SC(MODEL-A& APEX) Date:18-12- Time: 3HRS GTM-1 Max. Marks: 300 Name of the Student: ur.no:[-] [TTL] 18-12-24 SR.* CO-SUPER CHAINA (MODEL-A& APEX) JEE-MAIN_GTM-1_SYLLABUS. PHYSICS: Waves, Ray Optics And Optical Instruments, Wave Optics, Electrostatics, Capacitors, Current Electricity, Magnetism, EMI & AC, EM Waves, Modern Physics CHEMISTRY: Atomic structure, Liquid solutions, Electrochemistry, Chemical kinetics, d - and f- block Elements, Group-15 to 18, Coordination Compounds, Alcohols, Phenols and Ethers, Aldehyde and Ketones, Carboxylic Acids, Amine, Diazonium Salts, Biomolecules, Carbohydrates, Proteins, Vitamins, Nucleic acids MATHEMATICS: Complex Numbers, Quadratic Expressions, Sequence & Series, Permutations & Combinations, Binomial Theorem, Probability, Circle, Parabola, Ellipse, Hyperbola, Integration, Differential Equations. Page. No. 1 APex Narayana IIT Academy PHYSICS SECTION -1 (SINGLE CORRECT ANSWER TYPE) This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, ‘out of which ONLY ONE option can be correct. -4 for correct answer Marking schem ff not attempted and -1 if not correct. 1. Two waves are approaching towards each other with a velocity of 16m/s and frequency n. The distance between two consecutive nodes is ay ie ps 2 pf n n 8 2. Two monoatomic ideal gases 1 and 2 of molecular masses m, and m, respectively are enclosed in separate containers kept at the same temperature. The ratio of the speed of sound in gas 1 to that in gas 2 is given by A) B) J icy SS Dp) \m, Vm, m, m, 3. Three capacitors each of capacitance C and of breakdown voltage V are joined in series. The capacitance and breakdown voltage of the combi Sv By3c% © £3v 7 3 a + . we s 4. The dimension of 52," (, :permittvity of free space;E :electric field) is A) MLT” B) MLT? ©) ML'T? D) ML" 5. The electrostatic potential energy between proton and electron separated by a distance 1A is A) -13.6eV" B) 27.2eV ©) -144er D) -3.41ev 6. The effective capacitance between the points P and Q of the arrangement shown in the figure is — LaF P 1k Q 1k LaF A) sur B) ur D) 1.33uF Page. No.2 APex Narayana IIT Academy 18-12-24_SR.lIT_*CO-SC(MODEL-A& APEX)_JEE-MAIN_GTM-1 Pp 7. 10. ll. An electric bulb is designed to draw power , at voltage ¥,, If the voltage is V it draws a power P, Then (e)e B) r(Z}x py r= (Fe) When a battery connected across a resistor of 16 Q, the voltage across the resistor is 12 A) P V. When the same battery onnected across a resistor of 10 Q, voltage across it is LIV. The internal resistance of the battery (in ohm) is ae B) 2 o8 p)2 A rigid circular loop of radius r and mass m lies in the x—y plane of a flat table and has a current / flowing in it. Consider z axis to be vertically upwards. At this particular place the earth’s magnetic field is B= B,i+ 8, The value of 7 so that the loop start tilting is (assume friction to be sufficiently re == Be arB, 9 arB, A horizontal overhead powerline is at a height of 4 m from the ground and carries a current of 100 A from east to west. The magnetic field directly below it on the ground due to it is (u, =4nx107 Tma*) A) 2.5x107T, southward B) 5.0x10°T, northward C) 5.0«10°7, southward D) 2:5*107T, northward If the first order minima in Young’s double slit experiment occurs direct by in front of one of the slits. If distance between slits is d and the distance between slits and screen is D, then the wavelength of used light is id; d ad d@ Ay B) — oOo D) — YD ) oD ) 3D ) 4D Page. No.3 Narayana IIT Academy 18-12-24_SR.IIT_*CO-SC(MODEL-A& APEX)_JEE-MAIN_GTM-1_Q'P_ 12. A uniform electric field exists between two opposite charged parallel plates. An electron is released from rest from the surface of the negatively charged plate. The electron strikes the surface of the opposite plate 2.0%10° m from the first, in 1.5%10"s. Then, potential difference between plates is A)20.2.V B) 2.02 V ©) 404V D)4.04.V 13. A light bulb is at a depth of D below the surface of water. An opaque dise of radius R is placed on the surface of water just above the bulb, The bulb is not at all seen through the surface of water, then (n= Refractive index of water) D A) R= B) R> CPZ D) R=DVn'=1 vn 14. A lens is placed between a source of light and a wall, It forms images of area 4, and 4, on the wall for its two different positions. The area of the source or light is Ay Ata B) [se| : ©) laa D) el 2 A 2 15. What should be the velocity of an electron so that its momentum becomes equal to that of a photon of wavelength 52004 ? A) 10's" B)1.2x10'ms! ©) 14xt0'ms’ DD) 2.8«10"ms 16. A beam of cathode rays is first accelerated to a potential difference y an then is subjected to crossed Electric (E) and Magnetic field (B). The fields are adjusted such that the beam is not deflected. The specific charge of the cathode rays is given by. a pp era pb) WB 17. Using the following data Mass hydrogen atom = 1.00783 u Mass of neutron = 1.00867 Mass of nitrogen atom (,N"')= 14.00307 u The calculated value of the binding energy of the nucleus of the nitrogen atom (,N"*) is close to A) 56 MeV B) 98 MeV ©) 104 MeV ——D) 142 Mev Page. No.4 APex Narayana IIT Academy 18-12-24 SR.IIT_*CO-SC(MODEL-A& APEX)_JEE-MAIN_GTM-1_Q'P 18. The dependence of binding energy per nucleon, B, on the mass number, 4 is represented by aaa) A) 136 ~ B) a VATS "INA 9 CES a 19. Three infinitely long charge sheets are placed as shown in figure below. The electric field at point P is 20. A solid non-conducting sphere of radius R has a uniform distribution of charge working space throughout its volume. Ata distance.x from its centre, for x < R, the electric field is directly proportional to Bt Or De SECTION-IL (NUMERICAL VALUE ANSWER TYPE) This section contains 5 questions. The answer to each question is a Numerical value. If the Answer in the decimals Round off to the nearest Integer only. Have to Answer all 5 questions and question will be evaluated ‘according to the following marking scheme: Marking Scheme: +4 for correct answer, 0 if not attempted and 1 if not correct. Page. No.5 APex Narayana IIT Academy 18-12-24 SR.IIT_*CO-SC(MODEL-A& APEX)_JEE-MAIN_GTM-1_Q'P 21. 22, 23. 24, 25. In a Wheatstone’s network P= 20, Q = 2Q, R =2Q and $=3Q. The resistance with which S is to be shunted in order that the bridge may be balanced is A uniformly charged solid sphere made of an insulating material has potential 100V at its surface. What is the potential of center of the sphere in Volts? Three lenses /,,/,,L, are placed co-axially as shown in figure, Focal lengths of lenses are given 30cm,l0em and Sem respectively. If a parallel beam of light falling on lens 1,, emerging 1, as a convergent beam such that it converges at the second focus of 1,. Distance between Z, and L, will be boob da Ina compound microscope, the focal length of the objective and the eye lens are 2.5cm and Sem respectively. An object is placed at 3.75 om before the objective and image is formed at the least distance of distinct vision, then find the distance between two lenses upto nearest integer in centimeters. A circular coil of 100 turns and effective diameter 20 cm carries a current of 0.5 A. It is to be tumed in a magnetic field B = 2 T from a position of its stable equilibrium to unstable equilibrium. The work required in the process to nearest integer in Joules is Page. No. 6 Narayana IIT Academy CHEMISTRY SECTION -1 (SINGLE CORRECT ANSWER TYPE) This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, ‘out of which ONLY ONE option can be correct. -4 for correct answer Marking schem ff not attempted and -1 if not correct. 26. An electron beam can undergo diffraction by crystals which proves the wave nature of| electrons. The potential required for a beam of electrons to be accelerated from rest so that its wavelength becomes equal to 0.154 nm is A) 63.5V B)31.75V ©) 635V D)127V 27. Which of the following azeotropic solutions has the boiling point more than boiling point of the constituents A and B ? A) CH,CH.OH and CH,COCH, B) CS, and CH,COCH, C) CHCl, and CH,COCH, D) CH,CHO and CS, 28. If the standard electrode potentials of Fe” / Fe and Fe” / Fe are -0,04 V and-0.44 V respectively then that of Fe” / Fe” is A)0.76V B)-0.76 V ©) 0.40V D)-0.40 V 29. A current of 0.1 A was passed for 965 second through a solution of Cu’ solution and 0.03175 g of copper was deposited on the cathode, Calculate the current efficiency for the copper deposition, (Cu ~ 63.5) A) 79% B) 39.5% C) 63.25% D) 50% 30. The specific conductance of a N/10 KCI at 25°C is 0.0112 ohm em”, The resistance of cell containing solution at the same temperature was found to be 55 ohms. The cell constant will be A) 6.16cm" B) 0.616cm" C) 0.0616cem D) 616cm' 31. The mechanism of the reaction, 2NO +O, —»>2NO, is NO+NO===N.0, (fast); N,O, + 0, —*>2N0O, (slo The rate constant of the reaction is Page. No.7 APex Narayana IIT Academy 18-12-24. SR.lIT_*CO-SC(MODEL-A& APEX)_JEE-MAIN_GTM-1_Q'P ADK, BK K(k) OK, D) “{E) 32. _KMnO, in excess on treatment with concentrated H,SO, forms a compound (X) which decomposes explosively on heating forming (Y). The (X) and (Y) are respectively are A) Mn,O,,Mn0. B) Mn,0,,Mn,0, ©) MnSO,,Mn,0, D) Mn,0,,Mn0, 33. MnO‘ is of intense pink colour, though Mn is in +VII oxidation state. This is due to A) d-d transition B) charge transfer when Mn gives electron to oxygen C) charge transfer when oxygen gives its electrons to Mn making it +VI D) absorption of IR frequencies 34. Consider the following statements S1:[Cr(NH,), ]” ism inner orbital complex with crystal field stabilization energy equal to-12 A, S2 : The octahedral complex formed by joining the CN” ligands to Fe" ion has theoretical value of ‘spin only’ magnetic moment equal to 1.73 B.M. $3 : Na,S+ Na, [ Fe(CN), NO ]—>Na,[ Fe(CN), NOS], In reactant and product the oxidation states of iron are same and arrange in the order of True/False. A)FTE B)TTF OTTT D)FFF 35. The CORRECT order of stability of oxides of various halogens is A)CI>Br>I— B)BrCI>T 36. There is considerable increase in covalent radius from N to P. However, from Sb to Bi only small increase (of 7 pm) in covalent radius is observed. This is due to A) poor shielding by completely filled d- and f-orbitals in Bi. B) similar electronegativity of Sb and Bi C) Bi being the last element of the group. D) similar densities of Sb and Bi. Page. No.8 APex Narayana IIT Academy 18-12-24. SR.lIT_*CO-SC(MODEL-A& APEX)_JEE-MAIN_GTM-1_Q'P. 37. Which of the following acids is a vitamin? A) Aspartic acid B) Ascorbic acid C) Adipic acid D) Saccharic acid 38. Select the CORRECT option among the following A) n-Butylamine has higher boiling point than n-Butyl alcohol B) triethyl amine is more basic than ethyl amine in aqueous solution C) 2-methylpropan-2-amine is an example of tertiary amine D)All 39. Select the CORRECT option from the given below ‘A) Sodium salt of propionic acid on decarboxylation with sodalime gives propane as a major product B) Benzoic acid is more acidic than phenyl acetic acid 1. Cly/ Red phosphorus ‘Methanoie acid | ————___» cu. coon 2,0 ° 1 D)All 40. What is NOT true for both cellulose and DNA? A) Both are long chain polymers B) Both contain similar monomers C) Both have glycosidic Linkages) All oO OH : an ~~ ZV Which of the following reagents is NOT suitable for the above transformation? A) NaBH, /H B) LiAlH, /H° ©) HyPa/c D) CH.MgBr/ H° 42. The Ka of on on OH OH 2 NO, a 1 0 m v Page. No.9 APex Narayana IIT Academy 18-12-24 SR.IIT_*CO-SC(MODEL-A& APEX)_JEE-MAIN_GTM-1_Q'P Follows the order A) I> IV >1> IE B)IV>M>1>1 OU>I> Veil D)M>U>IV>1 43. Identify the major organic product [R] in the given reaction sequence rs 103 (ten) ps 10 ph 2. Zn+H,0 [ptsson IR] major organic product HC" 2 OH B) oon c) D) 44, The tests performed on compound X and their inferences are: Test Interference (@) [2.4-DNP test | No coloured precipitate (b) [Todoform test_| Yellow precipitate (© | Azo-dye test | Dye formation ‘Compound “ Page. No. 10 APex Narayana IIT Academy 18-12-24. SR.lIT_*CO-SC(MODEL-A& APEX)_JEE-MAIN_GTM-1_Q'P HC. CH a2 BCH cock. HO. . A) B) HeC CH NH, OH Ny cHo ‘CH ° D) 45. The compound ‘X’ undergoing the following reaction is 1. ait NaOH 2H x] ———__> ono, Wl yaakicno, MO 4 Meat cH.cl a oH ‘ : : CHCl : “ A) 2H B) OH C) Se D) OH SECTION-I (NUMERICAL VALUE ANSWER TYPE) ‘This section contains 5 questions. The answer to each question is a Numerical valve. If the Answer in the decimals Round off to the nearest Integer only. Have te Answer all 5 questions and question will be evaluated ‘according to the following marking scheme: Marking Scheme: +4 for correct answer, 0 if not attempted and ~1 if not correct. 46. Depression in freezing point of 0.01 molal aq. CH,COOH solution is 0.02046 °C. 1 molal urea solution freezes at ~1,86°C. Assuming molality equal to molarity, pH of CH,COOH solution is__ 47. Decomposition of HO, is a first order reaction. A “16” V solution of H,O, of half-life period 30 minutes is present at start, After how many minutes the solution will become vv? 48. How many total isomers (structural + stereo isomers) are possible for a compound with formula, [ Rh(en), Cl(NO. )] Page. No. 11 APex Narayana IIT Academy 18-12-24_SR.IIT_*CO-SC(MODEL-A& APEX) _JEE-MAIN_GTM-| 49. Number of different organic products obtained when a mixture of optically pure D- glucose and D-fructose are reduced with excess of NaBH, in same reaction vessel? 50, Among the given reactions in how many reactions number of carbon atoms is same in starting material and final product (note: consider major organic product in each case) 1 cncna MCX, _onnmo money, [P| arial iydra major product 2. . FelHClL_ NaNO, + HCL WHO CoHsNO: ae 7 1a) os td 3. cigar EL A el OF semis iy 0° product 4 20BrNaNOs+ CH;CO;H a robe NO iT major ae 5. Fel _NaNOytHC1_CuCNIKCN Lit, ; abe 0 CaHNO: 23K ervey major product 6. : FeCl, _NsNO+HCL 1,00, CaN, Se = vl uA major product Page. No. 12 APex Narayana IIT Academy 18-12-24. SR.lIT_*CO-SC(MODEL-A& APEX)_JEE-MAIN_GTM-1_Q'P. MATHEMATICS MAX.MARKS: 100 SECTION -1 (SINGLE CORRECT ANSWER TYPE) This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, ‘out of which ONLY ONE option can be correct. Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct. 51. Let complex numbers z,,z, satisfy Re(z,)>0, Re(z,)>0 and Re(z:)=Re(z: 2 ) (Re(z) represents the real part of a complex number z). then the minimum value of lz, +2|+ A) v2 B) 3y2 © 4v2 D) Sy2 52. The total number of 5-digit numbers, formed by using the digits 1, 2, 3, 5, 6, 7 without repetition which are multiple of 6, is A) 36 B) 48 c) 60 b)72 53. Suppose complex numbers z, w satisfy | 3 and (2+ w)(z—w)=7+4i where “i is the imaginary unit, and z, w are conjugates of complex numbers z,w respectively. Then the modulus of (z+ 2w)(z-2w) is A) V65 B) V75 ©) 65 D)49 54. In the Cartesian plane, ellipse ‘C’ is given by Bt Point F is the upper focus of C, 10” Ais the right vertex C, and P is a moving point on *C’ in the first quadrant. The maximum area of quadrilateral OAPF is A) VI B) a ov D) au 55. The area of the region described by A ={(x,y):x° +" Sland y* <1—x} is 2 att pz? p)Z44 23 rae) 2 Page. No. 13 APex Narayana IIT Academy 18-12-24. SR.lIT_*CO-SC(MODEL-A& APEX)_JEE-MAIN_GTM-1_Q'P 56. The solution of the differential equation i 4+2y=x'(x#0) with y(1) = 1, is ro A) y=X 4, yy 4 ae fel +x°=1)dx _ 37 pe (2x' +3x° +2) f(x)+c then f(x)=__ (where ¢ is integration constant) B) Flex ey ° ~EQw 43x' 42x)" D) (SeEet) 58. Let A= { re (0,24): A 2 spuy agin. ‘Then the sum of the elements in A —isind is A) 2a B) 42 Ox D) 3a 59. If the numbers appeared on the two throws ofa fair six faced die are « and f, then the probability that x° +ax +B >0, forall x eR, is A) Z B) 3 c) ; D) 2 60. If @ and are the roots of the equation, 7x*=3x~2=0, then the value of is equal to: 27 1 3 27 AS B) — Oz p= » 32 34 8 16 61. The 8° common term of the series S,=34THTFIS +19 tevcegS, =1+ 6411416 +214 vereee is A) 151 B) 171 ©) 160 D)161 Page. No. 14 Narayana IIT Academy 18-12-24. SR.lIT_*CO-SC(MODEL-A& APEX)_JEE-MAIN_GTM-1_Q'P 62. The value of j 209K a0 Leal A) x/2 B) az C) 2a D)x/a 63. The remainder, when 7" is divided by 17 is A)s B) 12 1B D)6 64. The maximum value of the term independent of t in the expansion of tery" [= er) . where x €(0,I)is 2.10! 10! Sey” Bay 65. Let A={x,.x. x,} and B={y,,y,,y,} be two sets containing seven and three distinct elements respectively. Then the total number of functions f : A —> B that are onto, if there exist exactly three elements x in A such that f(x) = A) 14/C, B) 16/C, ic tzece D) 14C, ;, is equal to 66. Let the solution curve y = y(x) of the differential equation dy _3x'tan“(x') a (ex) yrog| (here exp represents exponential function) Pass through the origin. Then y(1) is equal to 4-0 I=n A) exp{2*2\ By exp{3=2) og F=E\ Dy expy 24 Jeo{Sz} meolts} © aollag] orenltsf 67. _ Four distinct points (2k,3k),(1.0),(0.1)and(0,0) lie on a circle for k equal to : 2 3 5 1 A= B) = o= D)— 1B 3 1B 3 Page. No. 15 Narayana IIT Academy 18-12-24_SR.IIT_*CO-SC(MODEL-A& APEX)_JEE-MAIN_GTM-1_Q'P_ 68. The length of the chord of the parabola x’ = 4y having equation x — V2y +42 =0 is A) 3V2 B) 2ViT ©) 8V2 D) 6v3 23 6 baw 69, Let P]) ——,——|.Q,R and S be four points on the ellipse 9x’ +4y’ =36 Let PQ and | Wi #] ° " me one ty 1 1 RS be mutually perpendicular and pass through the origin. If ——~ (PQ) (RS) where p and q are coprime, then p + q is equal to A) 157 B) 143 ©) 137 D) 147 70. fxe'*(24+xsee" x)dx = A) 2e'™+C B) x’e'™ +C C) Tanx +xe"" +C D) x +xe™"4+C SECTION-I (NUMERICAL VALUE ANSWER TYPE) This section contains 5 questions. The answer to each question is a Numerical valve. If the Answer in the decimals Round off to the nearest Integer only. Have to Answer all 5 questions and question will be evaluated ‘according to the following marking scheme: ‘Marking Scheme: +4 for correct answer, 0 if not attempted and —1 if not correct. 71. Let ‘m’ be the real solution to the equation 29(2 8x +55 x+2 x43 then the minimum value of a+b is sin x ~ cos. )+xcosx n2 wees dx = Tan" (f(x))+C where *C’ is the constant x +(e -1-x) (f@) of integration and lim f(x) =0, if lim £08) _P here piq.eN then find the least value lin a ofp+a Page. No. 16 APex Narayana IIT Academy 18-12-24. SR.lIT_*CO-SC(MODEL-A& APEX)_JEE-MAIN_GTM-1_Q'P 73. Let N denote the sum of the numbers obtained when two dice are rolled. If the probability that 2°

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