ST ANDREWS SCOTS SR SEC SCHOOL

9th Avenue, I.P.Extension, Patparganj, Delhi - 92

WORKSHEET OF CHEMISTRY
Class 11 - Chemistry

Section A

1. Calculate the enthalpy change on freezing of 1.0 mol of water at 10.0oC to ice at -10.0oC. Δfus H = 6.03 kJ mol- [2]
1 at 0oC. Cp [H2O(1)] = 75.3 Jmol-1 K-1 ; Cp[H2O(s)] = 36.8 J mol-1 K-1.
2. Calculate the standard enthalpy of formation of CH3OH(l) from the following data: [2]

i. CH3OH(l) + 3

2
O2(g) ⟶ CO2(g) + 2H2O(l) ; Δ rH
⊖
= -726 kJ mol-1

ii. C(graphite) + O2(g) ⟶ CO2(g); Δ cH

⊖
= -393 kJ mol-1

iii. H2(g) + 1

2
O2(g) ⟶ H2O(l); Δ f H
⊖
= -286 kJ mol-1

3. Find out the value of the equilibrium constant for the following reaction at 298 K. [2]
2NH3 (g) + CO2 (g) ⇌ NH2 CONH2 (aq) + H2 O(l)

Standard Gibbs energy change, Δ rG

⊖
at the given temperature, is -13.6 kJ mol-1.
4. If water vapour is assumed to be a perfect gas, the molar enthalpy change for vapourization of 1 mol of water at [2]

1bar and 100°C is 41kJ mol–1. Calculate the internal energy change, when 1 mol of water is vapourised at 1 bar
pressure and 100°C.
5. Enthalpy of combustion of carbon to carbon dioxide is -393.5 kJ mol-1. Calculate the heat released upon the [2]
formation of 35.2 g of CO2 from carbon and oxygen gas.
6. Calculate the number of kJ of heat necessary to raise the temperature of 60 g of aluminium from 35 to 55° C. [2]

Molar heat capacity of Al is 24 J mol-1 K-1.

7. The standard molar enthalpy of formation, Δ f H
⊖
is just a special case of enthalpy of reaction,Δ
rH
⊖
. Is the [2]
Δr H
⊖
for the following reaction same as Δ f H
⊖
? Give the reason for your answer.
CaO(s) + CO2 (g) ⟶ CaCO3 (s)

⊖ −1
Δf H = −178.3kJ mol

8. Change in internal energy is a state function while work is not, why? [2]
9. An average healthy man needs about 10000 kJ of energy per day. How much carbohydrates (in mass) he will [2]
have to consume assuming that all these energy needs are met only by carbohydrates in the form of glucose? The

enthalpy of combustion of glucose is 2816 kJ mol-1.

10. A swimmer coming out from a pool is covered with a film of water weighing about 18 g. How much heat must [2]
be supplied to evaporate this water at 298 K? Calculate the internal energy of vaporisation at 100°C?
Δvap H
⊖
for water at 373 K = 40.66 kJ mol-1.
11. Show the polarization of carbon-magnesium bond in the following structure: CH3—CH2—CH2—CH2—Mg— [2]

X.
12. Using curved-arrow notation, show the formation of reactive intermediates when the following covalent bonds [2]

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 undergo heterolytic cleavage.
a. CH3–SCH3

b. CH3–CN
c. CH3–Cu
13. An alkane has a molecular mass of 72. Draw all its possible chain isomers and write their IUPAC names. [2]
14. What are the possible structures for a carboxylic acid with a molecular formula C4H8O2 and label each C atom [2]

as sp, sp2 and sp3?

15. Why is an organic compound fused with sodium in Lassaigne's test? [2]
16. Give IUPAC names of the following structures. [2]

i.

ii.

iii.

17. How does hybridization affect the electronegativity? [2]

18. What are electrophiles? Explain electrophile substitution reaction with the help of example. [2]
19. How many σ and π bonds are present in each of the following molecules? [2]
a. HC≡CCH=CHCH3
b. CH2=C=CHCH3

20. Which of the following ions is more stable? Use resonance to explain your answer. [2]

Section B
21. The standard molar enthalpies of formation of cyclohexane (l) and benzene (l) at 25oC are -156 and +49 kJ mol- [3]
1 respectively.
The standard enthalpy of hydrogenation of cyclohexene (l) at 25oC is -119 kJ mol-1. Use these data to estimate
the magnitude of the resonance energy of benzene.
22. Express the change in internal energy of a system when [3]
i. No heat is absorbed by the system from the surroundings, but work (w) is done on the system. What type of
wall does the system have?
ii. No work is done on the system, but q amount of heat is taken out from the system and given to the
surroundings. What type of wall does the system have?
iii. w amount of work is done by the system and q amount of heat is supplied to the system. What type of system
would it be?

23. The enthalpy of vaporisation of liquid diethyl ether (C2H5)2O is 26.0 kJ mol-1 at its boiling point (35.0°C). [3]

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 Calculate ΔS° for the conversion of
i. liquid to vapour and
ii. vapour to liquid at 35°C.
24. How will you calculate work done on an ideal gas in a compression, when the change in pressure is carried out [3]
in infinite steps?
25. Using the data (all values are in kilocalories per mole at 25°C) given below, calculate the bond energy of C-C [3]
and C-H bonds.
ΔH
o
combustion (ethane) = -372.0
ΔH
o
combustion (propane) = -530.0
ΔH
o
for C (graphite) → C(g) = 172.0
Bond energy of H - H = 104.0
Δf H
o
of H2O (l) = - 68.0

ΔH
o
for CO2(g) = - 94.0
26. Give reason for the following: [3]
i. Neither q nor w is a state function but q + w is a state function.
ii. A real crystal has more entropy than an ideal crystal.

27. For the reaction, 2A(g) + B(g) ⟶ 2D (g); ΔU = -10.5 kJ and ΔS = -44.1 JK-1. Calculate ΔG for the
o o o [3]

reaction and predict whether the reaction may occur spontaneously. (R = 8.314 × 10-3 kJ K-1mol-1, T = 298K)
28. Predict in which of the following, entropy increases/decreases [3]
i. A liquid crystallizes into a solid.
ii. The temperature of a crystallize solid is raised from 0 K to 115 K
iii. 2NaHCO3(s) ⟶ Na2CO3 (s) + CO2 (g) + H2O (g)
iv. H2(g) ⟶ 2H (g)

29. i. Why standard entropy of an elementary substance is not zero whereas standard enthalpy of formation is [3]
taken as zero?
ii. Under what conditions will the reaction occur, if
a. both ΔH and ΔS are positive
b. both ΔH and ΔS are negative

30. 221.4J is needed to heat 30g of ethanol from 150C to 180C. Calculate (a) specific heat capacity, and (b) molar [3]

heat capacity of ethanol.

31. Arrange the following: [3]
+ + + +

i. C H CHCH , C6 H5 CHCH
6 5 3
= CH2 , C6 H5 CH2 CH2 , C6 H5 C (CH3 )2 in order of increasing stability.
+ + + +
ii. CH CH 3 2
, C H CH
6 5 2
,( CH
3
)
3
C , CH2
= CHCH2 in order of decreasing stability.

iii. HC = C
−
, CH2 = CH-, CH3CH −

2
, CH
−

3
, (CH3)2CH-, C6H5CH in order of increasing stability.
−

32. Draw the resonance structures of the following compounds: [3]

i.

ii. CH2 = CH — CH = CH2

iii. CH 2 = CH − C = O
|

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33. Will CCl4 give a white precipitate of AgCl on heating it with AgNO3? [3]

34. Derive the structure of 3 – Nitrocyclohexene. [3]

35. Explain hyperconjugation effect. How does hyperconjugation effect explain the stability of alkenes? [3]
36. What are electrophiles and nucleophiles? Explain with examples. [3]
37. Write the IUPAC name of the compound from its given structure. [3]
1 2 3 4 5 6 7 8

C H3 − C H2 − C H − C H2 − C H2 − C H − C H2 − C H3
| C H3

OH

38. 0.395 g of an organic compound by Carius method for the estimation of sulphur gave 0.582 g of BaSO4. [3]

Calculate the percentage of sculpture in the compound.

39. An organic compound contains 69% carbon and 4.8% hydrogen, the remainder being oxygen. Calculate the [3]
masses of carbon dioxide and water produced when 0.20 g of this compound is subjected to complete
combustion.
40. Discuss the chemistry of Lassaigne's test. [3]
Section C
41. The figure given below represents pV diagram of different stages of a thermodynamic process. Calculate the [5]
work done in each stage and also the net work done in the complete cyclic process.

42. The lattice enthalpy of an ionic compound is the enthalpy when one mole of an ionic compound present in its [5]
gaseous state, dissociates into its ions. It is impossible to determine it directly by experiment. Suggest and
explain an indirect method to measure lattice enthalpy of NaCl(s).
43. i. An athlete is given 100 g of glucose of energy equivalent to 1560 kJ. He utilises 50% of this gained energy in [5]
the event. In order to avoid storage of energy in the body, calculate the weight of water that would need to

perspire. The enthalpy of vaporisation of water is 44 kJ mol-1.

ii. Compound with carbon-carbon double bond, such as ethylene, C2H4, add hydrogen in a reaction called

hydrogenation,
C2 H4 (g) + H2 (g) ⟶ C2 H6 (g)

Calculate enthalpy change for the reaction, using the following combustion data
C2 H4 (g) + 3O2 (g) ⟶ 2CO2 (g) + 2H2 O(l); Δc H
∘
= −1401kJ mol
−1
... (i)
C2 H6 (g) +
7

2
O2 (g) ⟶ 2CO2 (g) + 3H2 O(l); Δc H
∘
= −1550kJ mol
−1
... (ii)
H2 (g) +
1

2
O2 (g) ⟶ H2 O(l) ;Δ cH
∘
= −286.0kJ mol
−1
... (iii)

44. i. What is bond energy? Why is it called enthalpy of atomization? [5]

ii. Calculate the bond energy of C - H bond, given that the heat of formation of CH4, the heat of sublimation of

carbon and heat of dissociation of H2 are -74.8, + 719.6, 435.4 kJ mol-1 respectively.

45. i. A cylinder of gas supplied by a company is assumed to contain 14 kg of butane. If a normal family requires [5]

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 20000 kJ of energy per day for cooking, how long will the cylinder last?
ii. If the air supplied to the burner is insufficient, a portion of gas escapes without combustion. Assuming that
25% of the gas is wasted due to this inefficiency, how long will the cylinder last? (Heat of combustion of
butane = 2658 kJ/mol.)
46. Δ G is net energy available to do useful work and is thus a measure of “free energy”. Show mathematically that [5]
Δ G is a measure of free energy. Find the unit of ΔG. If a reaction has positive enthalpy change and positive
entropy change, under what condition will the reaction be spontaneous?
47. The combustion of one mole of benzene takes place at 298 K and 1 atm. After combustion, CO2(g) and H2O (I) [5]
are produced and 3267.0 kJ of heat is liberated. Calculate the standard enthalpy of formation, Δ f H
⊖
of

benzene. Standard enthalpies of formation of CO2 (g) and H2O (I) and -393.5 kJ mol-1 and -285.83 kJ mol-1

respectively.
48. i. When 20.0 g of ammonium nitrate (NH4N03) is dissolved in 125 g of water in a coffee-cup calorimeter, the [5]

temperature falls from 296.5 K to 286.4 K. Find the value of q for the calorimeter. (Treat heat capacity of
water as the heat capacity of the calorimeter and its contents).
ii. A chemist while studying the properties of gaseous CCl2F2, a chlorofluorocarbon refrigerant, cooled a 1.25 g
sample at constant atmospheric pressure of 1.0 atm from 320 K to 293 K. During cooling, the sample volume
decreased from 274 to 248 mL. Calculate ΔH and ΔU for the chlorofluorocarbon for this process. For
CCl2F2, Cp = 80.7 J/(mol K).

49. Extensive properties depend on the quantity of matter but intensive properties do not. Explain whether the [5]
following properties are extensive or intensive:
Mass, internal energy, pressure, heat capacity, molar heat capacity, density, mole fraction, specific heat,
temperature and molarity.
50. Derive the relationship between ΔH and ΔU for an ideal gas. Explain each term involved in the equation. [5]
51. Three students, Manish, Ramesh and Rajni were determining the extra elements present in an organic compound [5]
given by their teacher. They prepared the Lassaigne’s extract (L.E.) independently by the fusion of the
compound with sodium metal. Then they added solid FeSO4 and dilute sulphuric acid to a part of Lassaigne’s

extract. Manish and Rajni obtained Prussian blue colour but Ramesh got a red colour. Ramesh repeated the test
with the same Lassaigne’s extract but again got red colour only. They were surprised and went to their teacher
and told him about their observation. The teacher asked them to think over the reason for this. Can you help
them by giving the reason for this observation? Also, write the chemical equations to explain the formation of
compounds of different colours.
52. Draw the resonance structures for the following compounds. Show the electron shift using curved-arrow [5]
notation.
a. C6H5OH

b. C6H5NO2

c. CH3CH=CHCHO
d. C6H5–CHO
+

e. C6 H5 − C H2

f. C H 3CH = C H C H2

[5]

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53. What is meant by hybridization? Compound CH2 = C = CH2 contains sp or sp2 hybridized carbon atoms. Will it

be a planar molecule?
54. Expand each of the following bond-line formulas to show all the atoms including carbon and hydrogen. [5]

a.

b.

c.

d.

55. The following organic compounds are popularly known by their common names: [5]
a. neo-pentane
b. Acetone
c. Vinyl-chloride
d. test-amyl alcohol
e. iso-butyl bromide
f. Allyl alcohol
g. Formaldehyde
h. Glycerol
Write the structural formulas and IUPAC names.
56. Discuss the principle of estimation of halogens, sulphur and phosporus present in an organic compound. [5]
57. A liquid with high boiling point decomposes on simple distillation but it can be steam distilled for its [5]
purification. Explain how is it possible?
58. Give a brief description of the principles of the following techniques taking an example in each case: [5]
a. Crystallisation
b. Distillation
c. Chromatography
59. Write the IUPAC names of the compounds i-iv from their given structures. [5]
1 2 3 4 5 6 7 8

i. C H 3
− C H2 − C H − C H2 − C H2 − C H − C H2 − C H3
| |
OH CH
3

O O
|| ||

ii. C H 3 − C H2 − C − C H2 − C − C H3
6 5 4 3 2 1

O
||

iii. C H 3 − C − C H2 − C H2 − C H2 − C OOH
6 5 4 3 2 1

iv. C H ≡ C − C H = C H − C H = C H2
6 5 4 3 2 1

60. Draw the structures of [5]

i. 2-chlorohexane,
ii. pent-4-en-2-oI,
iii. 3-nitrocyclohexene,
iv. cyclohex-2-en-1-ol,

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v. 6-hydroxy-heptanal.

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