DELTA SC ®

Surface Control Additives

MORDRY ® DELTA FC ®
Foam Control Additives
Driers

DELTA DC ®
Dispersion Control Additives

DELTA S®
MORDRY ®
Specialty Additives
Table of Contents
DELTA IN BRIEF 04
ABOUT US 4
CORE VALUES 6
BRAND PROMISE 8

FOAM CONTROL ADDITIVES 10

01 COMPOSITION OF A FOAM CONTROL ADDITIVE

CHOOSING A FOAM CONTROL ADDITIVE
PRODUCT SELECTION GUIDE

SURFACE CONTROL ADDITIVES

12
13
14

16

02 SURFACE DEFECTS
CHOOSING A SURFACE CONTROL ADDITIVE
PRODUCT SELECTION GUIDE

DISPERSION CONTROL ADDITIVES

18
19
20

22

03 TYPES OF DISPERSION CONTROL ADDITIVES

CHOOSING A DISPERSION CONTROL ADDITIVE
PRODUCT SELECTION GUIDE

SPECIALTY ADDITIVES
24
26
28

32

04 MULTI-PURPOSE ADDITIVES
MULTI-FUNCTIONAL ADDITIVES
REPLACEMENTS FOR COBALT DRIER

DRIERS & CATALYSTS

34
36
37

38

05 DEFINITION
PRODUCT LIST
38
40
Delta in Brief

About Us
Delta Specialties is a specialized multinational company serving the Our technical department holds the key for the continuous success of the
market with optimized solutions in multiple industries namely coatings, company. The Research & Development labs together with the Technical
graphic arts and plastics industries. The core business arms are the Service & Application labs work very closely in testing existing products for new
driers and additives offered with consistent quality to more than 30 applications and developing new products according to the customers’ demand.
countries serving local, regional, and multinational base of clients
around the GLOBE. Our business model is built around serving our customers in an industry that
revolves around technology and innovation, but above all positive impact.
Having been in the market for over 15 years, Delta is currently operating From the huge change little additives can bring to your performance comes
ZLWKRIߔFHVLQ&DQDGD,QGLD7XUNH\DQG(J\SW our belief that little makes difference.
 DELTA IN BRIEF
Delta…Your Global Reliable Partner
for Additive Solutions

Canada Turkey

India

Egypt

04
05
Delta in Brief

Core Values

Honesty is our guiding principle;

LWUHߕHFWVRQRXULQWHJULW\ZLWKDOO
stakeholders while bringing a
high sense of trust to our
markets and community at large.

Our deep belief in developing

SHRSOHDQGVROXWLRQVUHߕHFWV
on our ability to successfully
develop markets and business.
 DELTA IN BRIEF
Our entrepreneurial acumen
supports our forthcoming
vision; adapting to market
changes and responding with
KLJKߕH[LELOLW\

We deal with business as

humans; we understand their
challenges and we cherish a
partnership relation led by our
devoted passionate team.

We are proactive and courageous;

we take calculated risk trusting an
empowered team enjoying
self-realization and achieving
outstanding performance. 06
07
Delta in Brief

Brand Promise
Optimized Solution-Based Portfolio Human-to-Human Service
Understanding our customers’ needs is key to adopt the most relevant Empathy is in the heart of the way we deliver service; we will always
VROXWLRQVWKDWߔWWKHLUUHTXLUHPHQWVDQGSURYLGHWKHPZLWKEHWWHUSURGXFW deliver a close and personal relationship all backed up with responsive
performance. We will be the ultimate choice contributing value for money technical support and on- time & budget delivery.
partnership.

Reliable Partnership Sustainable Impact

Trust is a pillar formulating our relationship with our stakeholders. We will We work with impact, and we promise to embed sustainable development
always deliver on promise to assure a partnership relation with all our and support our customers aiming at more environmental friendly
stakeholders around the globe. solutions.
DELTA IN BRIEF
08
09
01
Foam Control
Additives
Air can be incorporated into a coating by
mixing during the polymer/pigment
grinding and let-down steps, by pumping
GXULQJSDFNDJHߔOOLQJ‫ڢ‬HWF

Effective foam control additives are

EHQHߔFLDOLQSUHYHQWLQJRUUHGXFLQJPDQ\
common coating problems such as
viscosity increase and loss of mechanical
shearing power during milling, volume
increase during the letdown and mixing
VWHSV‫ڢ‬HWF

Delta Specialties offer a comprehensive

range of foam control additives
(silicone-free and silicone-based) to help
you get rid of foam and achieve foam-free
formulations in coatings, printing inks,
adhesives and plastics (composite).
FOAM CONTROL ADDITIVES
11
10
Composition of a Foam
Control Additive
Typical foam control additives consist of the following components:
- &DUULHU ߕXLGV7KH\
- DFW WR WUDQVIHU WKH JHQHUDOO\ K\GURSKRELF DFWLYH - The most often used substances showing incompatible spreading
VXEVWDQFH XQLIRUPO\ LQWR WKH K\GURSKLOLF PHGLXP7\SLFDO FDUULHU ߕXLGV LQFOXGH IDWW\ DFLG HVWHUV DQG DPLGHV JO\FROV VLOLFRQHV DQG PRGLߔHG
include aliphatic and aromatic mineral oils, solvent blends, and water in silicones.
WKHFDVHRISUHHPXOVLߔHGGHIRDPHUV

- 6XUIDFHDFWLYHDJHQWV7KH\EULQJWKHDFWLYHVXEVWDQFHWRWKHDLULQWHUIDFH
- - $FWLYH VXEVWDQFHV 7KH\ DGVRUE VXUIDFWDQW LQJUHGLHQWV SUHVHQW LQ WKH
and into contact with the stabilized foam structure. These substances formulation and destabilize foam. Hydrophobic particles such as metal
work by having a general incompatibility with the formulation and disrupt soaps, waxes and hydrophobic fumed silica are adsorption compounds
the spreading mechanism for stabilizing foam. for foam destruction.
 FOAM CONTROL ADDITIVES
Choosing a Foam
Control Additive
For solvent-based and solvent-free systems, polysiloxanes, polyacrylates An important point to consider is the incorporation of the foam control
DQGSRO\ROHߔQVDUHHIIHFWLYH additive in the paint system. Since they are not soluble in the system, a
good distribution of the active substance is necessary. This can be
Pure polysiloxanes are also suitable but critical in terms of their controlled by the mixing speed and time, otherwise craters can be formed
compatibility, which can cause cratering. The best balance between RUORVVRIGHIRDPLQJHIߔFLHQF\LVREVHUYHG
FRPSDWLELOLW\DQGLQFRPSDWLELOLW\LVDFKLHYHGWKURXJKRUJDQLFDOO\PRGLߔHG
polysiloxanes. 6LQFHWKHSHUIRUPDQFHRIDIRDPFRQWURODGGLWLYHLVGLIߔFXOWWRSUHGLFWGXH
to the variety of raw materials used in a paint formulation and the
0RGLߔFDWLRQ RI WKH SRO\VLOR[DQH EDFNERQH ZLWK ߕXRULQH UHVXOWV LQ WKH application method, evaluation of your own system is indispensable.
VRFDOOHG ߕXRURVLOLFRQHV NQRZQ IRU WKHLU YHU\ ORZ VXUIDFH WHQVLRQ DQG
strong defoaming properties. The stirring or shaking tests are based on the incorporation of air in a
system. After this air incorporation, the samples can be analysed on
For waterborne systems, a wider range of chemical structures can be weight or volume. The foam reduction over time of these stirred or shaked
used due to the generally higher surface tension of these systems. samples can also be observed. These tests give the effectiveness of the
foam control additive during the manufacturing process.

Foam control additives for waterborne systems can The roll test can be used to control the foam behaviour during the
application of the paint. After application of the paint with a roller on a
generally be based upon: WHVWSDSHUWKHZHWDQGGU\ߔOPLVDQDO\]HGRQVXUIDFHGHIHFWV
- 0LQHUDO RLO $V RSSRVHG WR VROYHQWEDVHG V\VWHPV WKH VSUHDGLQJ RI
PLQHUDORLOVLQZDWHUEDVHGV\VWHPVLVVXIߔFLHQWWRDFWDVDIRDPFRQWURO
additive. In the presence of hydrophobic particles, the mineral oil acts in
addition as carrier for these particles.

- 6LOLFRQH%RWKGLPHWK\OSRO\VLOR[DQHVDQGPRGLߔHGSRO\VLOR[DQHVFDQEH
used as foam control agents in water-based systems.

12
13
 Alkyd & PE OH-melamine
Alkyd & PE OH-functional
Solvent-based coatings

Acrylic self-crosslinking
Acrylic OH-functional

Acrylic thermoplastic
Active Ingredients %

Chlorinated rubber
Medium-oil alkyd

Short-oil alkyd
Long-oil alkyd
Acid curable
Product Name Chemical Type

DELTA FC® 1020 Silicone-free -

DELTA FC® 1022 Silicone-based -

DELTA FC® 1030 Silicone-based -

DELTA FC® 1040 Silicone-based -

DELTA FC® 1041 Silicone-based -

DELTA FC® 1501 Mineral oil >98

Additives

DELTA FC® 1504 Mineral oil >98

Control

DELTA FC® 1520M Mineral oil 60

DELTA FC® 1522M Mineral oil >98

Foam

DELTA FC® 1525 Silicone-based 23

DELTA FC® 1531 Mineral oil >98

DELTA FC® 1590 Silicone-based 28

DELTA FC® 1720 Silicone-free -

DELTA FC® 1722 Silicone-based -

DELTA FC® 1730 Silicone-based -

 Solvent-based epoxy

Solvent-free epoxy

Nitrocellulose

Unsaturated polyester

Silicon resin

Vinyl copolymer

Water-based coatings and

Adhesives

Acrylic emulsion

Acrylic water reducible

Alkyd emulsion

Alkyd melamine

Alkyd water reducible

Epoxy

Polyester melamine

Polyurethane emulsion

Polyvinyl Acetate

‫ݾ‬ Printing inks

UV curable

3DFNDJLQJ JUDYXUH ߕH[R

Water-based

Composite

Gelcoats

Laminating

Lay-up & spray-up

15
14

FOAM CONTROL ADDITIVES

02
Surface Control
Additives
The surface of coating (coating could
mean paint, ink or composite) is exposed
to "the outside world" and has to withstand
some severe circumstances which may
lead to a fast degradation of the system
itself.

In most cases, superior surface properties

cannot be achieved without the addition
of surface control additives that alter the
surface properties of the coating.

Depending on the kind of additive used,

properties such as mar, slip and
scratch resistance, abrasion resistance,
anti-blocking ...etc can be altered.

Delta Specialties offer a variety of surface

control additives suitable for water and
solvent-based systems.
SURFACE CONTROL ADDITIVES
16
17
Surface Defects
'HIHFWVRIZHWDQGFRQVHTXHQWGU\FRDWLQJߔOPVDIIHFWLQJ
coating appearance and sometimes performance are:

- %HQDUG FHOOV +H[DJRQDO FHOOV ZLWK PDUNHG FHQWHUV SURGXFHG E\ - 3LFWXUHIUDPLQJ HGJHFUDZOLQJ 'HZHWWLQJRIWKHDSSOLHGFRDWLQJDQG
FLUFXODWLRQ LQ WKH ߔOP FDXVHG E\ JUDGLHQWV RI FRQFHQWUDWLRQ GHQVLW\ the appearance of fat edges or picture framing around the edges of a
and/or temperature. panel or metal part. It is generally caused by increase of surface tension
on the edge during drying. Low viscosity increases this phenomenon.
- )ORDWLQJ %HQDUG FHOO FLUFXODWLRQ LQߕXHQFHV FRORU VKDGH DQG DSSHDUDQFH
REVHUYHGDVPRWWOHGEORWFK\RUVWUHDNHGDSSHDUDQFHRIDSDLQWߔOP - )LVK H\HV &UDWHUOLNH KROHV ZKRVH FHQWHUV FRQVLVW RI D XQLIRUP ߕDW
painted region, surrounded by a depression, followed by a ridge of paint.
- )ORRGLQJ 6XUIDFH FRORU LV XQLIRUP EXW GLIIHUHQW WR WKH RULJLQDO RQH 7KH\DUHFDXVHGE\XQGLVSHUVHGߕXLGJOREXOHVLQWKHSDLQWRUE\DLUERUQH
FDXVHGE\XQHYHQGLVWULEXWLRQRISLJPHQWVLQWKHߔOPGXULQJGU\LQJ droplets (silicones, water, dried soap, dust, wax, and oil) deposited on the
SDLQWHGVXUIDFH/DUJHߔVKH\HVFDQEHIRXQGLQGLYLGXDOO\DQGVPDOORQHV
- &UDWHUV6PDOOERZOVKDSHGGHSUHVVLRQVRIWHQKDYLQJGURSVRUEDQGVRI are often found in small densely packed clusters.
PDWHULDO DW WKHLU FHQWHUV DQG UDLVHG FLUFXODU HGJHV LQ D FRDWLQJ ߔOP
Caused by contaminants of lower surface tension. - &UDZOLQJ 'HZHWWLQJ RI WKH DSSOLHG ߔOP IURP WKH VXEVWUDWH GXH WR
surface tension differentials.
- 2UDQJHSHHO6XUIDFHEXPSLQHVVRUZDYLQHVVWKDWORRNVOLNHWKHVNLQRI
an orange. It is often caused by poor levelling and is a common defect - 7HOHJUDSKLQJ )ORZ RI SDLQW LQGXFHG E\ WHPSHUDWXUH JUDGLHQWV RU
in both spray and roll-applied coatings. contaminant of the substrate surface.
 SURFACE CONTROL ADDITIVES
Choosing a Surface
Control Additive
Surface control additives are silicones,
SRO\DFU\ODWHVRUSHUߕXRURVXUIDFWDQWV

Polysiloxanes (silicones) have a very high surface activity and 3RO\HVWHUPRGLߔHG VLOR[DQHV H[KLELW D KLJKHU VWDELOLW\ DJDLQVW WKHUPDO
therefore are often used as surface control additives. Commercial degradation and improvements in compatibility. These products provide
VLOLFRQHEDVHG VXUIDFH FRQWURO DGGLWLYHV DUH PRGLߔHG E\ SRO\HWKHUV long-term slip and water repellency.
polyesters or alkyl side groups to improve recoatability and inter-coat
DGKHVLRQ 0RGLߔFDWLRQ SDUDPHWHUV DUH VLOLFRQH FRQWHQW PROHFXODU Homo and copolymers based on (meth)acrylic monomers are well known
ZHLJKWDQGPRGLߔFDWLRQGHJUHH polyacrylate surface control additives. In some cases, they are
incompatible in the paint system, which leads to the development of haze
Dimethylpolysiloxanes (PDMS) are used for different purposes depending in clear-coats.This problem can be solved by choosing an acrylic leveling
on their degree of polymerization. Low molecular weight products are agent with lower molecular weight and improved compatibility. Gloss
used as levelling agents. levels in solid colors are normally not affected by the incompatibility.

Increasing the molecular weight creates a higher degree of incompatibility ,QDGGLWLRQWRWKHLUSRVLWLYHLPSDFWRQߕRZDQGOHYHOLQJDFU\OLFKRPRDQG

with the coating medium and can generate a defoaming action. co-polymers are effective as air-release agents. Since they are not
reducing the surface tension of the coating to the extent of
silicone-based products, the wetting of substrate surfaces is improved
(substrate wetting).

These products can be used to create a strong cratering tendency, a

socalled hammer-tone effect. However, in most cases, recoatability is
a problem with this product group and methylalkyl polysiloxanes are 3HUߕXRURPRGLߔHG VXUIDFH FRQWURO DGGLWLYHV DUH WKH PRVW HIIHFWLYH
superior in this respect. compounds to decrease surface tension, however, recoatability and
foam stabilization and cratering may occur. These undesired
3RO\HWKHUPRGLߔHGVLOR[DQHVFDQEHWDLORUHGWRFHUWDLQFRDWLQJW\SHVDQG side-effects depend very much on the system parameters that have to
are superior to the dimethylpolysiloxanes. However, in certain applications, be optimized and adjusted to gain optimum results. Controlling the
hydrolytic stability may be a problem. Self-condensation of hydroxyl SDUDPHWHUV RI PROHFXODU ZHLJKW SRODULW\ GHJUHH RI ߕXRULQH
functional polysiloxane can give rise to the formation of incompatible PRGLߔFDWLRQ FXULQJ FRQGLWLRQV DQG DGGLWLYH FRQFHQWUDWLRQ LQ WKH 18
products with a strong tendency for cratering. formulation must be evaluated carefully. 19
 Alkyd & PE OH-melamine
Alkyd & PE OH-functional
Solvent-based coatings

Acrylic self-crosslinking
Acrylic OH-functional

Acrylic thermoplastic
Active Ingredients %

Chlorinated rubber
Medium-oil alkyd

Short-oil alkyd
Long-oil alkyd
Acid curable
Product Name Chemical Type

DELTA SC® 2030 Silicone-based 52

DELTA SC® 2031 Silicone-based 52.5

DELTA SC® 2033 Silicone-based 15

DELTA SC® 2034 Silicone-based 52.5

DELTA SC® 2035 Silicone-based 52.5

Additives

DELTA SC® 2211 Silicone-based >98

DELTA SC® 2212 Silicone-based >98

Surface
Control

DELTA SC® 2230 Silicone-based >98

DELTA SC® 2231 Silicone-based >98

DELTA SC® 2239 Silicone-based >98

DELTA SC® 2284 Silicone-based >98

DELTA SC® 2580 Silicone-based >98

DELTA SC® 2777 Polyacrylate-based 70

DELTA SC® 2780 Polyacrylate-based 50

 Solvent-based epoxy

Solvent-free epoxy

Nitrocellulose

Unsaturated polyester

Silicon resin

Vinyl copolymer

Water-based coatings

Acrylic emulsion

Acrylic water reducible

Alkyd emulsion

Alkyd melamine

Alkyd water reducible

Epoxy

Polyester melamine

Polyurethane emulsion

2K water-based polyurethane

Printing inks

UV curable

3DFNDJLQJ JUDYXUH ߕH[R

Water-based

Composite

Gelcoats

Laminating

Lay-up & spray-up

21
20

SURFACE CONTROL ADDITIVES

03
Dispersion
Control Additives
When dispersing pigments, one frequently
HQFRXQWHUVSUREOHPVVXFKDVߕRFFXODWLRQ
LQVXIߔFLHQW FRORU RU WUDQVSDUHQF\ SRRU
rheological qualities or stability. With our
dispersion control additives, you can
HQVXUH\RXUSLJPHQWDQGߔOOHUSDUWLFOHVZLOO
keep apart for quite long and thus avoid
DQ\ UH ߕRFFXODWLRQ RU VHWWOLQJ WKDW PD\
occur in your liquid formulations.

Delta Specialties offer a comprehensive

UDQJHRIGLVSHUVLRQFRQWURODGGLWLYHV ORZ
DQGKLJKPROHFXODUZHLJKW IRUVROYHQWDQG
ZDWHUEDVHGV\VWHPVWRKHOS\RXRSWLPL]H
your dispersions in coatings, printing inks
and plastics (composite).
DISPERSION CONTROL ADDITIVES
22
23
Types of Dispersion
Control Additives
Delta Specialties manufactures 2 types
of dispersion control additives:

1 - Low molecular weight wetting and dispersing • This interaction is of great importance in this class of dispersion control
agents (DELTA DC® 4000 series) DGGLWLYHVVLQFHWKHUHODWLYHO\ORZPROHFXODUZHLJKWZLOOQRWJLYHVXIߔFLHQW
steric hindrance.
Properties: • ,QRUJDQLF SLJPHQWV DUH XVXDOO\ PHWDO R[LGHV ZKLFK FRQWDLQ SRVLWLYH
• JPRO0ROHFXODUZHLJKWJPRO PHWDO LRQV DQG QHJDWLYH R[LGH LRQV 7KHVH LRQV DUH JRRG DQFKRULQJ
• &DWHJRUL]HG DFFRUGLQJ WR WKHLU FKHPLFDO VWUXFWXUH DQG WKH QDWXUH RI WKHLU SRLQWVZKHUHWKHDQFKRULQJJURXSVWKDWEXLOGXSWKHSRODUKHDGRIWKH
hydrophilic groups (amphoteric, cationic … etc). dispersion control additive can attach to (polar interactions).
• 7KH LQWHUDFWLRQ RI WKHLU SRODU JURXSV ZLWK WKH SLJPHQW VXUIDFH DQG WKH • 8QIRUWXQDWHO\WKLVW\SHRIFKDUJHLQWHUDFWLRQLVQRWSRVVLEOHZLWKRUJDQLF
behavior of the non-polar chains in the medium determine their effectiveness. or black pigments.
• 2QO\XVHGIRUVWDELOL]LQJLQRUJDQLFSLJPHQWVDQGH[WHQGHUV
Mode of Action:
• 7KHSRODUKHDGVZLOOIRUPK\GURJHQERQGLQJLQWHUDFWLRQVEHWZHHQGLIIHUHQW DELTA DC® 4000 series
SLJPHQW XQLWV UHVXOWLQJ LQ D QHWZRUN WKDW HQKDQFHV WKH VHSDUDWLRQ RI WKH
SDUWLFOHV FRQWUROOHGߕRFFXODWLRQ  Anchoring group Non-polar tail
2 - High molecular weight wetting and dispersing • ,QRUJDQLF SLJPHQWV DUH XVXDOO\ WUHDWHG ZLWK GLIIHUHQW W\SHV RI SRODU
RUJDQLFFRPSRXQGVZKLFKHQDEOHWKLVLQWHUDFWLRQWRWDNHSODFHDVLWGRHV
agents (DELTA DC® 3000 series) by the organic pigments.
Properties:
• JPRO0ROHFXODUZHLJKWJPRO
• 7KH\ DUH EXLOW RI EUDQFKHG RU ORQJ OLQHDU PROHFXOHV ZKLFK LQ JHQHUDO
have a polyurethane or polyacrylate structure. DELTA DC® 3000 series
• 'HVLJQHGWRDGVRUEYLDVSHFLDOJURXSVZLWKKLJKDIߔQLW\WRZDUGVVSHFLߔF
sites on the pigment surface. These are called anchoring groups, and Anchoring Group Polymer Backbone
are built in at strategic points on the polymer backbone.
• Suited for inorganic and organic pigments, in addition to carbon black
pigments.
The compatibility of the dispersion control additive chain in various
Mode of Action: vehicles is determined by its chemical nature. Therefore different
• $QFKRULQJ JURXSV HQDEOH VWURQJ LQWHUDFWLRQ EHWZHHQ WKH GLVSHUVLRQ chemistries were developed by Delta Specialties, which are divided
control additive and the pigment surface. according to their chemical composition into two groups:
• 7KLVLQWHUDFWLRQLVPXFKVWURQJHUWKDQLQWKHFDVHRIWKHORZPROHFXODU • Polyurethane-based: 7KH\ KDYH D EUDQFKHG EDFNERQH ZLWK D 
ZHLJKW W\SHV DV WKH GLVSHUVLRQ FRQWURO DGGLWLYH LV ERXQG WR QXPHURXV GLPHQVLRQDO QHWZRUN VWUXFWXUH 2Q YDULRXV SODFHV RI WKLV QHWZRUN
VLWHVRQWKHVXUIDFHYLDWKHDQFKRULQJJURXSVDVVXULQJDQHIߔFLHQWVWHULF structure, different anchoring groups are introduced. They are compatible
KLQGUDQFHEHWZHHQWKHVROLGSDUWLFOHVE\NHHSLQJWKHPDSDUW ZLWKV\VWHPVIURPPHGLXPWRKLJKSRODULW\7KH\UHGXFHWKHYLVFRVLW\RI
the mill-base greatly and therefore promote the use of higher pigment
ORDGLQJ GXULQJ JULQGLQJ SLJPHQW FRQFHQWUDWH DSSOLFDWLRQV  +RZHYHU
since viscosity and tendency for settling may increase in the case of high
density pigments (inorganic pigments), it is essential to use a rheological
PRGLߔHU RU DQ DQWLVHWWOLQJ DJHQW QH[W WR WKH SRO\XUHWKDQHEDVHG
dispersion control additives.
• The remaining parts of the dispersion control additive act as a steric • Polyacrylate-based:7KH\KDYHOLQHDUVWUXFWXUHVZLWKDFDUERQFDUERQ
barrier to the surroundings by stretching into the liquid phase preventing EDFNERQHZKLFKEHDUVYDULRXVIXQFWLRQDOVLGHJURXSVDQGVKRUWFKDLQV
ߕRFFXODWLRQ 7KH\ EHDU JURXSV ZKLFK SDUWLFLSDWH LQ WKH DQFKRULQJ RI WKH SLJPHQW
• 7KHVHSDUWVKDYHDJRRGDIߔQLW\ZLWKWKHVROYHQWDQGWKHUHVLQV\VWHP Others play a role in the solvation of the acrylate in the liquid medium, or
VRWKHFRPSDWLELOLW\ZLWKWKHOLTXLGSKDVHLVLQFUHDVHGDQGWKHYLVFRVLW\ LQGXFHDVWHULFDOKLQGUDQFHWKDWWKZDUWVWKHUHDJJORPHUDWLRQDIWHUWKH
of the paint system is reduced as a desired side effect. adsorption of the polymer onto the pigment surface. They are compatible
• Organic pigments molecules consist mainly of the elements C, H, O and ZLWKV\VWHPVIURPQRQSRODUWRYHU\KLJKSRODUV\VWHPVDQGGRQRWUHGXFH
N. These atoms are not charged and are connected to each other WKH YLVFRVLW\ DV PXFK DV LQ WKH ߔUVW FODVV 7KLV DOORZV WKH
through covalent bonds. Despite the fact that the main interaction polyacrylate-based dispersion control additives to promote anti-settling
EHWZHHQWKHDQFKRULQJJURXSVDQGSLJPHQWVXUIDFHLVK\GURJHQERQGLQJ 24
EHKDYLRXUDVZHOO
this mechanism applies for both organic and inorganic pigments. 25
Choosing a Dispersion
Control Additive

7R DFKLHYH WKH EHVW GHߕRFFXODWLRQVWDELOLW\ HIIHFW RI SLJPHQW $GGLWLRQOHYHOVXVHGLQWKHFDVHRIORZPROHFXODUZHLJKWGLVSHUVLRQFRQWURO

dispersions, one must consider three main points: DGGLWLYHVDUHJHQHUDOO\ORZDQGWKXVFDQHDVLO\EHGHWHUPLQHG,QWKHFDVH
‫&ڞ‬RPSDWLELOLW\RIWKHGLVSHUVLRQFRQWURODGGLWLYHZLWKWKHYHKLFOH RI KLJK PROHFXODU ZHLJKW GLVSHUVLRQ FRQWURO DGGLWLYHV LW LV RI SULPH
• Quantity of the dispersion control additive in relation to pigment importance to use the right addition level in order to achieve an optimum
• Proper application procedure pigment dispersion.

A quick preliminary test can be carried out to ensure that no major errors )URPSDVWH[SHULHQFHDKDQG\FDOFXODWLRQPHWKRGKDVEHHQGHYHORSHG
are made in the initial choice of the dispersion control additive. The test is WKDWZLOOPLQLPL]HLQLWLDOWHVWLQJWULDOV
GRQHE\PL[LQJWKHGLVSHUVDQWZLWKWKHPDLQOHWGRZQYHKLFOHLQWKHUDWLR
7KHPL[WXUHVKRXOGEHFOHDU,WPLJKWEHQHFHVVDU\LQVRPHFDVHV )RU LQRUJDQLF SLJPHQWV WKH SHUFHQWDJH RI KLJK PROHFXODU ZHLJKW
WRVKDNHWKHPL[WXUHZLWKJODVVEHDGV E\ZHLJKW XVLQJDVKDNHUOLNH dispersant (as active material) used on pigment is usually 10% of the oil
6NDQGH[®IRUKRXU7KHPL[WXUHPXVWWKHQEHFOHDU7KHH[WUDPL[LQJLV absorption value*.
QHHGHGWRߔQGRXWZKHWKHUWKHGLVSHUVDQWLVGLIߔFXOWWRLQFRUSRUDWHRULV
completely incompatible. For carbon black pigments, the minimum percentage (as active material)
used on pigment is 20% of the DBP-value**.
7KLV WHVW KRZHYHU LV QRW LQGLFDWLYH RI WKH HIIHFWLYHQHVV RI WKH GLVSHUVLQJ
DJHQW,WFDQRQO\SUHGLFWSRVVLEOHGHߔFLHQFLHVLQGHߕRFFXODWLRQSHUIRUPDQFHV
ORVVRIJORVV DQGLQWKHFDVHRIPL[HGSLJPHQWVWKHULVNIRUߕRDWDWLRQ

(*)Oil Absorption (OA) value of a

SLJPHQWLVGHߔQHGDVWKHQXPEHU
of grams of linseed oil absorbed
by 100g of the pigment.

(**)DBP (Dibutylphtalate) -value

LVGHߔQHGDVEHLQJWKHYROXPHRI
Dibutylphtalate absorbed by
100g of carbon black pigment.
 DISPERSION CONTROL ADDITIVES
7KHUHTXLUHGSHUFHQWDJHIRURUJDQLFSLJPHQWVLVPRUHGLIߔFXOWWRGHWHUPLQH access to a list (sorted by pigment color) containing a large number of
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pigments, the percentage (as active material) used on pigment is 50% of the LQIRUPDWLRQ FRORULQGH[VXSSOLHUQDPH%(7YDOXHHWF 
BET-value. For phthalo-cyanine blue, phthalo-cyanine green, maroon and In case a pigment is not listed in, please contact your pigment supplier
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active material) used on pigment are 50% of the BET-value. dispersant dosage.

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GLVSHUVLRQFRQWURODGGLWLYHUHTXLUHGWRVWDELOL]HDFHUWDLQW\SHDQGTXDQWLW\ \RX ߔQG GLIߔFXOWLHV FROOHFWLQJ WKH WHFKQLFDO LQIRUPDWLRQ IURP \RXU
RISLJPHQWZLOOEHFRUUHFWLQPRVWFDVHV+RZHYHURUJDQLFSLJPHQWVPLJKW supplier. All you have to do is to send our Technical Service team a
UHTXLUHDPRXQWVRIGLVSHUVDQWVEH\RQGRUEHORZWKHFDOFXODWHGRQHV small sample of your pigment.

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SLJPHQWLVSUHWUHDWHG0DQ\SLJPHQWVDUHSUHWUHDWHGQRZDGD\VLQVXFK
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3OHDVH WDNH D ORRN DW RXU ZHEVLWH ZZZGHOWDVSHFLDOWLHVFRP (select

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being the surface area of a
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determined by N2 adsorption
method according to Brunauer,
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26
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 Alkyd & PE OH-melamine
Alkyd & PE OH-functional
Solvent-based coatings

Acrylic self-crosslinking
Acrylic OH-functional

Acrylic thermoplastic
Active Ingredients %

Chlorinated rubber
Medium-oil alkyd

Short-oil alkyd
Long-oil alkyd
High-Molecular Weight Wetting

Acid curable
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Product Name Chemical Type

Additives
DELTA DC® 3009 Polyurethane-based 60
Control

DELTA DC® 3011 Polyurethane-based 60

& Dispersing Agents

Anionic
DELTA DC® 3013 Polyester-based >98

DELTA DC® 3046 Polyurethane-based 40

DELTA DC® 3047 Polyurethane-based 35

DELTA DC® 3591 Polyester-based 40

Ammonium
DELTA DC® 3740 Polyacrylate 43

DELTA DC® 3750 Sodium Polyacrylate 43

DELTA DC® 3080 Polyester Polymer 52

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$FU\OLFZDWHUUHGXFLEOH

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Printing inks

UV curable

3DFNDJLQJ JUDYXUH ߕH[R

Water-based

Composite

Gelcoats

Laminating

Lay-up & spray-up

29
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DISPERSION CONTROL ADDITIVES

Low-Molecular Weight Wetting
& Dispersing Agents

Dispersion
Control
Additives

DELTA DC® 4066

Product Name

DELTA DC® 4211

DELTA DC® 4296

DELTA DC® 4244
DELTA DC® 4274
DELTA DC® 4242
DELTA DC® 4208
DELTA DC® 4207
DELTA DC® 4075
DELTA DC® 4073
DELTA DC® 4071
DELTA DC® 4065
DELTA DC® 4054
DELTA DC® 4044
DELTA DC® 4007
DELTA DC® 4001

DELTA DC® 4010 M

90
50
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52
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70
30

Active Ingredients %

>98
>98
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Acrylic self-crosslinking

Acrylic thermoplastic

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Medium-oil alkyd

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31
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DISPERSION CONTROL ADDITIVES

04
Specialty
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This range represents specialty additives
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technical features.
SPECIALTY ADDITIVES
32
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Multi-Purpose Additives
DELTA S® 5220 & DELTA S® 5225
In addition, the ‘unsaturation’ provides drying properties by cross-linking
DELTA S® 5220 and DELTA S® 5225 are LQWKHSUHVHQFHRIR[\JHQ
multi-functional additives, both can be used as: The anchoring groups used in DELTA S® 5225 are similar to those of our
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DELTA S® 5225 can be used as sole dispersion control additive for the
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manufacturing of universal colorants.
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prepared by using one single dispersion control additive.
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preparation of slurries and matting agent dispersions. Colour Acceptance Improvement
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Both DELTA S® 5225 and DELTA S® 5220 are 100% active, APE-free EDVHGSDLQWV ZKHQXVLQJERWKDELTA S® 5225 or DELTA S® 5220 as post-
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having polar tertiary amines heads. used for the formulation of universal colorants.

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 SPECIALTY ADDITIVES
Universal Colorants for Architectural Paints
Production of colorants is essential for tinting of the architectural paints. Due to many construction projects in the pipeline and the unusual and fast
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steady increase in the coming years.
With DELTA S®  \RX FDQ IURP QRZ RQZDUG IRUPXODWH \RXU 
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Making universal colorants has never been so easy! IULHQGO\ FRORUDQWV ZLWK QR $3( UDZ PDWHULDOV DQG ORZHUHG RU QR
VOC content.
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‫&ڞ‬RPSO\ZLWKWKHFXUUHQWDQGDQWLFLSDWHGUHTXLUHPHQWVLQWHUPVRI$3(V solvent-based) from different manufacturers in the Middle East. Their
$U\OSKHQ\OHWKR[\ODWHV DQGHQYLURQPHQWDODVSHFWV compatibility and stability over time are just stunning.

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PG 36 3%.3< 3< PR 168 PB 15:4

PC 23 Violet /PR 101 Orange 3< PR 112 Red
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Amber <HOORZ

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PY 74 PB 15:3 PR 112 PG 7 PR 101 PY 42 PW 6 PBK 7 Please note that the above formulations
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Monoethyleneglycol 18.0 16.0 11.0 16.0 15.3 18.0 15.5 18.0 SLJPHQWV ZLWK GHWHUPLQHG 2$ %(7‫ڏ‬
and DBP- value (Please refer to
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,Q FDVH \RX XVH SLJPHQWV ZLWK GLIIHUHQW
1D2+ LQZDWHU 1.0 1.5 2.6 1.5 1.0 1.1 1.1 1.1 properties, it is obvious that your
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Should you require tailored colorant
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Preservative 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2
more than pleased to assist.
Pigment 40.0 39.0 30.0 39.0 64.0 55.0 61.0 18.0
:H FDQ LQGHHG SURYLGH \RX ZLWK DOO WKH
7RWDOZHLJKW 100.0 100.0 100.0 100.0 99.9 100.0 100.0 100.0 VXSSRUW \RX QHHG WR GHYHORS \RXU RZQ
Pigment tinting system. 34
BET=17 BET=57 BET=30 BET=44 OA=26 OA=34 OA=16 DBP=93
characteristics 35
Multi-Functional
Additives

DELTA S® 5700LVDQDQWLJHODJHQWDQGYLVFRVLW\VWDELOL]HUIRUDLUGU\LQJ DELTA S® 97 provides pH control and stability. It can substitute ammonia
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RFFXUDVDUHVXOWRIR[LGDWLRQRUFRQGHQVDWLRQRIWKHELQGHU • ,W DOVR UHGXFHV WKH GRVH RI GLVSHUVDQW ZHWWLQJ DJHQW DQWLIRDP DQG
• ,WDOVRUHGXFHVWKHUHDFWLRQRIWKHSLJPHQWVZLWKWKHYHKLFOH FRDOHVFHQWDJHQWDQGSURYLGHVH[FHOOHQWZHWWLQJSURSHUWLHV
• It is usually added prior to grinding, but already gelled materials can be
restored to processing viscosity by the addition of DELTA S® 5700.

DELTA S® 5750 is a diol ester compound that function as a coalescing

DJHQWIRUGLIIHUHQWW\SHVRIODWH[HVLQZDWHUEDVHGSDLQWVDELTA S® 5750
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improving adhesion on different substrates.

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pastes, prevents pigment caking and maintains the pigment pastes quality
upon storage.

DELTA S® 5845LVDKLJKPROHFXODUSRO\PHULFZHWWLQJDQGGLVSHUVLQJDJHQW
particularly developed for dispersing organic and carbon black pigments in
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strength. DELTA S® 5845 is supplied as %50 active in phthalate-free
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 SPECIALTY ADDITIVES
Replacements for
Cobalt Drier
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025'5<410DQG025'5<420DUHKLJKO\HIߔFLHQWUHSODFHPHQWVIRU • The improvement of alkali resistance.
FREDOWGULHULQXUHWKDQHPRGLߔHGDON\GVDQGDON\GV ‫ڞ‬7KHLQFUHDVHLQ\HOORZLQJUHVLVWDQFHRIDLUGU\LQJDON\GߔQLVKHV
7KH\ FDQ EH HIߔFLHQWO\ DSSOLHG LQ FOHDU DQG EULJKWO\ SLJPHQWHG especially those subjected to prolonged heat or alkaline fumes.
XUHWKDQHPRGLߔHGDON\GVDQGLQFRQYHQWLRQDODON\GVZKLFKWHQGWR • The prevention of ‘loss of dry’ on aging.
discolor. ‫ڞ‬7KHUHODWLYHORZHUOHYHORIWR[LFLW\FRPSDUHGWRFREDOW

As compared to cobalt octoate, these cobalt replacements can offer To highlight the performance of one of these special driers,
superior properties such as: MORDRY®410ZDVWHVWHGLQ2GLIIHUHQWXUHWKDQHPRGLߔHGDON\GV VHH
• 7KH PLQLPL]DWLRQ RI GLVFRORUDWLRQ RI FOHDU XUHWKDQHPRGLILHG WDEOH EHORZ  LQ FRPSDULVRQ WR FREDOW RFWRDWH FRQVLGHUHG WR EH WKH
alkyds in can. benchmark.

Internal reference: Formulation 6/ 2009 Formulation 1 Formulation 2 Formulation 3 Formulation 4

Uralac AR 202 W50 (DSM) SEZ SEZ -- --

U-alkyd 20621 (60%) (Local) -- -- SEZ SEZ

White Spirit SEZ SEZ SEZ SEZ

MORDRY® 410 SEZ -- SEZ --

MORDRY® Cobalt 10% -- SEZ -- SEZ

MORDRY® Calcium 10% SEZ SEZ SEZ SEZ

MORDRY® Zirconium 18% SEZ SEZ SEZ SEZ

Color/Gardner 4-5 13 - 14 4-5 14

36
Drying time @25 C (min) 140 min 130 min 150 min 145 min
37
05
Driers
& Catalysts
The chemical hardening of unsaturated
liquid binders by means of the reaction
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“drying”.

Metal-organic compounds (metal soaps

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concentrations to control drying processes.
Such additives are described as driers .

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molecular (homophase) catalysts for free
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chain process developing in the presence
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DRIERS & CATALYSTS
38
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 DRIERS & CATALYSTS
Product List
Delta Specialties can offer a broad range of driers to
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For solvent-based For water-reducible

systems, systems,
Single Metal Driers MORDRY® Barium 10 WD
MORDRY® Calcium 4 WD
MORDRY® Barium 12.5 MORDRY® Cobalt 6 WD
MORDRY®Calcium 4 MORDRY® Manganese 6 WD
MORDRY® Calcium 5 MORDRY® Zirconium 12 WD
MORDRY® Calcium 10
MORDRY® Cerium 10
MORDRY® Cobalt 6 Catalysts
MORDRY® Cobalt 10 MORCURE® 6P
MORDRY® Cobalt 12 MORCURE® 8P
MORDRY® Copper 8 MORCURE® 6P HV
MORDRY® Lead 24 MORCURE 730
MORDRY® Lead 32 MORCURE 140
MORDRY® Lead 36 MORCURE 145
MORDRY® Lithium 2
MORDRY® Manganese 10
MORDRY® Potassium 10
MORDRY® Strontium 10
MORDRY® Zinc 12
MORDRY® Zinc 18
MORDRY® Zirconium 12
MORDRY® Zirconium 18
MORDRY® Zirconium 24

Mixed Driers
MORDRY® 210
MORDRY® 320
MORDRY® 390
40
Additives for Coatings, Printing Inks,
Adhesives and Composites
Egypt:
Building 22A, 10th District,
6th of October City.
Tel.: +20 2 36862607
[email protected]

North America:
1128 Woodington Lane Oakville, ON, L6H 7T9,
Canada
Tel: +1 289 400 4572
[email protected]

$VLD3DFLߔF
259/383 Soi pridee Panomyong 15,
<DHN6XNKXPZLW3KUD.DQRQJ1XD
Vattana Bangkok 10110 Thailand
Tel: +66 0 831 335 030
[email protected]

India:
Plot No.C 343, Indira Nagar, 2nd Floor,
TTC Industrial Area,
3DZDQH1DYL0XPEDL0+
Maharashtra, India
Tel.: +91 771 589 8361
[email protected]

Turkey:
,NLWHOOL26%0DKSHIDNR\6DQD\L6LWHVL
%ORN1R, %DVDNVHKLU / Istanbul, Turkey
Tel : 
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0($,1',$785.(<&$1$'$
www.delta-specialties.com