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SENIOR INTERMEDIATE CHEMISTRY
Andhra Pradesh
IMPORTANT QUESTIONS FOR IPE – 2024
@@@

Marks Distribution of Chapters

VSAQ’s SAQ’s LAQ’s
Sr.No. Chapter Name Total
2M 4M 8M
1. Solid State - 1 - 4M
2. Solutions 1 1 - 6M
Electrochemistry and Chemical
3 1 - 1 10M
Kinematics
4. Surface Chemistry - 1 - 4M
5. General Principles of Metallurgy 1 1 - 6M
p – Block Elements (16 to 18
th th
6. 2 1 1 16M
Groups)
d & f – Block Elements & Co-
7. 1 1 - 6M
ordination Compounds
8. Polymers 2 1* - 4M
9. Biomolecules 1* 1 - 4M
10. Chemistry in Everyday Life 2 - - 4M
11. Halo Alkanes and Halo Arenes - 1 - 4M
Organic compounds containing
12.
C,H,O
- - 1 8M
Organic Compounds containing
13.
Nitrogen
Total 10 8 3 76
Note : “*” indicates sometimes may questions will come in Examinations.

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Model Paper – Sr. Chemistry
Section : A – Answer ALL the questions. 10 X 2 = 20M
Section : B – Answer any SIX questions. 6 X 4 = 24M 60 Marks
Section : C – Answer any TWO questions. 2 X 8 = 16M
Sample Question Paper According to Weightage
223
PART – III
CHEMISTRY
Paper – II
Marks : 60 Time : 3 Hours
Note : Read the following instructions carefully.
(i) Answer all the questions in Section – A. Answer any six questions out of eight in
Section – B and answer any two questions out of three in Section – C.
(ii) In Section – A, questions from Sr. Nos. 1 to 10 are of “Very Short Answer Type”.
Each question carries two marks. Every answer may be limited to 5 lines. Answer
all questions at one place in the same order.
(iii) In Section – B, questions from Sr. Nos. 11 to 18 are of “Short Answer Type”.
Each question carries four marks. Every answer may be limited to 20 lines.
(iv) In Section – C, questions from Sr. Nos. 19 to 21 are of “Long Answer Type”.
Each question carries eight marks. Every answer may be limited to 60 lines.
(v) Draw labelled diagrams, wherever necessary, for questions Section – B and C.
SECTION – A
Answer all the questions. Each answer maybe limited to 5 lines. 10×2=20M
1. What is relative lowering of vapour pressure ?
2. Give two examples of zero order reaction.
3. Give the composition of the following alloys :
(a) Brass
(b) Bronze
(c) German silver
4. How is chlorine manufactured by Deacon’s Method ?
5. What happens when white phosphorus is heated with conc. NaOH solution
in an inter atmosphere of CO2 ?
6. What is Misch metal ? Give its composition and use.

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7. What is PHBV ? How is it useful to man ?
8. What is PDI (Poly Dispersity Index) ?
9. What are analgesics ? How are they obtained ?
10. What are antiseptics ? Give examples.
SECTION – B
Answer any SIX questions. Each answer maybe limited to 20 lines. 6×4=24M
11. Describe the two main types of semi-conductors and contrast their
conduction mechanism.
12. Vapour pressure of water at 293K is 17.535 mmHg. Calculate the vapour
pressure of solution at 293K when 25g of glucose is dissolved in 450g of
water ?
13. Name any four enzyme catalyzed reactions.
14. Explain the purification of sulphide ore by Forth Floatation Method ?
15. How are XeF2 and XeF4 prepared ? Give their structures.
16. Using IUPAC norms, write the systematic names of the following :
(a) [Co(NH3)6]Cl3. (b) Fe(C2O4)3]–3
(c) [Fe(CN)6]–4 (d) [NiCl4]–2
17. What are Hormones ? Give one example for each
(a) Steroids Hormones
(b) Polypeptide Hormones
(c) Amino Acid derivatives
18. Which compound in each of the following pairs will react faster in SN2
reaction with OH– ?
(a) CH3Br (or) CH3I
(b) (CH3)3CCl (or) CH3Cl
SECTION – C
Answer any TWO questions. Each answer maybe limited 60 20 lines. 2×8=16M
19. Give the different types of Batteries and explain the construction and
working of each type of Battery.
20. How is ozone prepared from oxygen ? Explain its reaction with :
(a) C2H2 (b) KI (c) Hg (d) PbS
21. Describe the following :
(a) Acetylation (b) Cannizaro reaction
(c) Cross aldol condensation (d) Decarboxylation
*****

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VERY SHORT ANSWER QUESTIONS (2M)
Chapter – 2 : Solutions (1Q)
1. Define molarity.
2. Define molality.
3. Define mole fraction.
4. What is ppm of a solution ?
5. State Raoult’s law.
6. State Henry’s law.
7. What is ebullioscopic constant ?
8. What is cryoscopic constant ?
9. Define osmotic pressure.
10. What are isotonic solution ?
11. What is Van’t Hoff’s factor ‘i’ and how it is related to α in the case of
a binary electrolyte (1:1)?
12. Calculation the mole fraction of H2SO4 in a solution containing 98%
H2SO4 by mass.
13. Calculate the amount of glucose required for preparing 500 ml of
0.1m solution.
14. Calculate the molarity of a solution containing 5gr of NaOH in 450ml
solution.
15. Calculate molality of 2.5 of ethanoic acid (CH3COOH) in 75g of
benzene.

Chapter – 3 : Electrochemistry and Chemical Kinematics (1Q)

Electrochemistry
1. Write the cell reaction taking place in the cell Cu/Cu2+ //Ag+/Ag.
2. How is Gibbs Energy (G) related to EMF of cell (E) mathematically?
3. What is molar conductivity ?
4. Write the Nernst equation for the EMF of the cell :

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Ni/Ni+2 // Ag+/Ag.
5. State first law of electrolysis.
6. State second law of electrolysis.
7. What is a primary battery give one example.
8. What is metallic corrosion. Give one example.
9. A solution of CuSO4 is electrolyzed for 10 minutes with a current of
1.5 amperes. What is the mass of copper deposited at cathode ?
Chemical Kinematics
10. Identify the reaction order from each of the following the role
constant.
(a) K=2.3×10–5 L mol–1 s–1 (b) K=3×10– 4 s–1
11. Give two examples for zero order reactions.
12. Give two examples for gaseous first order reactions.
13. Give the units of rate constants for Zero, first order and second order
reactions.
14. What are pseudo first order reactions. Give one example.
15. Write the equation for the rate of the reaction.

16. A reaction has a life of 10 min. calculate the rate constant for the first
order reaction.
17. What is half-life of a reaction? Illustrate your answer with an example.
18. Calculate the half-life of first order reaction whose rate constant is
200s–1.
19. Calculate the overall order of a reaction which has the rate expression.
(a) Rate = K (A)1/2 (B)3/2 (b) Rate = K (A)3/2 (B)–1
20. A first order reaction is found to have a rate constant K = 5.5×10–4.
Find the half life of the reaction.

Chapter – 5 : General Principles of Metallurgy (1Q)

1. State the role of silica in the metallurgy of copper.

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2. Explain poling.
3. What is the role of cryolite in the metallurgy of aluminum?
4. Write any two “Ares” with formula of the following metals?
a) Aluminum b) Zinc c) Iron d) Copper
5. What is blister copper? Why is it so called?
6. What is mattes? Give its composition?
7. Give the composition of the following alloys.
a) Brass b) Bronze c) German silver.
8. What is flux? Give an example.

Chapter – 6 : P – Block Elements (2Q)

15th Group Elements
1. Nitrogen exists as diatomic molecule and phosphorous as P4. Why?
2. Nitrogen molecule is highly stable. Why?
3. What is inert pair effect?
4. Explain why is NH3 basic while BiH3 is only feebly basic?
5. PH3 is a weaker base than NH3. Explain.
6. What happens when white phosphorous is heated with con NaOH
solution in an inert atmosphere of CO2?
7. NH3 forms hydrogen bonds but PH3 does not. Why?
8. Ammonia is a good complexing agent. Explain with Example.
9. A mixture of Ca3P2 and CaC2 is used in making Holme’s signals.
Explain.
10. PH3 has lower boiling point than NH3. Why?
11. NO is paramagentic in gaseous state but diamagnetic in liquid and
solid states, why ?
12. Give an example of a) acidic oxide of phosphorus b) neutral oxide of
nitrogen ?
16th Group Elements
1. Why is H2O a liquid while H2S is a gas?

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2. Give the Hybridization of ‘s’ in the following.
a) SO2 b) SO3 c) SF4 d) SF6
3. What is a tailing of mercury? How is it removed?
4. SO2 can be used as an anti chlor explain.
5. How does ozone react with ethylene?
6. Explain the structure of SF4 and SF6.
7. H2O is neutral while H2S is acidic – Explain.
17th Group Elements
1. What is the use of CIF3?
2. What is Aqua Regia ? Write its reaction with Gold and Platinum.
3. Write the reactions of F2 and Cl2 with water.
4. What happens when Cl2 reacts with dry slaked lime?
5. Chlorine and SO2 acts as bleaching agent in presence of moisture.
Explain.
6. HF is a liquid while HCl is a gas explain.
7. How is chlorine manufactured by Deacon’s process?
18th Group Elements
1. List out the uses of Neon?
2. Write any two uses of Argon?
3. In modern diving apparatus a mixture of He and O2 is used why?
4. Explain the structure of XeO3.
5. How is XeOF4 prepared? Describe its molecular shape?

Chap. – 7 : d & f – Block Elements & Co-ordination Compounds (1Q)

1. Why Zn2+ is diamagnetic where as Mn2+ is paramagnetic?
2. Calculate the spin only magnetic moment of Fe2+ ion.
3. Aqueous Cu2+ ions are blue in colour where as aqueous Zn2+ ions are
colourless. Why?
4. What is an alloy? Give example.
5. What is lanthanoid contractions?

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6. What is misch metal? Give its composition and uses.
7. Define ligand and Ambidentate ligand give example.
8. CuSO4 5H2O is blue in colour where as anh. CuSO4 is colourless.
Why?
9. Calculate the magnetic moment of a divalent ion in aqueous solution
it its atomic number is 25.

Chapter – 8 : Polymers (2Q)

1. What are polymers? Give example.
2. What is polymerization give an example of polymerization reaction.
3. What is addition polymer. Give example.
4. What is condensation polymer. Give example.
5. What are homopolymers. Give example.
6. What are copolymers. Give example.
7. What are elastomers. Give example.
8. What are fibres? Give example.
9. What is zicgler – Natta catalyst?
10. What are the repeating monomeric units of Nylon 6 and Nylon 6, 6?
11. What is the difference between Buna – N and Buna – S?
12. What is PDI?
13. What is vulcanization of rubber.
14. What is biodegradable polymer. Give one example of biodegradable
polyester?
15. What is PHBV? How it is useful to man?

Chapter – 10 : Chemistry in Everyday Life (2Q)

1. What are drugs?
2. What is allosteric site?
3. What are antacids? Give example.

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4. What are antihistamines? Give example.
5. What are tranquilizers? Give example.
6. What are Analgesics? How are they classified?
7. What are narcotic analgesics? Give example.
8. What are non-Narcotic analgesics? Give example.
9. What are antibiotics? Give example.
10. What are antiseptics? Give example.
11. What are disinfectants? Give example.
12. What is tincture of iodine? What is its use?
13. What are antifertility drugs. Give example.
14. What are artificial sweetening agents. Give example.
15. What are food preservatives? Give example.
16. Name two most familiar antioxidants used as food additives.
17. What is the difference between a soap and a synthetic detergent?

SHORT ANSWER QUESTIONS (4M)

Chapter – 1 : Solid State (1Q)
1. Derive Bragg’s equation.
2. Describe the two main types of semi-conductors and construct their
conduction mechanism.
3. Explain Schottky & Frenkel Defects
4. Classify each of the following as either a p-type or n-type
semiconductor.
(i) Ge doped with In (ii) Si doped with B
Chapter – 2 : Solutions (1Q)
1. A solution of sucrose in water is labeled as 20% w/w. what would be
the mole fraction of each component in the solution?

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2. Calculate the mass of a non-volatile solute (molar mass 40g/mol)
which should be dissolved in 114gr octane to reduce its vapour
pressure to 80%.
3. Vapour pressure of water at 293k is 17.535 mm Hg. Calculate the
vapour pressure of the solution at 293k when 25gr of glucose is
dissolved in 450g of water.
4. What is relative lowering of vapour pressure? How is it useful to
determine the molar mass of a solute.
5. What is meant by positive deviations from Raoult’s law and how is the
sign of the ∆𝑚𝑖𝑥 H related to positive deviation from Raoult’s law.
6. What is meant by negative deviations from Raoult’s law and how is
the sign of the ∆𝑚𝑖𝑥 H related to negative deviation from Raoult’s law.

Chapter – 4 : Surface Chemistry (1Q)

1. What are different types of adsorption? Give any four differences
between characteristics of these different types.
2. What is catalysis classified? Give two examples for each type of
catalysis.
3. Name any six enzyme catalyzed reactions.
4. How are colloids classified on the basis of interaction between
dispersed phase and dispersion medium.
5. Explain about Tyndal effect and Brownian movement?
6. What are emulsions? How are they classified.
Chapter – 5 : General Principles of Metallurgy (1Q)
1. Explain the purification of sulphide ore by Froth Floatation Method.
2. Giving examples to differentiate roasting and calcination.
3. Explain briefly the extraction of Aluminium from Bauxite.

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Chapter – 6 : p – Block Elements (1Q)
15th Group Elements
1. Explain the anomalous nature of nitrogen in group – 15.
2. How does PCl5 reacts with the following?
a) Water b) C2H5oH c) CH3COOH d) Ag
16th Group Elements (4M or 8M)
1. How is ozone prepared? How does it react with the following?
a) PbS b) KI c) Hg d) Ag e) C2H4 f) NO
2. Explain in detail the manufacture of sulphuric acid by contact process.
17th Group Elements (4M or 8M)
1. Explain about oxo acids of chlorine.
2. How CH3 prepared? How does it react with water explain its structure.
3. How is chlorine prepared by laboratory and electrolytic method? How
does it react with the following.
a) Dil. and conc. NaoH b) Slaked lime c) Na2S2O3 e) Fe
f) I2 g) H2S h) FeSO4
18th Group Elements (4M or 8M)
1. How are XeF2, XeF4 and XeF6 prepared? Explain their reaction with
water discuss their structures.
2. How are XeO3 and XeOF4 prepared? Explain their structures?

Chapter – 7 : d & f – Block Elements & Co-ordination Compounds

(1Q)
1. Explain Werner’s theory of coordination compounds with suitable
examples.
2. Explain the terms:
i) Ligand ii) Coordination number
iii) Coordination entity iv) Central atom/ion

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3. Give the oxidation numbers of the central metal atoms in the
following complex entities.
i) [Ni(CO)4] ii) CO(NH3)3+ 6 iii) [Fe(CN)6]4-
iv) Fe(C2O4)3−3
4. Write the IUPAC names of the following.
i) Tetrahydroxozincate(II) iron
ii) Hexaamine cobalt (III) sulphate
iii) Potassium tetea chloro
iv) Potassium trioxolate chromate (III)
5. Using IUPAC norms write the names of the following.
i) [CO(NH3)6]Cl3 ii) [Pl(NH3)2 Cl(NH2 CH3)]Cl
iii) [Ti(H2O)6]3+
iv) [Fe(C2O4)3]3- v) (NiCl4)2- vi) [K4Fe(CN)6]
vii) [Cu(NH3)4]SO4 viii) [Fe(CN)6]4-
6. Explain different types of structural isomerism with example
7. Explain different types of structural isomerism with example.
8. What are interstial compounds? How they formed given two
examples.
9. Write the characteristic properties of transition elements

Chapter – 9 : Biomolecules (1Q)

1. Give the sources of the following vitamins and the name diseases
causes by their deficiency.
a) A b) D c) E d) K
2. What are Hormones? Give one example for each?
i) Steroid hormones
ii) Polypeptide hormones
iii) Amino acid derivatives.
3. Explain the denaturation proteins.
4. What are enzymes. Give examples.

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5. Example the structure of glucose.

Chapter – 11 : Halo Alkanes and Halo Arenes (1Q)

1. Explain SN1 reaction with example.
2. Explain SN2 reaction with example.
3. Explain (a) Carbylamine (b) Sandmeyer (c) Gatterman reactions
4. Define (i) Recemic mixture (ii) Enantiomers
5. Which compound in each of the following pairs will react faster in S N2
reaction with OH– ?
(a) CH3Br (or) CH3I
(b) (CH3)3CCl (or) CH3Cl

LONG ANSWER QUESTIONS (8M)

Chapter – 3 : Electrochemistry and Chemical Kinematics (1Q)
1. What is Electrolysis? Give Faraday’s First and second law of
electrolysis? A solution of CuSO4 is electrolyzed for 10 minutes with
a current of 1.5 amperes. What is the mass of copper deposited at
cathode ?
2. State and explain Kohlrausch’s law of independent migration of ions?
What is ‘Molecularity’ of reaction? How is it different from the ‘Order’
of a reaction? Name one Bimolecular & one Trimolecular gaseous
reactions.
3. Give the detailed account of the Collision theory of reaction rates of
bimolecular gaseous reaction.
4. What are galvanic cells ? Explain the working of a galvanic cell with a
neat sketch taking Daniel cell as an example.
5. State and Explain Nernst equation with the help of a metallic electrode
and a non-metallic electrode.
6. Derive the integrated rate equation for a zero order and first order
reaction.

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Chapter – 6 : p – Block Elements (1Q)
1. How is Ammonia manufactured by Haber’s process ? Explain the
reactions of ammonia with (a) ZnSO4(aq) (b) CuSO4(aq) (c) AgCl(s)
2. How is nitric acid manufactured by Ostwald process ? How does it
react with: (a) Copper (b) Zinc (c) S8 (d) P4
3. How is ozone prepared? How does it react with the following?
a) PbS b) KI c) Hg d) Ag e) C2H4 f) NO
4. How is Chlorine prepared in the Laboratory? How does it react with
the following?
a) Iron b) Hot, conc. NaOH c) Acidified FeSO4 d) Iodine
e) H2S f) Na2S2O3 h) dry slaked lime g) KI
5. How is Chlorine prepared by Electrolytic method ? Explain its
reaction with (a) NaOH and (b) NH3 under different conditions.
6. How are Xenon fluorides XeF2, XeF4 and XeF6 are obtained ?
Explain its structure and reactions with water ?
Chapter – 12/13 : Organic Chemistry (1Q)
1. Explain the acidic nature of phenols and compare with that of
alcohols.
Give two preparation methods of phenols
Give the equations for the preparation of phenols from Cumene.
Write the equations for the preparation of phenols using benzene,
con. H2SO4 & NaOH.
2. With suitable examples write equations for the following :
(a) Kolbe’s reaction
(b) Reimer-Tiemann reaction
(c) Williamson’s ether synthesis
(d) Esterification
(e) Acetylation
(f) Cannizoro Reaction
(g) Cross aldol condensation

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(h) Decarboxylation
(i) Diazotisation reaction
(j) Sadmeyer reaction
(k) Gatterman reaction
(l) Carbyl amine reaction
(m) Wurtz reaction
(n) Wurtz Fitting reaction
(o) Friedel Crafts Acylation
(p) Friedel Crafts Alkylation
____________

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