Eng.

Admission Program, 2024

WM-11, Physical, Written, Set-D
HMath 1st Paper, Ch-09+10, (AšÍixKiY+†hvMRxKiY)
D”PZi MwYZ HMath
01 10
y = x + √1 + x + x + √1 + x n‡j, (1 + x )y + If y = x + √1 + x + x + √1 + x , then
xy − m y Gi gvb wbY©q Ki| determine the value of (1 + x )y + xy − m y.
awi, z = x + √1 + x Let, z = x + √1 + x
⇒ =1+ . 2x ⇒ =1+ . 2x
√ √
√ √
⇒ = ⇒ = ⇒ = ⇒ =
√ √ √ √
GLb, y = z + z ⇒ y = mz . − mz . Now, y = z + z ⇒ y = mz . − mz .
⇒y =m z . −z . ⇒y =m z . −z .
√ √ √ √
⇒y = (z − z ) ⇒y = (z − z )
√ √
⇒ (1 + x )y = m (z − z ) ⇒ (1 + x )y = m (z − z )
⇒ (1 + x )y = m [(z + z ) − 4 z . z ] ⇒ (1 + x )y = m [(z + z ) − 4 z . z ]
⇒ (1 + x )y = m (y − 4) ⇒ (1 + x )y = m (y − 4)
⇒ 2x. y + (1 + x ). 2y . y = m 2y. y ⇒ 2x. y + (1 + x ). 2y . y = m 2y. y
⇒ (1 + x )y + xy − m y = 0 (Ans.) ⇒ (1 + x )y + xy − m y = 0 (Ans.)

b¤^i eÈbt Marks distribution:

= ; wbY©‡qi Rb¨ 04 b¤^i| 04 marks for determining, = .
√ √
y = (z − z ) ; wbY©‡qi Rb¨ 02 b¤^i| 02 marks for determining, y = (z − z ).
√ √
(1 + x )y + xy − m y = 0; wbY©‡qi Rb¨ 04 b¤^i| 04 marks for determining, (1 + x )y + xy − m y = 0

D”PZi MwYZ HMath

02 10
hw` 6 ft D”PZvi GKRb e¨w³ 20 ft D”PZvi GKwU j¨v¤^‡cv‡÷i w`‡K If a 6 ft tall person runs towards a height of 20 ft lamp post
5 ft/s †e‡M †`uŠ‡o hvq, Zvn‡j j¨v¤^‡cv‡÷i Av‡jvq e¨w³i †h Qvqv co‡Q with 5 ft/s velocity, then determine the rate of change of
Zvi ˆ`N©¨ cwieZ©‡bi nvi wbY©q Ki| the shadow length of the person formed due to the lamp
post’s light.

awi, wbw`ó mg‡q e¨w³ n‡Z j¨v¤^‡cv‡÷i `~iZ¡ y ft I Zvi Qvqvi ˆ`N©¨ x ft| Let, at a certain time the distance of the lamp post from the
= −5 ft/s [(−ve)wPý, y Gi n«vmgvb wb‡`©k Ki‡Q] person is y ft and length of the shadow is x ft.
= −5 ft/s [(−ve) sign indicates the decrease of y]
GLb, = ⇒ 10x = 3x + 3y ⇒ 7x = 3y ⇒ 7
GLb, = ⇒ 10x = 3x + 3y ⇒ 7x = 3y ⇒ 7
=3 ⇒ = (−5) = − ft/s
=3 ⇒ = (−5) = − ft/s
∴ ft/s nv‡i Qvqvi ˆ`N©¨ n«vm cv‡”Q|
∴ A𝑡 ft/s rate the length of the shadow is decreasing.
b¤^i eÈbt
 = ; wbY©‡qi Rb¨ 04 b¤^i| Marks distribution:
For determining, = ; 04 marks.
ft/s nv‡i Qvqvi ˆ`N©¨ n«vm cv‡”Q; wbY©‡qi Rb¨ 06 b¤^i|
[we:`ª: GKK bv wjL‡j ev fzj GKK wjL‡j 01 b¤^র KZ©b Kiv n‡e|] For determining, A𝑡 ft/s rate the length of the shadow
is decreasing; 06 marks.
[N. B: 01 mark will be deducted if unit is not written or
wrong unit is written.]

D”PZi MwYZ HMath

03 10
GKwU e× †jvnvi AvqZvKvi duvcv Nbe¯‘ 5 cm Zij aviY Ki‡Z cv‡i| A rectangular solid made of iron can hold 5 cm of liquid.
𝑐𝑚 GK‡K Gi cÖ‡¯’i gvb (width) D”PZvi gv‡bi ¸YvZ¥K wecixZ| Its width is the multiplicative inverse of its height in cm
AvqZvKvi Nbe¯‘wUi ˆ`N©¨, cÖ¯’ I D”PZv wbY©q Ki †h‡bv e¯‘wU me©wb¤œ unit. Determine the length, width and height of the
cwigvY †jvnv w`‡q ˆZix Kiv hvq| rectangular solid such that it can be made with the least
amount of iron
ˆ`N©¨ → a cm; cÖ¯’ → b cm; D”PZv → h cm Length → a cm; Width → b cm; Height → h cm
cÖkœg‡Z, b = ATQ, b =
∵ AvqZb = 5 cm ∵ Volume = 5 cm
⇒a×b×h= 5 ⇒a×b×h= 5
⇒a× ×h=5 ∴a =5 ⇒a× ×h=5 ∴a =5
†ÿÎdj, A = 2(ab + bh + ha) cm = 2(5b + bh + Area, A = 2(ab + bh + ha) cm = 2(5b + bh + 5h) 𝑐𝑚
5h) 𝑐𝑚
= 2 5b + × h + 5h 𝑐𝑚
= 2 5b + × h + 5h 𝑐𝑚
A = 2(5b + 5h + 1) = 2 + 5h + 1 𝑐𝑚
A = 2(5b + 5h + 1) = 2 + 5h + 1 𝑐𝑚
∴ =2 − + 5 𝑐𝑚 = 0 ⇒ − +5=0
∴ =2 − + 5 𝑐𝑚 = 0 ⇒ − +5=0
=5∴h =1∴h=1∴b=1
=5∴h =1∴h=1∴b=1
∴ length→ 5 cm; Width → 1 cm; Height → 1 cm
∴ ˆ`N©¨ → 5 cm; cÖ¯’ → 1 cm; D”PZv → 1 cm

Marks distribution:
b¤^i eÈbt 02 marks for determining, a = 5
a = 5 ; wbY©‡qi Rb¨ 02 b¤^i| 03 marks for determining, A = 2 + 5h + 1 𝑐𝑚
A=2 + 5h + 1 𝑐𝑚 ; wbY©‡qi Rb¨ 03 b¤^i| 02 marks for determining, h = 1
03 marks for determining, length→ 5 cm; Width → 1 cm;
h = 1; wbY©‡qi Rb¨ 02 b¤^i|
ˆ`N©¨ → 5 cm; cÖ¯’ → 1 cm; D”PZv → 1 cm; wbY©‡qi Rb¨ 03 b¤^i| Height → 1 cm

D”PZi MwYZ HMath

04 10
y = x (2a − x) eµ‡iLvi †hme we›`y‡Z ¯úk©K x- A‡¶i mgvšÍivj, †m Find the points on the curve y = x (2a − x) where the
we›`y¸‡jv wbY©q Ki| tangents of the curve are parallel to the x-axis.
y = x (2a − x) = 2ax − x y = x (2a − x) = 2ax − x
Dfqc¶‡K AšÍixKiY K‡i cvB, 3y = 4ax − 3x ⇒ = Differentiating both sides we get, 3y = 4ax − 3x ⇒
=
¯úkK© x- A‡¶i mgvšÍivj n‡j, =0⇒ = 0 ⇒ 4ax − The tangent being parallel to the x axis,
3x = 0 ⇒ x(4a − 3x) = 0 ⇒ x = 0, =0⇒ = 0 ⇒ 4ax − 3x = 0 ⇒ x(4a − 3x) =
x = 0 n‡j y = 2a × 0 − 0 = 0 ⇒ y = 0 0 ⇒ x = 0,
x= n‡j, y = 2a × − = = If x = 0, y = 2a × 0 − 0 = 0 ⇒ y = 0
⇒ y = √32 = √2 × 4 = √4 If x = , y = 2a × − = =
 wb‡Y©q we›`y mg~‡ni ¯’vbvsK (0, 0), ( , √4) (Ans.) a a 2a
⇒ y = √32 = 2 ×4= √4
b¤^i eÈbt 3 3 3
 coordinates of points (0, 0), ( , √4) (Ans.)
= ; wbY©‡qi Rb¨ 02 b¤^i|
Marks distribution:
x = 0, ; wbY©‡qi Rb¨ 03 b¤^i|
For determining, = ; 02 marks.
wb‡Y©q we›`y mg~‡ni ¯’vbvsK (0, 0), , √4 ; wbY©‡qi Rb¨ 05 b¤^i|
For determining, x = 0, ; 03 marks.
For determining, coordinates of points (0, 0), , √4 ;
05 marks.

D”PZi MwYZ HMath

05 10
y = cos x , y = sin x I y = −πx Øviv Ave× As‡ki If area of region enclosed by y = cos x , y = sin x & y =
†ÿÎdj A eM© GKK n‡j, A Gi wbKUZg c~Y©mvswLK gvb wbY©q Ki| −πx is A sq. unit, determine the approximate integer value of
(‡iwWqv‡b) ‘A’. (In Radian)

y=-𝜋𝑥 I 𝑦 = 𝑠𝑖𝑛 𝑥 Gi †Q`we›`y (0,0) y = −π 𝑥 & y = sin x intersection point (0,0)

y = cos x I y = sin x Gi †Q`we›`y , y = cos x & y = sin x intersection point ,
√ √
y = −πx I y = cos x Gi †Q`we›`y (−0.976,2.923) y = −πx & y = cos x intersection point (−0.976,2.923)
[By Calculator] [By Calculator]

∴A=∫ (cos x + πx ) dx + ∫√ (cos x− ∴𝐴=∫ .

(cos x + πx ) dx + ∫√ (cos x − sin x) dx
.
sin x) dx = 1.357 + 0.583
= 1.357 + 0.583 = 1.94 sq. units ≈ 2 𝑠𝑞. units
= 1.94 eM© GKK ≈ 2 eM© GKK
Alternative:
weKí: y = −π 𝑥 & y = sin x intersection point (0,0)
y=-𝜋𝑥 I 𝑦 = 𝑠𝑖𝑛 𝑥 Gi †Q`we›`y (0,0) y = cos x & y = sin x intersection point ,
√
y = cos x I y = sin x Gi †Q`we›`y , y = −πx & y = cos x intersection point (−0.976,2.923)
√
y = −πx I y = cos x Gi †Q`we›`y (−0.976,2.923) [By Calculator]
[By Calculator]
Area = ∫√ .
cos 𝑥 𝑑𝑥 − ∫√ sin 𝑥 𝑑𝑥 +
Area = ∫ √
cos √
𝑥 𝑑𝑥 − ∫ sin 𝑥 𝑑𝑥 + .
−𝜋𝑥 𝑑𝑥 ≈ 2 sq.units
. ∫
.
∫ −𝜋𝑥 𝑑𝑥 ≈ 2 sq.units
Marks distribution:
b¤^i eÈbt
03 marks for determining, intersection points
†Q`we›`yÎq (0,0); , Ges (−0.976,2.923); wbY©‡qi Rb¨ (0,0); , & (−0.976,2.923)
√
√
03 b¤^i|
03 marks for determining, A = ∫ .
(cos x + πx ) dx +
√
A=∫ .
(cos x + πx ) dx + ∫ (cos x−
sin x) dx; wbY©‡qi Rb¨ 03 b¤^i| ∫√ (cos x − sin x) dx
A ≈ 2 eM© GKK; wbY©‡qi Rb¨ 04 b¤^i| 04 marks for determining, 𝐴 ≈ 2 𝑠𝑞. units
[we:`ª: K¨vjKz‡jUi †iwWqvb †gv‡W †i‡L gvb †ei Ki‡Z n‡e] [Note: Calculator should be in radian mode while determining
the answer]
weKí b¤^i eÈbt
Alternative Marks distribution:
†Q`we›`yÎq (0,0); , Ges (−0.976,2.923); wbY©‡qi Rb¨ 03 marks for determining, intersection points
√
03 b¤^i|
(0,0); , & (−0.976,2.923)
√
Area = ∫ √
.
cos √
𝑥 𝑑𝑥 − ∫ sin 𝑥 𝑑𝑥 +
. 03 marks for determining, Area = ∫√ cos 𝑥 𝑑𝑥 −
∫ −𝜋𝑥 𝑑𝑥; wbY©‡qi Rb¨ 03 b¤^i| .

Area ≈ 2 eM© GKK; wbY©‡qi Rb¨ 04 b¤^i| ∫√ sin 𝑥 𝑑𝑥 + ∫

.
−𝜋𝑥 𝑑𝑥
[we:`ª: K¨vjKz‡jUi †iwWqvb †gv‡W †i‡L gvb †ei Ki‡Z n‡e] 04 marks for determining, 𝐴𝑟𝑒𝑎 ≈ 2 𝑠𝑞.units
[Note: Calculator should be in radian mode while determining
the answer]

D”PZi MwYZ HMath

06 10
y = log |x| Ges y = 0 Øviv Ave× As‡ki †ÿÎdj wbY©q Ki| Determine the area of region enclosed by y = log |x|
&y=0.
y=loge(-x) y=loge x [x>0] y=loge(-x) y=loge x [x>0]
Y Y
[x<0] [x<0]

X y=0 X y=0
-1 1 -1 1

𝑦 = ln 𝑥 ∴ x = e 𝑦 = ln 𝑥 ∴ x = e
†ÿÎdj = 2 ∫ 𝑒 𝑑𝑦 = |2[𝑒 ] | Area = 2 ∫ 𝑒 𝑑𝑦 = |2[𝑒 ] |
= |2(𝑒 − 𝑒 )| = 2 eM© GKK = |2(𝑒 − 𝑒 )| = 2 sq. units

b¤^i eÈbt Marks distribution:

x = e ; wbY©‡qi Rb¨ 02 b¤^i| 02 marks for determining, x = e
†ÿÎdj = 2 ∫ 𝑒 𝑑𝑦 ; wbY©‡qi Rb¨ 04 b¤^i| 04 marks for determining, Area = 2 ∫ 𝑒 𝑑𝑦
†ÿÎdj = 2 eM© GKK; wbY©‡qi Rb¨ 04 b¤^i| 04 marks for determining, Area = 2 sq. units
 Eng. Admission Program, 2024
WP-11, Weekly Physical, Written, Set-D
nd
Physics 2 Paper, Ch-07+08, Physical Optics and Modern Physics
c`v_©weÁvb Phy
01 [Medium] 10
Bqs Gi wØwPo cixÿvq e¨eüZ Av‡jvi Zi½‰`N©¨ λ = 500 nm, wPo؇qi In Young’s double-slit experiment, light with a wavelength
`~iZ¡ 1 mm Ges wPo n‡Z c`©vi `~iZ¡ 4 m| †K›`ªxq D¾¡j †Wviv n‡Z of λ=500 nm is used. The distance between the two slits is
b~¨bZg x × 10 m `~i‡Z¡i Rb¨ ZxeªZv m‡e©v”P ZxeªZvi A‡a©K nq| 1 mm, and the distance from the slits to the screen is 4 m.
x=? At a minimum distance of x × 10 m from the central
bright fringe, the intensity becomes half of the maximum
intensity. x = ?
I = 4I ; I = I + I + 2I cos φ I = 4I ; I = I + I + 2I cos φ
⇒ = 2I + 2I cos φ ⇒ cos φ = 0 ⇒ = 2I + 2I cos φ ⇒ cos φ = 0
⇒φ= ; ∆x = ⇒φ× = ⇒φ= ; ∆x = ⇒φ× =
× × × × × × × ×
⇒ × = ∴x=5 ⇒ × = ∴x=5
× ×
b¤^i eÈbt Marks Distribution:
I = I + I + 2I cos φ ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, I = I + I + 2I cos φ
φ = ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, φ =
x = 5 ; wbY©q Kivi Rb¨ 05 b¤^i| 05 marks for determining, x = 5

c`v_©weÁvb Phy
02 10
Bqs Gi wØwPo cixÿvq 485 𝑛𝑚 Ges 582 𝑛𝑚 Zi½‰`‡N©¨i Av‡jv In Young’s double slit experiment, lights of wavelength
e¨eüZ nq| wPo n‡Z c`©vi `~iZ¡ 1.2 𝑚 Ges wPo؇qi ga¨eZ©x e¨eavb 485 nm and 582 nm are used. Distance of slits from the
0.2 𝑚𝑚| †K›`ªxq Pig n‡Z KZ `~i‡Z¡ 485 𝑛𝑚 Av‡jvi D¾¡j †Wviv I screen is 1.2 m and distance between two slits is 0.2 mm.
582 𝑛𝑚 Av‡jvi AÜKvi †Wviv wgwjZ n‡e? At what distance from central maxima, bright fringe of 485
nm and dark fringe of 582 nm will meet?
𝑛 𝜆 = 𝜆 ⇒ 2𝑛 𝜆 = (2𝑛 − 1)𝜆 𝑛 𝜆 = 𝜆 ⇒ 2𝑛 𝜆 = (2𝑛 − 1)𝜆
⇒ = = ⇒ = =
∴ 𝑛 = 3, 𝑛 = 3 ∴ 𝑛 = 3, 𝑛 = 3
× × × . × × × .
∴𝑦= = = 8.73 × 10 𝑚 [Ans.] ∴𝑦= = = 8.73 × 10 𝑚 [Ans.]
× ×
b¤^i eÈbt Marks Distribution:
= ; wbY©q Kivi Rb¨ 04 b¤^i| 04 marks for determining, = =
𝑦 = 8.73 × 10 𝑚 ; wbY©q Kivi Rb¨ 06 b¤^i| 06 marks for determining, 𝑦 = 8.73 × 10 𝑚
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|] [Note: 01 mark will be deducted if unit is not written or
wrong unit is written.]

c`v_©weÁvb Phy
03 [Easy] 10
mgZjxq Zi½ E = 100 sin(6 × 10 t − 4x) Vm | GKwU A plane wave
gva¨‡gi ga¨ w`‡q cÖevwnZ n‡”Q| H gva¨‡gi cÖwZmiYv¼ KZ? E = 100 sin(6 × 10 t − 4x) Vm propagates through a
medium. What is the refractive index of the medium?
E = 100 sin(6 × 10 t − 4x) E = 100 sin(6 × 10 t − 4x)
∴ ω = 6 × 10 rads ∴ ω = 6 × 10 rads
× ×
f= = Hz f= = Hz
k= =4∴λ= m k= =4∴λ= m
× ×
v = fλ = × = 1.5 × 10 ms v = fλ = × = 1.5 × 10 ms
 × ×
= ⇒μ = ∴μ =2 = ⇒μ = ∴μ =2
. × . ×
b¤^i eÈbt Marks Distribution:
× ×
f= Hz ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, f = Hz
λ= m ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, λ = m
v = 1.5 × 10 ms ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, v = 1.5 × 10 ms
μ = 2 ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, μ = 2
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|] [Note: 01 mark will be deducted if unit is not written or
wrong unit is written.]

c`v_©weÁvb Phy
04 [Medium] 10
1 mm cÖ¯’‡”Q‡`i cwievnx Zv‡ii cÖwZ GKK AvqZ‡b e msL¨v A conductor wire with a cross-sectional area of 1 mm has
4.8 × 10 wU| ZviwU GKwU d‡UvZwor †Kv‡l hy³ hv‡Z 300 nm an electron number of 4.8 × 10 per unit volume. It is
Zi½‰`‡N©¨i Av‡jv AvcwZZ n‡”Q| cwievnxi ZworcÖevn 1.5 𝐴| cwievnx connected to a photoelectric cell where wavelength of
B‡jKUª‡bi †eM, d‡Uv e Gi †e‡Mi KZ kZvsk? [λ = 340 nm Ges incident light 300 nm. The current flow of the conductor is
me cwievnx e Zwor cÖev‡n Ask †bq] 1.5 A. What is the percentage of velocity of the conduction
electrons compared to the velocity of the photoelectrons?
[λ = 340 nm and assume all conduction electrons
contribute to the current.]
= + mv = + mv

⇒v= − = 4.14 × 10 ms ⇒v= − = 4.14 × 10 ms

. .
GLb, Zvob‡eM, V = = here, drift velocity, V = =
× . × × . × × . × × . ×
= 1.953125 ms = 1.953125 ms
. .
∴p= × 100 = 0.000472% ∴p= × 100 = 0.000472%
. × . ×
b¤^i eÈbt Marks Distribution:
= + mv ; ‡jLvi Rb¨ 02 b¤^i| 02 marks for Writing, = + mv
v = 4.14 × 10 ms ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, v = 4.14 × 10 ms
V = 1.953125 ms ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, V = 1.953125 ms
p = 0.000472% ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, p = 0.000472%

c`v_©weÁvb Phy
05 [Medium] 10
2km j¤^v GKwU weªR‡K 0.6c †e‡M GKwU 600 kg Mvwo Gi AwZµg A 600 kg car attempts to cross a 2 km long bridge at a
Ki‡Z Pvq| MvwowUi fi‡e‡Mi Kxiƒc cwieZ©b Ki‡j MvwowU b~¨bZg mg‡q velocity of 0.6c. What should be the change in the car’s
weªR‡K AwZµg Ki‡e? [weª‡Ri aviYÿgZv 9800N] momentum to cross the bridge in minimum time? [The
bridge’s load capacity is 9800N]
ধারণ মতা
m = = = 1000 kg m = = = 1000 kg
. . . .

GLb, v = c 1 − = 2.4 × 10 ms Now, v = c 1 − = 2.4 × 10 ms

GLb, p = mv = ×v Now, p = mv = ×v

= 1.35 × 10 kgms = 1.35 × 10 kgms

ρ =m v = 1000 × 2.4 × 10 = 2.4 × 10 Ns ρ =m v = 1000 × 2.4 × 10 = 2.4 × 10 Ns
∴ ∆ρ = ρ − ρ = (2.4 × 10 − 1.35 × 10 ) ∴ ∆ρ = ρ − ρ = (2.4 × 10 − 1.35 × 10 )
= 1.05 × 10 kgms = 1.05 × 10 kgms
b¤^i eÈbt Marks Distribution:
v = 2.4 × 10 ms ; wbY©q Kivi Rb¨ 02 b¤^i| 02 marks for determining, v = 2.4 × 10 ms
02 marks for determining, p = 1.35 × 10 kgms
p = 1.35 × 10 kgms ; wbY©q Kivi Rb¨ 02 b¤^i| 03 marks for determining, ρ = 2.4 × 10 Ns
ρ = 2.4 × 10 Ns ; wbY©q Kivi Rb¨ 03 b¤^i| 03 marks for determining, ∆ρ = 1.05 × 10 kgms
∆ρ = 1.05 × 10 kgms ; wbY©q Kivi Rb¨ 03 b¤^i| [Note: 01 mark will be deducted if unit is not written or
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|] wrong unit is written.]

c`v_©weÁvb Phy
06 [Easy] 10
350m wbðj ˆ`‡N©¨i GKwU gnvKvkhvb 0.85c †e‡M Pj‡Q| 0.82c †e‡M A spaceship of rest length 350 m is moving at a velocity of
wecixZ w`‡K Pjgvb GKwU DévwcÐ KZ mg‡q gnvKvkhvbwU‡K AwZµg 0.85c. A meteor is travelling in the opposite direction at a
Ki‡e? velocity of 0.82c. How much time will it take for the
meteor to pass the spaceship?
. . . .
V = = × c = 0.984c V = = × c = 0.984c
. × . . × .

√ . √ .
∴ mgqKvj, t = = = 2.11 × 10 s ∴ time, t = = = 2.11 × 10 s
. × × . × ×
b¤^i eÈbt Marks Distribution:
V = 0.984c ; wbY©q Kivi Rb¨ 04 b¤^i| 04 marks for determining, V = 0.984c
mgqKvj, t = 2.11 × 10 s ; wbY©q Kivi Rb¨ 06 b¤^i| 06 marks for determining, time, t = 2.11 × 10 s
[we.`«: GKK bv wjL‡j ev fyj GKK wjL‡j 01 b¤^i KZ©b Kiv n‡e|] [Note: 01 mark will be deducted if unit is not written or
wrong unit is written.]

Eng. Admission Program-2024

Weekly Exam Chemistry-11 (Physical) Written ‰Re †hŠM (A¨vjwWnvBW - A¨vwgb)
Set-D

imvqb Chem
01 10
‘A’ †hŠMwU‡K Pd I BaSO Gi Dcw¯’wZ‡Z H mn weRvwiZ Ki‡j ‘B’ Compound ‘B’ is produced when compound ‘A’ is reduced
†hŠM Drcbœ nq| ‘B’ †hŠMwU 𝐾 𝐶𝑟 𝑂 I jNy 𝐻 𝑆𝑂 mn RvwiZ n‡q with H in presence of Pd and BaSO . When compound ‘B’
‘C’ †hŠM Drcbœ K‡i| ‘C’ †hŠMwU 10% NaHCO Gi mv‡_ wewµqv is oxidized with 𝐾’ 𝐶𝑟 𝑂 and diluted 𝐻 𝑆𝑂 , compound
K‡i GKwU M¨vm Drcbœ K‡i hv Pz‡bi cvwb‡K †Nvjv K‡i| Dchy³ wewµqvmn ‘C’ is produced. Compound ‘C’ reacts with 10% NaHCO
A, B, C †hŠMmg~n kbv³ Ki| D‡jøL¨, B †hŠ‡M Kve©b msL¨v 2 I ‘A’ and produces a gas which turbids lime water. Identify
†hŠ‡M †K¬vwib Dcw¯’Z| compounds A, B, C with suitable reaction. Note that, there
are 2 Carbon in compound ‘B’ and Chlorine is present in
compound ‘A’.
// . // .
CH − C\ + H ⎯⎯⎯⎯⎯⎯ CH CHO + HCl CH − C\ + H ⎯⎯⎯⎯⎯⎯ CH CHO + HCl

CH CHO + [O] ⎯⎯⎯⎯⎯⎯ CH COOH + H O CH CHO + [O] ⎯⎯⎯⎯⎯⎯ CH COOH + H O

CH COOH + NaHCO ⎯⎯⎯⎯⎯ CH COONa + CO ↑ +H O CH COOH + NaHCO ⎯⎯⎯⎯⎯ CH COONa + CO ↑ +H O

Ca(OH) + CO ⎯⎯⎯⎯⎯ CaCO + H O Ca(OH) + CO ⎯⎯⎯⎯⎯ CaCO + H O
A ⎯⎯⎯⎯⎯ CH COCl ; B ⎯⎯⎯⎯⎯ CH CHO A ⎯⎯⎯⎯⎯ CH COCl ; B ⎯⎯⎯⎯⎯ CH CHO
C ⎯⎯⎯⎯⎯ CH COOH C ⎯⎯⎯⎯⎯ CH COOH

b¤^i eÈbt Mark Distribution:

A I B †hŠ‡Mi mswkøó wewµqv ‡jLvi Rb¨ (02×02) = 04 b¤^i| (02 × 02) = 04 marks for writing the reactions concerned
C †hŠ‡Mi mswkøó wewµqv ‡jLvi Rb¨ 03 b¤^i| with Compound A & B.
03 marks for writing the reactions concerned with
A, B I C kbv³Ki‡Yi Rb¨ (01×03) = 03 b¤^i| Compound C
[we.`«.t c«fveK/ ZvcgvÎv bv wjL‡j ev fyj wjL‡j 01 b¤^i KZ©b Kiv n‡e|] (01 × 03) = 03 marks for identifying A, B & C
[N.B.: 01 mark will be deducted if temperature/catalyst is
not written or wrong written.]

imvqb Chem
02 10
‘𝐴’ †hŠMwU‡K †mvWvjvB‡gi mv‡_ DËß Ki‡j B †hŠM Drcbœ nq| ‘B’ When compound ‘A’ reacts with soda lime with heated,
†hŠMwU‡K MoO cÖfve‡Ki Dcw¯’wZ‡Z Aw·‡R‡bi mv‡_ wewµqvq ‘C’ compound ‘B’ is produced. Again, when compound ‘B’
†hŠM Drcbœ nq| C †hŠM mswkøó †kÖwYi ÿz`ªZg m`m¨ Ges 2,4: 𝐷𝑁𝑃 reacts with Oxygen in presence of the catalyst MoO ,
cixÿv †`q| wewµqvmn A, B, C †hŠMmg~n kbv³ Ki| compound ‘C’ is produced. Compound ‘C’ is the smallest
member the concerned series and gives 2,4: 𝐷𝑁𝑃 test.
Identify the compounds A, B, C with reaction.
,∆ ,∆
CH COOH + NaOH ⎯⎯⎯ CH + Na CO CH COOH + NaOH ⎯⎯⎯ CH + Na CO

CH + O ⎯⎯⎯ HCHO + H O CH + O ⎯⎯⎯ HCHO + H O

NO2 NO2
\ \
HCHO + NH − NH NO ⎯⎯ /C = N − NH HCHO + NH − NH NO ⎯⎯ /C = N − NH

NO2 NO2
NO + H O NO + H O
A ⎯⎯ CH COOH A ⎯⎯ CH COOH
B ⎯⎯ CH B ⎯⎯ CH
C ⎯⎯ HCHO C ⎯⎯ HCHO

Mark distribution:
b¤^i eÈb: (02 ×02) = 04 marks for writing the reactions concerned
A I B †hŠ‡Mi mswkøó wewµqv ‡jLvi Rb¨ (02×02) = 04 b¤^i| with Compound A & B.
C †hŠ‡Mi mswkøó wewµqv ‡jLvi Rb¨ 03 b¤^i| 03 marks for writing the reactions concerned with
A, B I C kbv³Ki‡Yi Rb¨ (01×03) = 03 b¤^i| Compound C
(01×03) = 03 marks for identifying A, B & C.
[we.`«.t c«fveK/ ZvcgvÎv bv wjL‡j ev fyj wjL‡j 01 b¤^i KZ©b Kiv
[N.B.: 01 mark will be deducted if temperature/catalyst is
n‡e|] not written or wrong written.]

imvqb Chem
03 10
wb‡¤œi wewµqv¸‡jv wjL: Write down the following reactions:
(i) wK¬‡gbmb weRviY wewµqv (i) Clemmensen reduction reaction
(ii) U‡jb weKviK wewµqv (ii) Tollen’s reagent reaction
(iii) M¨vUvig¨vb-KP wewµqv (iii) Gattermann-Koch reaction
(iv) HVZ wewµqv (iv) HVZ reaction
. .
(i) R − CO − R/H + 4[H] ⎯⎯⎯ R − CH − R/H + H O (i) R − CO − R/H + 4[H] ⎯⎯⎯ R − CH − R/H + H O

(ii) R − CHO + [Ag(NH ) ]OH → R − COONH + (ii) R − CHO + [Ag(NH ) ]OH → R − COONH +
Ag ↓ + NH + H O Ag ↓ + NH + H O
িসলভার দ পণ
 CHO CHO

(iii) +CO + HCl ⎯⎯⎯ (iii) +CO + HCl ⎯⎯⎯

| লাল বা | | |
(iv) R − CH − COOH + X ⎯⎯⎯⎯ R − CH − COOH + HX (iv) R − CH − COOH + X ⎯⎯⎯⎯⎯⎯ R − CH − COOH +
ূ টনাংক
b¤^i eÈbt HX
4wU wewµqvi Rb¨ (2.5× 04) = 10 b¤^i| Mark distribution:
[we.`«.t c«fveK/ ZvcgvÎv bv wjL‡j ev fyj wjL‡j 01 b¤^i KZ©b Kiv (2.5 × 04) = 10 marks for writing four reactions.
n‡e|] [N.B.: 01 mark will be deducted if temperature/catalyst is
not written or wrong written.]

imvqb Chem
04 10
wewµqvmg~n m¤ú~Y© Ki: Complete the reactions:
% পূণিবন াস %
(a) CH ≡ CH + H O ⎯⎯⎯⎯⎯⎯ ? ⎯⎯ ? (a) CH ≡ CH + H O ⎯⎯⎯⎯⎯⎯ ? ⎯⎯⎯⎯⎯⎯⎯⎯⎯⎯ ?
% %
লঘু
(b) CH CHO ⎯⎯⎯⎯⎯ ? (b) CH CHO ⎯⎯⎯⎯⎯ ?
° °

(c) 2CH COOH ⎯⎯⎯ ? (c) 2CH COOH ⎯⎯⎯ ?

∆ ∆

(iv) R − C ≡ N + 2[H] ⎯⎯⎯ ? (iv) R − C ≡ N + 2[H] ⎯⎯⎯ ?

( .) ( .)
(v) RCOOR + NH − OH + HCl ⎯⎯⎯⎯⎯⎯ ? (v) RCOOR + NH − OH + HCl ⎯⎯⎯⎯⎯⎯ ?
∆ ∆
(a) CH = CHOH → CH CHO (a) CH = CHOH → CH CHO
| |
(b) CH − CH − CH − CHO (b) CH − CH − CH − CHO
|| || || ||
(c) CH − C − O − C − CH + H O (c) CH − C − O − C − CH + H O
(iv) R − CH = NH (iv) R − CH = NH
|| ||
(v) R − C − 𝑁𝐻𝑂𝐻 + 𝑅 − 𝑂𝐻 + 𝑁𝑎𝐶𝑙 + 𝐻 𝑂 (v) R − C − 𝑁𝐻𝑂𝐻 + 𝑅 − 𝑂𝐻 + 𝑁𝑎𝐶𝑙 + 𝐻 𝑂

b¤^i eÈb: Mark distribution:

wewµqvmg~n m¤ú~Y© Kivi Rb¨ (02×05) = 10 b¤^i| (02×05) = 10 marks for completing the reactions.

imvqb Chem
05 10
†Kv‡bv GKwU bgybv †hŠM eªvwWi weKvi‡Ki mv‡_ wewµqvq njy` Aat‡¶c †`q| A sample compound gives yellow precipitate in reaction
GwU n¨v‡jvdig wewµqv I U‡jb weKvi‡Ki mv‡_ Kvw•ÿZ wewµqv †`q bv| with Brady’s reagent. It does not give haloform reaction
†hŠMwU wK¬‡gbmb weRviY wewµqvq n-‡n‡·b Drcbœ K‡i| bgybv †hŠMwUi and doesn’t give the desired reaction with Tollen’s reagent.
IUPAC c×wZ‡Z bvg, ms‡KZ Ges Zxeª Rvi‡Y cÖvß cÖavb Drcv`mg~n wjL| The compound produces n-hexane in Clemmensen
reduction reaction. Write down the name in IUPAC
 method, the formula and the major products obtained from
the strong oxidation of the sample compound.
†h‡nZy eªvwWi weKvi‡K njy` Aat‡¶c → A¨vjwWnvBW/wK‡Uvb As yellow precipitate with Brady’s reagent →
†h‡nZy, U‡jb weKvi‡K wewµqv †`q bv → wK‡Uvb aldehyde/ketone
wK¬‡gbmb wewµqvq n-hexane, → 6-C hy³ wK‡Uvb Since, it does not give reaction with Tollen reagent →
ketone
n-hexane in Clemmensen reaction → 6-C ketone

m¤¢ve¨,
Probable,

wØZxqwU n¨v‡jvdig wewµqv †`q bv|

The second one does not give haloform reaction.
So, ; bvg: †n·vb-3-Ib|
[ ] So, ; Name: Hexan-3-
𝐶𝐻 𝐶𝐻 𝐶𝑂𝐶𝐻 𝐶𝐻 𝐶𝐻 2𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻
one.
[ ]
b¤^i eÈbt 𝐶𝐻 𝐶𝐻 𝐶𝑂𝐶𝐻 𝐶𝐻 𝐶𝐻 2𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻
U‡jb weKvi‡K wewµqv †`q bv → wK‡Uvb ‡jLvi Rb¨ 01 b¤^i|
wK¬‡gbmb wewµqvq n-hexane, → 6-C hy³ wK‡Uvb Mark distribution:
‡jLvi Rb¨ 01 b¤^i| 01 mark for writing, it does not give reaction with Tollen
reagent → ketone.
†hŠMwU n¨v‡jvdig wewµqv †`q bv, 01 mark for writing, n-hexane in Clemenson reaction, → 6-
‡jLvi Rb¨ 02 b¤^i| C ketone.
†hŠ‡Mi ms‡KZ ‡jLvi Rb¨ 02 b¤^i|
†hŠ‡Mi IUPAC bvg ‡jLvi Rb¨ 02 b¤^i| 02 marks for writing, it
bgybv †hŠMwUi Zxeª Rvi‡Y cÖvß cÖavb Drcv` 2𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 ‡jLvi Rb¨ does not give haloform reaction.
02 b¤^i| 02 marks for writing, the structure of the compound.
02 marks for writing, the name of compound in IUPAC
method.
02 marks for writing the major products obtained
2𝐶𝐻 𝐶𝐻 𝐶𝑂𝑂𝐻 from the strong oxidation of the sample
compound.

imvqb Chem
06 10
B_vBj A¨vwgb Ges wg_vBj A¨vwg‡bi cvi¯úwiK iƒcvšÍi Ki| Do the mutual conversion between Ethyl amine and Methyl
amine.
wg_vBj A¨vwgb → B_vBj A¨vwgb : Methyl amine → Ethyl amine :
CH − NH + HNO ⎯⎯⎯ CH − OH CH − NH + HNO ⎯⎯⎯ CH − OH

CH OH ⎯⎯⎯⎯ CH Cl ⎯⎯⎯ CH − CN CH OH ⎯⎯⎯⎯ CH Cl ⎯⎯⎯ CH − CN

CH − CN + 4[H] ⎯⎯⎯ CH − CH − NH CH − CN + 4[H] ⎯⎯⎯ CH − CH − NH
ইথাইল অ ািমন
B_vBj A¨vwgb → wg_vBj A¨vwgb : Ethyl amine →Methyl amine :

CH − CH − NH + HNO ⎯⎯⎯⎯ CH − CH − OH + CH − CH − NH + HNO ⎯⎯⎯⎯ CH − CH − OH +

[O] ⎯⎯⎯⎯ CH − COOH [O] ⎯⎯⎯⎯ CH − COOH
Δ Δ
CH − COOH + NH → CH − CO − NH + Br + CH − COOH + NH → CH − CO − NH + Br +
4KOH ⎯⎯⎯ CH − NH 4KOH ⎯⎯⎯ CH − NH
িমথাইল অ ািমন

b¤^i eÈb: Mark distribution:

wg_vBj A¨vwgb †_‡K B_vBj A¨vwg‡bi iƒcvšÍi ‡`Lv‡bvi Rb¨ 05 b¤^i| 05 marks for showing conversion reactions of Methyl amine to
B_vBj A¨vwgb †_‡K wg_vBj A¨vwg‡bi iƒcvšÍi ‡`Lv‡bvi Rb¨ 05 b¤^i| Ethyl amine.
[we.`«.t c«fveK/ ZvcgvÎv bv wjL‡j ev fyj wjL‡j 01 b¤^i KZ©b Kiv 05 marks for showing conversion reactions of Ethyl amine to
n‡e|] Methyl amine.
[N.B.: 01 mark will be deducted if temperature/catalyst is not
written or wrong written.]