SUBJECT : CHEMISTRY

1. What is maximum number of emission lines 7. The ratio between kinetic energy and the total
when the excited electron of a H atom in n = 6 energy of the electrons of hydrogen atom
drops to the ground state ? according to Bohr's model is :-
(1) 13 (2) 14 (3) 15 (4) 6 (1) 2 : 1 (2) 1 : 1 (3) 1 : – 1 (4) 1 : 2
2. In the Bohr's orbit, what is the ratio of the total 8. The electrons, identified by n & ℓ ;
kinetic energy and the total energy of the (i) n = 4 , ℓ = 1
electron ? (ii) n = 4 , ℓ = 0
(1) – 1 (2) – 2 (3) +1 (4) +2 (iii) n = 3 , ℓ = 2
(iv) n = 3 , ℓ = 1
3. The uncertainty involved in the measurement of
can be placed in order of increasing energy, from
velocity within in a distance of 0.1 Å is -
the lowest to highest as:
(1) 5.79 × 108 ms – 1 (2) 5.79 × 105 ms – 1
(1) (iv) < (ii) < (iii) < (i)
(3) 5.79 × 106 ms – 1 (4) 5.79 × 107 ms – 1
(2) (iii) < (ii) < (iv) < (i)
4. The energy of second Bohr orbit of the
(3) (i) < (iii) < (ii) < (iv)
hydrogen atom is – 328 kJ mol – 1. The energy of
fourth Bohr orbit would be (4) (iii) < (i) < (iv) < (ii)
(1) – 41 kJ mol – 1 (2) – 82 kJ mol – 1 9. The maximum number of electrons in an atom
with quantum number n =3, l=2 is
(3) – 164 kJ mol – 1 (4) – 1312 kJ mol – 1
(1) 2 (2) 6 (3) 10 (4) 30
5. If in X+2 has number of electron is 14 and mass
number is 32, what is symbol of element X ? 10. A 0.66 kg ball is moving with a speed of 100
32 31 m/s. The associated wavelength will be (h = 6.6
(1) 16S (2) 15P (3) 7N14 (4) 8O16
× 10 – 34 Js) :-
6. Which of the following electron transitions in a
(1) 6.6 × 10 – 34 m (2) 1.0 × 10 – 35 m
hydrogen atom will require the largest amount
of energy? (3) 1.0 × 10 – 32 m (4) 6.6 × 10 – 32 m
(1) From n = 1 to n = 2 11. A 0.66 kg ball is moving with a speed of 100
m/s. The associated wavelength will be
(2) From n = 2 to n = 3
(h = 6.6 × 10 – 34 Js) :-
(3) From n = 3 to n = 5
(1) 6.6 × 10 – 34 m (2) 1.0 × 10 – 35 m
(4) From n = ∞ to n = 2
(3) 1.0 × 10 – 32 m (4) 6.6 × 10 – 32 m
12. The ion that is isoelectronic with CO is :-
(1) CN – (2) O2+ (3) O2 – (4) N2+

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13. In a hypothetical condition assuming 3 electrons 18. Magnetic quantum number specifies
can be accomodated in an orbital & all the (1) Size of orbitals
remaining rules for configuration applicable, the
magnetic moment of Mn+x is 6.87 BM. What is (2) Shape of orbital
the value of x and azimuthal quantum number of (3) Nuclear stability
last electron. Assuming out of 3 electrons in an (4) Orientation of orbitals
orbital 1 remains unpaired :-
19. The energy of an electron of 2py orbital is
(1) Zero, 2 (2) 3, 0 (3) 1, 1 (4) 3, 2
(1) greater than 2px orbital
14. Find out orbital angular momentum for 2s sub-
shell > (2) Less than 2pz orbital
(2) 2h (3) h (4) 2h (3) same as that of 2px and 2pz orbital
(1) zero
π π 3π
(4) Equal to 2s orbital
15. Ionization energy of gaseous Na atoms is 495.5
kJmol – 1. The lowest possible frequency of light 20. The number of d-electrons in Fe2+ (Z = 26) is not
that ionizes a sodium atom is equal to the number of electrons in which one of
(h = 6.623 × 10 – 34 Js, NA = 6.022 × 1023 mol – 1) the following?
(1) 3.15 × 1015 s – 1 (2) 4.76 × 1014 s – 1 (1) p-electrons in Cl (Z = 17)

(3) 1.24 × 1015 s – 1 (4) 8.50 × 104 s – 1 (2) d-electrons in Fe (Z = 26)

16. Total energy for an e – in an orbit of Hydrogen (3) p-electrons in Ne (Z = 10)

Z2 (4) s-electrons in Mg (Z = 12)
atom is given by En = ( −13.6 ) eV.
n2
Calculate the total energy of the orbit having a 21. In H-atom, if ‘x’ is the radius of the first Bohr
radius 9r1 where r1 is the radius of first orbit ? orbit, de Broglie wavelength of an electron in
3rd orbit is :
(1) – 1.51 eV (2) – 10.2 eV
9x x
(1) 3 π X (2) 6 π X (3) (4)
(3) – 13.6 eV (4) 1.36 eV 2 2

17. Which of the following statements is not correct 22. Calculate the energy in joule corresponding to
light of wavelength 45 nm :
(1) Rydberg constant and wave number have (Planck’s constant h = 6.63 × 10 – 34 Js; speed of
same units light c = 3 × 108 ms – 1)
(2) Lyman series of hydrogen spectrum occurs (1) 6.67 × 1015 (2) 6.67 × 1011
in the U.V region
(3) 4.42 × 10 – 15 (4) 4.42 × 10 – 18
(3) The angular momentum of the eletron in
the ground state of hydrogen atom is equal
to h/2π
(4) The radius of the first Bohr orbit of
hydrogen atom is 2.116 × 10 – 8 cm

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23. An increasing order (lower first) for the values 29. If the radius of first Bohr orbit is x, then de
of e/m for electron (e), proton (p), neutron (n) Broglie wavelength of electron in 4th orbit is
and ( α ) particle is :- nearly
(1) e, p, n, α (2) n, α , p, e (1) 8 π x (2) 6 π x (3) 4 π x (4) 2 π x
(3) n, p, e, α (4) n, p, α , e 30. It ‘ λ 0’ is the threshold wavelength for
24. The orbital angular momentum of a P electron is photoelectric emission, ‘ λ ’ the wavelength of
given as :- light falling on the surface of a metal and ‘m’ is
the mass of the electron, then the velocity of
(1) √
3 h (2) √ 6
h
ejected electron is given by
2 π 2π
(1) 1/2
(3) h (4) h 2h
√3 [ (λ0 − λ)]
√ 2π 2π m
(2) 1/2
25. According to Bohr’s theory the energy required 2hc
[ (λ0 − λ)]
for an electron in the Li2+ ion to be emitted from m
n = 2 state is (given that the ground state (3) 2hc λ0 − λ
1/2
[ ( )]
ionization energy of hydrogen atom is 13.6 eV) m λ0 λ
(1) 61.2 eV (2) 13.6 eV (4) 1/2
2h 1 1
[ ( − )]
(3) 30.6 eV (4) 10.2 eV m λ0 λ
31. Which of the following set of quantum numbers
26. According to Bohr’s theory, the angular
belong to highest energy?
momentum of an electron in 5th orbit is
(1) n = 2, l = 1, m = 0, s = + 1
(1) 10 h/ π (2) 2.5 h/ π 2
(3) 25 h/ π (4) 1.0 h/ π (2) n = 3, l = 0, m = 0, s = + 1
2
27. The kinetic energy of the electron present in the (3) n = 4, l = 0, m = 1, s = + 1
ground state of Li2+ ion is represented by : 2
(4) n = 4, l = 1, m = 1, s = + 1
(1) 3e2 (2) 3e2
− 2
8π∈0 r 8π∈0 r
32. Which of the following statement is correct in
(3) 3e2 (4) 3e2
− relation to the hydrogen atom?
4π∈0 r 4π∈0 r
28. Out of X-rays, infrared rays, visible rays and (1) 3s – orbital is lower in energy than 3p –
microwaves, the largest frequency is of orbital.
(1) X-rays (2) IR rays (2) 3p – orbital is lower in energy than 3d –
(3) Visible (4) Microwaves orbital.
(3) 3s and 3p – orbitals are of lower energy than
3d – orbitals.
(4) 3s, 3p and 3d – orbitals all have same
energy.

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33. An electron is accelerated through V voltage. Its 37. An electron is in excited state in hydrogen atom.
de Broglie wavelength is The orbital, in which electron is present, is
(1) h (2) shown the curve. The value of quantum numbers
of electron in this exited state are
√
2m. eV
(3) (R : Radial wave function) [r : distance of
(4) all of these electron from atomic nucleus (keeping it at
origin)]
34. The ratio of radii of first orbits of H, He+ and
Li2+ is
(1) 1 : 2 : 3 (2) 6 : 3 : 2
(3) 1 : 4 : 9 (4) 9 : 4 : 1
35. Which of the following statements is incorrect
for anode rays ?
(1) n = 2, ℓ = 0, m = 0, s = +1/2 or – 1/2
(1) They are deflected by electric and magnetic
fields (2) n = 2, ℓ = 1, m = 0, s = +1/2 or – 1/2

(2) Their e/m ratio depends on the gas in the (3) n = 3, ℓ = 0, m = 0, s = +1/2 or – 1/2
discharge tube used to produce the anode (4) n = 3, ℓ = 1, m = 0, s = +1/2 or – 1/2
rays
38. Calculate the energy associated with photon of
(3) The e/m ratio of anode rays is constant o
light having a wavelength of 6000 A
(4) They are produced by the ionization of the
(1) 3.312 × 10 – 12 erg (2) 3.312 × 10 – 12 J
gas in the discharge tube
(3) 3.312 × 10 – 12 Cal (4) 3.312 × 10 – 12 kJ
36. A gas absorbs a photon of 300 nm and emits two
wavelengths. If one of the wavelengths of 39. The quantum number of four electrons are given
emission is of 750 nm, wave number to below -
associated with other wavelength is I. n = 4, l = 2, ml = – 2, ms = – ½
II. n = 3, l = 2, ml = 1, ms = + ½
(1) 2 × 106m – 1 (2) 200 × 106m – 1
III. n = 4, l = 1, ml = 0, ms = + ½
(3) 300 × 106m – 1 (4) None IV. n = 3, l = 1, ml = 1, ms = – ½
The correct order of their increasing energies
will be -
(1) IV < III < II < I (2) IV < II < III < I
(3) I < II < III < IV (4) I < III < II < IV

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40. Which of the following orbits is incorrect with 45. The circumference of the third orbit of He+ ion is
respect to de – Broglie concept of Bohr orbit. 'x' m. The de Broglie wavelength of electron
(1) revolving in this orbit will be
(2)
(1) x
m (2) 3x m
3
(3) x
m (4) 9x m
9

(3) (4) 46. Any f-orbital can accommodate upto

(1) 2 electrons with
(2) 6 electrons
parallel spin
(3) 2 electrons with
(4) 14 electrons
41. The maximum number of electrons in an atom opposite spin
with quantum number n = 3, ℓ = 2 is 47. How many orbitals upto n = 4 ?
(1) 2 (2) 6 (3) 10 (4) 30 (1) 8 (2) 30 (3) 16 (4) 4
42. If the kinetic energy of an electron is increased 4 48. If radius of second stationary orbit (in Bohr's
times, the wavelength of the de – Broglie wave atom) is R. Then radius of third orbit will be:
associated with it would become : (1) R/3 (2) 9R
(1) 4 times (2) 2 times
(3) R/9 (4) 2.25 R
(3) 1 (4) 1
2
times
4
times 49. Radius of 2nd shell of He+ (where a0 – Bohr
43. The ionization energy of hydrogen atom (in the radius)
ground state) is 'x' kJ. The energy required for (1) 3a0 (2) a0 (3) 3 (4) 2a0
a0
an electron to jump from 2nd orbit to the 3rd 2
orbit will be – 50. Cathode ray experiment which led to the
discovery of electrons was performed under
(1) x/6 (2) 5x conditions of:
(3) 7.2x (4) 5x/36 (1) High voltage, very low gas pressure
44. Which of the following is correct for second line (2) Low voltage, high gas pressure
of Balmer series :-
(3) High voltage, high gas pressure
(1) 4 → 2 (2) 2 → 4
(4) Low voltage, very low gas pressure
(3) 3 → 1 (4) 5 → 2

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