Eng.

Admission Program, 2024

WM-11, Physical, Written, Set-E
HMath 1st Paper, Ch-09+10, (AšÍixKiY+†hvMRxKiY)
D”PZi MwYZ HMath
01 10
x = sec y n‡j, x (x − 1)y + x(2x − 1)y − 2 Gi gvb If x = sec y , then determine the value of, x (x − 1)y +
wbY©q Ki| x(2x − 1)y − 2.
x = sec y x = sec y
y = sec x y = sec x
⇒ y = (sec x) ⇒ y = 2 sec x× ⇒ y = (sec x) ⇒ y = 2 sec x×
√ √
⇒ x√x − 1y = 2 sec x ⇒ x√x − 1y = 2 sec x
× ×
⇒ x√x − 1y + √x − 1 + y = ⇒ x√x − 1y + √x − 1 + y =
√ √ √ √

⇒ x√x − 1y + ×y = ⇒ x√x − 1y + ×y =
√ √ √ √
⇒ x (x − 1)y + x(2x − 1)y = 2 ⇒ x (x − 1)y + x(2x − 1)y = 2
∴ x (x − 1)y + x(2x − 1)y − 2 = 0 ∴ x (x − 1)y + x(2x − 1)y − 2 = 0

b¤^i eÈbt Marks distribution:

y = 2 sec x× ; wbY©‡qi Rb¨ 04 b¤^i| 04 marks for determining, y = 2 sec x× .
√ √

x√x − 1y + ×y = ; wbY©‡qi Rb¨ 02 b¤^i| 02 marks for determining, x√x − 1y + ×y =

√ √ √
x (x − 1)y + x(2x − 1)y − 2 = 0; wbY©‡qi Rb¨ 04 b¤^i|
√
04 marks for determining, x (x − 1)y + x(2x − 1)y −
2=0

D”PZi MwYZ HMath

02 10
hw` 5 𝑓𝑡 D”PZvi GKwU evjK 19 𝑓𝑡 D”PZvi GKwU j¨v¤ú‡cv‡÷i w`‡K A 5 ft boy runs towards a 19 ft tall lamp post. The rate of
†`uŠovq Z‡e j¨v¤ú‡cv‡÷i Av‡jvq Zvi †h Qvqv c‡o Zv cwieZ©‡bi nvi change in the boy’s shadow length is 2.5 𝑓𝑡/𝑠. Determine
2.5 𝑓𝑡/𝑠| evj‡Ki †`uŠ‡oi †eM wbY©q Ki| the running velocity of the boy.

v 19 ft v 19 ft
5 ft 5 ft
x ft y ft x ft y ft
awi, evjK n‡Z j¨v¤ú‡cv‡÷i `yiZ¡ y ft Ges Zvi Qvqvi ˆ`N©¨ x ft Let, the distance from the boy to lamp post is y ft and length
∴v=− ; Avevi = −2.5 ft/s of shadow is x ft.
∴v=− ; Again = −2.5 ft/s
GLb, =
Now, =
⇒ 19x = 5x + 5y ⇒ 14x = 5y ⇒ 14 =5 ⇒
⇒ 19x = 5x + 5y ⇒ 14x = 5y ⇒ 14 =5 ⇒
14(−2.5) = 5
14(−2.5) = 5
= −7 ft/s
∴ evj‡Ki †`uŠ‡oi †eM 7 ft/s = −7 ft/s
 ∴ running velocity of the boy’s 7 ft/s
b¤^i eÈbt
= ; wbY©‡qi Rb¨ 04 b¤^i| Marks distribution:
For determining, = ; 04 marks.
evj‡Ki †`uŠ‡oi †eM 7 ft/s; wbY©‡qi Rb¨ 06 b¤^i|
[we:`ª: GKK bv wjL‡j ev fzj GKK wjL‡j 01 b¤^র KZ©b Kiv n‡e|] For determining, running velocity of the boy’s 7 ft/s; 06
marks.
[N. B: 01 mark will be deducted if unit is not written or
wrong unit is written.]

D”PZi MwYZ HMath

03 10
GKwU wÎgvwÎK dvsk‡b x = −3 we›`y‡Z Mwiôgvb 15 Ges x = 1 we›`y‡Z In a 3 degree function the maxima at point x = −3 is 15 and at
jwNôgvb −17 n‡j, dvskbwU wbY©q Ki| point x = 1 the minima is – 17. Find the function.
awi, dvskbwU f(x) = ax + bx + cx + d ∴ f (x) = 3ax + Let, the function be f(x) = ax + bx + cx + d ∴ f (x) =
2bx + c 3ax + 2bx + c
†h‡nZy x = −3 Gi Rb¨ Mwiôgvb ∴ f (−3) = 0 As there is a maxima at x = −3, ∴ f (−3) = 0
∴ 27a − 6b + c = 0 ..................(i) ∴ 27a − 6b + c = 0 ..................(i) And for x = −3 the maxima
Ges x = −3 Gi Rb¨ Mwiôgvb = 15 ∴ f(−3) = 15 is = 15 ∴ f(−3) = 15
∴ −27a + 9b − 3c + d = 15 .........(ii) ∴ −27a + 9b − 3c + d = 15 .........(ii); Again, there is a
Avevi, x = 1 Gi Rb¨ dvskbwUi jwNôgvb ∴ f (1) = 0; 3a + 2b + minima at, x = 1, ∴ f (1) = 0
c = 0 ...........(iii) 3a + 2b + c = 0 ...........(iii)
Ges x = 1 Gi Rb¨ jwNôgvb = −17 ⇒ a + b + c + d = −17 and for x = 1 the minima will be = −17 ⇒ a + b + c + d =
−17 ...............(iv
...............(iv)
Solving the equations (i), (ii), (iii), (iv), a = 1, b = 3, c =
(i), (ii), (iii), (iv) mgvavb K‡i cvB, a = 1, b = 3, c = −9, d =
−9, d = −12
−12 ∴ dvskbwU f(x) = x + 3x − 9x − 12 (Ans.)
∴ The required function is f(x) = x + 3x − 9x − 12 (Ans.)

b¤^i eÈbt
Marks distribution:
27a − 6b + c = 0 & − 27a + 9b − 3c + d = 15; wbY©‡qi Rb¨ 02 marks for determining, 27a − 6b + c = 0 & − 27a +
02 b¤^i| 9b − 3c + d = 15
3a + 2b + c = 0 & a + b + c + d = −17; wbY©‡qi Rb¨ 02 b¤^i| 02 marks for determining, 3a + 2b + c = 0 & a + b + c +
f(x) = x + 3x − 9x − 12; wbY©‡qi Rb¨ 06 b¤^i| d = −17
06 marks for determining, f(x) = x + 3x − 9x − 12

D”PZi MwYZ HMath

04 10
y = (x + 1)(x − 1)(x − 3) eµ‡iLvwU †h me we›`y‡Z x - A¶‡K Determine the slopes of the tangents drawn on the points
†Q` K‡i, H we›`y¸‡jv‡Z Aw¼Z ¯úk©Kmg~‡ni Xvj wbY©q Ki| where the curved line y = (x+1) (x-1) (x-3) intersects x-axis.
cÖ`Ë †iLvwU x A¶‡K †Q` K‡i| †m‡¶‡Î y = 0 The given line intersects x-axis. Thus y = 0
†Q`we›`ymg~n (–1,0), (1, 0), (3, 0) The intersecting points are (– 1,0), (1, 0), (3, 0)
cÖ`Ë mgxKiY n‡e, lny = ln (x + 1) + ln (x –1) + ln (x – 3) The given equation will be, ln y = ln (x + 1) +
∴ = + + ⇒ = (x– 1) (x– 3) + (x + ln (x – 1) + ln (x – 3)

1) (x– 3) + (x + 1) (x – 1) ∴ = + + ⇒ = (x– 1) (x– 3) + (x +

cÖ`Ë mgxKi‡Y we›`y¸‡jvi ¯’vbvs‡Ki gvb ewm‡q cvB, wb‡Y©q Xvj = 8, - 4, 1) (x– 3) + (x + 1) (x – 1)
8 (Ans.)
weKí: Putting the values of coordinates of the points in the equation,
†Q`we›`ymg~n (−1, 0), (1, 0), (3, 0) Required slope = 8, −4, 8 (Ans.)
y = (x + 1)(x − 1)(x − 3) = (x − 1)(x − 3) = x − Alternative:
3x − x + 3 ∴ = 3x − 6x − 1 Intersecting points (−1, 0), (1, 0), (3, 0)
y = (x + 1)(x − 1)(x − 3) = x2 − 1 (x − 3)
∴ = −4; = 8; =8 (Ans.) dy
= x − 3x2 − x + 3 ∴ = 3x2 − 6x − 1
dx

b¤^i eÈbt = −4; = 8; = 8 (Ans.)

†Q`we›`ymg~n (–1,0), (1, 0), (3, 0); wbY©‡qi Rb¨ 02 b¤^i|
= + + ; wbY©‡qi Rb¨ 04 b¤^i| Marks distribution:
For determining, intersecting points (−1, 0), (1, 0), (3, 0) ; 02
Xvj = 8, - 4, 8; wbY©‡qi Rb¨ 04 b¤^i|
marks.
For determining, = + + ; 04 marks.
weKí b¤^i eÈbt
†Q`we›`ymg~n (–1,0), (1, 0), (3, 0); wbY©‡qi Rb¨ 02 b¤^i| For determining, slope = 8, −4, 8 ; 04 marks.

= 3x − 6x − 1; wbY©‡qi Rb¨ 04 b¤^i|

Alternative Marks distribution:
= −4; = 8; = 8; wbY©‡qi Rb¨ 04 For determining, intersecting points (−1, 0), (1, 0), (3, 0) ; 02
b¤^i| marks.
For determining, = 3x − 6x − 1; 04 marks.

For determining, = −4; = 8; = 8;

04 marks.

D”PZi MwYZ HMath

05 10
S = {(x, y): xy = 8; y = x ; y = 1} Øviv Ave× mvaviY As‡ki Determine the area of common region enclosed by S =
†ÿÎdj wbY©q Ki| {(x, y): xy = 8; y = x ; y = 1}.
y=x2 xy=8 y=x2 xy=8
(2,4) (2,4)
(1,1) (8,1) (1,1) (8,1)
y=1 y=1
12 8 12 8

GLv‡b, 𝑥𝑦 = 8; 𝑦 = 𝑥 Here, 𝑥𝑦 = 8; 𝑦 = 𝑥
y = 1 I y = x Gi mgvavb: Solution of y = 1 and y = x
y=1∴x =1⇒x=1 y=1∴x =1⇒x=1
∴we›`y (1,1) ∴point (1,1)
xy = 8 I y = 1 Gi mgvavb: Solution of xy = 8 and y = 1
𝑥(1) = 8 ⇒ 𝑥 = 8 𝑥(1) = 8 ⇒ 𝑥 = 8
∴we›`y (8,1) ∴point (8,1)
xy = 8 I y = x Gi mgvavb: Solution of xy = 8 and y = x

=x ⇒x =8⇒x=2 =x ⇒x =8⇒x=2

y=x =4 y=x =4
∴we›`y (2,4) ∴point (2,4)
∴ A = ∫ (x − 1) dx + ∫ − 1 dx ∴ A = ∫ (x − 1) dx + ∫ − 1 dx

= −x + [8 ln x − x] = −x + [8 ln x − x]

= 16 ln 2 − eM© GKK = 16 ln 2 − sq. unit

b¤^i eÈbt Marks distribution:

we›`ymg~n (1,1), (8,1), (2,4); wbY©‡qi Rb¨ 03 b¤^i| For determining, points (1,1), (8,1), (2,4) ; 03 marks.
For determining, A = ∫ (x − 1) dx + ∫ − 1 dx; 04
A = ∫ (x − 1) dx + ∫ − 1 dx; wbY©‡qi Rb¨ 04 b¤^i| marks.
A = 16 ln 2 − eM© GKK; wbY©‡qi Rb¨ 03 b¤^i| For determining, A = 16 ln 2 − sq. unit; 03 marks.

D”PZi MwYZ HMath

06 10
y= Ges x-Aÿ Øviv Ave× †ÿ‡Îi †ÿÎdj wbY©q Ki| Determine the area of region enclosed by y = and x-
axis.
Y Y
1 1
X X
0 1 0 1

y=( )
; x = 1; y =1 y=( )
; x = 1; y =1
𝑥 → ±∞, 𝑦 → 0 𝑥 → ±∞, 𝑦 → 0
Area = 2 ∫ ( )
dx = 2[tan (x − 1)] = 2 × = Area = 2 ∫ ( )
dx = 2[tan (x − 1)] = 2 × = π
π eM© GKK sq. units

b¤^i eÈbt Marks distribution:

Area = 2 ∫ dx; wbY©‡qi Rb¨ 02 b¤^i| For determining, Area = 2 ∫ ( )
dx; 02 marks.
( )
For determining, Area = 2[tan (x − 1)] ; 02 marks.
Area = 2[tan (x − 1)] ; wbY©‡qi Rb¨ 02 b¤^i| For determining, Area = π sq. unit; 06 marks.
Area = π eM© GKK; wbY©‡qi Rb¨ 06 b¤^i|

Eng. Admission Program, 2024

WP-11, Weekly Physical, Written, Set-E
Physics 2nd Paper, Ch-07+08, Physical Optics and Modern Physics

c`v_©weÁvb Phy
01 [Medium] 10
Bqs Gi wØwPo cixÿvq GKwU wPo n‡Z AvMZ Av‡jvi ZxeªZv Aci wPo In Young's double-slit experiment, the intensity of light
†_‡K AvMZ Av‡jvi ZxeªZvi wZb¸Y| e¨wZPv‡ii d‡j m„ó †Wvivi m‡e©v”P I coming from one slit is three times than that from the other
me©wb¤œ ZxeªZvi AbycvZ KZ? slit. What is the ratio of the maximum and minimum
intensities of fringes formed due to interference?
 √ √
= ⇒ = ⇒ = = ⇒ = ⇒ =
√ √
GLb, = ∴ 𝐴 + 𝐴 = √3 + 1 𝐴 Now, = ∴ 𝐴 + 𝐴 = √3 + 1 𝐴
∴ MVbg~jK e¨wZPv‡ii †ÿ‡Î, A = √3 + 1 A ∴ For constructive interference: A = √3 + 1 A
√ √
Avevi, = ∴ 𝐴 − 𝐴 = √3 − 1 𝐴 Again, = ∴ 𝐴 − 𝐴 = √3 − 1 𝐴
aŸsmvZ¥K e¨wZPv‡ii †ÿ‡Î, A = √3 − 1 𝐴 For destructive interference: A = √3 − 1 𝐴
√ √
= = = 7 + 4√3 = 13.93 [Ans.] = = = 7 + 4√3 = 13.93 [Ans.]
√ √

b¤^i eÈbt Marks Distribution:

A = √3 + 1 A ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, A = √3 + 1 A
A = √3 − 1 𝐴 ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, A = √3 − 1 𝐴
= 13.93 ; wbY©q Kivi Rb¨ 04 b¤^i|
04 marks for determining, = 13.93

c`v_©weÁvb Phy
02 [Medium] 10
Bqs Gi wØ-wPo cixÿvq mv`v mym½Z Av‡jv (400 − 700nm) wPo؇qi In Young’s double-slit experiment, white coherent light
ga¨ w`‡q cvVv‡bv n‡jv| wPo؇qi ga¨eZx© `~iZ¡ 0.5 mm Ges wPoØq n‡Z (400-700 nm) was passed through two slits. The distance
c`©vi-`~iZ¡ 50 cm| c`©vi †K›`ªxq Pig n‡Z 1mm `~‡i GKwU we›`y Av‡Q| between the two slits is 0.5 mm, and the distance from the
we›`y‡Z AvcwZZ Av‡jv‡Z †Kvb †Kvb Zi½‰`‡N©¨i Av‡jv Abycw¯’Z _vK‡e? slits to the screen is 50 cm. There is a point located 1 mm
away from the central maxima on the screen.
Which wavelengths of light will be absent from the light
incident on the point?
λ = 400 − 700 nm λ = 400 − 700 nm
d = 0.5 × 10 m d = 0.5 × 10 m
D = 0.5m D = 0.5m
y = 1 × 10 m y = 1 × 10 m
( ) ( )
Ae‡gi †ÿ‡Î Av‡jvi ZxeªZv k~b¨, y = intensity of light will be zero for minima, y =
( )× . × ( )× . ×
⇒ 10 = ⇒ 10 =
× . × × . ×
n = 1 n‡j, λ = 2000 nm (MÖnY‡hvM¨ bq) If n = 1, λ = 2000 nm [Which is not acceptable]
n = 2 n‡j, λ = 667 nm (Ans) If n = 2, λ = 667 nm (Ans)
n = 3 n‡j, λ = 400 nm (Ans) If n = 3, λ = 400 nm (Ans)

b¤^i eÈbt Marks Distribution:

( ) ( )
y = ; m~Î ‡jLvi Rb¨ 04 b¤^i| 04 marks for writing formula, y =
λ = 667 nm ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, λ = 667 nm
λ = 400 nm ; wbY©q Kivi Rb¨ 03 b¤^i|
03 marks for determining, λ = 400 nm
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| m~Î bv
wj‡L mivmwi gvb emv‡jI m~‡Îi Rb¨ eivÏK…Z b¤^i cv‡e|] [Note: 01 mark will be deducted if unit is not written or
wrong unit is written. Direct input of values without writing
formula is also acceptable.]

c`v_©weÁvb Phy
03 [Easy] 10
AceZ©b †MÖwUs G GKwU bxj e‡Y©i Av‡jvi Rb¨ cÖ_g AceZ©b †KvY 45° In a diffraction grating, the first-order diffraction angle for
cvIqv †Mj| cÖwZ wgUv‡i `vM msL¨v KZwU cwieZ©b Ki‡j AceZ©b †KvY blue light was found to be 45°. By how many number of
30° n‡e? [λ = 4700 Å] lines per meter should be changed to make the diffraction
angle 30° ?[λ = 4700 Å]
sin θ = nλ ⇒ N = sin θ = nλ ⇒ N =
° °
⇒N= ∴ N = 1.5 × 10 m ⇒N= ∴ N = 1.5 × 10 m
× ×
= ; ∆N = N − N = ; ∆N = N − N
° °
=N −1 =N − 1 = −4.4 × 10 =N −1 =N − 1 = −4.4 × 10
° °
cÖwZ wgUv‡i `vM msL¨v 4.4 × 10 wU Kgv‡Z n‡e| 4.4 × 10 lines have to be decreased per meter

weKí mgvavb: Alternative Solution:

𝑑 = = 𝑑 = =
∴ 𝑁 = 1.5 × 10 𝑙𝑖𝑛𝑒𝑠/𝑚 ∴ 𝑁 = 1.5 × 10 𝑙𝑖𝑛𝑒𝑠/𝑚
𝑑 = = 𝑑 = =
∴ 𝑁 = 1.06 × 10 𝑙𝑖𝑛𝑒𝑠/𝑚 ∴ 𝑁 = 1.06 × 10 𝑙𝑖𝑛𝑒𝑠/𝑚
∴ ∆N = 𝑁 − 𝑁 = − 4.4 × 10 ∴ ∆N = 𝑁 − 𝑁 = − 4.4 × 10
cÖwZ wgUv‡i `vM msL¨v 4.4 × 10 wU Kgv‡Z n‡e| 4.4 × 10 lines have to be decreased per meter

b¤^i eÈbt Marks Distribution:

N = 1.5 × 10 m ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, N = 1.5 × 10 m

∆N = N − 1 ; ‡jLvi Rb¨ 04 b¤^i| 04 marks for writing, ∆N = N −1

cÖwZ wgUv‡i `vM msL¨v 4.4 × 10 wU Kgv‡Z n‡e ; wbY©q Kivi Rb¨ 04 04 marks for determining, 4.4 × 10 lines have to be
b¤^i| decreased per meter

weKí b¤^i eÈbt Alternative Marks Distribution:

𝑁 = 1.5 × 10 𝑙𝑖𝑛𝑒𝑠/𝑚 ; wbY©q Kivi Rb¨ 04 b¤^i| 04 marks for determining, 𝑁 = 1.5 × 10 𝑙𝑖𝑛𝑒𝑠/𝑚
𝑁 = 1.06 × 10 𝑙𝑖𝑛𝑒𝑠/𝑚 ; wbY©q Kivi Rb¨ 04 b¤^i|
04 marks for determining, 𝑁 = 1.06 × 10 𝑙𝑖𝑛𝑒𝑠/𝑚
cÖwZ wgUv‡i `vM msL¨v 4.4 × 10 wU Kgv‡Z n‡e ; wbY©q Kivi Rb¨ 02
b¤^i| 02 marks for determining, 4.4 × 10 lines have to be
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| decreased per meter
[Note: 01 mark will be deducted if unit is not written or
wrong unit is written.

c`v_©weÁvb Phy
04 [Medium] 10
1mm cÖ¯’‡”Q‡`i cwievnx Zv‡ii cÖwZ GKK AvqZ‡b e msL¨v 4.5 × A conductive wire with a cross-sectional area of 1mm
10 wU| ZviwU GKwU d‡UvZwoZ †Kv‡l hy³| †KvlwU‡Z 370 nm Gi Av‡jv has e number of 4.5 × 10 per unit volume. The
AvcwZZ n‡j 1.7A we`y¨r cÖevwnZ nq| hw` d‡Uv B‡jKUªb Gi †eM cwievnx wire is connected to a photoelectric cell. If 370 nm
B‡jKUªb Gi †e‡Mi 2.5 × 10 ¸Y nq Z‡e d‡Uv Zwor †Kv‡li Kvhv©‡cÿK light is incident on the cell, then 1.7 A current flows. If
KZ? [ai, cÖwZwU cwievnx B‡jKUªb Zwor cÖev‡n Ask †bq] the velocity of the photoelectrons is 2.5 × 10 times
the velocity of the conduction electrons, what is the
work function of the photoelectric cell? [Assume, each
conduction electron contributes to the current flow]
V = 2.5 × 10 × V V = 2.5 × 10 × V
⇒ V = 2.5 × 10 × = 5.9 × 10 ms ⇒ V = 2.5 × 10 × = 5.9 × 10 ms
GLb, = + mv ⇒ − mv = W Now, = + mv ⇒ − mv = W
. × × × . × × ×
∴W = − × 9.11 × 10 × (5.9 × 10 ) ∴W = − × 9.11 × 10 ×
× ×
= 3.79 × 10 J = 2.37 eV (5.9 × 10 )
 = 3.79 × 10 J = 2.37 eV
b¤^i eÈbt
V = 5.9 × 10 ms ; wbY©q Kivi Rb¨ 03 b¤^i| Marks Distribution:

− mv = W ; ‡jLvi Rb¨ 03 b¤^i| 03 marks for determining, V = 5.9 × 10 ms

W = 3.79 × 10 J = 2.37 eV ; wbY©q Kivi Rb¨ 04 b¤^i| 03 marks for writing, − mv = W
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|
04 marks for determining, W = 3.79 × 10 J=
2.37 eV
[Note: 01 mark will be deducted if unit is not written
or wrong unit is written.

c`v_©weÁvb Phy
05 [Medium] 10
2 km j¤^v GKwU weªR‡K ïiæ‡Z 0.4c †e‡M GKwU 600 kg f‡ii Mvwo cvi n‡Z A 600 kg car tries to cross a 2 km long bridge at an
†Póv Kij| b~¨bZg mg‡q cvi n‡Z Mvwoi kw³i cwieZ©b KZ n‡Z n‡e? [weª‡Ri initial velocity of 0.4c. What should be the change in
aviY ÿgZv 9800N] energy of the car to cross the bridge in the shortest
time? [The bridge's load capacity is 9800N]
E = mc = × c = 5.892 × 10 J E = mc = × c = 5.892 × 10 J
√ . √ .
ধারণ মতা
Avevi, m = = = 1000 kg Again, m = = = 1000 kg
. .
∴E =m c = 1000 × 9 × 10 = 9 × 10 J ∴E =m c = 1000 × 9 × 10 = 9 × 10 J
∴ b~¨bZg mg‡q cvi n‡Z kw³i cwieZ©b, E − E = 3.108 × 10 J ∴ Energy change to cross the bridge in the shortest
time, E − E = 3.108 × 10 J
b¤^i eÈbt
Marks Distribution:
E = 5.892 × 10 J ; wbY©q Kivi Rb¨ 03 b¤^i|
E = 9 × 10 J ; wbY©q Kivi Rb¨ 05 b¤^i| 03 marks for determining, E = 5.892 × 10 J
E − E = 3.108 × 10 J ; wbY©q Kivi Rb¨ 02 b¤^i| 05 marks for determining, E = 9 × 10 J
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e| 02 marks for determining, E − E = 3.108 × 10 J
[Note: 01 mark will be deducted if unit is not written
or wrong unit is written.

c`v_©weÁvb Phy
06 [Easy] 10
350 m wbðj ˆ`‡N©¨i GKwU gnvKvkhvb Gi †eM 0.85c| GKwU wecixZgyLx A spaceship of rest length 350 m travels at a velocity
DévwcÐ gnvKvkhvbwU‡K 1.5 μs-G AwZµg Ki‡j G‡`i ga¨vKvi Av‡cwÿK of 0.85c. If a meteor travelling in the opposite direction
†eM KZ wQj? crosses the spaceship in 1.5 μs, what was the relative
velocity between the meteor and the spaceship?

× ×
t= ⇒ 1.5 × 10 = t= ⇒ 1.5 × 10 =
⇒ V = 1.842 × 10 ms [Ans.] ⇒ V = 1.842 × 10 ms [Ans.]

b¤^i eÈbt Marks Distribution:

t= ; ‡jLvi Rb¨ 03 b¤^i| 03 marks for writing, t =

mwVKfv‡e gvb emv‡bvi Rb¨ 04 b¤^i| 04 marks for putting the values correctly.
V = 1.842 × 10 ms ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, V = 1.842 × 10 ms
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|
[Note: 01 mark will be deducted if unit is not written or
wrong unit is written.
 Eng. Admission Program-2024
Weekly Exam Chemistry-11 (Physical) Written ‰Re †hŠM (A¨vjwWnvBW - A¨vwgb)
Set-E

imvqb Chem
01 10
‘𝐴’ †hŠM‡K RvwiZ K‡i I ‘𝐵’ †hŠM‡K weRvwiZ K‡i GKB †hŠM ‘𝐶’ Oxidation of compound ‘A’ and reduction of compound ‘B’
produces same compound ‘C’ whose molecular mass is 44.
cvIqv hvq, hvi AvYweK fi 44| ‘𝐶’ †hŠMwU wg_vBj A¨vwg‡bi mv‡_
wewµqv K‡i ‘𝐷’ †hŠM Drcbœ K‡i| Dchy³ wewµqvmn 𝐴, 𝐵, 𝐶 I 𝐷 When compound ‘C’ reacts with methyl amine, compound
†hŠMmg~n kbv³ Ki| ‘D’ is produced. Identify compounds A, B, C and D with
suitable reactions.
𝐶 Aek¨B A¨vjwWnvBW n‡e| †h‡nZz A¨vj‡Kvnj Rvi‡Y I Kve©w·wjK C is obviously aldehyde. Since the oxidation of alcohol and
GwmW weRvi‡Y A¨vjwWnvBW cvIqv hvq| reduction of carboxylic acid produces aldehyde.
myZivs C ⎯⎯ CH CHO Therefore C ⎯⎯ CH CHO

CH CH OH + [O] ⎯⎯⎯⎯ CH CHO + H O CH CH OH + [O] ⎯⎯⎯⎯ CH CHO + H O

( ) ( )

CH COOH + [H] ⎯⎯⎯⎯ CH CHO CH COOH + [H] ⎯⎯⎯⎯ CH CHO

( ) ( )

\ \
CH CHO + CH − NH ⎯⎯⎯ /C = N − CH CH CHO + CH − NH ⎯⎯⎯ /C = N − CH

A ⎯⎯⎯ CH CH OH ; B ⎯⎯⎯ CH COOH A ⎯⎯⎯ CH CH OH ; B ⎯⎯⎯ CH COOH

C ⎯⎯⎯ CH CHO ; D ⎯⎯⎯ CH − CH = N − CH C ⎯⎯⎯ CH CHO ; D ⎯⎯⎯ CH − CH = N − CH
b¤^i eÈb: Mark distribution:
mswkøó 3wU wewµqv ‡jLvi Rb¨ (02×03) = 06 b¤^i| (02 ×03) = 06 marks for writing concerned with three
A,B,C I D kbv³ Ki‡Yi Rb¨ (01×04) = 04 b¤^i| reactions correctly.
(01×04) = 04 marks for identifying compound A,B,C & D.

imvqb Chem
02 10
‘𝐴’ †hŠMwU‡K Av`ª©we‡køwlZ Ki‡j `yB Kve©bwewkó `yBwU †hŠM ‘𝐵’ I ‘𝐶’ When compound ‘A’ is hydrolyzed, two compounds ‘B’
Drcbœ nq| ‘𝐵’ avZe †mvwWqv‡gi mv‡_ wewµqvq H M¨vm gy³ K‡i Ges and ‘C’ are produced having two carbons. The reaction
‘𝐶’ †hŠMwU‡K †K¬v‡ivdig I A¨vj‡Kvnjxq KOH Gi mv‡_ DËß Ki‡j between ‘B’ with metallic sodium liberates H gas and the
compound ‘C’ is heated in presence of alcoholic KOH and
DrKU `yM©Ühy³ †hŠM ˆZwi nq| wewµqvmn 𝐴, 𝐵 I 𝐶 †hŠMmg~n kbv³ Ki| chloroform, an extremely bad odoured compound is
produced. Identify compounds 𝐴, 𝐵 and 𝐶 with reactions.
∥ | ∥ |
CH − C − N − CH + H O ⎯⎯⎯ CH − COOH + CH NH CH − C − N − CH + H O ⎯⎯⎯ CH − COOH + CH NH
CH − COOH + Na ⎯⎯⎯ CH COONa + H CH − COOH + Na ⎯⎯⎯ CH COONa + H
∆ ∆
CH NH + KOH(alc) + CHCl ⎯⎯⎯ CH − NC + H O + CH NH + KOH(alc) + CHCl ⎯⎯⎯ CH − NC + H O +
𝐾𝐶𝑙 𝐾𝐶𝑙
∥ ∥
A ⎯⎯⎯ CH − C − NH − CH A ⎯⎯⎯ CH − C − NH − CH
B ⎯⎯⎯ CH COOH B ⎯⎯⎯ CH COOH
C ⎯⎯⎯ CH NH C ⎯⎯⎯ CH NH
b¤^i eÈb:
A I B †hŠ‡Mi mswkøó wewµqv ‡jLvi Rb¨ (02×02) = 04 b¤^i| Mark distribution:
C †hŠ‡Mi mswkøó wewµqv ‡jLvi Rb¨ 03 b¤^i| (02 ×02) = 04 marks for writing the reactions concerned
A, B I C kbv³Ki‡Yi Rb¨ (01×03) = 03 b¤^i| with Compound A & B.
[we.`«.t c«fveK/ ZvcgvÎv bv wjL‡j ev fyj wjL‡j 01 b¤^i KZ©b Kiv n‡e|] 03 marks for writing the reactions concerned with
Compound C
(01×03) = 03 marks for identifying A, B & C.
[N.B.: 01 mark will be deducted if temperature/catalyst is
not written or wrong written.]

imvqb Chem
03 10
CH COOCH †hŠMwU kbv³ Kiv hvq Kxfv‡e? wewµqvmn wjL| How the compound CH COOCH can be detected?
Write with reactions.
|| || || ||
CH −C −OCH + H N − OH ⎯⎯ CH −C −NHOH + CH −C −OCH + H N − OH ⎯⎯ CH −C −NHOH +
| |
CH OH ⇌ CH − C = NOH + CH OH CH OH ⇌ CH − C = NOH + CH OH

3CH − CO − NHOH + FeCl

3CH − CO − NHOH + FeCl → Fe + 3HCl
→ Fe + 3HCl
D¾¡j jvj ev`vwg eY©/ †e¸wb
G‡¶‡Î D¾¡j jvj ev`vwg eY©/ †e¸wb eY© Drcbœ nq, hv †`‡L G÷vi g~j‡Ki bright red brown colour/
kbv³KiY Kiv hvq| violet
b¤^i eÈb: In this case bright red brown/violet
m¤ú~Y© wewµqv ‡`Lv‡bvi Rb¨ 08 b¤^i| color is produced, by observing which ester group can
“D¾¡j jvj ev`vwg eY© Drcbœ nq, hv †`‡L G÷vi g~j‡Ki kbv³KiY Kiv be detected.
hvq|” ‡jLvi Rb¨ 02 b¤^i|
[we.`«.t c«fveK/ ZvcgvÎv bv wjL‡j ev fyj wjL‡j 01 b¤^i KZ©b Kiv n‡e|] Mark distribution:
08 marks for showing complete reactions.
02 marks for writing “Bright red brown color is
produced, by observing which ester group can be
detected.
[N.B.: 01 mark will be deducted if temperature/catalyst
is not written or wrong written.]

imvqb Chem
04 10
(a) B_vb¨vj n‡Z j¨vKwUK GwmW cÖ¯‘Z Ki| (a) Prepare lactic acid from ethanal.
(b) wewµqv¸‡jv m¤ú~Y© Ki : (b) Complete the reaction :

(i) CO +[O] ⎯⎯⎯⎯⎯ (i) CO +[O] ⎯⎯⎯⎯⎯

. .

(ii) CH CHO + NH OH → (ii) CH CHO + NH OH →

% , % ,
(iii) CH − C ≡ C − CH − CH + H O ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ (iii) CH − C ≡ C − CH − CH + H O ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯
% %

(iv) CH − CO − NH − CH ⎯⎯ (iv) CH − CO − NH − CH ⎯⎯
 (a) CH CHO + HCN ⎯⎯⎯⎯⎯ CH − (a) CH CHO + HCN ⎯⎯⎯⎯⎯ CH −
| , | | , |
CH ⎯⎯⎯⎯ H − C − OH + NH CH ⎯⎯⎯⎯ H − C − OH + NH
| | | |

ল াক ক এিসড
COOH COOH

(b) (i) +6CO + H O (b) (i) +6CO + H O

| |
(ii) CH − C = N − OH + H O (ii) CH − C = N − OH + H O

|| ||
(iii) CH − C = CH − CH − CH → CH − C − CH − (iii) CH − C = CH − CH − CH → CH − C − CH −
| |

CH − CH CH − CH
(iv) wewµqv n‡e bv
(iv) No reaction

Mark distribution:
b¤^i eÈb:
(a) 04 marks for showing the reaction of preparing lactic
(a) B_vb¨vj n‡Z j¨vKwUK GwmW cÖ¯‘wZi wewµqv †`Lv‡bvi Rb¨ 04 b¤^i|
acid from ethanal.
(b) wewµqv¸‡jv m¤ú~Y© Kivi Rb¨; (1.5×04) = 06 b¤^i| (b) (1.5 × 04) = 06 marks for completing the reactions.
[we.`«.t c«fveK/ ZvcgvÎv bv wjL‡j ev fyj wjL‡j 01 b¤^i KZ©b Kiv [N.B.: 01 mark will be deducted if temperature/catalyst is
n‡e|] not written or wrong written.]

imvqb Chem
05 10
GKwU †hŠ‡Mi bgybv `ªe‡Y eªvwWi weKviK †hvM Ki‡j njy` Aat‡¶c c‡o| A sample compound gives yellow precipitate in reaction with
Z‡e D³ †hŠM †dnwjs `ªe‡Yi mv‡_ wewµqv K‡i bv| wK¬‡gbmb weRvi‡Y Brady’s reagent. But the compound does not react with
GwU n-†c‡›Ub Drcbœ K‡i Ges n¨v‡jvdig wewµqvq Ask †bq| bgybv Fehling's solution. It produces n-pentane in Clemmensen
†hŠMwUi IUPAC c×wZ‡Z bvg, ms‡KZ Ges Zxeª Rvi‡Y cÖvß cÖavb reduction and takes part in Haloform reaction. Write down the
Drcv`mg~n wjL| name in IUPAC method, the formula and the major products
obtained from the strong oxidation of the sample compound.
†h‡nZy eªvwWi weKvi‡K njy` Aat‡¶c → A¨vjwWnvBW/wK‡Uvb Since yellow precipitate with Brady’s reagent →
†h‡nZy, †dnwjs `ªe‡Yi mv‡_ K‡i bv → wK‡Uvb aldehyde/ketone
†h‡nZy wK¬‡gbm‡b †c‡›Ub nq → C-5 msL¨v wewkó wK‡Uvb| Since, it does not give reaction with Fehling's solution →
ketone
|| ||
m¤¢ve¨ CH − C − CH − CH − CH , CH − CH − C − Since, pentane in Clemmensen reaction → 5-C ketone
CH − CH || ||
Gi g‡a¨ cª_gwU n¨v‡jvdig wewµqv †`q| Probable, CH − C − CH − CH − CH , CH − CH − C −
CH − CH
||
So, CH − C − CH − CH − CH ; †c›Uvb-2-Ib The first one gives haloform reaction.
[ ] ||
𝐶𝐻 𝐶𝑂𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 + 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 So, CH − C − CH − CH − CH ; name: Pentan-2-one.
[ ]
b¤^i eÈbt 𝐶𝐻 𝐶𝑂𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 + 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻
†dnwjs `ªe‡Yi mv‡_ K‡i bv → wK‡Uvb ‡jLvi Rb¨ 01 b¤^i|
wK¬‡gbm‡b †c‡›Ub nq → C-5 msL¨v wewkó wK‡Uvb ‡jLvi Rb¨ 01 b¤^i| Mark distribution:
01 mark for writing it does not give reaction with Fehling’s
||
CH − C − CH − CH − CH ‡hŠMwU n¨v‡jvdig wewµqv †`q solution → ketone.
‡jLvi Rb¨ 02 b¤^i| 01 mark for writing pentane in Clemenson reaction → 5-C
†hŠ‡Mi ms‡KZ ‡jLvi Rb¨ 02 b¤^i| ketone.
†hŠ‡Mi IUPAC bvg ‡jLvi Rb¨ 02 b¤^i| ||
02 marks for writing CH − C − CH − CH − CH gives
bgybv †hŠMwUi Zxeª Rvi‡Y cÖvß cÖavb Drcv`mg~n
haloform reaction.
𝐶𝐻 𝐶𝑂𝑂𝐻, 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 ‡jLvi Rb¨ 02 b¤^i|
02 marks for writing the structural formula.
02 marks for writing the name of compound in IUPAC
method.
02 marks for writing the major products obtained
𝐶𝐻 𝐶𝑂𝑂𝐻, 𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 from the strong oxidation of the
sample compound.

imvqb Chem
06 10
‡Zvgvi Kv‡Q mbv³Kvix wPý Qvov wfbœ wfbœ weKviK †evZ‡j wZbwU ˆRe You have three different reagent bottles without any
†hŠM i‡q‡Q| †hŠM¸‡jv nj- CH CH OH, HCHO I CH COCH | identification mark containing CH CH OH, HCHO and
ïaygvÎ `ywU wfbœ weKviK Øviv wKfv‡e †hŠM wZbwU mbv³ Ki‡e? wewµqv¸‡jv CH COCH . How can you identify them with only two
†`LvI| different reagents? Show with reactions.
(i) DNPH cix¶v: (i) DNPH Test:

CH CH OH ⎯ (†Kv‡bv wewµqv n‡e bv) (A¨vj‡Kvnj) CH CH OH ⎯ (No reaction) (Alcohol)

NO2 NO2
\ \
HCHO + H N − NH NO2 ⎯ HCHO + H N −NH NO2 ⎯ /C =N −
/C = N−
হলু দ
NO2 NO2

NH NO2 ↓ + H O NH NO2 ↓ + H O
 NO2 NO2
\ \
CH COCH + H N − NH NO2 ⎯ /C = N− CH COCH + H N − NH NO2 ⎯ /C =N−
হলুদ
NO2 NO2
NH NO2 ↓ + H O NH NO2 ↓ + H O

(ii) U‡jb weKviK cix¶v: (ii) Tollen's reagent test:

HCHO + 2[Ag(NH ) ] + 3OH ⎯⎯ 2Ag ↓ HCHO + 2[Ag(NH ) ] + 3OH ⎯⎯ 2Ag ↓

+HCOONH + 3NH + 2H O (A¨vjwWnvBW) +HCOONH + 3NH + 2H O (Aldehyde)

CH COCH ⎯ (†Kv‡bv wewµqv n‡e bv) (wK‡Uvb) CH COCH ⎯ (No reaction will occur) (Ketone)

A_ev, Or,

†dnwjs `ªeY cixÿv: Fehling’s Solution Test:

HCHO + 2Cu(OH) + NaOH ⎯⎯ HCOONa + Cu O
HCHO + 2Cu(OH) + NaOH ⎯⎯ HCOONa + Cu O +
+ H O (Reddish)
H O (jvj‡P eY©) CH COCH ⎯ (No reaction will occur) (Ketone)
CH COCH ⎯ (†Kv‡bv wewµqv n‡e bv) (wK‡Uvb) Mark Distribution:
b¤^i eÈb: (05 × 02) = 10 marks for showing the reactions for
`ywU wfbœ weKviK Øviv †hŠM wZbwU kYv³Ki‡Yi wewµqv †`Lv‡bvi Rb¨ ; identifying 3 compounds using two different reagents.
(05×02) = 10 b¤^i|
[we.`ª. : B_vb‡ji kbv³Ki‡Y PCl e¨envi Ki‡j 02 b¤^i KZ©b Kiv [N.B.: 02 marks will be deducted if PCl test is showed for
ethanol identification. Because, for confirmation PCl and
n‡e| †Kbbv GLv‡b wbwðZKi‡Y PCl Ges NH /NH OH `ywU weKviK
NH /NH OH two reagents are already used here]
e¨envi Kiv n‡q hvq ]