Lec01_LectureNotes
Lec01_LectureNotes
Definitions
Why take Thermodynamics I?
• Develop basic problem solving, organizational, time management, and professional skills.
Properties
• Specific volume, pressure, temperature, internal energy, enthalpy, entropy
• Property tables
• Models: incompressible substance and ideal gas
Work
• Pressure (aka “p dV” work)
• Shaft work
• Electrical work
• Spring work
Fundamental Laws
• Conservation of Mass
• The First Law of Thermodynamics Heat Transfer
• The Second Law of Thermodynamics
Limits of performance
• Thermal efficiency
Problem solving
• Systems and control volumes
• Steady and transient analyses
• Cycles
energy addition
via heat transfer energy addition via
electrical work
• A control volume (CV) (aka open system) is a particular volume chosen for study. Unlike a
system, matter may change within a control volume. Note that the control volume does not need to
remain fixed in size or location; it may move or change size and shape.
• A control surface (CS) is the surface enclosing a control volume. The orientation of the CS at a
particular location is given by the direction of its outward-pointing unit normal vector, 𝒏
", at that
location. The outward-pointing unit normal vector has a magnitude of one, is perpendicular to the
control surface, and always points out of the CV.
𝒏
"
𝒏
"
𝒏
"
𝒏
" Image by Jeff Dahl, CC BY-SA 4.0,
https://commons.wikimedia.org/w/index.php?curid=3235265
• Properties are macroscopic characteristics of a system. Example properties include mass, volume,
energy, pressure, and temperature. A quantity is a property if and only if its change in value
between two states is independent of the process between these states. For example, pressure is a
property since its value only depends on the current state, but the work done on a system is not
since the work depends on the process taken to reach a given state.
o An extensive property is one that depends on the mass in the system. For example,
kinetic energy and mass are extensive properties since their values are proportional to the
mass in the system.
o An intensive property is one that is independent of the mass in the system. For example,
temperature and pressure are intensive properties since their values are independent of
how much mass is in the system.
o An easy way to determine whether a property is extensive or intensive is to divide the
system into two parts and see how the property is affected.
o A specific property is an extensive property per unit mass. A specific property is also an
intensive property. An example of a specific property is specific volume v = V/m where V
is the system property and m is the system mass.
• The state of a system is the system’s condition or configuration as described by its properties in
sufficient detail so that it is distinguishable from other states. Often only a subset of properties is
needed to define a state since some properties may be related.
• A process is the transformation of a system from one state to another. A few common processes
include:
o isothermal process: A process that occurs at constant temperature.
o isobaric process: A process that occurs at constant pressure.
o isochoric or isometric process: A process that occurs at constant volume.
o adiabatic process: A process in which there is no heat transfer between the system and
surroundings.
o isentropic process: A process that occurs at constant entropy.
temperature, T
state 1
state 2 state 3
pressure, p
o A process is in steady state if the system’s state does not change with time.
o A system is in a state of equilibrium if there are no potentials driving the system to
another state. Examples of driving potentials include unbalanced forces, unbalanced
temperatures, an electric potential (aka voltage).
o A process path is the series of states that a system passes through during some process.
o A quasi-equilibrium process is one where the process proceeds in such a manner that the
system remains infinitesimally close to an equilibrium state at all times. One can interpret
a quasi-equilibrium process as occurring slowly enough so that the system has time to
adjust internally such that properties in part of the system do not change any faster than
those properties in other parts of the system.