Naturally Innovative
Innovative Polyols and waterbased Dispersions
for Floor Coatings
Jessica Hoffmann
November 2017
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The ALBERDINGK® Package
ALBODUR® Polyurethane- und
Castor Oil
Polyols Acrylate-Dispersions
© Alberdingk Boley GmbH November 2017 | Chart 2
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Layer build-up of floor coats
Topcoat
Polish
Substrate Selflevelling
floor coating
Balancing coat
Primer
© Alberdingk Boley GmbH November 2017 | Chart 3
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Layer build-up of floor coats – Primer
Purpose Details
Pore-wetting Layer: 0.2-0.3 mm ~0,4g/m2 (depends on substrate)
Glueing dust to the substrate Hydrosol-Technology: H 595, H 735
Adhesion primer Selfcrosslinking: AC 2403, AC 2514, AC 2714
Wet-look: AC 3660
Membrane: AS 2040
Polish Topcoat
Selflevelling
floor coating
Substrate
Balancing coat
Primer
© Alberdingk Boley GmbH November 2017 | Chart 4
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Layer build-up of floor coats – Balancing coat
Purpose Details
Pore-wetting Layer: 1-6 mm ~1mm: 0.8 - 1,6kg/m2
Levelling / balancing effect ALBODUR® 912
Compatible with cement: AS 6800
Polish Topcoat
Selflevelling
floor coating
Substrate
Balancing coat
Primer
© Alberdingk Boley GmbH November 2017 | Chart 5
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Layer build-up of floor coats – Selflevelling floor coating
Purpose Details
Mechanical & chemical resistance Layer: 1-3 mm (1mm : ~1,5 kg/m2)
Appearance All ALBODUR® Grades
Conductibility (Antistatic)
Anti-slip properties
Polish Topcoat
Selflevelling
floor coating
Substrate
Balancing coat
Primer
© Alberdingk Boley GmbH November 2017 | Chart 6
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Layer build-up of floor coats – Topcoat
Purpose Details
Abrieb- und Kratzbeständigkeit Layer: 0,06 – 0,1 mm (0,1 - 0,6kg/m2)
UV-stability UC 8400 (hot tire resistance)
Final appearance AC 2592 + Capa 3031
Anti-slip properties U 9000, AC 3699
Matt: AC 27401, AC 3660/AC 3600, PUR-MATT 970
UV: LUX 220, LUX 265
Polish Topcoat
Selflevelling
floor coating
Substrate
Balancing coat
Primer
© Alberdingk Boley GmbH November 2017 | Chart 7
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Layer build-up of floor coats – Polish
Purpose Details
Surface sealing Layer: 0,06 – 0,1 mm
Protection of the topcoat Alkali-soluble: AC 2570, AC 3640
Permanent: UC 90, AFU 850
Polish Topcoat
Selflevelling
floor coating
Substrate
Balancing coat
Primer
© Alberdingk Boley GmbH November 2017 | Chart 8
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Concrete-Impregnation: Comparison of waterbased Dispersions
48h Water
Topcoat: PUR-MATT 970 PUR-MATT 970
Topcoat: AC 3699 AC 3699
Primer: H 735 AC 2403 H 735 AC 2403
© Alberdingk Boley GmbH November 2017 | Chart 9
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Applications of the ALBODUR® portfolio
Coatings
(MDI-based)
Adhesives Coatings
(2 component) (HDI-based)
ALBODUR®
Technology
Adhesives
Elastomers
(1 component)
Corrosion-protection
© Alberdingk Boley GmbH November 2017 | Chart 10
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ALBODUR® Properties
• Branched Polyether/Polyester-Polyols
• Castor Oil based Renewable ressources
• Adjustable hardness (soft to hard)
• Low viscous, hydrophobic
• Crosslinkable with aliphatic and aromatic Polyisocyanates
• No VOC absolutely solvent-free
• Economic
© Alberdingk Boley GmbH November 2017 | Chart 11
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ALBODUR® Product family for aromatic Isocyanates
Soft Medium hard to hard
Medium hard industrial flooring,
ALBODUR® 901 Sports flooring
2-component adhesives, primers for
ALBODUR® 912
difficult substrates (contaminated),
easy to formulate
Sports flooring, crack-bridging,
ALBODUR® 903 Hard industrial flooring & parking
membranes, 2-component adhesives
ALBODUR® 921 decks, very good pigment wetting
properties, easy to formulate
Very hard expoxy-like coatings, 2-
Crack-bridging membranes, highly ALBODUR® 941
component adhesives, elastomers
ALBODUR® 904 elastic @low temperatures, industrial
roof-coating ALBODUR®941 with longer application
ALBODUR® 942
time
© Alberdingk Boley GmbH November 2017 | Chart 12
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ALBODUR® Product family
Soft, MDI-crosslinking ALBODUR® 90X
OH-value Viscosity Mechanical Chemical
Product
[mg KOH/g] [mPas] properties resistances
soft
ALBODUR® 901 185 600
Tg ~-5°C
soft
ALBODUR® 903 160 600
g ~-15°C
soft
ALBODUR® 904 214 700
Tg ~-30°C
© Alberdingk Boley GmbH November 2017 | Chart 13
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MDI-based system: Indoor sports flooring
Selflevelling coating
ALBODUR® 901 / Suprasec 2330
Sealer Pore-wetting Adhesive
AC 27401 + AC 2592 / ALBODUR® 901 + Sylothix 51/ ALBODUR® 901 +
Easaqua M 501 Suprasec 2330 if necessary Sylothix 51 / S‘sec 2330
Stripes / Lines Rubber mat
Primer
ALBODUR® 912 /
Suprasec 9584
Substrate
© Alberdingk Boley GmbH November 2017 | Chart 14
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ALBODUR® Product family
Medium hard to hard, MDI crosslinking
OH-value Viscosity Mechanical Chemical
Product
[mg KOH/g] [mPas] properties resistances
ALBODUR® 912 208 600 medium hard
hard
ALBODUR® 921 218 600
Tg ~+60°C
ALBODUR® 941 very hard
318 500
/ 942 Tg ~+85°C
© Alberdingk Boley GmbH November 2017 | Chart 15
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MDI-based system: Industrial flooring
„Wear coat“
ALBODUR® 912 / Suprasec 2496
Levelling layer
Sealer ALBODUR® 912 + 0,7-1,2 mm Sand /
Suprasec 2496
AC 27401 / Easaqua M 501
Primer
ALBODUR® 912 /
Suprasec 9584
Substrate
© Alberdingk Boley GmbH November 2017 | Chart 16
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“Floor Art - European Coatings Show 2017”: Booth-floor, VOC-free
Primer based on ALBODUR® 912 Wear coat based on ALBODUR® 921
Standard floor preparation: Board size 3 m²
© Alberdingk Boley GmbH November 2017 | Chart 17
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Special effect “Green marble”
© Alberdingk Boley GmbH November 2017 | Chart 18
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Pot-life comparison 45°C (OH-group loss)
Albodur X 115 TM 105345 O
Topfzeit: 1016 s Topfzeit: 1573 s
Shore A: 92 Shore A: 92
ALBODUR® X-115 TM 105345 O
Albodur X115- 3mm Foil application
Time in sec.
© Alberdingk Boley GmbH November 2017 | Chart 19
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Moisture sensitivity
ALBODUR® X-115 - 3mm Layer TM 105345 O - 3mm Layer
© Alberdingk Boley GmbH November 2017 | Chart 20
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Comparison of aliphatic and aromatic hardeners - 24h QUV B
ALBODUR® 965 ALBODUR® 965 ALBODUR® 955 ALBODUR® 912
Before QUV Tolonate HDLV2 Des. XP 2838 Supr. 2029
O OH
C (CH2)7 CH CH CH2 CH (CH2)5 CH3
O
H2C O OH
HC O C (CH2)7 CH CH CH2 CH (CH2)5 CH3 Castor Oil
O OH
H2C
O
C (CH2)7 CH CH CH2 CH (CH2)5 CH3
© Alberdingk Boley GmbH November 2017 | Chart 21
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Aliphatic Polyols comparison
Viscosity
Chemical backbone OH-value [%]
[mPa.s]
Aliphatic Polyols
ALBODUR® 955 Branched PES 8.79 1600
ALBODUR® 956 Branched PES 9.24 2300
ALBODUR® 965 Branched PES 8.82 1100
Standard Polyols
Polyol 050/049 Branched PES/ PE 10.90 3000
© Alberdingk Boley GmbH November 2017 | Chart 22
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ALBODUR® Portfolio for HDI-crosslinking
OH-value Viscosity Mechanical Chemical
Product
[mg KOH/g] [mPas] properties resistances
ALBODUR® 941/942 318 500 very soft
medium hard,
ALBODUR® 955 290 1600 very good impact
resistance
very hard,
ALBODUR® 956 305 2300 very good impact
resistance
soft,
ALBODUR® 965 291 1100 very good impact
resistance
© Alberdingk Boley GmbH November 2017 | Chart 23
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Water absorption of the ALBODUR® Polyols (23°C & 85% rel. air humidity)
8 ALBODUR® 955
ALBODUR® 956
7
ALBODUR® 965
Water absorption [%]
6 Polyol 050/Polyol 049
0
0 Tage 7 Tage 14 Tage 21 Tage
© Alberdingk Boley GmbH November 2017 | Chart 24
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Chemical resistances of aliphatic Polyols (e.g. ALBODUR® 956)
0
Skydrol Essigsäure Ethanol Kaffee Rotwein Senf
(10 Tage) (25%, 3 Tage) (48%, 1 Std.) (4%, 1 Tag) (1 Tag) (1 Tag)
© Alberdingk Boley GmbH November 2017 | Chart 25
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Mechanical properties
Test Result
Taber abrasion, CS 17 (10N, 1000 cycles) approx. 13 mg
Tensile strength approx. 10,2 MPa
Elongation @ break approx. 117 %
Shore A approx. 91
Shore D approx. 45
Gloss (20° / 60° / 85°) approx. 80 / 88 / 105
© Alberdingk Boley GmbH November 2017 | Chart 26
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Compatibility with hardeners
NCO- ALBODUR® ALBODUR® ALBODUR®
Isocyanate Chemical backbone
content (%) 965 955 956
Tolonate HDT 22 HDI-Trimer X X X
Tolonate HDLV2 22 HDI-Trimer X O O
Desmodur N 3200 23 Biuret X O O
Desmodur N 3900 23,5 HDI-Trimer X O O
Desmodur 3400 21,6 Uretdione x x x
Desmodur XP 2838 21 HDI/IPDI/Dimer/ Trimer X X X
Desmodur XP 2840 23 Uretdione / Trimer X X X
X= compatible
O= limited compatibility
Evaluation: reaction-foam, turbidity, fish-eyes
© Alberdingk Boley GmbH November 2017 | Chart 27
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HDI-based system: Balcony refurbishment
Sealer Primer
AC 27401 + AC 2592 / ALBODUR® 912 /
Easaqua M 501 Suprasec 9584
Wear coat
ALBODUR® 965 /
Tolonate HDT LV
PVC - Chips
Adhesion promoter
Tiles
Substrate
© Alberdingk Boley GmbH November 2017 | Chart 28
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First results: enhanced weathering of the new aliphatic products
(after 432h QUV B)
ALBODUR® 955 TM 105554 O
© Alberdingk Boley GmbH November 2017 | Chart 29
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Product choice for sealants
Chemical Glossy or matt /
resistances Softfeel
• Regulatory • Optical
limitations appearance
• e.g. AgBB
Curing method Special
• selfcrosslinking, requirements
Product • 2-component • Hot tire resistance
• UV • Alcohol resistance
/ Peroxide
© Alberdingk Boley GmbH November 2017 | Chart 30
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Product choice for sealants
Industry Office Garage
• High chemical • Optically attractive • No professional
resistance application
• Resistance against
• Walking and forklift- coffee & detergents • Hot tire resistance
traffic
• Haptic impression, • Mainly 1-component
• Professional comfort products (single-
application pack)
• PUR-MATT 970
• AC 27401 • UC 8400
• AC 3699
• AC 3699 • AC 2714
© Alberdingk Boley GmbH November 2017 | Chart 31
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ALBERDINGK® OH-functional Acrylate Dispersion for industrial applications
Solids Viscosity pH-value MFFT OH-value
[%] [mPas] [°C] [%]
AC 3699 39-41 50–500 7.0–8.0 ~ 40 ~ 4.4
© Alberdingk Boley GmbH November 2017 | Chart 32
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ALBERDINGK® AC 3699 – clear coat FP 3699-01, with Easaqua L 600
Hardness development
180
160
Koenig Pendulum Hardness [s]
140
120
100
80
60
40
20
0
1 day 2 days 3 days 6 days 7 days
© Alberdingk Boley GmbH November 2017 | Chart 33
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Floor refurbishment with ALBERDINGK® PUR-MATT 970
© Alberdingk Boley GmbH November 2017 | Chart 34
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ALBERDINGK® PUR-MATT 970
Hard, aliphatic, inherent matt Polyurethanedispersion
Gloss: <5 @20° | <20 @60° | <50 @85°
Good sandability, also with sanding machines
Scratch- and chemical resistant (detergents)
Transperent on dark substrates
No solid sediment
As single binder or combination-partner
© Alberdingk Boley GmbH November 2017 | Chart 35
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Why is ALBERDINGK® PUR-MATT 970 inherently matt?
ALBERDINGK® PUR-MATT 970 VP: very big particle size: 4-6 µm!
© Alberdingk Boley GmbH November 2017 | Chart 36
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Comparison of inherent matt dispersion to standard matting agents
ALBERDINGK® PUR-MATT 970 VP: homogen surface-morphology leads to
high scratch resistance
1.5% pyrogenic silica
ALBERDINGK® PUR-MATT 970 VP in standard PUD
© Alberdingk Boley GmbH November 2017 | Chart 37
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FP 970/06 - Test results
Test Chemicals Duration Result (5 = best)
Ethanol (48%) 1h 3
NH4OH (10%) 1h 5
Water (deion.) 16 h 5
Coffee (4%) 16 h 4
Test feature Test conditions Result
Gloss(20° / 60° / 85°) 2 x 120µm wet layer thickness 0.7 / 3.1 / 1.7
CoF (Coefficient of Friction) EN 13893 0.46
Abrasion resistance [mg] Taber (CS-17) after 1000 cycles approx. 41
© Alberdingk Boley GmbH November 2017 | Chart 38
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ALBERDINGK® PUD with superior chemical resistance (hospitals etc.)
Solids pH-value Viscosity MFFT Organic
[%] [mPas] [°C] solvent
12%
200- N-Butyl-
U 9000 29-31 7.0-8.5
2000
~0
pyrro-
lidone
© Alberdingk Boley GmbH November 2017 | Chart 39
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ALBERDINGK® PUD with superior chemical resistance (hospitals etc.)
1. Sudan yellow 146 (1% in white spirit, 16 h)
2. Sudan blue 670 (1% in white spirit, 16 h)
3. Sudan red 500 (1% in white spirit, 16 h)
4. Neozapon red 335 (1% in ethanol, 16 h)
5. Basonyl blue 644 (1% in ethanol, 16 h)
6. Basacid yellow 093 fl. (1% in water, 16 h)
7. Basacid blue fl. 762 (1% in water, 16 h)
8. Basacid red 316 (1% in water, 16 h)
9. Tar (1 h)
10.Shoe polish (Kiwi Red, 2 h)
11.Iodine (1% in ethanol, 2 min)
12.Permanent marker 3000 rot & schwarz (1 min)
© Alberdingk Boley GmbH November 2017 | Chart 40
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Garage-flooring: comparison of hot tire resistance after 3 days @50°C
AC 2514 AC 2714 AC 3660 Commercial
product
Early water
resistance 3 3-4 4-5 2-3
(after 1h)
Abrasion
51 mg 60 mg 66 mg 80 mg
(CS 10, 1000 cycles)
Gloss
2 / 11 / 23 2 / 12 / 26 2 / 13 / 36 2 / 13 / 30
(20°, 60, 85°)
© Alberdingk Boley GmbH November 2017 | Chart 41
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Garage-flooring: Chemical resistances (EN 12720)
5,0
4,5
4,0
3,5
3,0
2,5
2,0
1,5
1,0
0,5
0,0
AC2514
AC 2514 AC2714
AC 2714 AC 3660
AC 3660 Schöner Wohnen
commercial Swing Color
prd. 1 commercial prd. 2
ethanol [1h] ammonia [1h] coffee [16h] red wine [16h]
motor oil [16h] brake fluid [16h] early water [1h]
© Alberdingk Boley GmbH November 2017 | Chart 42
Page 42 of 43
Naturally Innovative
Innovative Polyols and waterbased Dispersions
for Floor Coatings
Jessica Hoffmann
November 2017
Page 43 of 43
