Dr.

Ravishankara BE - 9886414024
JEE/CET/NEET

VVS INDEPENDENT PU SCIENCE COLLEGE,BELLARY

HYDROCABONS
1. Wurtz reaction on a mixture of ethyl halide and isobutyl halide gives
(1) Butane and isobutane (2) Butane and 2,5–dimethylhexane
(3) Butane, 2,5-dimethylhexane and isohexane (4) Butane and isohexane
2. Which of the following acids on decarboxylation gives isobutane
(1) 2,2–Dimethyl butanoic acid (2) 2,2–dimethyl propanoic acid
(3) 3–Methyl pentanoic acid (4) 2–Methyl butanoic acid
3. The volume of methane evolved by treatement of 16.6 g of methyl magnesium iodide with water at S.T.P. is
(1) 224 mL (2) 2.24 L (3) 0.224 L (4) 22.4 L
4. Give reactivity order for decarboxylation ?
CH3—CH2—COOH ; (I) CH2 CH—COOH ; (II) CH C—COOH (III)
(1) I > II > III (2) III > II > I (3) III > I > II (4) II > I > III
5. (A) CH3 CH COOH   Re d P /
 B
HI

OH
'B' looses its optical activity because of
(1) Chirality of the molecule destroyed (2) Symmetry of molecule is destroyed
(3) Spatial arrangement is changed (4) Racemic mixture is formed
(i ) Li
6. (CH3 ) 3C–Br    A  
CH CH CH Br
 B ; 'B' is
(ii ) CuI 3 2 2

(1) CH 3(CH 2 )2 C(CH 3 ) 3 (2) (CH3 )3 C–C (CH3 )3 (3) CH3 (CH2 )4 CH 3 (4) (CH3 )2 CH2 C(CH3 ) 3
7. Prolysis of alkanes is a
(1) Nucleophilic addition reaction (2) Free radical substitution reaction
(3) Electrophilic addition reaction (4) Free radical elimination reaction
8. The nitrating agent for the nitration of alkanes is:
(1) Conc. HNO3 (2) Mixture of conc. HNO3 and conc. H2SO4
(3) Acetyl nitrate (4) HNO3 vapours at high temperature
9. Bromination of an alkane as compared to chlorination proceeds
(1) At a slower rate (2) At a faster rate (3) With equal rates
(4) With equal or different rate depends upon the temperature
10. Which of the following alkyl halides gives a mixture of alkenes on dehydrohalogenation
(1) n–Propyl halide (2) Isopropyl halide (3) s–Butyl bromide (4) t–Butyl bromide
11. The products A and B in the reaction
CH3 CH2 CH CH3  
alc.KOH
   are given by the set
Br
(1) CH3—CH2—CH(OH)—CH3 and CH3—CH2—CH CH2
(2) CH3—CH CH—CH3 and CH3—CH2—CH2—CH2OH
(3) CH3—CH CH—CH3 and CH3—CH2—CH CH2
(4) CH3—CH2—CH2—CH2OH and CH3—CH2—CH CH2
12. The olefine, which on ozonolysis give CH3CH2CHO and CH3CHO is
(1) But-1-ene (2) But-2-ene (3) Pent-1-ene (4) Pent-2-ene
13. Which of the following compound on oxidative ozonolysis give malonic acid as only product)
(1) CH2 = CH – CH2 – CH = CH2 (2) CH2 = CH – CH = CH2

(3) (4)
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 Dr. Ravishankara BE - 9886414024
JEE/CET/NEET
14 In the following sequence of reactions, the product (D) is
HBr HBr alc KOH NaNH2
CH  CH   A   B   C  D
(1) Ethanol (2) Ethyne (3) Ethanal (4) Ethene
dil H2SO4
15. Ph – CH2 – CH = CH2  A , A is

Ph  CH2  CH CH3

(1) Ph—CH2—CH2—CH2—OH (2) |
OH

Ph  CH CH2  CH3

(3) | (4) Ph—CH2—OH
OH
16. The compound 1, 2-butadiene has
(1) only sp-hybridized carbon atoms (2) only sp2-hybridized carbon atoms
(3) both sp & sp2-hybridized carbon atoms (4) sp, sp2 and sp3 hybridized carbon atoms
17. The compound which has one isopropyl group is
(1) 2, 2, 3, 3 tetramethyl pentane (2) 2, 2 dimethyl pentane
(3) 2, 2, 3-trimetyl pentane (4) 2-methyl pentane
18. When cyclohexane is poured on water, it floats, because :
(1) cyclohexane is in boat form (2) cyclohexane is in chair form
(3) cyclohexane is in crown form (4) cyclohexane is less dense than water
19. Which of the following alkanes is not obtained by Wurtz reaction?
(1)Methane (2) Ethane (3)Propane (4) Butane
20. Which one of following has the smallest heat of hydrogenation per mole?
(1) 1-butene (2) trans-2-butene (3) cis-2-butene (4) ethene
21. C6H12(A) has chirality but on hydrogenation A is converted into C6H14(B) in which chirality disappears)
Hence A is
(1) 3-Methyl-1-pentene (2) 2-Methyl-2-pentene (3) 2, 3-dimethyl-2-buen (4) 3, 3-dimet hyl-1-
butene

22. The reagent(s) for the following conversion, Br ?

Br   H H is/are
(1) alcoholic KOH (2) alcoholic KOH followed by NaNH2
(3) aqueous KOH followed by NaNH2 (4) Zn/CH3OH
23. C C C C
L i/N H ( l)
  3  X , X is

(1) (2) (3) (4)

CH3
24. The major product formed by the acid catalysed hydration of is
OH
OH OH
OH

(1) CH 3 (2) CH3 (3) (4)

CH3
H3C

25. In the compound CH 2  CH  CH 2  CH 2  C  CH , the C2–C3 bond is of the type :

(1) sp–sp2 (2) sp3–sp3 (3) sp–sp3 (4) sp2–sp3
26. A gas decolourised KMnO 4 solution but gives no precipitate with ammoniacal cuprous chloride is or Which
of the following gases does not give a precipitate with ammoniacal solution of silver nitrate but decolourizes
KMnO 4 (neutral or slightly alkaline)
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 Dr. Ravishankara BE - 9886414024
JEE/CET/NEET
(1) Ethane (2) Methane (3) Ethene (4) Acetylene
27. Ozonolysis of 2-methyl butene-2 yields
(1) Only aldehyde (2) Only ketone (3) Both aldehyde and ketone (4) None of these
28. Presence of peroxides affects the addition of
(1) HBr (2) HCl (3) HI (4) All of these
29. Decolourization of alkaline KMnO 4 is used as a test for
(1) Aromatic hydrocarbons (2) Olefinic hydrocarbons
(3) Acetylenic hydrocarbons (4) Cycloalkanes
30. An alkene given two moles of HCHO, one mole of CO 2 and one mole of CH 3 COCHO on ozonolysis. What
is its structure
CH 3
(1) CH 2  C  CH  CH 2  CH 3 (2) |
CH 2  CH  CH  CH  CH 2

CH 2  C  C  CH 3 CH 3
| |
(3) (4) CH 2  C  C  CH  CH 2
CH 3
31. Which of the following alkenes gives only acetic acid and on oxidation with potassium permanganate solution
(1) Ethylene (2) 1-Butene (3) Propene (4) 2-Butene
32. Ethylene reacts with ozone to give
(1) Formaldehyde (2) Ethyl alcohol (3) Ozonide (4) Acetaldehyde
33. The shapes of methane, ethene and ethyne molecules are, respectively
(1) Tetrahedral, planar and linear (2) Tetrahedral, linear and planar
(3) Pyramidal, planar and linear (4) Tetrahedral, pyramidal and planar
34. Acetylene can be prepared from
(1) Potassium fumarate (2) Calcium carbide (3) Ethylene bromide (4) All of these
35. Acetylene is obtained by the electrolysis of
(1) Sodium succinate (2) Potassium fumarate (3) Both (1) and (2) (4) None of these
36. The compound C 3 H 4 has a triple bond, which is indicated by its reaction with
(1) Bromine water (2) Bayer’s reagent (3) Fehling solution (4) Ammonical silver nitrate
37. Acetylene gives
(1) White precipitate with AgNO 3 and red precipitate with Cu 2 Cl 2
(2) White precipitate with Cu2 Cl2 and red precipitate with AgNO3
(3) White precipitate with both the reagents
(4) Red precipitate with both the reagents
38. The C - H bond length is minimum in the bond formed by
(1) sp - s overlapping (as in alkynes) (2) sp 2  s overlapping (as in alkenes)
(3) sp 3  s overlapping (as in alkanes) (4) None of these
39. KMnO 4 will oxidise acetylene to
(1) Ethylene glycol (2) Ethyl alcohol (3) Oxalic acid (4) Acetic acid
40. Ethylidine dichloride can be prepared by the reaction of HCl and
(1) C 2 H 4 (2) C 2 H 2 (3) C 2 H 5 (4) All of these
41. What is the product when acetylene reacts with hypochlorous acid
(1) CH 3 COCl (2) ClCH 2 CHO (3) Cl 2 CHCHO (4) ClCHCOOH
42. Benzene cannot undergo
(1) Substitution (2) Addition (3) Elimination (4) Oxidation
43. Attacking or reactive or electrophilic species in nitration of benzene is or In the nitration of benzene with
concentrated HNO 3 and H 2 SO 4 the attack on ring is made by
(1) NO 2 (2) NO 2 (3) NO 3 (4) NO 2
44. Most common reactions of benzene (aromatic hydrocarbon) and its derivatives are
(1) Electrophilic addition reactions (2) Electrophilic substitution reactions

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 Dr. Ravishankara BE - 9886414024
JEE/CET/NEET
(3) Nucleophilic addition reactions (4) Nucleophilic substitution reactions
45. Which of the following will be obtained by the bromination ‘of ethylbenzene in the presence of light?

46. 2.84 g of methyl iodide was completly converted into methyl magnesium iodide and the product was
decomposed by excess of ethanol. The volume of the gaseous hydrocarbon produced at NTP will be
1) 22.4 ltr 2) 22400 ltr 3) 0.448 ltr 4) 0.224 ltr
47. The.addition of HBr to an alkene in the presence of peroxide is the example of
1) electrophilie addition reaction 2) nucleophilic addition reaction
3) free radical addition reaction 4) the formation of carbocation as an-intermediate
48. What are the products obtained upon the ozonolysis of pent-2-ene ?
1)CH3CH2CHO 2) CH3CHO 3) CH3COCH3 4) Both 1 and 2
49. The direct iodination of benzene is not possible because
1) Iodine is an oxidising agent 2) resulting C6H5I is reduced to C6H6 by HI
3) HI is unstable 4) the ring gets activated
50. The electrophile attacks the benzene ring to generate the intermediate a-complex.Of the following, which a-
complex is of lowest energy ?

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