Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
Sec:Sr.Super60_NUCLEUS & STERLING_BT Paper -1(Adv-2024-P1-Model) Date: 08-12-2024
Time: 09.00Am to 12.00Pm RPTA-21 Max. Marks: 180
08-12-2024_Sr.Super60_NUCLEUS&STERLING_BT_Jee-Adv(2024-P1)_RPTA-21_Syllabus
PHYSICS : Waves & Sound: Wave motion (plane waves only), longitudinal and transverse waves, superposition of
waves; Progressive and stationary waves; Vibration of strings and air columns; Resonance; Beats; Speed of
sound in gases; Experiments: Speed of sound using resonance column Doppler effect (in sound)
(Important for ADVANCED)
CHEMISTRY : Basic Concepts Of Chemistry: Dalton’s atomic theory, Concept of atoms (subatomic particles, Atomic
Number, mass number, Isotopes, Isotones, Isobars) and molecules, Classification of matter into elements,
compounds and mixtures (examples), physical and chemical properties of matter, Laws of chemical
combinations, Dalton’s atomic theory, Atomic and molecular masses, Average atomic mass and relative
abundance, Molecular mass and formula mass; Density, relative density, Vapour density, relation
between vapour density and degree of dissociation, Mole concept and molar masses, Percentage
composition, Empirical and molecular formula
STOICHIOMETRY -II: Introduction,Oxidation, Reduction, Electronic concept of oxidation and reduction,
Oxidising agent or Oxidant, Reducing agent or reductant, Oxidation number and state. Oxidation state of
oxygen in different forms, Highest oxidation number state of the group element, Fractional oxidation
state, Balancing of redox reactions, Types of redox reactions, Concept of Gram Equivalent, Equivalent
weight of oxidants and reductants
STOICHIOMETRY -III: Volume strength of Hydrogen peroxide, Labelling of Oleum,Volumetric analysis,
Simple titrations, back titrations, Double titrations, Use of indicators, Redox titrations –potassium
permanganate, potassium dichromate; Iodimetric and Iodometric tritrations, Strength of Bleaching
powder in terms of percentage of available chlorine from the sample of bleaching powder, hardness of
water in terms of ppm of calcium carbonate
MATHEMATICS : Probability and Random Variables

Name of the Student: ___________________ H.T. NO:

 Sri Chaitanya IIT Academy 08-12-2024_Sr.Super60_NUCLEUS & STERLING_BT_Jee-Adv(2024-P1)_RPTA-21_Q.P

JEE-ADVANCED-2024-P1-Model
Time:3Hr’s IMPORTANT INSTRUCTIONS Max Marks: 180
MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Single Correct
Sec – I(Q.N : 1 – 4) +3 -1 4 12
Choice
Questions with Multiple Correct
Sec – II(Q.N : 5 – 7) +4 -2 3 12
Choice with partial mark
Questions with NON-NEGATIVE INTEGER
Sec – III(Q.N : 8 – 13) +4 0 6 24
Type
Sec – IV(Q.N : 14 – 17) Matching Type +3 -1 4 12
Total 17 60

PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Single Correct
Sec – I(Q.N : 18 – 21) +3 -1 4 12
Choice
Questions with Multiple Correct
Sec – II(Q.N : 22 – 24) +4 -2 3 12
Choice with partial mark
Questions with NON-NEGATIVE INTEGER
Sec – III(Q.N : 25 – 30) +4 0 6 24
Type
Sec – IV(Q.N : 31 – 34) Matching Type +3 -1 4 12
17 60

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions with Single Correct
Sec – I(Q.N : 35 – 38) +3 -1 4 12
Choice
Questions with Multiple Correct
Sec – II(Q.N : 39 – 41) +4 -2 3 12
Choice with partial mark
Questions with NON-NEGATIVE INTEGER
Sec – III(Q.N : 42 – 47) +4 0 6 24
Type
Sec – IV(Q.N : 48 – 51) Matching Type +3 -1 4 12
Total 17 60

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MATHEMATICS Max Marks: 60

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
1. Let R,S,T be three events such that P(R) =0.5, P(S)=0.3, P(T)=0.2, P(R  S)=0.15,
P(R  T) =0.1 and P(S  T)=0.06, (where P(E) represents the chance of occurrence of


event E). Then the greatest possible value of R c  S c  T c (where E c represent the 
complement of the event E) is
A) 0 B) 0.25 C) 0.26 D) 0.31
3
2. The chance that a particular day in the month of August is a rainy day is . Two persons
4
4 2
whose credibility are and respectively to claim that 15th August was a rainy day.
5 3
Then the probability that it was really a rainy day is
A) 3/4 B) 8/9 C) 24/25 D) 9/13
3. In a major league world series two teams play until one team wins 4 games. (each game
gives the result of either “win” or ‘’loose’’). If both teams are equally likely to win, the
probability that the series will end in less than 7 games is
3 5 11 15
A) B) C) D)
16 32 16 32
4. A bag contains tickets numbered 1 to 25. Five tickets are drawn at random and arranged
in ascending order. The probability that 2nd and 4th bear the numbers 12 and 18
respectively is-
1 1 1 1
A) B) C) D)
138 115 230 69

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SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get +1 mark; choosing no option (i.e.
the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

5. Two Buses A and B are scheduled to arrive at a town central bus station at noon (each
bus will arrive either on time or late). The probability that bus A and bus B will be late
are 1/5 and 7/25 respectively. The probability that the bus B is late given that bus A is
late is 9/10.Then
A) The probability that neither of the two buses is late an a particular day is 7/10
B) The probability that bus A is late given that bus B is late is 9/14
C) The probability that at least one bus is late is 3/10
D) The probability that at least one bus is on time is 41/50
6. A bag contains ‘b’ blue balls and ‘r’ red balls. Two balls are drawn at random. The
chance of drawing two red balls is five times the chance of drawing two blue balls. Also
the chance of drawing one ball of each colour is six times the chance of drawing two blue
balls. Then which of the following is /are true?
b
A) b  r  9 B) br  182 C)
D) | b  r | 4
r
7. A ship is fitted with three motor engines M 1 , M 2 and M 3 . The motors function independent
to each other with the probabilities 1/2 , 1/4 and 1/4 respectively. For the ship to be in
operational, at least two of the motors must function. Let E denote the event that ship is
in operational and Let E1,E2,E3 be the events that the motor M1,M2 &M3 are function.
Then which of the following is/are true?
A) P  E1C / E   3 / 16
B) P  E1C / E2   5 / 16
C) P  E / E1   7 / 16
D) P  (Exactly two of the motors are functioning ) / E   7 / 8
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SECTION-III
(NON-NEGATIVE INTEGER.)
This section contains SIX (06) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme
Full Marks : +4 If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.
8. Let h,k be choosen one by one from the set {1, 2, 3, 2, e,  } (‘e’ is the Euler’s’ constant)
with replacement. Now a circle is drawn with (h,k) as its center. If the probability that at
the most two rational points exist on the circle can be written as p/q where p and q are
relatively prime positive integers then the value of (p+q) is
9. Let Pn denote the probability of getting n heads a when a fair coin is tossed m times

 n  m . If P , P , P
4 5 6 are in A.P. then the value of m  0  m  10  is
10. A fair coin is flipped n times. Let E be the event “a head is obtained on the first flip”, and
Let Fr be the event that “exactly r heads are obtained”. Then the value of n/r for which E
and Fr are independent is___
11. Thirty-two players ranked 1 to 32 playing in a knockout tournament. Assume that in
every match between any two players the better ranked player wins. The probability that
ranked 1 and ranked 2 players are winners and runners up respectively is P. Then the
value of   is (where [.] represent the greatest integer function)__
2
P
12. Three hunters shoot simultaneously at a wild Tiger, which is killed by exactly one bullet
hitting the animal. If the chance of these three hunters hitting the Tiger are respectively
0.2,0.4 and 0.6 then the probabilities that the Tiger is killed by the first, second or the
third hunter are in the ratio 3: n :18 where n=
13. A box contains 7 slips bearing the numbers -3,-2,-1,0,1,2,3. A slip is drawn 9 times with
replacement. The number on the slips are arranged row wise to form a 3x3 matrix starting
from the first element of first row. The probability that matrix so formed is a skew
a
1
symmetric matrix is equal to   . (where ‘a’ and ‘b’ are successive natural numbers)
b
then a+b=__
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SECTION – IV
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: –1 In all other cases.
C
14. Let E and F be two independent events such that P(E)=1/2 and P(F )=4/5 where P(E)
represents the chance of event E. Now match the following
List-I List-II
I) P(E/(E  F)) P) 0
II) P((E  F)/(EC  FC)) Q) 2/5
III) P(E/F) R) 5/6
IV) P(EC  FC) S) 1/2
T) 1
A) I  R, II  S , III  P, IV  Q B) I  Q, II  R, III  S , IV  P
C) I  R, II  P, III  S , IV  Q D) I  S , II  P, III  Q, IV  R
15. Mr. X posts a letter to Y. It is known that one letter out of 10 letters do not reach the
destination. It is certain that Mr. Y will reply only if he receives the letter. If ‘A’ denotes
the event that Mr. Y receives the letter and ‘B’ denotes the event that Mr. X gets a reply,
then match the following (where P(E) represents the probability of occurrence of E)
List-I List-II
I) P(B)= P) 9/10
II) P(A/BC) = Q) 81/100
III) P(A  B) = R) 9/100
IV) P(A  B) = S) 9/20
T) 9/19
A) I  R, II  P, III  T , IV  Q B) I  Q, II  T , III  Q, IV  P
C) I  R, II  T , III  P, IV  S D) I  S , II  Q, III  P, IV  R

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16. A set X contains 20 elements. A subset A (may be void also) is selected at random from
set X and & set A is then reconstructed by replacing the elements of A. A subset B (may
be void also) of X again chosen at random. Then match the probabilities of Column-I
with the values of Column-II
COLUMN-I COLUMN-II
I) A  B   is P) 40C20 / 420
II) B is a subset of A is Q) 2 40
 40C20  / 2 41
III) n(A)=n(B) is (where n(S) represents no of elements of S) R) 40C21 / 4 20
IV) n(A)> n(B) S) 3 / 4
20

T) 3 / 4 20
A) I  P, II  R, III  S , IV  Q B) I  P, II  Q, III  R, IV  S
C) I  S , II  S , III  P, IV  Q D) I  P, II  Q, III  S , IV  S
17. Two players A and B play a game against each other. In every round of the game, each
player roll’s a fair die, once where have six faces of the die have distinct numbers. Let n1
and n2 be the readings on the die rolled by A and B respectively. If n1  n2 , then A scores
‘5’ points B scores ‘0’ points if n1  n2 each player gets 2 points. If n1  n2 the A scores ‘0’
points and B scores ‘5’ points. Let M i and Ni be the total scores of A and B respectively
after ith round then match the following
COLUMN-I COLUMN-II
I) Probability of  M 2  N 2  P) 3/8

II) Probability of  M 2  N 2  is Q) 11/16

III) Probability of  M 3  N3  R) 5/16

IV) Probability of  M 3  N 3  S) 355/864

T) 77/432
A) I  Q, II  R, III  T , IV  S B) I  Q, II  R, III  T , IV  T
C) I  P, II  R, III  Q, IV  S D) I  P, II  R, III  Q, IV  T

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PHYSICS Max Marks: 60
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
18. A wire of variable mass per unit length   0 y, is hanging from the celling as shown in
the figure. The length of the wire is L0. A small transverse disturbance is produced at its
lower end. The time after which the disturbance will reach the other end is

2L0 8L0 L0 12L0

A) B) C) 2 D)
g g g g
19. A plane progressive transverse wave is passing through medium along the positive x-axis
at the given instant of time. The nature of the displacement-position (y vs x) graph of
particles of medium at that instant is as shown in figure. Which of the following of
particles of medium at that instant is as shown in figure. Which of the following
statement are correct. (A,B,C are three particles of the vibrating string)

1) Elastic potential energy per unit length of the string at the point B is more than that at
points A and C
2) Elastic potential energy per unit length of them string at the point C is more than that
at points A and B
3) Velocity of the particle at A is along negative y-axis.
4) Velocity of the particle at C is along positive y-axis.
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A) Only 2,3,4 are correct B) Only 1,3,4 are correct
C) Only 1,3 are correct D) Only 1,4 are correct
20. An open organ pipe is vibrating in its fifth overtone. The distance between two
1
consecutive points where pressure amplitude is time pressure amplitude at pressure
2
antinodes, is 40 cm. Then the length of open organ pipe is (neglect end connection)
A) 3m B) 3.6 m C) 4.2 m D) 4.8 m
u
21. A wall is moving with velocity u and a source of sound moves with velocity in the
2
same direction as shown in the figure. Assuming that the sound travels with velocity
10 u. The ratio of incident sound wavelength on the wall to the reflected sound
wavelength by the wall, is equal to
u
2
u
S

A) 9:11 B) 11:9 C) 4:5 D) 5:4

SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get +1 mark; choosing no option (i.e.
the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

22. Two uniform strings of mass per unit length  and 4  , and length L and 2L,
respectively, are joined at point O, and tied at two fixed ends P and Q, as shown in the
figure. The strings are under a uniform tension T. if we define the frequency
1 T
f0  , which of the following statement(s) is (are) correct?
2L 

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 O 4
P Q
L 2L
A) With a node at O, the minimum frequency of vibration of the composite string is f 0
B) With an antinode at O, the minimum frequency of vibration of the composite string is
2 f0
C) When the composite sting vibrates at the minimum frequency with a node at O, it has
6 nodes, including the end nodes
D) No vibrational mode with an antinode at O is possible for the composite string
23. A metallic rod of length L, linear mass density  rotates about one of it’s end ’O’ in a
smooth horizontal plane with an angular velocity  about an end axis which is
perpendicular to plane of rotation shown in figure. A transverse pulse generated at the
free end P to reach the axis of rotation. (neglect the gravitational effect)

A) The speed of the transverse pulse just after generated at the free end point P with
respect to ground is L
B) The speed of the transverse pulse when it reaches the mid point of metallic rod with
5
respect to ground is L
8
  L2   L  x  
2

C) The tension in the metallic rod at a distance ‘x’ from the free end   2
2
D) The time taken by the transverse pulse to reach the axis of rotation from the free end is

2

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24. A hypothetical pulse is travelling along positive x direction on a taut string. The speed of
the pulse is 10 cm/sec. The shape of the pulse at t=0 is given as
x
y  1 for  6  x  0
6
  x  1 for 0  x  1
 0 for all other values of x
 x, y are in cm
Choose correct options from following
5
A) The vertical displacement of the particle at x  1cm at t  0.2sec is cm
6
3
B) The vertical displacement of the particle at x  1cm at t  0.2sec is cm
5
4
C) The magnitude of transverse velocity of the particle at x  1cm at t  0.2sec is cm / sec
3
5
D) The magnitude of transverse velocity of the particle at x  1cm at t  0.2sec is cm / sec
3
SECTION-III
(NON-NEGATIVE INTEGER.)
This section contains SIX (06) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme
Full Marks : +4 If ONLY the correct integer is entered; Zero Marks : 0 In all other cases..
25. A source (S) of sound has frequency 240 Hz. When the observer (O) and the source move
towards each other at a speed V with respect to the ground (as shown in case 1 in figure),
the observer measures the frequency of the sound to be 288 Hz. However, when the
observer and the source move away from way from each other at the same speed V with
respect to the ground (As shown in case 2 in figure), the observer measures the frequency
of sound to be n Hz. The value of n is____
S V V O
Case (1)

S V V O
Case (2)

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26. An ant with mass m is standing peacefully on top of a horizontal stretched rope. The rope
has mass per unit length  and is under tension F. Without warning, a student starts a
sinusoidal transverse wave of wavelength  propagating along the rope, the motion of the
rope is in a vertical plane. What minimum wave amplitude (in mm) will make the ant feel
weightless momentarily? Assume that m is very small and that the presence of the ant has
no effect on the propagation of the wave (Given,   0.5m,   0.1 kg m1 , F  3.125 N , g   2 )
27. When 0.98 m long metallic wire is stressed, an extension of 0.02 m is produced. An
organ pipe 0.5 m long and open at both ends, when sounded with this stressed metallic
wire, produces 8 beats in its fundamental mode of both the instruments. By decreasing
the stress in the wire, the number of beats is found to decrease. The density of metallic
wire is 104 kg m3 and sound velocity in air is 292 ms 1. If the Young’s modulus of the
wire is  x  588  108 Nm 2 Find the value of x.
28. A motor cycle starts from rest and accelerates along a straight path at 2 m/s 2. At the
starting point of the motor cycle there is a stationary electric siren. How far (in cm) has
the motor cycle gone when the driver hears the frequency of the siren at 94% of its value
when the motor cycle was at rest? (speed of sound =330 ms-1)
29. A thin string of density 0.1 kg/m is held at one end and the other end is oscillated
according to the equation y  l  0, t   20  cm  sin  40t  where t is in seconds and l in cm is
the coordinate along the length of the string. The string is under a uniform tension of
40
10N. The string passes through a bath filled with kg of water. Due to wet friction,
21
heat is transferred through the bath and a snapshot at sometime is given in figure. After 
second the temperature of the bath rises by one kelvin. Then find the value of  [specific
heat capacity of water =4.2kJ/kg-K]
A
(where A is the amplitude of the wave on the string before entering the tub and is the
2
amplitude of the wave on the string after coming from the tub)

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30. Two sound waves of frequencies 100 Hz and 102 Hz and having same amplitude ‘A’
Are interfering A detector which can detect waves of amplitude greater than or equal to A
is kept at rest. In a time interval of 12 seconds, find the total duration (in sec) in which
detector is active.
SECTION – IV
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: –1 In all other cases.
31. In the figure are shown, two strings. Linear mass density of string 2 is nine times that of
string 1. Tension in both the strings is same. A transverse wave in sting 1 is incident at
the boundary. Part of waves is reflected in to medium 1 (i.e. string 1) and part is
transmitted in medium 2(i.e string 2). If A,v,I and P represent amplitude, speed of wave,
intensity and power, ,Match the Column I with Column II and mark the correct option

COLUMN-I COLUMN-II
I) | A1 / A2 | P) 9
II) V1 / V2 Q) 1
III) I1 / I 2 R) 3
IV) P2 / P1 S) Data insufficient
T) 1/3
A) I  Q, II  R, III  S , IV  R B) I  S , II  T , III  P, IV  R
C) I  Q, II  T , III  S , IV  P D) I  P, II  R, III  Q, IV  T
32. Column I contains figures of systems, each of length L, for producing standing waves.
The wave length in fundamental mode is represented by 0 . Match the following
columns and mark the correct option

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COLUMN-I COLUMN-II
I) Pipe closed at one end P) Longitudinal waves

II) Pipe open at both ends Q) Transverse waves

III) Stretched wire clamped at both ends R) 0  L

IV) Stretched wire clamped at both ends S) 0  2L

and the middle

T) 0  4L
A) I  P, T II  P, S III  Q, S IV  Q, R B) I  Q, T II  Q, R III  P, T IV  P, S
C) I  P, S II  P, T III  Q, S IV  Q, R D) I  P, S II  Q, T III  Q, T IV  Q, S
33. The horn of a car gives a sound of frequency 800 Hz. The listener is on bicycle. Match
the Column I with Column II and mark the correct option. Speed of sound is 343 ms -1 and
there is no wind.
COLUMN-I COLUMN-II
I) The frequency that the listener hears when he moves towards P) 873 Hz
the stationary car with a velocity 15 ms-1
II) The frequency that the listener hears when the car moves Q) 733 Hz
towards the stationary listener, with a velocity 15 ms -1
III) The frequency that the listener hears, when the car and the R) 835 Hz
listener move towards each other, each with a velocity 15 ms-1
IV) The frequency that the listener hears when the car and the S) 836. 6 Hz
listener recede from each other, each with a velocity 15 ms-1
T) 833 Hz
A) I  P, II  Q, III  R, IV  S B) I  R, II  S , III  P, IV  Q
C) I  Q, II  S , III  R, IV  T D) I  S , II  T , III  R, IV  P
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34. In the figure below two strings of different linear mass density 1 and 2 and length
l1 and l2 are connected to each other. The string passes over the ideal pulley and

connected to weight ‘W’. When exited with a turning fork the string vibrates such that the
joint between the two wires does not move at all. If N1 and N 2 are the number of
harmonics in the first and second wire respectively, match the entries in column-I
Column-II and mark the correct option

COLUMN-I COLUMN-II
I) 2 P) l1  3l2 , N1 : N 2  1:1
 4 :1
1

II) 1 Q) l1  l2 , N1 : N 2  1: 2
 1: 9
2

III) 2 R) l1 : l2  1: 6, N1 : N 2  1: 3
 1: 4
1

IV) 1 S) l1 : l2  3 :1, N1 : N 2  3: 2
 4:9
2
T) 2l1  l2 , N1 : N2  1: 3

A) I  Q, S , II  P, III  R, IV  T B) I  Q, II  P, III  R, IV  T
C) I  Q, S , II  R, III  P, IV  T D) I  P, II  Q, III  T , IV  R

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CHEMISTRY Max Marks: 60
SECTION – II
(SINGLE CORRECT ANSWER TYPE)
This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases
35. 9 moles of “D” and 14 moles of E are allowed to react in a closed vessel according to
given reactions. Calculate number of moles of B formed in the end of reaction, if 4 moles
of G are present in reaction vessel. (percentage yield of reaction is mentioned in the
reaction)
Step-1 3D  4 E 
80%
 5C  A
Step-2 3C  5G 
50%
 6B  F
A) 2.4 B) 1.2 C) 3.6 D) 4.8
36. A solution of Na2S2O3 is standardized iodometrically against 0.167 g of KBrO3. This
process requires 50 mL of the Na2S2O3 solution. What is the normality of the Na2S2O3?
(Given: atomic weight of K=39, Br=80,O=16 g.mol -1 respectively)
4 KBrO3  3Na2 S 2O3  3H 2O  4 KBr  3Na2 SO4  3H 2 SO4
A) 0.2N B) 0.12 N C) 0.72 N D) 0.02 N
37. 3Cl2  6 NaOH  
 5 NaCl  NaClO3  3H 2O
As per this reaction, which statements are correct?
(Given: atomic weight of Cl=35.5 g.mol 1 respectively)
5
A) th Cl2 Content undergoes reduction
6
1
B) th Cl2 content undergoes oxidation
6
C) The equivalent weight of chlorine molecule is 42.6
D) All the above
38. 20g of sample of Ba  OH 2 is dissolved in 10mL of 0.5 N HCl solution. The excess of
HCl was titrated with 0.2 N NaOH. The volume of NaOH used was 10 cm3. Calculate the
percentage of Ba  OH 2 in the sample (Given atomic weight of Ba=137,O=16,H=1
g.mol-1 receptively )?
A) 20% B) 10% C) 12.8 % D) 1.28%
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SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains THERE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks :+4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are correct ;
Partial Marks: +1 If two or more options are correct but ONLY two options are chosen, and it is a correct option ;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B) will get +1 mark; choosing ONLY (D) will get +1 mark; choosing no option (i.e.
the question is unanswered) will get 0 marks; and choosing any other combination of options will get -2 marks.

39. 50 ml of H2O2 is completely oxidized by10 ml, 0.2 N KMnO4 solution in acidic medium.
The strength of hydrogen peroxide is ?
M N
A) 0.68 gm/lit B) C) D) 0.068%  W V 
50 25
40. To check the principle of multiple proportions, a series of pure binary compounds
 PmQn  were analyzed and their composition is tabulated below. The correct option(s) is
(are)
Compound Weight % of P Weight % of Q
1 50 50
2 44.4 55.6
3 40 60
A) if empirical formula of compound 3 is P3Q4 , then the empirical formula of compound
2 is P3Q5 .
B) if empirical formula of compound 3 is P3Q2 , and atomic weight of element P is 20,
then the atomic weight of Q is 45.
C) if empirical formula of compound 2 is PQ, then the empirical formula of the
compound 1 is P5Q4 .
D) If atomic weight of P and Q are 70 and 35, respectively, then the empirical formula of
compound 1 is P2Q .
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41. When a equimolar mixture of Cu2 S and CuS is titrated with Ba  MnO4 2 in acidic medium,
the final products contain Cu 2 , SO2 and Mn 2 . If the molar Mass of
Cu2 S , CuS and Ba  MnO4 2 are M 1 , M 2 and M 3 respectively then:
M1
A) eq. mass of Cu2 S is
8
M
B) eq. mass of CuS is 2
6
M3
C) eq. mass of Ba  MnO4 2 is
5
D) Cu2 S and CuS both have same equivalents in mixture
SECTION-III
(NON-NEGATIVE INTEGER.)
This section contains SIX (06) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual numeric keypad in the place
designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme
Full Marks : +4 If ONLY the correct integer is entered; Zero Marks : 0 In all other cases.
42. 5g of NaOH was dissolved in de-ionised water to prepare a 450 ml stock solution. What
volume (in ml) of this solution would be required to prepare 500 ml of 0.1M NaOH by
dilution? (Given: molar mass of Na, O and H is 23,16 and 1g.mol-1 receptively)?
43. 6  10 3 mole K 2Cr2 O7 reacts completely with 9 103 mole X n  to give XO3 and Cr 3 . The value
of n is:
44. The equivalent mass of HCl (nearest to integer) in the given reaction is:
K 2Cr2O7  14 HCl  2 KCl  2CrCl3  3Cl2  7 H 2O

(Given: atomic weight of H  1, Cl  35.5 g. mol 1 respectively)

45. One litre of a sample of hard water contain 4.44 mg CaCl2 and 1.9 mg of Mg Cl2 . What
is the total hardness in terms of ppm of CaCO3 ?
(Given: atomic weight of Ca  40, Mg  24 g. mol 1 respectively)
46. Galena (an ore) is partially oxidized by passing air through it at high temperature. After
some time, the passage of air is stopped, but the heating is continued in a closed furnace
such that the contents undergo self-reduction. The weight (in kg) of Pb produced per
32 kg of O2 consumed is? ___

(Atomic weights in g mol 1 : O  16, S  32, Pb  207 )

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47. 0.71 g of a sample of bleaching powder  CaOCl2  solution is dissolved in 100 mL of

water. 50 mL of this solution is titrated with KI solution. The I 2 So liberated required 10
ml of 0.1 M Na2 S 2O3 (Hypo) solution in acidic medium for complete neutralization.
Calculate the percentage of available Cl2 from the sample of bleaching powder? (Atomic
mass of Ca=20, O=16, Cl=35.5, Na=23, S=32 )
SECTION – IV
(MATCHING TYPE)
This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks:+3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks: 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks: –1 In all other cases..
48. Column-I and Column-II contain four entries in each. Entries of Column-I are to be
matched with some entries of Column-II One or more than one Entries of Column-I may
have the matching with the same entries of Column-II. E= Equivalent weight of reactant,
M=molecular weight
COLUMN-I COLUMN-II
I) 118 % of oleum P) E
3M
4

II) 104.5 % of oleum Q) 20% of free SO3

III) As2 S3  AsO3  SO4 2  R) E
M
28

IV) H 3 PO2  PH 3  H 3 PO3 S) 80% of free SO3

T) E
15M
26

A) I  S , II  Q, III  R, IV  P B) I  Q, II  S , III  R, IV  P
C) I  P, II  Q, III  R, IV  S D) I  S , II  R, III  Q, IV  P

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49. Match the following
COLUMN-I COLUMN-II
I) 10V H 2O2 P)  w
30.36%   H 2O2
v

II) 20V H 2O2 Q)  w

0.3036%   H 2O2
v

III) 30V H 2O2 R) 2.679 M H 2O2

IV) Per hydrol S) 1.786 M H 2O2

T)  w
3.036%   H 2O2
v

A) I  P, II  R, III  S , IV  T B) I  T , II  R, III  S , IV  P
C) I  T , II  S , III  R, IV  P D) I  S , II  R, III  Q, IV  P
50. Match the following
COLUMN-I COLUMN-II
(Reaction) (n-factor of reactants)
I) When FeS2 Converted in to Fe2O3 and SO2 P) 3

II) Cl2  OH   ClO3  Cl  Q) 61

III) FeC2O4  Fe 3  CO2 R) 5/3
IV)  Fe  CN 6 
4
 Fe3  CO2  NO3 S) 5/6

T) 11
A) I  Q, II  R, III  P, IV  T B) I  T , II  R, III  S , IV  P
C) I  T , II  S , III  R, IV  P D) I  T , II  R, III  P, IV  Q

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51. Given two mixtures
(1) NaOH  Na2CO3
(2) NaHCO3  Na2CO3
100 ml of mixture 1 required ‘w’ and ‘x’ ml of 1M HCl in separate titrations using
phenolphthalein and methyl orange indicators. While 100ml of mixture 2 required ‘y’ and
’z’ ml of same HCl solution in separate titration using same indicators.
COLUMN-I COLUMN-II
(Substance) (Molarity in solution)
I) Na2CO3 in mixture 1 P)  2 w  x  10 2
II) Na2CO3 in mixture 2 Q)  z  2 y   10 2
III) NaOH in mixture 1 R) y 10 2

IV) NaHCO3 in mixture 2 S)  x  w   102

T)  w  2 x  10 2
A) I  S , II  R, III  Q, IV  P B) I  S , II  R, III  P, IV  Q
C) I  P, II  Q, III  S , IV  R D) I  P, II  S , III  Q, IV  R

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