mole concept

1. A sample of Mg3(PO4)2 contains 72 g Mg in the sam- 11. X is molecular substance containing 21 atoms of car-
ple. Calculate the number of g molecule of oxygen in bon per molecule. The weight % of C in X is 50.4%.
the sample. What is the molecular weight of X in amu?
(a) 2 (b) 3 (c) 3.5 (d) 4 (a) 500 (b) 200 (c) 300 (d) 400
2. What mass (in gram) of Na2SO4 would contain the same 12. Calculate pressure (in atm) exerted by gas at 27°C,
number of total ions as present in 930 g of Ca3(PO4)2? which is produced by the complete decomposition of
(a) 710 (b) 800 (c) 200 (d) 500 162.5 g of FeCl3 in 0.0821 L container according to the
3. A sample of Cl contains 80% Cl35 and 20% Cl37 iso- following reaction: (Assume volume occupied by the
topes. The average number of neutrons per atom is solid substances is negligible.)
(a) 18.4 (b) 19.4 (c) 35.4 (d) 20.4 FeCl3(s) æÆ FeCl2 (s) + Cl2 (g)
4. A sample of K2SO4. Al2(SO4)3. 24 H2O contains 6.4 kg (a) 250 (b) 150 (c) 15 (d) 300
oxygen. Calculate mass of sulphur (in gram) in same 13. A term ‘P’ is defined as
sample. P = 294 ¥ (Ratio of masses of Al2 (SO4)3 and H2SO4 in
(a) 1280 (b) 1000 (c) 128 (d) 12.8 g each containing 96 g of sulphur).
7. A 448 L vessel contains O2(g) and CO2 (g) in 2 : 3 ratio Calculate P.
at 1 atm and 0°C. Calculate the number of moles of (a) 342 (b) 294 (c) 684 (d) 171
CO2 (g) present in the vessel. 14. Calculate molality(m) of pure water if its density is
(a) 12 (b) 1.1 (c) 1.2 (d) 120 0.936 g/mL.
5. Find the value of ‘x’, if hydrated salt A2SO4 . xH2O (a) 50 (b) 55.56 (c) 57.56 (d) 56.56
undergoes 45% loss in mass on heating and becomes 15. The volume (in mL) of 0.5 M NaOH required for the
anhydrous (where atomic weight of ‘A’ is 7). complete reaction with 150 mL of 1.5M H3PO3 solu-
(a) 8 (b) 9 (c) 10 (d) 5 tion is
6. Calculate the volume of Cl2 gas (in mL) liberated at 1 (a) 1350 (b) 900 (c) 1250 (d) 1150
atm and 273 K when 1.74 g MnO2 reacts with 2.19 g 16. For the reaction,
HCl according to the following reaction with % yield AlCl3 + NaOH æÆ Al(OH)3 + NaCl
40: if initially, 1 mole of each reactant is taken, then the
MnO2 + HCl æÆ MnCl2 + Cl2 + H2O number of moles of AlCl3 remaining after the comple-
(a) 336 mL (b) 112 mL (c) 134.4 mL(d) 44.8 mL tion of reaction is
7. Calculate the mass % of CaCO3 in the 103 g mixture 1
containing CaCO3 and Na2CO3, which produces 24 L (a) 1 (b)
3
of CO2 at 1 atm and 300 K with excess of HCl. 2
(c) (d) None of these
[Given : R = 0.08 atm. lit / mol/ K] 3
(a) 50 % (b) 48.5 % (c) 53 % (d) 40 % 17. A mixture of CaCO3 and CaO on heating gives off
8. Calculate the mass of HCl (in g) produced if 2 g H2 is 22.4 L of CO2 gas at 273 K and 1 atm. If the same mass
mixed with 71 g Cl2. of mixture when treated with HCl required 219 g of
H2 + Cl2 æÆ 2HCl HCl for complete reaction, then the mole % of CaCO3
(a) 35.5 (b) 72 (c) 36.5 (d) 73 in the mixture is
9. Select the correct statement(s): (a) 50% (b) 33.33%
(a) Number of oxygen atoms are same in 1 g O2 and (c) 25% (d) None of these
1 g O3. 18. The relative density of a mixture of CO2 (g) and H2O (g)
(b) 1 g molecule of any substance contains equal w.r.t. gaseous hydrogen atoms is 30. The molecular %
number of atoms. of the CO2 is
(c) Reactant having minimum number of moles, acts 600 2400
(a) (b) %
as limiting reagent. 13 13
(d) During a chemical reaction total number of moles 1200
may increase or constant. (c) (d) None of these
13
10. Calculate the volume (in mL) of NO2 at 1 atm and 273 19. Molar mass of electron is nearly (NA = 6 ¥ 1023)
K obtained by treating 12.7 g of Cu with excess of con- (a) 9.1 ¥ 10–31 kg mol–1 (b) 9.1 ¥ 10–31 g mol–1
centrated nitric acid from the following reaction: (c) 54.6 ¥ 10–8 g mol–1 (d) 54.6 ¥ 10–8 kg mol–1
Cu(s) + HNO3 (aq) æÆ Cu(NO3)2 (aq) + H2O (l) + NO2
20. Calculate the number of moles of compound (KH-
(a) 8960 (b) 896 (c) 89.3 (d) 6900 C2O4)0.95· H2C2O4 in its pure sample if sample contains
4 moles of oxygen atoms.
(a) 0.5 (b) 0.5 ¥ 0.95
4 4
(c) (d)
(4 + 0.95 ¥ 4) 0.95

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 21. What is the relationship between mole fraction of of a 29. One of the major uses of H2O2 is for artificial respira-
solute (XA) and its molality (m). If molar mass of sol- tion. It is stored in cylinder of 3 L capacity completely
vent is 100. (g/mol). filled with H2O2 solution of ‘44.8 V’. In a hospital, pa-
(X A) (X A) tient under artificial respiration takes 200 mL O2 per
(a) (b) min at 1 atm at 273 K for 2.8 hours from cylinder.
10 (1 - X A ) 100 (1 - X A )
[Assume volume of solution and rate of decomposition
10 (1 - X A ) 10 ( X A ) remain constant.]
(c) (d) Then which of the following statements is incorrect?
(X A) (1 - X A )
(a) Initial moles of H2O2 in a cylinder are 12.
22. 100 mL of 0.1 M ammonium phosphite solution is (b) Volume of oxygen used for respiration is 33.6 L.
mixed with 200 mL of 0.2 M sodium pyrophosphate (c) Volume strength of H2O2 left in solution is 11.2 V.
solution. Assuming complete dissociation of each salt (d) Volume strength of H2O2 left in solution is 33.6 V.
and no reaction occurs between the ions produced, cal- 30. Two gases N2 and H2 are allowed to react completely to
culate the concentration of total positive ions in mil- form mixture of N2H2(l) and N2H4 (g) leaving no reac-
limoles per litre.
tants. Formation of N2H2 (l) does not create any energy
(a) 600 (b) 200 (c) 500 (d) 60
change whereas formation of 1 mL N2H4 (g) absorbs 2 J
23. A mixture of C2H4, CO and N2 gases having total pres-
energy. Ratio of volume contraction to energy change
sure 250 mm of Hg in which 250 mm Hg of O2 is added
(in mL / Joule) when 30 mL N2 and 40 mL H2 react
at 27°C and then sparked. After the system is brought
to the original temperature, the total pressure becomes under similar conditions of temperature and pressure.
370 mm of Hg. If the partial pressure of CO2 is 200 mm (a) 3mL /J (b) 5mL /J
of Hg, then calculate the sum of initial pressure of CO (c) 6mL /J (d) None of these
and O2 in mm of Hg before the sparking 31. 150 mL mixture of CO and CO2 is passed through a
Given : At 27°C aqueous tension is 20 mm of Hg. tube containing excess of red hot charcoal. The volume
(a) 100 (b) 200 (c) 300 (d) 350 becomes 200 mL due to reaction.
24. Human lungs can absorb 8 g O2 per hour by respira- CO2 (g) + C(s) æÆ 2CO (g)
tion. If all oxygen atoms are converted to carbohy- Select the correct statement(s).
drates (C6H12O6), how long will it take to produce 180 (a) Mole percent of CO2 in the original mixture is 50.
g C6H12O6? (b) Mole fraction of CO in the original mixture is 0.56.
(a) 8 hr (b) 12 hr (c) 10 hr (d) 6 hr (c) Original mixture contains 50 mL of CO2.
25. If in a sample of oleum, mole fraction of SO3 is 0.5, (d) Original mixture contain 50 mL of CO.
label the oleum sample. 32. A mixture of formic acid and oxalic acid is heated in
(a) 109 % (b) 110.11 % the presence of H2SO4.
(c) 104.5 % (d) 114.22 HCOOH æÆ H2O + CO
26. Manganese oxide (MnO2) is heated in a stream of hy- H2C2O4 æÆ H2O + CO2 + CO
drogen to give water and new oxide MnxOy. If 17.4 g of
MnO2 produces 12.6 g of MnxOy then y : x will be The produced gaseous mixture is collected and cooled.
On its treatment with KOH solution, the volume of
1 3 5
(a) 1 (b) (c) (d) gaseous mixture decreases by one-tenth. Calculate the
2 2 2 molar ratio of the two acid in original mixture. [If the
27. A pure sample of an element ‘E’ is cut by knife into
simplest ratio is a : b then find a + b.]
perfect cubes. If 7.5 ¥ 1022 atoms are present in one
(a) 6 (b) 9 (c) 2 (d) 5
such cube and ‘a’ is edge length of cube in cm, then
33. In a tyre of a ‘ferrari’ car, a tube having a volume of
what will be the value of a6 (in cm6)?
12.3 L is filled with air at a pressure of 4 atm at 300
[Given : Atomic mass of E = 32, NA = 6 ¥ 1023, Density
K. Due to travelling, the temperature of the tube and
of element = 4/3 g/cm3 ]
air inside it is raised to 360 K. The porosity (number
(a) 9 (b) 4 (c) 16 (d) 25
of pores per unit area) of the tube material is 5 ¥ 105
28. Which of the following option(s) is incorrect?
pores/cm2 and each pore can transfer air from inside to
[Take H2O to be solvent in every case and solute is
outside of tube at the rate of 6.023 ¥ 108 molecules per
completely soluble]
minute. Due to above factors, pressure reduces to 3.6
(a) If mass fraction of CaBr2 and H2O are same then
atm in 20 min. Calculate the total surface area (m2) of
molality of CaBr2 is 5 m.
the tube, assuming volume of tube to be constant. (R =
(b) If equal moles of NaCl and H2O are taken then
0.082 lit-atm/mole-K)
molality of NaCl is 55.55 m.
(a) 5000 (b) 500 (c) 4000 (d) 400
(c) If in place of NaCl we use NaBr as solute in op-
34. Calculate the number of milligrams of SO2 in a sample
tion (2) then molality of NaCl changes.
of air, if in the following reaction 9 mL of 0.008 M
(d) If mole fraction of NaCl is same as that of H2O
KMnO4 solution is required for titration.
then molality of NaCl will be 55.55 m.

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 SO2 + MnO4– æÆ SO4 –2 + Mn+2 44. Calculate the number of Na+ ion present in 142 amu of
(a) 11.52 mg (b) 0.18 mg Na2SO4 in aqueous solution.
(c) 0.072 mg (d) None of these (a) 5 (b) 2 (c) 1 (d) 4
35. Two acids H2SO4 and H3PO4 are neutralised separately 45. 1 mole of diatomic gas A2 contains 32 and 36 moles
by the same amount of base, producing sulphate and of electrons and neutrons respectively. Find the mass
dihydrogen phosphates respectively. The ratio of mass number of element A.
of H2SO4 and H3PO4 reacted with base respectively is (a) 32 (b) 68 (c) 40 (d) 34
(a) 1 : 1 (b) 2 : 1 46. Find the number of moles of Na3PO4 which contain as
(c) 1 : 2 (d) Data insufficient many ions as present in 6840 g of Al2(SO4)3.
36. Calculate mass % of oxygen in water (a) 20 (b) 25 (c) 30 (d) 60
(a) 88.88% (b) 73.68 % 19 39
47. An equimolar mixture of 9 F, 19 K and 32XA have
(c) 20.61% (d) 25.63 % average number of neutron of 25. Find average mass
37. 100 g ‘118% oleum’ sample is mixed with 9 g of H2O. number of mixture.
The final solution has (a) 22.5 (b) 21.5 (c) 45 (d) None
(a) mass % of H2SO4 is 2.7. 48. Find the correct option for 36 g C6H12O6.
(b) Mass % of combined SO3 is 16.3. (a) 4.8 NA molecules of C6H12O6
(c) New labelling as 108.25% oleum. (b) 19.2 NA electrons
(d) Mass % of free SO3 is 80. (c) 0.8 moles
M (d) 0.6 g molecules of oxygen
38. The two solutions of NaOH having molarity and 49. To obtain maximum mass of NO2 from a given mass of
M 10
are mixed to prepare 1 L of NaOH solution in such a mixture of NH3 and O2, the ratio of mass of NH3 to
30 O2 should be
a way that 300 mL of final solution is completely neu- 7
tralised by 10 mL of 0.5 M H3PO4 solution. Calculate 2NH3 + O2 æÆ 2NO2 + 3H2O
2
M 17 4
the volume (in mL) of NaOH solution used.
10 (a) (b)
40 7
[Assuming 100% dissociation]
17
(a) 250 mL (b) 350 mL (c) (d) None of these
(c) 50 mL (d) 500 mL 56
39. 1 mole of ammonium phosphite will contain 50. Find the mass (in g) of P4O10 produced if 31 g of phos-
(a) 2 moles of nitrogen atoms. phorus (P4) is mixed with 32 g of O2.
(b) 8 moles of hydrogen atoms. (a) 26.8 (b) 56.8 (c) 568 (d) 5.68
(c) 12 moles of hydrogen atoms. 51. If 200 mL of 0.1 M Na2SO4 is mixed with 100 mL of 0.2
(d) 6 moles of hydrogen atoms. M Na3PO4 solution, what is the molarity of Na+ in the
40. In a container 6 L N2 and 30 L H2 are taken which react final solution, if final solution has a density of 1.2 g/mL.
according to the following reactions and N2H2 reacts (a) 0.196 M (b) 0.33 M
with H2 to give N2H4. (c) 1.5 M (d) 0 .66 M
52. Mark the option containing temperature-independent
N2(g) + H2(g) æÆ N2H2(g)
concentration terms.
N2H2(g) + H2(g) æÆ N2H4(l)
(I) ppm
Find percentage of volume contracted. (II) %w/w
(a) 50 (b) 40 (c) 30 (d) 60 (III) Volume strength of H2O2
41. Find the total number of carbon atom present in one (IV) % labelling (V) %w/v
molecule, if 0.078 g hydrocarbon having simplest for- (a) All except V (b) I, II, IV
mula unit CH, occupy 22.4 mL of volume at 1 atm and (c) I, II only (d) Only II
0°C.
53. Total number of electrons present in 818O–2 is 1.2 ¥ 1022
(a) 5 (b) 4 (c) 2 (d) 6
then the number of moles of oxide ion present is
42. Find the % mass of Ca in 10 g of pure CaCO3.
(a) 2 ¥ 10–3 mole (b) 10–3 mole
(a) 40 (b) 30 (c) 60 (d) 50 (c) 10 mole (d) 0.02 mole
43. Find volume occupied by 1 molecule of CH3CH2OCH3 54. Ratio of number of protons to neutrons in 3.011 ¥ 1022
having density of 0.8 g/cm3. molecules of D3O+ is
[Given : NA = 6 ¥ 1023] (a) 2 (b) 1 (c) 4 (d) 3
(a) 1.25 ¥ 10–22 cm3 (b) 2.25 ¥ 10–22 cm3 55. 80 g of SOx gas occupies 14 L at 2 atm and 273 K. The
(c) 3.25 ¥ 10–22 cm3 (d) 1.00 ¥ 10–22 cm3 value of x is
(Use R = 0.0821L-atm/K-mole)
(a) 3 (b) 2 (c) 1 (d) None

IIT JEE PC-V1_01.indd 15 3/21/2017 5:10:24 PM

 56. Haemoglobin contains 0.25% iron by mass. The mo- 68. If one million atoms of silver weight is 1.79 ¥ 10–16 g,
lecular mass of haemoglobin is 89600 then the number the gram atomic mass of silver is
of iron atoms per molecule of haemoglobin (Atomic (a) 107 g (b) 107.2 g
mass of Fe = 56) is (c) 107.8 g (d) 108.2 g
(a) 8 (b) 4 (c) 12 (d) 160 69. How many g-atoms are present in 1.4 g of Nitrogen?
57. 12 g of mg was burnt in a closed vessel containing 32 g (a) 1 (b) 0.1 (c) 0.01 (d) 0.5
oxygen. Which of the following statements is not cor- 70. On heating a given mass of blue vitrol 95.7 g, anhy-
rect? drous copper sulphate is obtained. The number of water
(a) 2 g of mg will be left unburnt. molecules lost are
(b) 0.75 gram-molecule of O2 will be left unreacted. (a) 3 (b) 5
(c) 20 g of MgO will be formed. (c) 18.06 ¥ 1023 (d) 30.10 ¥ 1023
(d) The mixture at the end will weight 44 g. 71. The amount of zinc needed to produce 112 mL of H2 at
58. Calculate maximum mass of CaCl2 produced when STP on reaction with dil H2SO4 will be
2.4 ¥ 1024 atoms of calcium is taken with 96 L of Cl2 (a) 0.65 g (b) 0.325 g
gas at 380 mm pressure and at 27ºC. (c) 6.5 g (d) 3.25 g
[R : 0.08 atm L/mole-K and NA = 6 ¥ 1023] 72. Calculate the number of electrons present in 18 mL of
(a) 111 g (b) 444 g H2O at 25ºC.
(c) 61 g (d) 222 g
(a) 6.023 ¥ 1023
59. A mixture containing 3 moles each of C4H8 and C6H6
(b) 6.023 ¥ 1024
undergoes complete combustion with O2 to form CO2
180
and H2O. Calculate the total mass of CO2 produced. (c) ¥ 6.023 ¥ 1023
(a) 1320 g (b) 610 g 22400
(c) 528 g (d) 792 g 180
(d) ¥ 6.023 ¥ 1023
60. An impure sample of KClO3 of 50% purity on decom- 22.4
position produces 67.2 L of oxygen at 0ºC and 1 atm. 73. Experimentally it is found that a metal oxide has for-
The other product of decomposition is KCl. The initial mula M0.98O1. Metal M is present as M+2 and M+3 in its
mass of impure original sample (in gram) taken is oxide. Fraction of metal which exist as M+3 would be
(a) 245 (b) 122.5 (a) 7.01% (b) 4.08%
(c) 490 (d) None of these (c) 6.05% (d) 5.08%
61. A cylinder of compressed gas contains nitrogen and 74. The ratio of masses of O2 and N2 in a particular gaseous
oxygen gas in the mole ratio 3 : 1. If the cylinder is mixture is 1 : 4. The ratio of number of their molecules
known to contain 2.40 g of oxygen, what is the total is
mass of gas mixture? (a) 1 : 8 (b) 3 : 16 (c) 1 : 4 (d) 7 : 32
(a) 8.7 g (b) 7.2 g (c) 6.8 g (d) 6.3 g 75. A solution of H2O2 is labelled as 11.2 V. If the density of
62. If in urea [CO(NH2)2] there are 20 g – atoms of nitro- solution is 1.034 g/mL then identity the correct option.
gen present then the mass of urea will be (a) Molarity of solution = 2M
(a) 600 g (b) 60 g 1
(c) 6 g (d) 120 g (b) Molality of solution =
1.034
63. The weight of 2.8 liter of gas at NTP is 3.50 g. Its va- w 3400
pour density is (c) % =
w 1034
(a) 14 (b) 28 (c) 32 (d) 20
w 34
64. If nickel oxide has the formula Ni0.98 O1.00, then what (d) % =
fraction of nickel exist as Ni+3? v 1000
(a) 96% (b) 4% (c) 98% (d) 2% 76. A gaseous mixture of CO and CO2 having total volume
65. Find the number of iodine atoms present in 40 mL of its 150 mL is passed through a tube containing excess of
0.1 M solution. red hot charcoal to cause the following reaction:
(a) 48.1 ¥ 1020 (b) 4.81 ¥ 1020 CO2(g) + C(s) æÆ 2CO(g)
23
(c) 6.02 ¥ 10 (d) None of these The volume increases to 250 mL. Identify the correct
66. Assuming complete ionisation, the pH of 0.1 M HCl is statement.
1. The molarity of H2SO4 with same pH is (a) Original mixture contains 50% by moles CO.
(a) 0.1 (b) 0.2 (c) 0.05 (d) 2 (b) Original mixture contains 33.33% by moles CO.
67. The mole fraction of solute in one molal aqueous solu- (c) Original mixture contains 33.33% by moles CO2.
tion is (d) Mole fraction of CO2 in the original mixture is 0.4.
(a) 0.009 (b) 0.018 (c) 0.027 (d) 0

IIT JEE PC-V1_01.indd 16 3/21/2017 5:10:24 PM