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JEE
Practice Sheet (Chemistry)

Salt Analysis
Single Correct Type Questions (1 to 15) 10. Na2S + HCl ⎯→ NaCl + “X”. X is :
1. CO2 gas gives following test (1) H2S (2) H2SO4
(1) lime water (2) Baryta water (3) H2SO3 (4) H2S2O3
(3) Both (4) None
11. Which of the following gas has rotten egg smell
2. X + 70% HNO3 → H2SO4 + NO2 then, X can be (1) PH3 (2) NH3
(1) SO2 (2) S8 (3) H2S (4) PbS
(3) H2 (4) N2
12. What is possible oxidation state of S in Na2S2O3 ?
3. X + NaOH → XOH + H2 , X can be (1) 0 (2) +4
(1) Al (2) Na (3) –2 (4) –4
(3) Si (4) C

4. In the reaction sequence: 13. H2S + Na2[Fe(CN)5NO] ⎯→ NO, reaction, It

means
CrCl3 ⎯⎯⎯→ (1) ⎯⎯⎯⎯ → (B) ⎯⎯⎯
n
NH4Cl Na 2O2 sol lead
→ (3)
NH4OH acetate (1) S2– ion absent
In this reaction sequence compound C is (2) S2– ion may be present
(1) Na2CrO4 (2) Na2Cr2O7 (3) S2– ion is present in excess
(3) Cr(OH)3 (4) PbCrO4 (4) S2– ion form precipitate

5. Which compound is yellow coloured? 

14. Na2S2O3.5H2O ⎯⎯ → “X”, where X is :
(1) Ag2S (2) PbS
(1) Na2S5 (2) Na2SO4
(3) HgS (4) CdS
(3) Na2S2O3 (4) No reaction.
6. CO2 & SO2 can be distinguished by
15. S2O32– + BaCl2 ⎯→ White ppt of
(1) lime Water (2) Baryta Water
(1) BaSO4 (2) BaS
(3) Both (4) KMnO4 / H+
(3) BaS2O3 (4) BaSO3
7. Which of the following acid radical does not
produce white ppt with Pb(OAc)2 solution. More then one correct Type Questions (16-18)
(1) Br– (2) S2O32− 16. Which of the following salts will not give borax
bead test ?
(3) CO32− (4) None of these
(1) Al(NO3 )3 (2) CoCl2
8. H2S is passed into BaCl2 solution. The ppt formed is (3) CoC2O4 (4) K 2 C2 O 4
(1) BaS
(2) Ba(SH)2 17. Which of the following radicals evolve gas or
(3) Ba(OH)2 vapour when treated with dil. HCl ?
(4) no ppt. (1) SO32−
(2) C2O42−
9. Which is not easily precipitated from aqueous
solution (3) CH3COO−
(1) Cl– (2) SO24− (4) HCO3−
(3) NO3− (4) CO32−
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18. Which of the following sulphides are yellow ? HCl/dil. H2SO4)

(1) Cds (2) As2S3 (A) S2O32− P. Gas evolved turns
(3) SnS2 (4) ZnS lime water milky
(B) SO32− Q. Gas turns lead
Passage Type Questions (19-20)
acetale paper black
Borax [Na2B4O7 .10H2O] when heated on platinum loop it (C) CO32− R. Gas turns acidified
gives a dark transparent glass like bead. The hot K2Cr2O7 solution
bead is dipped in the salt till it reacts with transition green
metal oxide. It produces characteristic bead of meta (D) S2− S. Gives white turbidity
borate. A B C D
(1) P, R, S P, R P, Q, R
Colour of the bead Ion
(2) Q, R P P, R, S
(a) Bule green or light blue Cu+2 (3) P, Q, R, P, R, S
(b) Yellow Fe+2 or Fe+3 (4) P,Q S, P, R, R
(c) Green Cr+3 Integer Type Questions (23 to 25)
(d) Violet Mn+2 23. The oxidation number of Fe in [Fe(H2O)5 NO]SO4 is
(e) Dark blue Co+2
(f) Brown Ni+2
24. What will be oxidation state of iron in given complex
19. Glassy bead is of (Product)?
(1) B2O3 + NaBO2 (2) Na3BO3 Na2[Fe(CN)5 NO] + Na2S → Na4[Fe(CN)5 NOS]
(3) Na2B4O7 (4) SiO2
25. How many moles of KCN are required to convert 1
20. The colour of bead Ni(BO2)2 is
mole of CuSO4 to [Cu(CN)4 ]−3
(1) Green (2) Brown
(3) Violet (4) Blue

Matrix Match Type Questions (21 to 22)

21. Match the following :
Column I Column II
(A) Borax ⎯⎯ 
→ P. Inorganic
beznene
(B) Borax + NH4Cl ⎯⎯ 
→ Q. NaBO2+B2O3
(C) Borax + NH3 ⎯⎯ 
→ R. (BN)x
(D) Borax + H2O → S. H3BO3
A B C D
(1) P, R, P, R, S
(2) Q, R, P, R, S
(3) P, Q, R, P, R, S
(4) P,Q S, P, R, R
22. Match the following :
Column I Column II
(Addition of dil. (Observation)
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Answer Key
1. (3) 14. (3)
2. (2) 15. (3)
3. (1) 16. (1, 4)
4. (4) 17. (1, 3, 4)
5. (4) 18. (1, 2, 3)
6. (4) 19. (1)
7. (4) 20. (2)
8. (4) 21. (2)
9. (3) 22. (1)
10. (1) 23. (1)
11. (3) 24. (2)
12. (3) 25. (5)
13. (2)

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